化工储罐间距和体积对爆炸碎片多米诺效应概率的影响

化工储罐爆炸后将产生大量碎片,这些抛射碎片一旦击中相邻罐体容易引发多米诺效应。碎片的抛射方位和抛射距离具有很大的随机性,已有研究多采用概率模型来描述碎片抛射的各分过程。通过总结和发展已有的分过程模型,建立了求取多米诺效应的综合概率模型,并基于蒙特卡罗算法编制了模拟软件,可对化工储罐多米诺效应的发生概率进行预测计算。选取若干常用化工球罐为相邻目标储罐进行实例分析,计算结果表明储罐间距和体积是影响多米诺效应发生概率的两个重要影响因素：随着距离的增大,多米诺效应发生概率不断减小;目标储罐体积越大,多米诺效应发生概率将越大。其中,爆炸碎片对目标储罐的击中概率受上述因素的影响程度更大。该文工作对化工储罐区的安全评价具有一定的参考价值。     

火灾爆炸事故多米诺效应耦合模型研究

为了评估火灾爆炸事故中相邻储罐由于多米诺效应而引发二次事故的风险,提出了基于热辐射、冲击波超压以及碎片冲击等三种物理效应共同作用下的事故多米诺效应耦合分析模型.模型采用概率组合方法计算事故影响区域内目标对象发生二次事故的最可能组合及概率.研究表明,火灾爆炸事故多米诺效应的产生受到多种因素影响,其中平面布局、防火间距是影响二次事故发生的主要因素.在计算设施失效概率的过程中,考虑了热辐射、爆炸冲击波以及碎片冲击三种物理效应的耦合作用效果,采用影响系数法对二次事故的可能单元组合加以研究.最后,以一储罐区蒸气云爆炸事故为例对可能发生的二次事故进行了模拟,得到了相邻储罐二次事故的单元组合及概率.     

爆炸碎片撞击立式储罐数值模拟

爆炸碎片引发的事故是一种常见的化工园区多米诺效应事故形式。建立了立式拱顶罐的半结构模型以及球体、立方体、圆锥体三种形状的爆炸碎片模型,利用数值模拟,研究储罐在不同形状、速度、入射角的碎片撞击下破坏失效规律,以期更为准确地指导目标设备在多米诺效应事故参数影响下的风险评估。结果表明:罐壁Z轴方向最大位移绝对值随着碎片撞击速度的增大而降低,在相同碎片撞击速度相同的情况下,立方体碎片造成的罐壁Z轴方向最大位移绝对值最大;罐壁贯穿后的孔洞等效直径随入射角的增大而增大,碎片剩余速度随入射角的增大而减小;立方体碎片在贯穿罐壁过程中速度衰减最显著,所需贯穿能量最大。     

苯储罐区消防安全设计评价研究

依据苯储罐区危险特性及超压引起火灾爆炸模式的特点,通过实例,对苯储罐区的危险特性及事故后果进行了分析,得出在外界环境温度不同的条件下所对应的火灾爆炸模式;依据规范,对其消防安全设计现状进行了分析和评价。针对苯储罐区在不同温度条件下引发的火灾爆炸灾害模式,利用冲击波超压伤害准则、TNT当量法、蒸气云爆炸模型、池火灾事故后果模型和碎片抛射模型,定量分析评估了储罐内部空间爆炸性混合物超压爆炸和因爆炸引发的蒸气云爆炸、池火灾的事故后果及碎片抛射事故后果。结果表明:苯储罐区发生蒸气云爆炸产生的危害最大,死亡半径、重伤半径及轻伤半径分别为90.72 m、159.16 m、308.38 m;其次是池火灾,死亡半径、重伤半径及轻伤半径分别为74.25 m、103.12 m、132.16 m;当储罐碎片抛射概率为0.001时,3种充装水平事故罐对应的距离分别为60 m、30 m、40m;给出了设置大流量固定式消防冷却水系统、点火源最小能量控制、提高储罐减压泄爆的能力、增加防火堤内固定灭火设施和拦网等应进一步加强的消防安全措施。     

危化品储罐区多灾种耦合效应风险分析

基于危化品储罐区内发生的多米诺效应，以单灾种引发的多米诺事故研究为基础，根据物理学中的触发器原理解释多灾种耦合引发储罐区其他罐体失效的场景，并提出基于物理学理论的多灾种耦合效应模型；基于一储罐区实例分别建立在火灾、爆炸情况下罐区的灾害扩展网络图，并通过无量纲化处理得到综合灾害扩展网络图；分析储罐区在多储罐受灾情况下的灾害扩展情形，得到当D1，D2发生灾害时，D4，D5灾害扩展概率最大；当D1，D8发生灾害时，D4灾害扩展概率最大，建立了多灾种耦合效应的关联图。研究结果对化工园区多灾种耦合的后果预测评估具有指导意义，有助于减少危化品储罐区多米诺效应的发生以及强化危化品储存的安全基础。     

