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利用石生苔藓氮含量与氮同位素探讨江西省大气氮沉降量和来源
摘要点击 2401  全文点击 2285  投稿时间:2010-05-11  修订日期:2010-07-28
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中文关键词  苔藓  氮含量  氮同位素  大气氮沉降  江西省
英文关键词  moss  nitrogen concentration  nitrogen isotope  atmospheric nitrogen deposition  Jiangxi Province
作者单位
谢志英 南昌大学环境与化学工程学院南昌330031 
肖化云 南昌大学环境与化学工程学院南昌330031中国科学院地球化学研究所环境地球化学国家重点实验室贵阳550002 
朱仁果 南昌大学环境与化学工程学院南昌330031 
吴代赦 南昌大学环境与化学工程学院南昌330031 
中文摘要
      2009~2010年在江西省“R>”型酸控区11个地区采集了107个石生细叶小羽藓样品. 通过分析苔藓氮含量和氮同位素组成,以反映大气氮沉降强度和空间分布特征,并甄别大气氮的主要来源. 结果表明,江西省不同地区苔藓平均氮含量变化范围为2.46%~3.48%. 整体上呈现赣西北偏高、赣东南偏低的特点,反映出江西省大气氮沉降水平由北向南逐渐递减的空间分布特征. 江西省城市市区苔藓氮含量(2.79%~3.48%)明显高于郊区氮含量(2.46%~2.74%),说明市区大气氮沉降量高于郊区氮沉降量. 苔藓平均氮同位素均为负值[(-1.96±1.30) ‰~(-9.74±0.25)‰],并且市区比郊区明显偏负. 市区苔藓偏负的氮同位素值(-5.51‰~-9.74‰)指示了城市污水和人畜排泄物为主要的氨源,而郊区氮同位素值(-4.81‰~-1.96‰)反映出农业活动氨源的贡献. 本研究为大气氮沉降的生态环境效应提供基础资料.
英文摘要
      Atmospheric N deposition and N sources in Jiangxi Province were investigated on the basis of the nitrogen concentrations and nitrogen isotope in epilithic mosses which collected from 11 cities of the province during 2009-2010. Mean nitrogen concentrations ranged from 2.46% to 3.48% and showed a significant regional difference. The highest was found in the northwestern of the province and the lowest in the southeastern, reflecting that the level of the atmospheric N deposition gradually decreased from the north to the south in the province. The higher N concentrations in urban mosses than in suburban mosses indicated that the urban areas received higher rates of nitrogen deposition than suburbs areas. Mosses 15N values varied from (-9.74±0.25)‰ to (-1.96±1.30)‰. More negative δ15N values of urban mosses (-5.51‰--9.74‰) indicated that more NH3was released from excretory wastes and sewage, while less negative δ15N values of suburban mosses(-4.81‰--1.96‰) suggested an important contribution from agricultural NH3emission due to entensive fertilizer application. This research provides basic information for further study on the ecological and environmental effects of atmospheric N deposition.

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