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罐底油泥特性分析及其除油处理工艺
引用本文:张雷,刘惠玲,王丽杰.罐底油泥特性分析及其除油处理工艺[J].化工环保,2012,32(4):334-338.
作者姓名:张雷  刘惠玲  王丽杰
作者单位:1. 哈尔滨工业大学市政环境工程学院,黑龙江哈尔滨150090;东北石油大学地球科学学院,黑龙江大庆163318
2. 哈尔滨工业大学市政环境工程学院,黑龙江哈尔滨,150090
3. 中国石油大庆炼化公司质量检验部,黑龙江大庆,163318
摘    要:通过研究罐底油泥的理化性质,开发了适于处理罐底油泥的系列工艺:先采用调质技术提高罐底油泥流动性;再采用超声破乳降低油泥稳定性,改善油泥分离性能;最后采用卧式离心机对油泥进行离心分离处理.在复合型清洗剂加入量为800 mg/L、超声温度为60℃、超声功率为12 kW、超声时间为25 min、离心温度为60℃、絮凝剂加入量为600 mg/L、离心机转速为2200 r/min的条件下,系统稳定运行9d,离心机出口泥中含油率低于2.00%,水中悬浮固体质量浓度低于170 mg/L,达到了对罐底油泥进行除油的目的.

关 键 词:罐底油泥  调质  超声破乳  离心分离  固体废物  废物处理

Characteristics of Tank Bottom Oily Sludge and Its Oil-removing Treatment Process
Zhang Lei , Liu Huiling , Wang Lijie.Characteristics of Tank Bottom Oily Sludge and Its Oil-removing Treatment Process[J].Environmental Protection of Chemical Industry,2012,32(4):334-338.
Authors:Zhang Lei  Liu Huiling  Wang Lijie
Affiliation:1.School of Municiple and Environmental Engeering,Harbin Institute of Technology,Harbin Heilongjiang 150090,China;2.School of Earth Sciences,Northeast Petroleum University,Daqing Heilongjiang 163318,China;3.Quality Inspection Department,Daqing Refining and Chemical Company,CNPC,Daqing Heilongjiang 163000,China)
Abstract:Based on the research of physical and chemical properties of tank bottom oily sludge,a series of processes for tank bottom oily sludge treatment were developed as follows:first,improving the fluidity of tank bottom oily sludge by conditioning technology;second,reducing the oily sludge stability and improving the sludge separation property by ultrasonic demulsification;Finally,separating oil and water from the oily sludge by horizontal centrifuge.Under the conditions of composite cleaning agent dosage 800 mg/L,ultrasonic temperature 60 ℃,ultrasonic power 12 kW,ultrasonic time 25 min,centrifugalization temperature 60 ℃,flocculant dosage 600 mg/L,rotational speed 2 200 r/min and running time 9 d,the oil content of the sludge of the centrifuge export is less than 2.00%,the SS in the outlet water is less than 170 mg/L,and the purpose of oil-removal of the tank bottom oily sludge is achieved.
Keywords:tank bottom oily sludge  conditioning  ultrasonic emulsion breaking  centrifugation  solid waste  waste treatment
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