受限空间爆炸碎片影响分析

受限空间油气泄漏爆炸会产生巨大的能量,爆炸碎片在抛射距离和抛射方位上具有很大随机性,引发的多米诺事故容易对设备和人员造成重大伤害。为了研究爆炸碎片的影响范围及对设备、人员伤害程度,以地下密闭涵道作为研究对象,考虑爆炸能量影响,采用ANSYS Autodyn模拟软件,重点对涵道覆盖物爆炸碎片进行模拟,定量分析了爆炸碎片的影响范围及在影响区域内对设备、人员造成的伤害程度。结果表明:运用Autodyn软件进行仿真,能够更加准确地得出爆炸碎片的抛射情况及影响范围; 在爆炸能量一定的情况下,碎片的大小是影响设备和人员受伤害程度的重要因素。     

大型原油储罐火灾多米诺效应概率计算模型及应用

随着油品储罐区规模的不断扩大,近年来多储罐火灾事故呈上升趋势。现有的储罐防火间距是在以往事故经验的基础上设定的,通过罐组内的火灾多米诺效应概率计算,可从风险的角度为罐组内储罐防火间距的设定提供理论依据。通过综合考虑火灾环境下受辐射储罐失效时间和着火储罐火灾得到控制时间,确定了罐组内火灾多米诺效应的判定原则,并在火灾得到控制时间模型和储罐失效时间模型的基础上建立了火灾多米诺效应概率计算模型。以2万立外浮顶原油储罐为例进行模拟计算,得出在现行标准给出的防火间距下,发生罐组火灾多米诺效应的概率为3.94×10-8/a-1,属于可接受风险,为罐组内储罐的合理布局提供了理论依据。     

多米诺效应中的多事故点协同作用后果研究

为了研究多米诺效应中多事故点协同作用的后果,将并联系统概率模型运用到贝叶斯概率计算过程中,体现出多事故点协同作用对多米诺效应传播的概率影响;后果分析部分从人、物、环境3个方面出发,对事故的后果影响以及事故预防提出建议措施。最后运用模型对实例进行了应用分析,结果表明:多事故点协同作用下储罐的多米诺失效概率增大,罐区危险性增强,可以通过对储罐设置安全屏障等措施,有效的切断导致事故最大概率的链条。     

化工园区储罐多米诺效应的脆弱性评估

为减少化工园储罐区多米诺效应发生概率,找出最容易发生多米诺效应、且对事故影响最大的储罐,评估各储罐的脆弱性等级。首先基于不同领域脆弱性的内涵和多米诺效应的特点,提出多米诺效应情况下储罐脆弱性的定义;然后利用熵权物元可拓模型和风险矩阵法的客观性,并结合复杂网络模型和逼近理想排序法(TOPSIS)模型评估事故网络节点重要度,从初始事故的可能性与传播影响力2个方面,构建多米诺效应下储罐脆弱性分级评估模型;最后应用该模型评估某化工园储罐区各罐体脆弱性等级,并将结果与贝叶斯方法的评估结果对比。结果表明:该模型考虑了储罐自身属性及影响扩展范围,得到的脆弱性分级结果更准确。     

地震诱发储罐火灾多米诺效应的动态定量风险评估方法研究

为评估地震对化工储罐区可能造成的火灾多米诺效应的风险，提出了一种基于蒙特卡洛模拟和矩阵计算的动态风险评估方法。该方法考虑了时空演化过程的不确定性和协同效应，可用于多个储罐着火的主要事件场景和高级别多米诺传播的复杂情况，能够得到可能发生的主要事件场景及其发生概率、储罐群全过程失效概率、特定主要事件场景演化细节，进而指导制定更具针对性的应急管理措施。通过案例分析了不同地震和储罐条件，以及多米诺级别对储罐群多米诺失效概率的影响，验证了该方法的有效性，该方法可为多米诺效应的风险应急管理提供理论依据。     

The analysis of domino effect impact probability triggered by fragments

Explosion fragments are the main cause of domino effect in accidents of the chemical and process industry. A number of significant studies have been conducted to further our understanding of the mutual impact of two major hazard installations (MHIs). This work focused on the development of a new model for the impact probability of domino effect triggered by fragments. Firstly, an expression for the initial projection velocity of fragments was founded by taking the explosion moment as a polytropic process and solving energy transformation equation, then the flight trajectory and velocity were represented by some equations with the flight boundary conditions in flight process under gravity and air friction. With the obtained equations as the objective function, the projection uncertainty was analyzed through sampling of the random variables. Finally, a new systemic model for the impact probability of domino effect is put forward by integrating the flight laws and projection uncertainty of fragments, and the impact probability linear equations with the coefficient matrix of secondary effect were built up in order to calculate the impact probability of domino effect. The study on domino effect impact probability provides some useful insights into the generation mechanism, projection features, flight laws and impacts on targets of the fragments, and also lays a foundation for analysis of domino chain risk caused by explosive fragments in chemical industrial complex.     

