Chemical, biological, and ecotoxicological assessment of pesticides and persistent organic pollutants in the Bahlui River, Romania

Background, aim, and scope  

Current knowledge on environmental impacts of industrial activities in Romania, particularly persistent organic pollutants (POPs), indicates that environmental standards of the European Union are not systematically met. In our study area, additional sources of POPs are agriculture and domestic wastes. Very scarce information is available upon environmental contaminations and effects. In the present study, we investigated the chemical pollution and their eventual impact on the ecosystem by measuring POPs and by using biological indicators of pollution.     

Strategic environmental assessment of mining activities: A methodology for quantification of cumulative impacts on the air quality

Environmental impact assessments in Brazil have usually focused solely on project-related issues without considering the regional context. Although required by current environmental legislation, cumulative impact assessments have not been included in the overall environmental assessment of projects. However, in recent Strategic Environmental Assessment (SEA) studies of policies, plans, and programs undertaken on a voluntary basis in support of the decision-making process, this kind of assessment has been performed especially with respect to air quality. This paper presents the application of a methodology for the quantification of cumulative impacts on air quality under high uncertainty caused by various mining activities in a single region that is recommended for SEA studies. In this way, the methodology presented here is suitable for areas lacking detailed modeling information. The developed approach uses a relatively simplified mathematical model, lowering information gathering costs and requiring little processing time. The application of the methodology is illustrated in the case of a SEA of the Corumbá Mining and Industrial Complex Development Program. Despite the lack of data needed for a minimum characterization of conditions of the area surrounding the region modeled, the quantification of impact cumulativeness on air quality has played an important role in the context of the SEA.     

Development of risk-based air quality management strategies under impacts of climate change

Climate change is forecast to adversely affect air quality through perturbations in meteorological conditions, photochemical reactions, and precursor emissions. To protect the environment and human health from air pollution, there is an increasing recognition of the necessity of developing effective air quality management strategies under the impacts of climate change. This paper presents a framework for developing risk-based air quality management strategies that can help policy makers improve their decision-making processes in response to current and future climate change about 30-50 years from now. Development of air quality management strategies under the impacts of climate change is fundamentally a risk assessment and risk management process involving four steps: (1) assessment of the impacts of climate change and associated uncertainties; (2) determination of air quality targets; (3) selections of potential air quality management options; and (4) identification of preferred air quality management strategies that minimize control costs, maximize benefits, or limit the adverse effects of climate change on air quality when considering the scarcity of resources. The main challenge relates to the level of uncertainties associated with climate change forecasts and advancements in future control measures, since they will significantly affect the risk assessment results and development of effective air quality management plans. The concept presented in this paper can help decision makers make appropriate responses to climate change, since it provides an integrated approach for climate risk assessment and management when developing air quality management strategies. Implications: Development of climate-responsive air quality management strategies is fundamentally a risk assessment and risk management process. The risk assessment process includes quantification of climate change impacts on air quality and associated uncertainties. Risk management for air quality under the impacts of climate change includes determination of air quality targets, selections of potential management options, and identification of effective air quality management strategies through decision-making models. The risk-based decision-making framework can also be applied to develop climate-responsive management strategies for the other environmental dimensions and assess costs and benefits of future environmental management policies.     

Sediment quality in littoral regions of the Gulf of Cádiz: a triad approach to address the influence of mining activities

To evaluate sediment quality in different areas in the Gulf of Cádiz affected by mining activities, an integrative approach to assessment was used: the Sediment Quality Triad (SQT). Sediment samples were collected at six stations and subjected to replicated sediment acute and chronic toxicity tests, and comprehensive sediment chemistry analyses. Organisms collected synoptically at the same stations were analyzed for histopathological lesions and chemical concentrations in their tissues to determine 'in situ' alteration and bioavailability, in place of benthic community structure. The results obtained for each component were linked to the SQT using different methodologies of interpretation and expression of the integrated approach: (a) multivariate analysis, (b) significant statistical differences compared to the reference stations, (c) ANOVA-based pie charts, and (d) classical methods using triangles and the SQT index of pollution. SQT results indicated that the highest pollution was mainly associated with metals from mining activities and polyaromatic hydrocarbons in the Ría of Huelva. The use of histopathological measures and bioaccumulation of metals, improved the characterization of 'gray areas' of pollution and in the determination of the bioavailability of metals.     

