基于Excel和VBA的汽轮机排汽焓求解

热力性能测试和计算是火电机组热经济性分析的基础,其中排汽焓的确定不容忽视。在分析比较目前各种在线和离线计算方法的基础上,介绍了利用Excel的矩阵函数,配合少量VBA代码,快速求解汽轮机排汽焓的具体方法。该方法以汽轮机及回热系统能量平衡为基础,遵循GB 8117-1987要求并参考ASME PTC6-1996规范。实例计算表明,该方法编程简单,计算快速,可满足汽轮机热力性能试验报告等的需要。     

高频电源在300MW燃煤机组电除尘器节能提效改造中的应用

经国家对火电机组上大压小政策执行以来,300 MW火电机组成为超标排放的主力机组,运行10年以上的该规模机组配套的电除尘器都面临着提效节能的改造.介绍了国电益阳发电有限责任公司2号300 MW燃煤机组电除尘器的节能提效改造工程,提供了一种有针对性的改造实用方法.     

新型射汽抽气消声器

介绍了一种自行设计的、新型的汽轮机启动抽气器排汽消声装置，并对其结构原理和设计特点进行了较详细的叙述。应用实践表明，此种消声器降噪效果明显。     

电除尘器节能控制技术在600MW机组上的应用

结合华能汕头电厂3号炉600MW机组电除尘器节能改造实践,从电控角度总结了电除尘器节能保效技术在火电厂的应用,检测结果表明,改造后的节电率超过70%.     

高频电源在国电永福电厂300MW机组电除尘器改造中应用

介绍了高频电源的性能特点及优势,针对国电永福发电有限公司二期2×300MW机组电除尘器存在的问题,采用HF-01型高频电源对其进行改造。在电除尘器改造中不改变本体结构,采取改变电气中高压电源的运行方式,取得了较好的改造效果,实现了节能提效的目标。     

安徽电力系统科技工作成效显著

1986华以来,安徽电力系统充分利用科技人员密集的优势,依靠科技进步促进电力工作发展,完成科技项目554项,获省级以上科技成果奖92项。投入科技开发资金1352.96万元,取得经济效益12804.35万元。 1.在火电厂机组完善化和提高运行可靠性上下功夫。完成了125MW、200MW机组汽机通汽部分改     

满足新标准采用电除尘新技术改造的应用与分析

提出了现有电除尘器可采用余热利用节能、高频电源、双区结构、隔离振打等新技术进行提效节能改造的思路,分析了这些新技术的技术特性,并进行了实际案例剖析,对满足《火电厂大气污染物排放标准》（GB13223-2011）烟尘排放的要求,形成现有电除尘器的新型改造模式具有重要参考价值。     

高浓度水力除灰系统的运行概况

昆明发电厂在节能改造工程中扩建了两台100MW 机组,烟气收尘采用布袋除尘器,除灰系统为油隔离泵高浓度输灰,两炉灰渣量40t/h 左右。1号机于1987年12月投产,2号机于1988年8月投产。     

新型电除尘技术在200MW机组改造上的应用

介绍了国电双鸭山发电有限公司2号炉200MW机组除尘系统改造项目（原水膜除尘器改造为电除尘器）。由于受场地限制,常规结构除尘器难以布置,故采用EEII-G新型电除尘器,该除尘器是在EEII型电除尘器技术基础上进行了优化改进,较好地利用了现场空间,也取得了满意的除尘效果。     

石灰石—石膏湿法脱硫浆液氟化铝络合原因分析及对策

石灰石—石膏湿法脱硫装置运行过程中,浆液氟化铝络合会影响石灰石的溶解度。以某电厂125MW燃煤机组脱硫改造工程为例,分析脱硫装置吸收塔浆液出现氟化铝缝合物造成石灰石闭塞的原因。依据A l3＋、F-络合原理及组分变化规律,及时采取技术措施,消除了石灰石闭塞,恢复脱硫装置正常运行。     

Effects of washing with water on enzymatic saccharification and d-lactic acid production from steam-exploded sugarcane bagasse

