| 净化铁锰氨生物滤池内氨氮转化途径 |
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| 引用本文： | 李冬,梁雨雯,杨航,路健.净化铁锰氨生物滤池内氨氮转化途径[J].环境科学研究,2016,29(2):240-245. |
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| 作者姓名： | 李冬 梁雨雯 杨航 路健 |
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| 作者单位： | 1.北京工业大学, 水质科学与水环境恢复工程北京市重点实验室, 北京 100124 |
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| 基金项目： | 国家自然科学基金项目(51222807) |
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| 摘 要： | 为考察净化铁锰氨生物滤池内NH4+-N的转化途径,利用氮素计量关系和沿程试验研究了净化铁锰氨生物滤池内产生TNloss(氮损失)的原因和NH4+-N转化途径. 结果表明,净化铁锰氨生物滤池内DO消耗异常,TNloss不守恒,当进水ρ(NH4+-N)平均值分别为1.262、2.296、3.111 mg/L时,NLR(氮损失率)分别能达到7.89%、12.91%、17.73%. 利用硝化反应和CANON(全程自养脱氮)方程式计算得出理论TNloss和TDOC(理论耗氧量),与实际TNloss和ADOC(实际耗氧量)的差值分别小于±0.030、±0.10 mg/L,各阶段NH4+-N 通过CANON途径转化的比例分别为48.58%、60.77%、68.10%,硝化反应和CANON途径共同参与了NH4+-N转化. 沿程试验结果表明,整个试验阶段,NO2--N在滤层中均有积累,并在滤层厚度为10~18 cm内出现NO2--N和NH4+-N共存的现象,进一步证明CANON途径是净化铁锰氨生物滤池内产生TNloss的原因.
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| 关 键 词： | NH4+-N 氨氮转化途径 氮损失 厌氧氨氧化 全程自养脱氮 |
| 收稿时间： | 2015/8/8 0:00:00 |
| 修稿时间： | 2015/10/26 0:00:00 |
Ammonia Conversion Process in a Biofilter for Iron and Manganese Removal |
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| LI Dong,LIANG Yuwen,YANG Hang and LU Jian.Ammonia Conversion Process in a Biofilter for Iron and Manganese Removal[J].Research of Environmental Sciences,2016,29(2):240-245. |
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| Authors: | LI Dong LIANG Yuwen YANG Hang and LU Jian |
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| Affiliation: | 1.Key Laboratory of Beijing Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing 100124, China2.State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China |
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| Abstract: | In order to investigate the conversion of ammonia and the cause of nitrogen loss in an iron manganese ammonia biofilter, the stoichiometry and the variation of nitrogen along the filter were explored. The results indicated that an unusual DO consumption and nitrogen loss phenomenon occurred in the filter. When the NH4+-N concentrations were 1.262,2.296 and 3.111 mg/L, the nitrogen loss rates reached 7.89%, 12.91% and 17.73%, respectively. Moreover, when the nitrification and CANON equations were used to calculate the theoretical nitrogen loss and theoretical oxygen consumption, and then compared with the actual nitrogen loss and the actual oxygen consumption, the values were less than 0.030 and 0.10 mg/L, respectively. The calculation results demonstrated that both the CANON process and nitrification contributed significantly to the removal of NH4+-N, with the CANON process contribution being about 48.58%, 60.77% and 68.10%, respectively. The variation of nitrogen along the filter showed that throughout the test, NO2--N accumulated in the filter layer. In addition, a NO2--N and NH4+-N coexistence phenomenon appeared in the filter layer of 10-18 cm, which further illustrated that the CANON process was the main cause of the nitrogen loss. |
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| Keywords: | NH4+-N ammonia conversion process nitrogen loss anammox completely autotrophic nitrogen removal over nitrite |
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