Long-term simulation of effects of energy crop cultivation on nitrogen leaching and surface water quality in Saxony/Germany

The production of energy crops in Germany is a growing agronomic sector and is expected to occupy a substantial share of farmland in the near future. At the same time, there are concerns that energy crops might cause increased nitrogen pollution of soil water, surface water and groundwater. Therefore, the Federal State of Saxony, Germany, funded a study on potential effects of an intensified cultivation of energy crops. In frame of this study, we used the Web GIS-based model STOFFBILANZ to simulate N leaching from the rooting zone and N loads of surface water for a reference scenario and an energy crop scenario. For the reference scenario, we used data representing the crop cultivation for the year 2005 at municipality level. We found that the total loads for N leaching from the rooting zone of cropland are highest for the loess region (8,067 t year^?1), followed by mountainous region (6,797 t year^?1) and lowland (5,443 t year^?1). However, highest N fluxes in the leachate from rooting zones have been simulated for lowland (40.6 kg ha^?1 year^?1) and mountainous region (37.1 kg ha^?1 year^?1), while nitrate concentrations of leachate were highest for the lowland (101.8 mg l^?1). In terms of diffuse N input into surface water, the mountainous region is the most important source area (total N load 6,380 t year^?1, flux 34.6 kg ha^?1 year^?1). Retention by in-stream processes accounts for 15 % (3,784 t year^?1) of the total N load leaving the study area (25,136 t year^?1). In the 2020 energy crop scenario, shares of rape and silage maize (id., ensiled corn) were limited for each municipality to a maximum of 25 and 33 %, respectively. The conversion of grasslands to crop farming was not allowed. Under these conditions, we found slight to substantial reductions of nitrogen loads for leachate from the rooting zone and for surface waters. The simulated reduction depends strongly on local conditions. Only small reductions (ca. 4–8 %) were found for the lowlands and mountainous regions of Saxony, while reductions for the loess region were substantial (ca. 22 %). A major outcome of our study is that the cultivation of energy crops might reduce N loss if certain preconditions are assumed, for example, without conversion of grasslands to crop farming. However, effects might vary widely depending on local conditions.     

Direct N2O emission from agricultural soils in Poland between 1960 and 2009

Nitrogen fertilization (N) is commonly known as a main source of direct nitrous oxide (N₂O) emission from agricultural soils. An area of 38 % of the total land surface of Poland was covered by agricultural soils in 2009. In this paper, we aimed at analyzing data regarding the land exploitation for 13 selected subareas of Poland between 1960 and 2009. Seven out of the 13 subareas studied are located in the West (area A), and six subareas are located in southeast of Poland (area B). The total area covered by large farms (>20 ha) differed largely, between area A (10.6 %) and area B (0.9 %) in 2009. Both areas varied in terms of the amount of fertilizers used annually, average crop yield and crop structure. Average direct emissions of N₂O from agricultural soils were 1.66 ± 0.09 kg N₂O–N ha^?1 a^?1 for area A, 1.39 ± 0.07 kg N₂O–N ha^?1 a^?1 for area B and 1.46 ± 0.07 kg N₂O–N ha^?1 a^?1 for the whole country between 1960 and 2009.     

Towards green membranes: preparation of cellulose acetate ultrafiltration membranes using methyl lactate as a biosolvent

Ultrafiltration membranes were prepared using cellulose acetate (CA) as a polymer, LiCl and CaCl₂ as porogens and methyl-(S)-lactate as a solvent. CA, methyl lactate and the porogens used in this work are obtained from renewable resources; they are biodegradable, non-toxic and non-volatile organic compounds. Flat sheet ultrafiltration membranes were prepared by the phase inversion technique. A molecular weight cut-off between 15 and 35 kDa (polyethylene glycol) and pure water permeability between 13 and 177 litres h^? 1m^? 2 bar^? 1 were obtained. These parameters are in the ideal range for water treatment industry. Improvement of pollutant degree and ecotoxicity of the process was evaluated by ‘green’ metrics by the P (pollutants, persistent and bioaccumulative) and E (ecotoxicity) parameters. Both of these variables were recorded as zero using our method. This study represents a step ahead towards the production of ultrafiltration polymeric membranes by a ‘greener’ process than current methods.     