Framework for the environmental impact assessment of operational shipping

Shipping is an important source of pollution affecting both atmospheric and aquatic environments. To allow for efficient mitigation of environmental degradation, it is essential to know the extent of the impacts of shipping in relation to other sources of pollution. Here, we give a perspective on a holistic approach to studies of the environmental impacts of operational shipping through presentation of an assessment framework developed and applied on a case of shipping in the Baltic Sea. Through transfer of knowledge and concepts, previously used in assessments of air pollution, now applied to assessments of marine pollution and underwater noise, the horizon of understanding of shipping-related impacts is significantly improved. It identifies the main areas of environmental degradation caused by shipping and potential improvements through legislation and technological development. However, as the vast majority of contaminants discharged into the sea are not routinely monitored and assessed, the links between pressure of contaminants from shipping and environmental state and impacts will not be caught in the current environmental regulatory frameworks.     

Cross-Media Environmental Impacts of Air Pollution Regulations for a Coal-Fired Power Plant

The types and rates of pollutant emissions from a coal-fired power plant depend upon plant design, coal characteristics, and environmental control policy. In the past, air pollution regulations were often promulgated without rigorous analysis of the resulting energy penalties and secondary environmental impacts that occur in other environmental media (air, land, or water), which are counterproductive to overall environmental quality. This paper describes a Comparative Assessment Model that has been developed to consider systematically such tradeoffs for conventional and advanced coal-to-electric technologies. The model is applied to quantify the secondary (“cross-media”) environmental and resource impacts resulting from alternative air pollution control policies that reduce sulfur dioxide emissions from a 1000 MW power plant. Multimedia pollutant burdens are presented, together with the increased requirements for coal, limestone, and water that are incurred in generating a fixed net quantity of electricity. The development of sound public policy requires that environmental regulations be sensitive to adverse effects in all environmental media, and that tradeoffs involved in the regulation of specific pollutants to one medium be rigorously and systematically characterized.     

Submarine wastewater discharges: dispersion modelling in the Northern Adriatic Sea

Background, aim and scope   

Opposite interests must coexist in coastal areas: the presence of significant cities and urban centres, of touristic and recreational areas, and of extensive shellfish farming. To avoid local pollution caused by treated wastewaters along the Northern Adriatic coast (Friuli Venezia-Giulia and Veneto regions), marine outfall systems have been constructed. In this study, the application of a numerical dispersion model is used to support the traditional monitoring methods in order to link information concerning the hydrodynamic circulation and the microbiological features, to evaluate possible health risks associated with recreational and coastal shellfish farming activities. The study is a preliminary analysis of the environmental impact of wastewater treatment plants (WWTPs) with submarine discharge outfalls. It also could be useful for the water profile definition according to the Directive 2006/7/EC on the quality of bathing water and for the integrated areal analysis (Ostoich et al. 2006), to define the area of influence of each submarine discharge point.     

Biomonitoring aquatic environmental quality in a marine protected area: a biomarker approach

The main aims of the present study, conducted in the framework of the MONIQUA-Egadi Scientific Project, were twofold: first, to make the first step in the development and validation of an ecotoxicological approach for the assessment of marine pollution in coastal environments on the basis of a set of biomarker responses in new sentinel species; and second, to obtain preliminary information on environmental quality in an Italian marine protected area, the Egadi Islands (Sicily). Several cytochrome P450-dependent mixed-function oxidase activities were measured in the following sentinel species: rainbow wrasse Coris julis, gastropod limpet Patella caerulea, and sea urchin Paracentrotus lividus. The results suggest that specimens from the Favignana Harbor may be exposed to P450 inducers, whereas most of the other sites seem to share similar environmental quality. The proposed approach has potential for assessment of environmental quality in marine protected areas.     

