NITROGEN AND PHOSPHORUS IN WATER AS RELATED TO ENVIRONMENTAL SEVI'ING IN NEBRASKA1

ABSTRACT: Spatial distributions of nitrogen and phosphorus in water were related to environmental setting as part of a regional water-quality assessment of the Central Nebraska Basins. The environmental settings (Sandhills, Loess Hills, Glaciated Area, and Platte Valley) were characterized by different concentrations of nitrogen and phosphorus in ground water and stream water. Statistically significant differences in nitrate concentrations in both ground-water and stream-water samples were related to regional distributions of cropland and rangeland. Nitrate concentrations were larger, especially in shallow ground water, in environmental settings dominated by cropland and associated fertilizer use than in settings dominated by rangeland. Similarly, total-nitrogen and nitrate concentrations were relatively large in selected streams draining primarily cropland. Comparative concentrations of phosphorus in stream water on the basis of environmental setting were similar to those of nitrogen, although the largest phosphorus concentrations probably relate to wastewater discharge into small streams. Nitrogen and phosphorus concentrations in much of the Platte River apparently reflected the quality of water entering the study unit from upstream and limited base-flow contributions from within the Platte Valley itself.     

NUTRIENT MASS BALANCE AND TRENDS,MOBILE RIVER BASIN,ALABAMA, GEORGIA,AND MISSISSIPPI1

ABSTRACT: A nutrient mass balance — accounting for nutrient inputs from atmospheric deposition, fertilizer, crop nitrogen fixation, and point source effluents; and nutrient outputs, including crop harvest and storage — was calculated for 18 subbasins in the Mobile River Basin, and trends (1970 to 1997) were evaluated as part of the U.S. Geological Survey National Water Quality Assessment (NAWQA) Program. Agricultural nonpoint nitrogen and phosphorus sources and urban nonpoint nitrogen sources are the most important factors associated with nutrients in this system. More than 30 percent of nitrogen yield in two basins and phosphorus yield in eight basins can be attributed to urban point source nutrient inputs. The total nitrogen yield (1.3 tons per square mile per year) for the Tombigbee River, which drains a greater percentage of agricultural (row crop) land use, was larger than the total nitrogen yield (0.99 tons per square mile per year) for the Alabama River. Decreasing trends of total nitrogen concentrations in the Tombigbee and Alabama Rivers indicate that a reduction occurred from 1975 to 1997 in the nitrogen contributions to Mobile Bay from the Mobile River. Nitrogen concentrations also decreased (1980 to 1995) in the Black Warrior River, one of the major tributaries to the Tombigbee River. Total phosphorus concentrations increased from 1970 to 1996 at three urban influenced sites on the Etowah River in Georgia. Multiple regression analysis indicates a distinct association between water quality in the streams of the Mobile River drainage basin and agricultural activities in the basin.     

Land Use,Geology, Enrichment,and Stream Biota in the Eastern Ridge and Valley Ecoregion: Implications for Nutrient Criteria Development1

Abstract: The eastern panhandle region of West Virginia is entirely within the Appalachian Ridge and Valley ecoregion. It is underlain by limestone in the eastern part and by shale and sandstone in the western part. Agricultural and urban development has affected the condition of the streams of this region. We examined samples from 165 stations in the Ridge and Valley, collected from 1998 to 2004. Land use, geological characteristics, physical and chemical parameters, and algal and macroinvertebrate assemblages were used to identify potential stressors that affect streams in the region. Our analyses indicated that both human land uses and ecoregional differences led to elevated nutrient concentrations in streams of the study areas. Multiple regression analyses indicated that both agricultural and urban land use in the watershed were associated with high nutrient concentrations (NO₂₊₃, total nitrogen, and total phosphorus) in streams. These elevated nutrient concentrations have led to increased algal biomass, increased trophic state, and degradation of macroinvertebrate community in the streams. Values of the West Virginia Stream Condition Index, as well as several other benthic macroinvertebrate metrics, decreased with increased nutrient concentrations and conductivity, especially in the limestone region. When regional differences were partitioned out in the analysis, nutrient concentrations became the strongest stressor in the limestone region while conductivity exhibited less of an effect on macroinvertebrate metrics. Meanwhile, periphyton diagnostic metrics also responded to increased nutrient concentrations, suggesting nutrients could be a cause of biological degradation in the Eastern Ridge and Valley region. Multiple approaches and multiple lines of evidence (reference approach and stressor‐response approach) were applied to develop nutrient benchmarks for different geological regions in the study watershed.     

