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剩余污泥胞外聚合物回收:藻酸钠正渗透分离的影响因素
引用本文:曹达啟,孙秀珍,方晓敏,靳景宜,杨晓璇,郝晓地.剩余污泥胞外聚合物回收:藻酸钠正渗透分离的影响因素[J].环境工程,2020,38(8):71-75.
作者姓名:曹达啟  孙秀珍  方晓敏  靳景宜  杨晓璇  郝晓地
作者单位:北京建筑大学城市雨水系统与水环境省部共建教育部重点实验室/中-荷未来污水处理技术研发中心, 北京 100044
基金项目:北京市高水平创新团队"传统村落保护与居民建筑功能提升关键技术研究项目";北京"未来城市设计高精尖中心"项目
摘    要:剩余污泥中胞外聚合物(EPS)具有巨大的回收价值。然而,回收的EPS溶液含水率接近100%,其浓缩脱水是亟待解决的关键问题。正渗透(FO)膜分离具有膜污染小、浓缩率高、耐高浓度等特点,已成为新兴的节能脱水技术。提出了一种新型的死端FO浓缩方式,调查了模拟EPS(藻酸钠)的正渗透脱水行为。结果显示:FO膜活性层朝向料液侧时水通量下降速率小;类似于外加压力驱动,扫流模式可以减轻FO膜污染,提高水通量;为防止FO膜的拉伸变形,隔板需进行合理设计(如适宜的开孔率),以缓解水通量的下降;不同于外加压力驱动,尽管Ca2+也可减轻膜污染,但效果有限。

关 键 词:胞外聚合物    回收    正渗透    膜污染    藻酸钠
收稿时间:2020-03-20

RECOVERY OF EXTRACELLULAR POLYMERIC SUBSTANCE: IMPACT FACTORS IN FORWARD OSMOSIS SEPARATION OF SODIUM ALGINATE
CAO Da-qi,SUN Xiu-zhen,FANG Xiao-min,JIN Jing-yi,YANG Xiao-xuan,HAO Xiao-di.RECOVERY OF EXTRACELLULAR POLYMERIC SUBSTANCE: IMPACT FACTORS IN FORWARD OSMOSIS SEPARATION OF SODIUM ALGINATE[J].Environmental Engineering,2020,38(8):71-75.
Authors:CAO Da-qi  SUN Xiu-zhen  FANG Xiao-min  JIN Jing-yi  YANG Xiao-xuan  HAO Xiao-di
Affiliation:Sino-Dutch R & D Centre for Future Wastewater Treatment Technologies/Key Laboratory of Urban Stormwater System and Water Environment, Beijing University of Civil Engineering and Architecture, Beijing 100044, China
Abstract:Extracellular polymeric substances (EPSs) in excess sludge have great recycling value. However, the solutions of recycled EPSs afford the moisture contents of nearly 100% and therefore the dehydration of these solutions is an urgent problem. Forward osmosis (FO) membrane separation having advanteges of low membrane fouling, high concentration efficiency, and high concentration resistance, has become a novel low-energy dewatering technology. A novel dead-end FO concentration method was proposed and the FO dewatering of simulated EPS (sodium alginate) was investigated. The results showed that the decline rate of flux deceased when the active layer of FO membrane was towards the feed side; similar to external pressure drive, the cross flow mode could reduce FO membrane fouling and improve flux; the spacer, which was used for preventing the tensile deformation of the FO membrane, should be designed reasonably such as the appropriate holed ratio to reduce the flux decline; the mitigation of FO membrane fouling with Ca2+ addition was insignificant although it was reduced, different from the external pressure drive.
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