Effect of human use,season and habitat on ungulate density in Kanha Tiger Reserve,Madhya Pradesh,India

Conservation practitioners require strata specific, seasonal species densities for habitat management. Herein, we use stratified distance sampling in Kanha Tiger Reserve (KTR) with 200 spatial transects and an effort of 1200 km walk in the year 2013. Analysis was done to access (a) impact of human use and (b) effect of habitat and season on ungulate densities in KTR. While a single detection function for each species was used for estimating density within human-restricted core and multiple use buffer of KTR, species-specific seasonal detections were modelled for each habitat. Ungulate biomass was 4.8 times higher in the core area compared with the buffer zone. The core supported a herbivore density and biomass of 50 ± 4.80/km² and 26,806 ± 2573 kg/km², respectively. Chital were found to be most abundant, having a density of 30.1 ± 4.34/km² and contributing 33 % of the biomass with a habitat preference for grasslands (106 ± 39/km²) in summer and winter. Sambar had highest density (15.4 ± 3.34/km²) in bamboo-mixed habitat, in both seasons. Gaur contributed 39 % of the ungulate biomass and showed a seasonal shift in density from sal forests (9.65 ± 3.55/km²) in summer to miscellaneous forests (8.13 ± 1.94/km²) in winter. Barasingha were restricted to grasslands with similar summer and winter densities of 1.56 ± 0.76/km². Chousingha were rare (0.1 ± 0.04/km²), found mostly in miscellaneous forests and plateau grasslands. Grassland and bamboo-mixed forests supported 58 % of the total ungulate biomass. Management for an optimal habitat mosaic that maintains ungulate diversity, addresses the specific needs of endangered species and maximizes ungulate biomass is recommended.     

Climate change impacts on a pine stand in Central Siberia

The objective of this paper is to analyse the impacts of climate change on a pine forest stand in Central Siberia (Zotino) to assess benefits and risks for such forests in the future. We use the regional statistical climate model STARS to develop a set of climate change scenarios assuming a temperature increase by mid-century of 1, 2, 3 and 4 K. The process-based forest growth model 4C is applied to a 200-year-old pine forest to analyse impacts on carbon and water balance as well as the risk of fire under these climate change scenarios. The climate scenarios indicate precipitation increases mainly during winter and decreases during summer with increasing temperature trend. They cause rising forest productivity up to about 20 % in spite of increasing respiration losses. At the same time, the water-use efficiency increases slightly from 2.0 g C l^?1 H₂O under current climate to 2.1 g C l^?1 H₂O under 4 K scenario indicating that higher water losses from increasing evapotranspiration do not appear to lead to water limitations for the productivity at this site. The simulated actual evaporation increases by up to 32 %, but the climatic water balance decreases by up to 20 % with increasing temperature trend. In contrast, the risk of fire indicated by the Nesterov index clearly increases. Our analysis confirms increasing productivity of the boreal pine stand but also highlights increasing drought stress and risks from abiotic disturbances which could cancel out productivity gains.     

Channel migration zone mapping of the River Ganga in the Diara surrounding region of Eastern India

River channel migration is the universal phenomenon that is common in almost all alluvial rivers. The holy River Ganga, the heartbeat of India, is also not an exception in this case. It has shifted its course from time to time. After crossing the Rajmahal hills that is situated in the north-eastern corner of the Chota Nagpur plateau, this main river of India has started its lower course by flowing over the great low-lying flat plain of Bengal. In this flat plain area, the channel migration is a common phenomenon which is observed in the River Ganga also. The study is done in the segment of the Ganga River which is situated in the Diara surrounding area. Diara is a physical cum administrative region of the Malda district of the state of West Bengal of India which occupies an area of almost 900 km². For the identification of channel migration zone, several methods are used like construction of historical migration zone (HMZ), erosion buffer (EB), avulsion potential zone (APZ), restricted and un-restricted migration area (RMA and UrMA) and retreating migration zone (RMZ). The impact of the channel migration over the villages of the Diara region has also been depicted in this study. Remote Sensing and Geographical Information System (RS–GIS) is used to perform this study by taking the help of historical maps, Survey of India topographical sheets, LANDSAT imageries, etc. The results show that the river has a historical migration zone of 855.55 km² during 1926–2016 period which is near the entire area of the Diara region (i.e. 900 km²). The construction of EB over the Ganga River for the next 100 years shows that more than half of the area of the Diara region will go under the river bed.     