NITROGEN AND PHOSPHORUS IN SURFACE WATERS OF THE UPPER COLORADO RWER BASIN1

ABSTRACT: As part of a basinwide water-quality study, nitrogen and phosphorus data for the Upper Colorado River Basin from the Colorado-Utah State line to the Continental Divide were analyzed for spatial distributions, concentrations associated with various land uses, and temporal trends. Nitrogen and phosphorus concentrations generally increased in a downstream direction. Some nutrient concentrations were elevated at some sites in the upper parts of the basin in areas influenced by increasing urbanization. Sites were grouped according to land use and site type, and median nutrient concentrations were compared among groups. Sites within the agricultural areas of the basin generally had the highest concentrations of nitrogen and phosphorus; concentrations for main-stem, tributary, and urbanization sites were slightly lower than for the agricultural sites. Background sites, or sites with minimal land-use impacts, had very low median nutrient concentrations. Several sites with long-term data were analyzed for temporal trends in concentrations. Several statistically significant downward trends of low and moderate magnitude were observed for nitrogen and phosphorus species. No upward trends were observed in the data at any site.     

RELATION BETWEEN STREAM-WATER QUALITY AND GEOHYDROLOGY DURING BASE-FLOW CONDITIONS,ROBERTS CREEK WATERSHED,CLAYTON COUNTY,IOWA1

ABSTRACT: An investigation to determine the relation between stream water quality and geohydrology in the Roberts Creek watershed, Clayton County, Iowa, was conducted during selected base-flow periods in 1988–90. Discharge measurements were made and water samples collected for analyses of nutrients and selected herbicides in 19 subbasins along the main stem and tributaries of Roberts Creek. The areal extent of unconsolidated and bedrock units subcropping in each subbasin was quantified. The hydrologic data were correlated statistically with the geologic data to determine relations. Roberts Creek generally gained water and had larger nitrogen concentrations in subbasins in which bess and alluvial material were underlain primarily by low-permeability till and shale units. Roberts Creek generally lost water and had lower nitrate concentrations in subbasins with subcroppmg karstic units. Nitrogen concentrations decreased in streams underlain by the karstic units because the nitrogen removed by biological processes was not replaced by ground-water inflow. Seepage from Roberts Creek to ground water in areas of subcropping karstic carbonate rocks reduced the flow, which reduced the velocity, causing increased residence time of water in the stream. The additional residence time may allow additional time for biological processes to remove nitrogen from solution. There was no significant relation between dissolved orthophosphate or atrazine and the underlying geology.     

ACIDIFICATION AND FISH OCCURRENCE IN THE UPPER CHEAT RWER DRAINAGE,WEST VIRGINIA1

ABSTRACT: The decline of many fish populations within the mid-Appalachian region has been attributed to stream acidification as a result of acid precipitation. Many previous attempts to examine relationships between fish occurrence and acidification have been hindered by a lack of data on water quality and fish distributions. To assess relationships between water quality and bedrock type in the upper Cheat River drainage, we used EPA STORET water quality data (1969–1993) and calculated mean pH and mean alkalinity of streams associated with four bedrock types (Hampshire, Chemung, Mauch Chunk, and Pottsville). We examined the relationship between fish occurrence and bedrock type for 53 headwater streams. We found that acidity in headwater streams associated with Pottsville and Mauch Chunk groups often exceeded biological thresholds for acid-sensitive fish species (pH < 5.5). Streams associated with the Pottsville group typically had fewer cyprinid species and fewer total species than those associated with Mauch Chunk, Chemung, and Hampshire bedrock types. The congruent occurrence of streams with low buffering capacity, streams with pH > 5.5, and streams with low fish species richness indicate that acidification has influenced fish distributions in the upper Cheat River drainage.     

DISTRIBUTION OF NITRATE AND ORTHOPHOSPHATE IN SELECTED STREAMS IN CENTRAL NEBRASKA1

ABSTRACT: The Central Nebraska Basins is one of 60 study units in the National Water-Quality Assessment Program of the U.S. Geological Survey. The study unit includes the Platte River and two major tributaries, the Loup and Elkhorn Rivers. Agriculture is the predominant land use in the study unit, with only eight urbanized communities exceeding a population of 10,000. Water samples were collected from selected streams in the study unit during 1993–1995. The data were used to assess the distribution of nitrogen compounds and phosphorus in the streams and to relate the concentrations of these constituents to environmental settings. This article focuses on dissolved nitrate and orthophosphate. Dissolved nitrate concentrations were highest (90th percentiles were less than 7.0 milligrams per liter as nitrogen) in areas with extensive cropland and pasture, where chemical fertilizers are intensively applied. Synoptic measurements conducted in March and August 1994 indicate that relatively little residual fertilizer, as nitrate, applied during a single crop-growing season enters streams. Dissolved nitrate concentrations showed a seasonal pattern, being highest during winter months and lowest during the late spring and summer. Dissolved orthophosphate concentrations tended to be low across the study unit, 90 percent of all analyses did not exceed 1.7 milligrams per liter as phosphorus.     

