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O_3-H_2O_2催化氧化技术深度处理石化含盐废水
引用本文:周栋,俞彬,耿翠玉.O_3-H_2O_2催化氧化技术深度处理石化含盐废水[J].化工环保,2018,38(2):202-206.
作者姓名:周栋  俞彬  耿翠玉
作者单位:博天环境集团股份有限公司,北京 100082
摘    要:采用O_3-H_2O_2-催化剂氧化体系对某石化企业含盐废水的二级生化出水进行处理,考察了不同反应体系下的反应时间、O_3流量、H_2O_2投加量对COD去除效果的影响。实验结果表明:O_3-H_2O_2-催化剂氧化体系对石化含盐废水的处理效果最好;在臭氧流量为40 m L/min、H_2O_2投加量为50 mg/L、催化剂投加量为300 g/L、反应时间为60 min的条件下,COD去除率为51.4%,出水COD为52.0 mg/L,达到GB31570—2015《石油炼制工业污染物排放标准》的要求。

关 键 词:催化氧化  含盐废水  O3  H2O2  催化剂  
收稿时间:2017-05-15

Treatment of salt-containing petrochemical wastewater by O3-H2O2 catalytic oxidation technology
Zhou Dong,Yu Bin,Geng Cuiyu.Treatment of salt-containing petrochemical wastewater by O3-H2O2 catalytic oxidation technology[J].Environmental Protection of Chemical Industry,2018,38(2):202-206.
Authors:Zhou Dong  Yu Bin  Geng Cuiyu
Affiliation:Poten Environment Group Co. Ltd.,Beijing 100082,China
Abstract:The bio-treatment effluent of salt-containing wastewater in a petrochemical plant was treated in a O3-H2O2- catalyst oxidation system. The effects of reaction time,O3 flow and H2O2 amount on COD removal were studied in different reaction systems. The experimental results showed that:The treatment effect of the O3-H2O2- catalyst oxidation system was the best;Under the conditions of O3 flow 40 mL/min,H2O2 amount 50 mg/L, catalyst amount 300 g/L and reaction time 60 min,the COD removal rate was 51.4%,the COD of the effluent was 52 mg/L,which met the national discharge standard of GB31570-2015.
Keywords:catalytic oxidation  salt-containing wastewater  O3  H2O2  catalyst  
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