Trace metal element pollution of soil and water resources caused by small-scale metallic ore mining activities: a case study from a sphalerite mine in North China

Trace metal element contamination in mining areas is always a huge environmental challenge for the global mining industry. In this study, an abandoned sphalerite mine near the Yanshan Mountains was selected as subject to evaluate the soil and water contamination caused by small-scale mining. The results show that (1) Pearson correlation matrix and principal component analysis (PCA) results reveal that Zn, Cu, Cd, and Pb were greatly affected by the operation of mines, especially mineral tailings. The contents of trace metal elements decrease with the increase of the distance from the mining area. Zinc, Pb, and Cd were discovered in almost all soil samples, and Zn accounted for about 80% of pollution of the topsoil. (2) The trace element pollution levels in the topsoil of the three villages were ranked as follows: Cd?>?Cu?>?Pb~Zn. The potential ecological risk of farmland around the mine ranges from lower to higher, with Cd being the most harmful. (3) Human health risk assessment results show that trace elements in the mining area pose obvious non-carcinogenic health risks to children while the risks to adults are not equally obvious. The carcinogenic risk of Cd and Cr is within a safe range and does not pose an obvious cancer risk to the population.

     

Freight shipment modal split and its environmental impacts: An exploratory study

Freight transportation activities are responsible for a large share of air pollution and greenhouse gas emissions in the United States. Various freight transportation modes have significantly different impacts on air quality and environmental sustainability, and this highlights the need for a better understanding of interregional freight shipment mode choices. This paper develops a binomial logit market share model to predict interregional freight modal share between truck and rail as a function of freight and shipment characteristics. This model can be used to estimate the impacts of various factors, such as oil price, on shippers’ mode choice decisions. A set of multiyear freight and geographical information databases was integrated to construct regression models for typical freight commodities. The atmospheric impact levels incurred by different freight modal choice decisions are analyzed to provide insights on the relationship among freight modal split, oil price change, and air quality.

Implications:

Freight transportation has become a major source of energy consumption and air pollution, and emissions rates vary significantly across different modes. Understanding freight shipment mode choice under various economic and engineering factors will help assess the environmental impacts of freight shipment systems at the national level. This paper develops a binomial logit model for two dominating modes (truck and rail) and shows how this model is incorporated into an environmental impact analysis. The framework will be useful to policy makers to assess the impacts of freight movements on air quality and public health and to mitigate those adverse impacts.     

Indirect effect of nutrient accumulation intensified toxicity risk of metals in sediments from urban river network

The levels of metals in sediments of urban river ecosystems are crucial for aquatic environmental health and pollution assessment. Yet little is known about the interaction of nutrients with metals for environmental risks under contamination accumulation. Here, we combined hierarchical cluster, correlation, and principal component analysis with structural equation model (SEM) to investigate the pollution level, source, toxicity risk, and interaction associated with metals and nutrients in the sediments of a river network in a city area of East China. The results showed that the pollution associated with metals in sediments was rated as moderate degree of contamination load and medium-high toxicity risk in the middle and downstream of urban rivers based on contamination factor, pollution load index, and environmental toxicity quotient. The concentration of mercury (Hg) and zinc (Zn) showed a significant correlation with toxic risks, which had more contribution to toxicity than other metals in the study area. Organic nitrogen and organic pollution index showed heavily polluted sediments in south of the study area. Though correlation analysis indicated that nutrients and metals had different input zones from anthropogenic sources in the urban river network, SEM suggested that nutrient accumulation indirectly intensified toxicity risk of metals by 13.6% in sediments. Therefore, we suggested the combined consideration of metal toxicity risk with nutrient accumulation, which may provide a comprehensive understanding to identify sediment pollution.

Toxicity rate of metals in sediments from urban river network indirectly intensified by nutrients accumulation

     

Assessment of trace element pollution and ecological risks in a river basin impacted by mining in Colombia