DROUGHT EFFECTS ON WATER QUALITY IN THE SOUTH PLATTE RIVER BASIN,COLORADO1

ABSTRACT: Twenty‐three stream sites representing a range of forested, agricultural, and urban land uses were sampled in the South Platte River Basin of Colorado from July through September 2002 to characterize water quality during drought conditions. With a few exceptions, dissolved ammonia, Kjeldahl nitrogen, total phosphorus, and dissolved orthophosphate concentrations were similar to seasonal historical levels in all land use areas during the drought. At some agricultural sites, decreased dilution of irrigation return flow may have contributed to higher concentrations of some nutrient species, increased primary productivity, and higher dissolved oxygen concentrations. At some urban sites, decreased dilution of base flow and wastewater treatment plant effluent may have contributed to higher dissolved nitrite‐plus‐nitrate concentrations, increased primary productivity, and higher dissolved oxygen concentrations. Total pesticide concentrations in urban and agricultural areas were not consistently higher or lower during the drought. At most forested sites, decreased dilution of ground water‐derived calcium bicarbonate type base flow likely led to elevated pH and specific‐conductance values. Water temperatures at many of the forested sites also were higher, contributing to lower dissolved oxygen concentrations during the drought.     

AGRICULTURAL LAND USE EFFECTS ON NITRATE CONCENTRATIONS IN A MATURE KARST AQUIFER1

ABSTRACT: The impact on water quality by agricultural activity in karst terrain is an important consideration for resource management within the Appalachian Region. Karst areas comprise about 18 percent of the Region's land area. An estimated one-third of the Region's farms, cattle, and agricultural market value are on karst terrain. Nitrate concentrations were measured in cave streams draining two primary land management areas. The first area was pasture serving a beef cow-calf operation. The second area was a dairy. Nitrate-N concentrations were highest in cave streams draining the dairy and a cave stream draining an area of pasture where cattle congregate for shade and water. The dairy contributed about 60 to 70 percent of the nitrogen load increase in the study section of the cave system. It was concluded that agriculture was significantly affecting nitrate concentrations in the karst aquifer. Best management practices may be one way to protect the ground water resource.     

NUTRIENT CONCENTRATIONS IN WASTEWATER TREATMENT PLANT EFFLUENTS,SOUTH PLATTE RWER BASIN1

ABSTRACT: Accurate data about nutrient concentrations in wastewater treatment plant effluents are needed for river basin water-quality studies. As part of the U.S. Geological Survey's National Water-Quality Assessment Program in the South Platte River Basin, nutrient data were requested from 31 wastewater-treatment plants located in the basin. This article describes the types of nutrient data available from the plants, examines the variability of effluent nutrient concentrations, and discusses methods for estimation of nutrient concentrations where data are lacking. Ammonia was monitored at 88 percent of the plants, nitrite plus nitrate was monitored at 40 percent of the plants, and organic nitrogen and phosphorus were monitored at less than 25 percent of the plants. Median total nitrogen concentrations and median total phosphorus concentrations were small compared to typical literature estimates for wastewater-treatment plants with secondary treatment. Nutrient concentrations in effluent from wastewater-treatment plants varied widely between and within plants. For example, ammonia concentrations varied as much as 5 mg/L during a day, as much as 10 mg/L from day to day, and as much as 30 mg/L from summer to winter within a plant. In the South Platte River Basin, estimates of median annual ammonia and nitrite plus nitrate concentrations can be improved based on plant processes; and nitrite plus nitrate and organic nitrogen concentrations can be estimated based on ammonia concentrations. However, to avoid large estimation errors, more complete nutrient data from wastewater-treatment plants are needed for integration into river basin water quality studies. The paucity of data hinders attempts to evaluate the relative importance of point source and nonpoint source nutrient loadings to rivers.     