Greenhouse gas emissions from a semi-arid tropical reservoir in northeastern Brazil

We estimated carbon dioxide (CO₂) and methane (CH₄) emissions by diffusion, ebullition, and degassing in turbines from a semi-arid hydropower reservoir in northeastern Brazil. Sampling sites were allocated within the littoral and deeper waters of one embayment, the main-stream, and at turbines. Annual carbon emissions were estimated at 2.3?×?10⁵?±?7.45?×?10⁴ t C year^?1, or in CO₂-equivalents (CO₂-eq) at 1.33?×?10⁶?±?4.5?×?10⁵ t CO₂-eq year^?1. Diffusion across the water surface was the main pathway accounting for 96% of total carbon emissions. Ebullition was limited to littoral areas. A slight accumulation of CO₂, but not of CH₄, in bottom waters close to the turbines inlet led to degassing emissions about 8?×?10³ t C year^?1. Emissions in littoral areas were higher than in main-stream and contribute to 40% of the total carbon. Carbon (C) emissions per electricity generated, at 60% of installed capacity, is 0.05 t C-CO₂-eq MWh^?1. The ratio increases to 0.09 t C-CO₂ MWh^?1, equating 80% of the emissions from natural gas and 40% of diesel or coal power plants. Retention time and benthic metabolism were identified as main drivers for carbon emissions in littoral areas, while water column mixing and rapid water flow are important factors preventing CH₄ accumulation and loss by degassing. Our results indicate that Itaparica Reservoir, located in the semi-arid region of Northeastern Brazil, acts as a source of GHGs. Management measurements are needed to prevent emissions to raise in the future.     

A study on the arsenic concentration in groundwater of a coastal aquifer in south-east India: an integrated approach

The occurrence of arsenic in drinking water and its detrimental effects have drawn much attention in recent years. Several studies have been conducted in the deltaic plains of River Ganga, NE part of the India, and in other countries, but no systematic study was conducted in South India on occurrence of arsenic in groundwater. The main aim of this study is to determine the level of arsenic in groundwater and to understand the relation with other geochemical parameters of groundwater in the south-eastern coastal aquifer at Kalpakkam region, India. This region is represented by three different lithologies, viz. charnockites, flood plain alluvium and marine alluvium. Twenty-nine representative samples of groundwater were collected and analysed for major ions, metals and isotopes such as ²H and ¹⁸O. In addition, geophysical method was also attempted to understand the subsurface condition. The spatial variation in arsenic (As) indicates that higher concentration was observed around the landfill sites and irrigated regions, which was supported by geochemical, statistical and isotopic inferences. The variation in the As with depth, lithology and sources has been clearly brought out. Though the values of As does not exceed the drinking water permissible limit (10 mg/l), it has reached a near permissible level of 8.7 ppb. Hence, it is essential to understand the geochemical behaviour of As for a proper future management of the water resource in the study area.     

Mitigation of greenhouse gas emissions from an abandoned Baltic peat extraction area by growing reed canary grass: life-cycle assessment

Abandoned peat extraction areas are continuous emitters of GHGs; hence, abandonment of peat extraction areas should immediately be followed by conversion to an appropriate after-use. Our primary aim was to clarify the atmospheric impact of reed canary grass (RCG, Phalaris arundinacea L.) cultivation on an abandoned peat extraction area and to compare it to other after-treatment alternatives. We performed a life-cycle assessment for five different after-use options for a drained organic soil withdrawn from peat extraction: (I) bare peat soil (no management), (II) non-fertilised Phalaris cultivation, (III) fertilised Phalaris cultivation, (IV) afforestation, and (V) rewetting. Our results showed that on average the non-fertilised and fertilised Phalaris alternatives had a cooling effect on the atmosphere (?10,837 and ?477 kg CO₂-eq ha^?1 year^?1, respectively), whereas afforestation, rewetting, and no-management alternatives contributed to global warming (9,511, 8,195, and 2,529 kg CO₂-eq ha^?1 year^?1, respectively). The main components influencing the global warming potential of different after-use alternatives were site GHG emissions, carbon assimilation by plants, and emissions from combustion, while management-related emissions played a relatively minor role. The results of this study indicate that, from the perspective of atmospheric impact, the most suitable after-use option for an abandoned peat extraction area is cultivation of RCG.     