Trace element pollution in rivers by anthropogenic activities is an increasing problem worldwide. In this study, the contamination and ecological risk by several trace elements were evaluated along a 100-km stretch of the San Jorge River in Colombia, impacted by different mining activities. The increase of average concentration levels and range of trace elements in sediments (in μg/g) was as follows: Cu 6656 (454–69,702) > Cd 1159 (0.061–16,227) > Zn 1064 (102–13,483) > Ni 105 (31–686) > Pb 7.2 (5.1–11.7) > As 1.8 (1.0–3.2) > Hg 0.31 (0.12–1.37). Results showed that surface sediments could be classified as very high ecological risk index (RI > 600), associated with high contamination of Hg, Cd, and Cu, in stations close mining activities. Values for pollution load index indicate an environmental deterioration (PLI > 1), and sediment quality guidelines (SQGs) suggested that Cu, Ni, Zn, and Hg caused adverse biological effects. We further used pollution indices such as contamination factor (CF), enrichment factor (EF), and geoaccumulation index (Igeo) to assess the extent of contamination. According to these indices, discharges of hazardous chemicals over many years have resulted in a high degree of pollution for Cu, Pb, and Cd, with critical values in stations receiving wastes from mining activities. Multivariate statistical analysis suggested that Hg, Cd, Cu, and Zn derived from gold and coal mining, Ni and As were related from the mining of ferronickel and coal, respectively, whereas the high Pb load was attributed to diffuse source of pollution. In sum, our study provided the first detailed database on metal concentration and ecological risks to organisms in sediments of the San Jorge River Basin, and the current results also suggested future research for public health action.

     

地理信息系统在累积影响评价中的应用

累积影响评价是在可持续发展目标要求下环境影响评价的一种新类型,但目前进行累积影响评价的方法和工具仍较缺乏。文章分析了利用地理信息系统进行累积影响评价的能力,结果表明：地理信息系统能改善对发展行为和环境状况的监测和跟踪,能较好地分析环境影响的时、空累积特征,是进行累积影响评价的有效工具;但是,其对环境影响累积过程的本质考虑有限,需要与能反映累积过程的子模式相结合。     

From chemical risk assessment to environmental resources management: the challenge for mining

On top of significant improvements and progress made through science and engineering in the last century to increase efficiency and reduce impacts of mining to the environment, risk assessment has an important role to play in further reducing such impacts and preventing and mitigating risks. This paper reflects on how risk assessment can improve planning, monitoring and management in mining and mineral processing operations focusing on the importance of better understanding source–pathway–receptor linkages for all stages of mining. However, in light of the ever-growing consumption and demand for raw materials from mining, the need to manage environmental resources more sustainably is becoming increasingly important. The paper therefore assesses how mining can form an integral part of wider sustainable resources management, with the need for re-assessing the potential of mining in the context of sustainable management of natural capital, and with a renewed focus on its the role from a systems perspective. The need for understanding demand and pressure on resources, followed by appropriate pricing that is inclusive of all environmental costs, with new opportunities for mining in the wastes we generate, is also discussed. Findings demonstrate the need for a life cycle perspective in closing the loop between mining, production, consumption and waste generation as the way forward.     

Indoor metallic pollution related to mining activity in the Bolivian Altiplano

The environmental pollution associated with mining and metallurgical activities reaches its greatest extent in several Andean cities and villages. Many locations in this area have accumulated through centuries a large amount of mining wastes, often disregarding the magnitude of this situation. However, in these naturally mineralized regions, there is little information available stating the exact role of mining and metallurgical industries in urban pollution. In this study, we demonstrated that the various metallic elements present in indoor dust (As, Cd, Cu, Pb, Sb, Sn, Zn) had a common origin and this contamination was increased by the proximity to the mines. Lead dust concentration was found at concerning levels for public health. In addition, wrong behaviors such as carrying mining workwear home contributed to this indoor dust pollution. Consequently, the constant exposure of the population could represent a potential health hazard for vulnerable groups, especially children.     

The Use of a Multimedia Risk Analysis Approach in Designing Waste Management Strategies

ABSTRACT

A pollution source may release residuals to any of several environmental media, depending on the process design and control strategies. These residuals then are subject to transfer, transport, and transformation within the interconnected compartments of the environmental system. The exposure and susceptibility of people and other receptors to pollutants are different in these various media, and so the risks imposed will vary according to the fate of the pollutants in the system. Because of interactions between compartments in the system, a single-medium approach to environmental management that mitigates problems in one environmental medium at a time independently of risks through other media may not minimize the aggregate risk a receptor receives from all pathways. Alternatively, a multimedia approach advocates focusing on the full environmental system providing pathways for exposure and selecting risk management strategies based on minimization of the aggregate and cumulative risk from all pathways and all compounds. This study combines multimedia risk analysis and an optimization framework to examine a methodology for selecting waste treatment/disposal and pollution control measures, applies the methodology to a sludge management decision problem, and considers the implications for continued use of single-medium analyses.     