NONPOINT SOURCE POLLUTION POTENTIAL IN AN AGRICULTURAL WATERSHED IN NORTHWESTERN PENNSYLVANIA1

ABSTRACT: A 155,947 ha portion of the Shenango River watershed in western Pennsylvania was evaluated as to the potential impact of agriculture drainage on water quality. Approximately a third of the area is being used as either cropland or pasture with approximately an equal percentage in forest lands. Eleven subwatersheds were evaluated as to their potential for nonpoint source pollution according to the criteria established by the Pennsylvania Department of Environmental Resources for the Chesapeake Bay Pollution Abatement Program. The individual components and overall rating for each subwatershed were then evaluated as to their correlation with four water quality variables based on 104 samples collected at 26 sampling stations throughout the watershed. There was a significant correlation between the overall rating factor for each subwatershed and each of the four water quality variables. In general, the watershed delivery factor, animal nutrient factor, and management factors were correlated with fecal coliform and phosphorus in the receiving streams, whereas the ground water delivery factor appeared to be more important in determining nitrate concentrations in these streams. These results indicate that manure and nutrient management, along with the exclusion of livestock from streams and the enhancement and/or replacement of riparian wetlands, are important approaches in reducing agricultural impacts in fresh water ecosystems.     

NUTRIENT CONCENTRATIONS AND YIELDS IN UNDEVELOPED STREAM BASINS OF THE UNITED STATES1

ABSTRACT: Data from 85 sites across the United States were used to estimate concentrations and yields of selected nutrients in streams draining relatively undeveloped basins. Flow‐weighted concentrations during 1990–1995 were generally low with median basin concentrations of 0.020, 0.087, 0.26, 0.010, and 0.022 milligrams per liter (mg/L) for ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus, respectively. The flow‐weighted concentration of nitrate exceeded 0.6 mg/L in only three basins. Total nitrogen exceeded 1 mg/L in only four basins, and total phosphorus exceeded 0.1 mg/L in only four basins. The median annual basin yield of ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus was 8.1, 26, 86, 2.8, and 8.5 kilograms per square kilometer, respectively. Concentrations and yields of nitrate tended to be highest in northeastern and mid‐Atlantic coastal states and correlated well with areas of high atmospheric nitrogen deposition. Concentrations and yields of total nitrogen were highest in the southeastern part of the nation and in parts of the upper Midwest. In the northeast, nitrate was generally the predominant form of nitrogen, and in the southeast and parts of the upper Midwest, organic nitrogen was the dominant form. Concentrations of total phosphorus were generally highest in the Rocky Mountain and Central Plain states.     

NUTRIENTS DISCHARGED TO THE MISSISSIPPI RIVER FROM EASTERN IOWA WATERSHEDS, 1996.19971

ABSTRACT: The introduction of nutrients from chemical fertilizer, animal manure, wastewater, and atmospheric deposition to the eastern Iowa environment creates a large potential for nutrient transport in watersheds. Agriculture constitutes 93 percent of all land use in eastern Iowa. As part of the U.S. Geological Survey National Water Quality Assessment Program, water samples were collected (typically monthly) from six small and six large watersheds in eastern Iowa between March 1996 and September 1997. A Geographic Information System (GIS) was used to determine land use and quantify inputs of nitrogen and phosphorus within the study area. Streamliow from the watersheds is to the Mississippi River. Chemical fertilizer and animal manure account for 92 percent of the estimated total nitrogen and 99.9 percent of the estimated total phosphorus input in the study area. Total nitrogen and total phosphorus loads for 1996 were estimated for nine of the 12 rivers and creeks using a minimum variance unbiased estimator model. A seasonal pattern of concentrations and loads was observed. The greatest concentrations and loads occur in the late spring to early summer in conjunction with row‐crop fertilizer applications and spring nmoff and again in the late fall to early winter as vegetation goes into dormancy and additional fertilizer is applied to row‐crop fields. The three largest rivers in eastern Iowa transported an estimated total of 79,000 metric tons of total nitrogen and 6,800 metric tons of total phosphorus to the Mississippi River in 1996. The estimated mass of total nitrogen and total phosphorus transported to the Mississippi River represents about 19 percent of all estimated nitrogen and 9 percent of all estimated phosphorus input to the study area.     