Evaluation of decoloration potential of <Emphasis Type="Italic">Xanthium Strumarium</Emphasis> seed hull for adsorption of Direct red 81 in aqueous solution

An unmodified natural adsorbent, Xanthium Strumarium, was explored for its decoloration potential for treatment of textile effluents. Batch mode experimentation was carried out to optimize several process parameters with the well characterized adsorbent. For proper assessment of optimized pathway of adsorption, adsorption isotherms were implemented to the experimental data using nonlinear method. Apart from coefficients of determination, three error analysis methods standard error (S.E.), Chi-square (χ²) statistic and residual mean square error were additionally used to determine the best fitted isothermal model for the system. Freundlich model was creditably fitted to the adsorption data with minimum errors and high R ² values. The adsorption capacity obtained was 14.7, 15.2 and 18.7 mg g^?1 at 30, 40 and 50 °C, respectively. Overall adsorption process was endothermic with positive enthalpy and entropy values. Kinetic study revealed adsorption to be a two stage process initially controlled by film diffusion followed by pseudosecond order as the rate administering step during adsorption. About 95 % decoloration was achieved in 60 min. High decoloration tendency of the opted adsorbent proved that it is an effective and cheap adsorbent for treatment of coloured effluents providing a good alternative to activated carbon.     

Spatio-temporal variation of macrobenthic communities in the mangrove-fringed Segara Anakan lagoon, Indonesia, affected by anthropogenic activities

The benthic macrofauna of the Segara Anakan lagoon, Java, Indonesia and its fringing mangroves were investigated between May 2004 and August 2006. This lagoon has been affected by various human activities for decades, in particular fishing, effluents from agriculture and industry, and illegal deforestation. In total, 163 taxa were identified, including 127 species occurring in the mangrove forest and 59 species in the subtidal. Mean density of macrobenthos was 2.5-fold higher in the central (881.8 ± 1,151.3 ind. m^?2) than in the eastern mangrove site (356.3 ± 218.8 ind. m^?2). Community structures differed significantly between these sites and showed a serial shift during the investigation period. Gastropods dominated the community in the central mangrove location, whereas sipunculids, polychaetes and gastropods had similar densities in the eastern site. Differences in community composition were best explained by three sediment properties: pore water salinity, δ¹³C_org, and C_org/N. It is suggested that small-scale heterogeneity of food availability and quality is a main factor determining the small-scale variability of the community composition. Compared to other Indo-West Pacific mangroves, species richness and densities are high. However, the dominance of specific taxa, especially of opportunistic species and the comparably low species richness in the subtidal of the lagoon may be attributed to the high sediment input by rivers in the central part and to the large-scale cutting of mangroves. Continuous tree logging will probably lead to a further spread of two fast growing understorey plants and thus to an increase of uniform swamp sites and a decrease of micro-habitats for benthic macrofauna. To our knowledge, this is the first detailed study on the spatio-temporal variation of benthic macrofauna in mangroves of Indonesia.     

Carbon stock variation of Pinus roxburghii Sarg. Forest along altitudes of Garhwal Himalaya, India

The present study was undertaken in Pinus roxburghii forest along three different altitudes i.e., 1100, 1300 and 1500 meter above mean sea level of Garhwal Himalaya to understand the effect of altitudes on carbon stocks (live trees and soil) in Pinus roxburghii forest. Tree density of this forest ranged between 590 tree ha^?1 (upper altitude) to 640 tree ha^?1 (lower altitude). The highest total carbon density (TCD) of above and belowground carbon was 66.33 ± 29.92 Mg ha^?1 at lower altitude followed by 57.64 ± 16.75 Mg ha^?1 in middle altitude and 52.92 ± 6.52 Mg ha^?1 in upper altitude. Soil organic carbon was highest (33.20 ± 2.77 Mg ha^?1) at lower altitude followed by middle (22.61 ± 7.17 Mg ha^?1) and upper altitude (12.65 ± 6.10 Mg ha^?1). Total carbon stock (trees + soil) of Pinus roxburghii forest was maximum (99.53 Mg ha^?1) at lower altitude and minimum (65.57 Mg ha^?1) at upper altitude.     