Assessment of Aquifer Vulnerability in an Agricultural Area in Spain Using the DRASTIC Model

The assessment of aquifer vulnerability is a very important task, especially in agricultural areas because the quality and availability of groundwater affects both the sustainability of agriculture and the quality of life. In this study, an integrated approach is considered, with the use of the generic and agricultural DRASTIC models as well as a geographic information system (GIS), to assess groundwater vulnerability in the agricultural area of Barrax, in the province of Albacete, in Spain. Seven parameters—depth to water, net recharge, aquifer media, soil media, topography, impact of vadose zone media, and hydraulic conductivity of the aquifer (DRASTIC)—have been considered as weighted layers to enable an accurate groundwater risk mapping. The results of the generic DRASTIC model indicated very low vulnerability to contamination for Barrax groundwater due to limited urban and industrial development in the wider area. However, agricultural activities impose pressure to groundwater resources and the results of the agricultural DRASTIC model show that 6.86% of the study area is characterized by very high, 2.29% by high, 47.28% by medium, 38.28% by low, and the remaining 5.29% by no vulnerability to groundwater contamination. The distribution of nitrate concentration in groundwater in the area under study is quite well correlated with the agricultural DRASTIC vulnerability index. Sensitivity analysis was also performed to acknowledge statistical uncertainty in the estimation of each parameter used, to assess its impact, and thus to identify the most critical parameters that require further investigation. Depth to water and impact of vadose zone are the parameters that had the most noticeable impact on the generic DRASTIC vulnerability index followed by the soil media and topography. In contrast, the agricultural DRASTIC method is more sensitive to the removal of the depth to water parameter followed by the topography and the soil media parameters.     

Multimedia fate modeling and comparative impact on freshwater ecosystems of pharmaceuticals from biosolids-amended soils

This study modeled the impact on freshwater ecosystems of pharmaceuticals detected in biosolids following application on agricultural soils. The detected sulfonamides and hydrochlorothiazide displayed comparatively moderate retention in solid matrices and, therefore, higher transfer fractions from biosolids to the freshwater compartment. However, the residence times of these pharmaceuticals in freshwater were estimated to be short due to abiotic degradation processes. The non-steroidal anti-inflammatory mefenamic acid had the highest environmental impact on aquatic ecosystems and warrants further investigation. The estimation of the solid-water partitioning coefficient was generally the most influential parameter of the probabilistic comparative impact assessment. These results and the modeling approach used in this study serve to prioritize pharmaceuticals in the research effort to assess the risks and the environmental impacts on aquatic biota of these emerging pollutants.     

Air quality impacts of power plant emissions in Beijing

The CALMET/CALPUFF modeling system was applied to estimate the air quality impacts of power plants in 2000 and 2008 in Beijing, and the intake fractions (IF) were calculated to see the public health risks posed. Results show that in 2000 the high emission contribution induced a relatively small contribution to average ambient concentration and a significant impact on the urban area (9.52 microg/m(3) of SO(2) and 5.29 microg/m(3) of NO(x)). The IF of SO(2), NO(x) and PM(10) are 7.4 x 10(-6), 7.4 x 10(-6) and 8.7 x 10(-5), respectively. Control measures such as fuel substitution, flue gas desulfurization, dust control improvement and flue gas denitration planned before 2008 will greatly mitigate the SO(2) and PM(10) pollution, especially alleviating the pressure on the urban area to reach the National Ambient Air Quality Standard (NAAQS). NO(x) pollution will be mitigated with 34% decrease in concentration but further controls are still needed.     

The Potential of Current- and Wind-Driven Transport for Environmental Management of the Baltic Sea

The ever increasing impact of the marine industry and transport on vulnerable sea areas puts the marine environment under exceptional pressure and calls for inspired methods for mitigating the impact of the related risks. We describe a method for preventive reduction of remote environmental risks caused by the shipping and maritime industry that are transported by surface currents and wind impact to the coasts. This method is based on characterizing systematically the damaging potential of the offshore areas in terms of potential transport to vulnerable regions of an oil spill or other pollution that has occurred in a particular area. The resulting maps of probabilities of pollution to be transported to the nearshore and the time it takes for the pollution to reach the nearshore are used to design environmentally optimized fairways for the Gulf of Finland, Baltic Proper, and south-western Baltic Sea.