Controls on Nutrients Across a Prairie Stream Watershed: Land Use and Riparian Cover Effects

Nutrient inputs generally are increased by human-induced land use changes and can lead to eutrophication and impairment of surface waters. Understanding the scale at which land use influences nutrient loading is necessary for the development of management practices and policies that improve water quality. The authors assessed the relationships between land use and stream nutrients in a prairie watershed dominated by intermittent stream flow in the first-order higher elevation reaches. Total nitrogen, nitrate, and phosphorus concentrations were greater in tributaries occupying the lower portions of the watershed, closely mirroring the increased density of row crop agriculture from headwaters to lower-elevation alluvial areas. Land cover classified at three spatial scales in each sub-basin above sampling sites (riparian in the entire catchment, catchment land cover, and riparian across the 2 km upstream) was highly correlated with variation in both total nitrogen (r² = 53%, 52%, and 49%, respectively) and nitrate (r² = 69%, 65%, and 56%, respectively) concentrations among sites. However, phosphorus concentrations were not significantly associated with riparian or catchment land cover classes at any spatial scale. Separating land use from riparian cover in the entire watershed was difficult, but riparian cover was most closely correlated with in-stream nutrient concentrations. By controlling for land cover, a significant correlation of riparian cover for the 2 km above the sampling site with in-stream nutrient concentrations could be established. Surprisingly, land use in the entire watershed, including small intermittent streams, had a large influence on average downstream water quality although the headwater streams were not flowing for a substantial portion of the year. This suggests that nutrient criteria may not be met only by managing permanently flowing streams.     

The Influence of Two‐Stage Ditches with Constructed Floodplains on Water Column Nutrients and Sediments in Agricultural Streams

The two‐stage ditch is a novel management practice originally implemented to increase bank stability through floodplain restoration in channelized agricultural streams. To determine the effects of two‐stage construction on sediment and nutrient loads, we monitored turbidity, and also measured total suspended solids (TSS), dissolved inorganic nitrogen (N) species, and phosphorus (P) after two‐stage ditch construction in reference and manipulated reaches of four streams. Turbidity decreased during floodplain inundation at all sites, but TSS and P, soluble reactive phosphorus (SRP) and total phosphorus (TP) decreased only in the two‐stage ditches with longer duration of inundation. Both TSS and TP were positively correlated within individual streams, but neither were correlated with turbidity. Phosphorus was elevated in the stream to which manure was applied adjacent to the two‐stage reach, but not the reference reach, suggesting that landscape nutrient management plans could restrict nutrient transport to the stream, ultimately determining the efficacy of instream management practices. In addition, ammonium and nitrate decreased in two‐stage reaches with lower initial N concentrations. Overall, results suggest that turbidity, TSS, and TP were reduced during floodplain inundation, but the two‐stage alone may not be effective for managing high inorganic N loads.     

IMPACTS OF URBANIZATION ON NUTRIENT CONCENTRATIONS IN SMALL SOUTHEASTERN COASTAL STREAMS1

ABSTRACT: Coastal watersheds in the southeastern United States are rapidly changing due to population growth and attendant increases in residential development, industry, and tourism related commerce. This research examined spatial and temporal patterns of nutrient concentrations in streams from 10 small watersheds (< 4 km²) that drain into Murrells Inlet (impacted) and North Inlet (pristine), two high salinity estuaries along the South Carolina coast. Monthly grab samples were collected during baseflow during 1999 and analyzed for total and dissolved inorganic and organic forms of nitrogen and phosphorus. Data were grouped into forested wetland creeks (representing predevelopment reference sites), urban creeks, and urban ponds. DON and NH4 concentrations were greater in forested streams than in urban streams. NO3 and TP concentrations were greatest in urban streams. Seasonally, concentrations were highest during summer for TN, NH4, DON, and TP, while NO3 concentrations were greatest during winter. Nutrient ratios clearly highlighted the reduction in organic nitrogen due to coastal development. Multiple regression models to predict instream nutrient concentrations from land use in Murrells Inlet suggest that effects are not significant (small r²). The findings indicate that broad land use/land cover classes cannot be used to predict nutrient concentrations in streams in the very small watersheds in our study areas.     

VARIABLES INDICATING NITRATE CONTAMINATION IN BEDROCK AQUIFERS,NEWARK BASIN,NEW JERSEY1

ABSTRACT: Variables that describe well construction, hydrogeology, and land use were evaluated for use as possible indicators of the susceptibility of ground water in bedrock aquifers in the Newark Basin, New Jersey, to contamination by nitrate from the land surface. Statistical analyses were performed on data for 132 wells located throughout the Newark Basin. Concentrations of nitrate (as nitrogen) did not exceed the U.S. Environmental Protection Agency maximum contaminant level of 10 milligrams per liter (mg/L) in any of the water samples (U.S. Environmental Protection Agency, 1991). Variables that describe hydrogeology and well construction were found not to be statistically significant in relation to concentrations of nitrate. This finding can be attributed to the complex nature of flow in bedrock aquifers and mixing of water from shallow and deep water-bearing zones that occurs within these wells, which are constructed with long open intervals. Distributions of nitrate concentrations were significantly different among land-use groups on the basis of land use within both a 400 and an 800-m radius zone of the well. The median concentrations of nitrate (as N) in water from wells in predominantly urban-residential (2.5 mg/L) and agricultural areas (1.8 mg/L) were greater than the median concentration of nitrate in water from wells in predominantly undeveloped areas (0.5 mg/L).     