Study of the situation deduction of a domino accident caused by overpressure in LPG storage tank area

The production and storage of liquefied petroleum gas (LPG) is gradually becoming larger and more intensive, which greatly increases the risk of the domino effect of an explosion accident in a storage tank area while improving production and management efficiency. This paper describes the construction of the domino effect scene of an explosion accident in an LPG storage tank area, the analysis of the characteristics of the LPG tank explosion shock wave and the target storage tank failure, and the creation of an ANSYS numerical model to derive the development trend and expansion law of the domino accident in the LPG storage tank area. The research showed that: 400 m³ tank T1 explosion shock waves spread to T2, T4, T5, T3, and T6, and the tank overpressures of 303 kPa, 303 kPa, 172 kPa, 81 kPa, and 61 kPa respectively. The critical values of the target storage tank failure overpressure-range threshold were 70 kPa and 60 m. After the explosion of the initial unit T1 tank, at 38 ms, the T2 and T4 storage tanks failed and exploded; at 56 ms, the T5 storage tank exploded for the third time; at 82 ms, the T3 storage tank exploded for the fourth time; and at 102 ms, the T6 storage tank exploded for the fifth time. With the increase of explosion sources, the failure overpressure of the target storage tank increased, and the interval between explosions continuously shortened, which reflected the expansion effect of the domino accident. The domino accident situation deduction in the LPG storage tank area provided a scientific basis for the safety layout, accident prevention and control, emergency rescue, and management of a chemical industry park.     

Investigation of multiple domino scenarios caused by fragments

A model of multiple domino scenarios and the risk of the domino effect, which is a sequential chain escalating from the primary unit to the last unit, is presented in this paper. The trajectories of fragments from all units, the ground distribution of projectiles, and the risk of the sequential chain of the domino effect were calculated using Monte Carlo simulations. The results showed that the range affected by the fragments from each tank included the other tanks, meaning that fragments from one tank could hit the other tanks and cause multiple accidents, and that the sequential chain of the domino effect could indeed happen. The distributions of ground impacts showed that tank fragments were projected over long distances, up to 1200 m from the source. The spatial distribution of the kinetic energy at ground impact for tank fragments was also obtained. Moreover, the magnitudes of the probabilities of the primary, secondary, third, and fourth accidents in the domino chain were respectively about 10⁻⁷, 10⁻¹¹, 10⁻¹⁵, and 10⁻¹⁹. These results showed that for neighboring domino effect units in the same accident chain, the risk of the most recent domino effect was 10⁴ times that of the following domino effect.     

基于贝叶斯网络的事故多级多米诺效应计算方法研究

为了更合理地分析事故风险,提出了基于贝叶斯网络的多级多米诺效应计算方法及其计算步骤,并从个人风险和社会风险2个角度,定量分析了生产安全事故的多级多米诺效应。同时以某企业的2个汽油罐区为例,运用上述方法对其生产安全事故的多米诺效应进行定量计算,并将计算结果与未考虑多米诺效应、仅考虑一级多米诺效应时的计算结果进行比较。研究结果表明:基于贝叶斯网络的计算方法,同时考虑了多级多米诺效应和事故的协同效应,可以使计算的个人风险和社会风险更接近于实际。     

含磷酸盐对聚乙烯粉尘爆燃的抑制影响实验研究

为了揭示含磷酸盐（KH_{2PO4,NH4H2PO4,Ca(H2PO4)2）对聚乙烯粉尘爆炸的抑制作用,通过哈特曼管实验装置和20 L球形爆炸罐,研究含磷酸盐对聚乙烯粉尘爆炸火焰和压力传播特性的抑制效果。采用高速摄影方法记录含磷酸盐对聚乙烯粉尘爆炸火焰传播的影响;采用20 L球形爆炸罐,收集压力传感器数据,分析含磷酸盐对聚乙烯粉尘爆炸压力的影响;采用同步热分析仪研究聚乙烯粉尘和含磷酸盐的热解行为。研究结果表明:含磷酸盐对聚乙烯粉尘爆炸火焰传播特性参数和爆炸压力特性参数均有显著的影响,通过对比得到NH4H2PO4抑制效果相对最好。研究结果可为含磷酸盐在抑爆剂工程应用提供理论基础。}     

Coupling effects of the explosion shock wave and heat radiation on the dynamic response of a fixed-roof tank

The occurrence of leakage in large tank farms or oil deposits can lead to fire or explosion accidents. Coupling effects of fire and explosion loadings can cause considerably more damage to adjacent tanks or buildings than either loading individually does. In this study, the combined loadings of the explosion shock wave and heat radiation from a pool fire on a neighboring empty fixed-roof tank were numerically investigated. The effects of the explosion shock wave intensity and relative height of the explosion center [the ratio of the height of the explosion center to the height of the tank (h_r)] were analyzed. The results indicate that tanks damaged by explosion shock waves have decreased fire resistance and critical buckling temperature. Moreover, the thermal buckling deformation of the predamaged tank largely depends on the explosion shock wave. With an increase in the explosion shock wave intensity or a decrease in h_r, the explosion shock wave has greater influence on the fire resistance of the tank, and the critical buckling temperature decreases. This paper can provide an understanding of the dynamics of a tank under explosion shock wave loading, and of the critical failure criterion and failure modes of a target tank under the coupled loading of the explosion shock wave and an adjacent pool fire.