Possible use of Lingula sp. (Phylum Brachiopoda) as a dissemination strategy to promote sustainable development in Fangchenggang mangrove,China

The economic marketability of a brachiopod, Lingula was studied at three coastal mangrove sites, specifically based on socioeconomic parameters from 10 villages that utilized Lingula along Pearl Bay, Beilun Estuary Marine Nature Reserve, China. The significantly highest density of Lingula was at Jiao Dong (48.2 ± 35.14 individual/m²) whereas the biomass of Lingula was highest (0.76 ± 0.22 g/individual) at Gui Lao Bu. The shell size of the largest specimen was still less than that in other references. The socioeconomic study of the population related to Lingula involved a small group, and no relationship could be determined among the parameters of age range, education level, occupation, and financial status. The total economic value (320,927.4 Yuan) was based on the value of consumption whereas the value from sales was very low as recorded from Shan Xin over a three-month season. Analysis of the results to determine strengths, weaknesses, opportunities, and threats was undertaken to identify the potential of Lingula sp. to be promoted and supported in the market as a novel source of income for the local community who are associated with mangrove resources; and also to examine its potential as a new food source for the rapidly growing population of China.     

Greenhouse gases emissions from a closed old landfill cultivated with biomass crops

Closed landfills need after-closure rehabilitation. The chosen option should ensure greenhouse gases release, from the landfill, is not promoted once settled. The objective of this study was to estimate and confront, during different seasons, CH₄, CO₂ and N₂O emissions under three vegetation covers in a closed landfill in Buenos Aires, Argentina. CH₄ (methane), CO₂ (carbon dioxide) and N₂O (nitrous oxide) emissions from landfill’s technosol under spontaneous vegetation (control), Pennisetum purpureum and Miscanthus giganteus (biomass crops), were quantified with non-steady-state non-flow-through chambers, in July 2014 and from February to July 2015. A linear regression analysis was performed to relate the variables “flux of a gas” and “concentration of that gas” from the 3 treatments and 6 dates, separating the 5 sampling times. A high correlation between concentrations and fluxes of CO₂ and N₂O was found, but no correlation was established for CH₄. Mean emissions (2014–2015) varied from: ?2.3 to 639.41 mgCH₄ m^?2 day^?1, 3884 to 46,365 mgCO₂ m^?2 day^?1 and 0.40 to 14.59 mgN₂O m^?2 day^?1. Vegetation covers had no significant effect on CH₄ and N₂O concentration in time, but they had on CO₂ concentration. Season of the year had a significant effect on concentration of the three gases. This is the first study on CH₄, CO₂ and N₂O emissions from a landfill closed 27 years ago covered with biomass crops.     

Which crop production system is more efficient in energy use: wheat or barley?

Efficient use of energy helps to achieve increased production and productivity and contributes to the economy, profitability, and competitiveness of agricultural sustainability of rural communities. Evaluation of wheat and barley production systems in view of energy balance was conducted in Khorasan Razavi Province, Iran. Data were collected by using a face-to-face questionnaire from wheat and barley fields in 2011. Results revealed that total energy input for wheat was 51,040 MJ ha^?1 and for barley 44,866; in wheat and barley systems, renewable energy was consumed by 25.43 and 23.53 %, while non-renewable energy was consumed by 74.57 and 76.47 %, respectively. Energy use efficiency, energy productivity, and net energy were 1.7 kg MJ^?1, 0.088 kg MJ^?1, and 35,987 MJ ha^?1 in wheat system and 1.83 kg MJ^?1, 0.092 kg MJ^?1, and 33,833 MJ ha^?1 in barley system, respectively. Energy intensiveness in wheat fields (61.84 MJ $^?1) was higher than in barley fields (58.71 MJ $^?1). Also, benefit-to-cost ratio in wheat system (1.59) was higher than in barley system (1.35). In general, production in barley fields was more sustainable than wheat production because, in view of ecological indices such as amount of energy use and renewable energy consumption, it was more environment-friendly production.     

Dynamic simulation of a decentralized polygeneration plant providing SNG,steam and power

The behaviour of a decentralized polygeneration plant providing synthetic natural gas (SNG), steam and electrical power is simulated in three scenarios in this study. The plant size is based on an assumed capacity of decentralized polygeneration plants processing 1070 m³ h^?1 (STP) of syngas. 396 m³ h^?1 (STP) of raw SNG, 0.4 t h^?1 of steam at 5 bar and 670 kW of electrical power can be generated by the plant at the reference scenario. Methanation reactor and steam generator are modelled in detail. Further results indicate that such a polygeneration plant can provide positive and negative operation reserves for the electricity network to the extent of 100% of the reference power output, while the amount of generated steam varies by less than 40%. At the same time, the generated SNG quality keeps constant. Lower variations in the amount of generated steam are applicable when reducing the operation reserve capacity.     