NUTRIENT MASS BALANCE FOR THE ALBEMARLE-PAMLICO DRAINAGE BASIN,NORTH CAROLINA AND VIRGINIA, 19901

ABSTRACT: A 1990 nitrogen and phosphorus mass balance calculated for eight National Stream Quality Accounting Network (NASQAN) basins in the Albemarle-Pamlico Drainage Basin indicated the importance of agricultural nonpoint sources of nitrogen and phosphorus and watershed nitrogen retention and processing capabilities. Basin total nitrogen and phosphorus input estimates were calculated for atmospheric deposition (which averaged 27 percent of total nitrogen inputs and 22 percent of total phosphorus inputs); crop fertilizer (27 and 25 percent); animal-waste (22 and 50 percent, respectively); point sources (3 percent each of total nitrogen and total phosphorus inputs); and biological nitrogen fixation (21 percent of total nitrogen inputs). Highest in-stream nitrogen and phosphorus loads were measured in predominantly agricultural drainage areas. Intermediate loads were observed in mixed agricultural/urban drainage areas; the lowest loads were measured in mixed agricultural/forested drainage areas. The difference between the sum of the nutrient input categories and the sum of the in-stream nutrient loads and crop-harvest nutrient removal was assigned to a residual category for the basin. The residual category averaged 51 percent of total nitrogen inputs and 54 percent of total phosphorus inputs.     

ORIGIN AND TRANSPORT OF DISSOLVED CHEMICALS IN A KARST WATERSHED,SOUTHWESTERN ILLINOIS1

ABSTRACT: An extensive base of water quality information emphasizing the effects of land use and hydrology was obtained in the karstified Fountain Creek watershed of southwestern Illinois to help resolve local water quality issues. Agrichemicals dominate the loads of most water quality constituents in the streams and shallow karstic ground water. Only calcium (Ca), magnesium (Mg), Aluminum (A1), and sulfate (SO₄) ions are predominantly derived from bedrock or soils, while agrichemicals contribute most of the sodium (Na), potassium (K), chlorine (Cl), nitrate (NO₃), fluorine (F), phosphorus (P), and atrazine. Concentrations of individual ions correlate with discharge variations in karst springs and surface streams; highly soluble ions supplied by diffuse ground water are diluted by high flows, while less soluble ions increase with flow as they are mobilized from fields to karst conduits under storm conditions. Treated wastewater containing detergent residues dominates the boron load of streams and provides important subordinate loads of several other constituents, including atrazine derived from the Mississippi River via the public water supply. Average surface water concentrations at the watershed outlet closely approximate a 92:8 mixture of karst ground water and treated wastewater, demonstrating the dominance of ground water contributions to streams. Therefore the karst aquifer and watershed streams form a single water quality system that is also affected by wastewater effluent.     

WATER QUALITY IN AGRICULTURAL WATERSHEDS: IMPACT OF RIPARIAN VEGETATION DURING BASE FLOW1

ABSTRACT: Water quality was monitored for 17 months during base flow periods in six agricultural watersheds to evaluate the impact of riparian vegetation on suspended solids and nutrient concentrations. In areas without riparian vegetation, both instream algal production and seasonal low flows appeared to be major determinants of suspended solids, turbidity, and phosphorus concentrations. Peak levels of all parameters were reached during the summer when flows were reduced and benthic algal production was high. Similar summer peaks were reached in streams receiving major point inputs but peaks occurred downstream from the input. Instream organic production was less important in regulating water quality in areas with riparian vegetation and permanent flows. Concentrations of suspended solids remained relatively constant, while phosphorus and turbidity increased in association with leaf fall in autumn. Intermittent flow conditions in summer increased the importance of instream organic production in controlling water quality, even when riparian vegetation was present. Efforts to improve water quality in agricultural watersheds during base flow should emphasize maintenance of riparian vegetation and stable flow conditions.