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连续流分段进水短程反硝化-厌氧氨氧化耦合工艺的反硝化脱氮特性
引用本文:张树军,黄剑明,马淑勍,王聪,田夏迪,李琨,赵丹,韩晓宇.连续流分段进水短程反硝化-厌氧氨氧化耦合工艺的反硝化脱氮特性[J].环境工程,2022,40(11):13-18.
作者姓名:张树军  黄剑明  马淑勍  王聪  田夏迪  李琨  赵丹  韩晓宇
作者单位:1. 北京市资源化工程技术研究中心, 北京 100124;
基金项目:北京市科技计划项目(Z181100005518003)
摘    要:采用连续流分段进水短程反硝化-厌氧氨氧化(partial denitrification-anaerobic ammonium oxidation,PD-Anammox)耦合反硝化工艺处理低C/N生活污水,研究了污染物去除、典型周期COD及氮素沿程变化特征、短程反硝化-厌氧氨氧化和反硝化对TN去除贡献。结果表明:在平均进水ρ(COD)、ρ(NH4+-N)、ρ(TN)为193.1,58.6,60.3 mg/L的条件下,系统出水平均ρ(COD)、ρ(NH4+-N)、ρ(TN)分别为46.3,1.5,13.4 mg/L,低于GB 18918—2002《城镇污水处理厂污染物排放标准》一级A标准。采用NO3--N预缺氧和进水点后置,可实现缺氧区NO3--N→NO2--N转化,同时完成厌氧氨氧化过程;缺氧区设置厌氧氨氧化悬浮填料,可提高系统TN去除率。通过缺氧区物料衡算,缺氧1区厌氧氨氧化对TN去除贡献率(ΔPD-Anammox/ΔTN)均值为54.37%,缺氧2区的ΔPD-Anammox/ΔTN均值为64.17%。

关 键 词:分段进水    连续流    短程反硝化-厌氧氨氧化    预缺氧    贡献率
收稿时间:2022-07-05

NITROGEN REMOVAL CHARACTERISTICS OF A STEP-FEED CONTINUOUS FLOW PARTIAL DENITRIFICATION-ANAEROBIC AMMONIUM OXIDATION COUPLED WITH DENITRIFICATION PROCESS
Affiliation:1. Beijing Engineering Research Center of Wastewater Resource, Beijing 100124, China;2. Beijing Drainage Group Co., Ltd, Beijing 100044, China;3. Beijing Drainage Technology Co., Ltd, Beijing 100044, China
Abstract:The low C/N domestic sewage was treated by a step-feed continuous flow partial denitrification-anaerobic ammonium oxidation (PD-Anammox) process coupled with denitrification, the pollutants' removal characteristics, pollutants' concentrations in different stages of the system at a typical operation cycle, and total nitrogen(TN) removal contribute efficiencies of PD-anammox and denitrification were studied. The results showed that when the average influent concentrations of COD, NH4+-N, and TN were 193.1, 58.6 and 60.3 mg/L respectively, their effluent concentrations were 46.3, 1.5, and 13.4 mg/L respectively, complying with the first level A criteria specified in the Discharge Standard of Pollution for Municipal Wastewater Treatment Plants (GB 18918-2002). The nitrate transformed to nitrite in anoxic by nitrate pre-starvation and post-inlet to provide the anammox matrix of nitrite and ammonium. The TN efficiency got improved by setting anammox filler in the anoxic zones. The average PD-Anammox process's contribution rates to TN removal of anoxic zone Ⅰ and Ⅱ were 54.37% and 64.17% respectively, through mass balance calculation at the anoxic zones.
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