Dividivi tannins: an ecological product for water-based drilling fluids

Modified tannins are used as deflocculant additives in the formulation of water-based drilling fluids (WBDF) for drilling operations in any scenario. Due to their high heavy metals content, these additives are toxic and hazardous for any environmental scenario. Deflocculant efficiency of unmodified tannins (UDT) extracted from fruit pods of “dividivi” (Caesalpinia coriaria) as an additive for WBDF was assessed. Raw materials for UDT elaboration come from the rural and sustainable exploitation of natural occurring dividivi trees, growing in dry tropical forests in Anzoátegui state (Orinoco Oil Belt, eastern Venezuela). The tannins extract, in the form of dividivi fruit powder, contains 47.0 % of total tannins (hydrolyzable tannins plus condensed tannins), of which 67.4 % corresponds to hydrolyzable tannins. Dividivi tannins in WBDF showed nine (9) times deflocculant efficiency than heavy metals commercial modified tannins. Moreover, commercial modified tannins do not improve their deflocculant efficiency with increased tannin content. Ecotoxicological studies were carried out for WBDF formulations with UDT, using freshwater microalgae Scenedesmus dimorphus as chronic toxicity bioindicator. Toxicity bioassays performed with these microalgae did not show significant effects on its population growth. The EC₅₀ values resulted in over 100,000 mg L^?1, and these formulations were therefore considered non-toxic. Values of LC₅₀ obtained this time with Poecilia reticulata, as acute toxicity bioindicator are around 100,000 mg L^?1, with no significant effects on population mortality. Thus, WBDF formulated with UDT can be considered non-toxic formulations for populations of this freshwater fish. From the social perspective, the use of UDT in WBDF fosters organized communities economical activities based on the maintenance of a sustainable supply chain for processing fruits in a quantity enough to obtain three thousand seven hundred fifty kilograms (3750 Kg). The UDT so obtained was used as deflocculant in four (4) oil wells producing excellent performance and relevant savings compared with commercial modified tannin.     

Factors influencing farmers’ decisions on nitrogen fertilizer application in the Liangzihu Lake basin,Central China

Overuse of nitrogen (N) fertilizers in agriculture activities has caused severe water pollution in China. The lack of data at producer level hampers decision makers in the development and implementation of efficient policies to curb excessive N-fertilizer use. In a survey of 300 farm households in the Liangzihu Lake basin, we identified factors associated with farmers’ decisions on N-fertilizer use and application rate. Household survey and multiple linear regression models indicate that the average application rate in the study region is 229 kg N ha^?1, which exceeds the recommended rate for maximum profit for cereal crops (maize, wheat, and rice) in China of 150–180 kg N ha^?1. High N-application rates are associated with low farmland productivity (coefficient = ?15.66, p = 0.02), a high share of off-farm income (coefficient = 27.14, p = 0.003), and a low education level of the household head (coefficient = ?10.83, p = 0.039). Neither physical infrastructure nor access to input markets appears to be related to N-application rates. It may be concluded that excessive use of N in agriculture of Central China is mainly a problem of insufficient awareness and high share of off-farm income.     

A pore water study of plutonium in a seasonally anoxic lake

Data are presented here on the distribution of ^239,240Pu in the pore waters of two cores taken from a seasonally anoxic lake. The pore water ^239,240Pu profile exhibits a subsurface activity maximum of 230 ± 30 μBqkg^?1 in the 3–6 cm interval in June, as compared to an activity of 5 ± 3 μBqkg^?1 in the overlying water. The pore water ^239,240Pu profile in June follows the solid phase distribution pattern of ^239,240Pu and also the pore water distributions of Fe and Mn. Under more reducing conditions in August, pore water ^239,240Pu activities drop off to undetectable levels at all depths. This rapid change in the pore water ^239,240Pu activity reflects the dynamic nature of Pu diagenesis in these sediments. Potential diffusional fluxes of ^239,240Pu into the lake's hypolimnion in June are calculated to be on the order of 2·5 μBq cm^?2y^?1. This flux would not be significant in altering the solid phase ^239,240Pu inventory (2·8 × 10⁴μBqcm^?2).