This study investigated the production of d-lactic acid from unutilized sugarcane bagasse using steam explosion pretreatment. The optimal steam pressure for a steaming time of 5?min was determined. The steam-exploded sugarcane bagasse was hydrolyzed using cellulase (Meicelase) and then the hydrolyzate was subjected to fermentation substrate. By enzymatic saccharification using Meicelase, the highest recovery of glucose from raw bagasse, 73.7?%, was obtained at a steam pressure of 20?atm. For extracted residue with water after steam explosion, the glucose recovery increased up to 94.9?% at a steam pressure of 20?atm. These results showed that washing with water is effective in removing enzymatic reaction inhibitors. After steam pretreatment (steam pressure of 20?atm), d-lactic acid was produced by Lactobacillus delbrueckii NBRC 3534 from the enzymatic hydrolyzate of steam-exploded bagasse and washed residue. The conversion rate of d-lactic acid obtained from the glucose concentration was 66.6?% for the hydrolyzate of steam-exploded bagasse without washing with water and 90.0?% for that derived from the extracted residue with water after steam explosion. These results also demonstrated that the hydrolyzate of steam-exploded bagasse (without washing with water) contains fermentation inhibitors and washing with water can remove them.     

Influence of mixed molten carbonate composition on hydrogen formation by steam gasification

Steam gasification in the presence of carbonate compounds is an effective method to recover useful materials from electronic waste streams by converting plastics into gaseous products that can be used for energy production and avoiding the expensive manual disassembly process. We investigated steam gasification of activated carbon in the presence of various mixtures of lithium carbonate, sodium carbonate, and potassium carbonate. The activated carbon was almost completely converted into hydrogen and carbon dioxide at 700°C under 0.1 MPa pressure in the presence of carbonate mixtures. Carbon dioxide was also derived from partial decomposition of lithium carbonate. Steam gasification was accelerated in the presence of various carbonate mixtures and at increasing steam partial pressures. These experimental results show that fluidity of carbonates, the potassium content of the carbonate, and the steam partial pressure are important factors in accelerating steam gasification.     

蒸汽输送半干半湿法烟气脱硫剂/脱硫灰的研究

半干半湿法烟气脱硫工艺采用锅炉蒸汽作为脱硫剂和循环脱硫灰的输送介质,在分析所输送物料的粒度分布、化学成分以及输送过程中物料性质变化的基础上,自行研制了1套蒸汽输送系统。对这种蒸汽输送系统进行了试验研究,结果表明,在蒸汽压力为0.8MPa,温度为200℃时,文丘里喷射器入料口的真空度最高达0.02MPa。该系统可同时输送石灰和粉煤灰两种不同的物料,在蒸汽消耗量只有120 kg/h的条件下,物料总流量达480 kg/h,输送总体积流量为1 040m3/h。     

Steam gasification of epoxy circuit board in the presence of carbonates

To recover useful metals from end-of-life electronic devices and to convert plastic components from these devices into clean fuel gas, steam gasification of epoxy board samples was carried out at 600–700?°C and 0.1?MPa pressure in the presence of a ternary eutectic carbonate (lithium carbonate, sodium carbonate, and potassium carbonate). Hydrogen and carbon dioxide were the main products, and methane and carbon monoxide were detected as minor products. The gasification proceeded in two steps: an initial rapid pyrolysis followed by secondary steam gasification of char produced from the pyrolysis. The ternary eutectic carbonate accelerated not only the latter steam gasification but also the initial rapid pyrolysis. The activation energy for the steam gasification of epoxy board samples in the presence of the carbonate was 122?kJ/mol.     

Evaluation of in situ steam‐injection processes for reduction of petroleum compounds within an abandoned canal

A conceptual approach of a novel application of in‐situ thermal processes that would either use a steam injection process or a steam/surfactant injection process was considered to remediate petroleum contaminated sediment residing in an abandoned canal. Laboratory tests were conducted in an attempt to volatilize or mobilize contaminants of concern (selected polycyclic aromatic hydrocarbons [PAHs]) from the contaminated sediment into a phase that could be physically removed. The processes were operated above ambient temperature and pressure in an attempt to increase the removal of the contaminants of concern from the sediment. The ability of both the steam injection process and the steam/surfactant process to remove PAHs from the sediment was considered ineffective; as only two of the seventeen selected PAHs (naphthalene and C1 naphthalene) were associated with a percentage mass reduction greater than 34% for both treatments (four trials). The steam/surfactant injection process generally resulted in higher reductions than the steam injection process, but had larger variances within the two trials using the treatment type. This preliminary evaluation suggests that steam‐based injection processes for removing petroleum contamination from this canal sediment, using the surfactants selected, equipment set‐up, and operating conditions studied, would be considered ineffective. © 2010 Wiley Periodicals, Inc. *

1 This article is a U.S. Government work and, as such, is in the public domain of the United States of America.

     

锅炉空预器堵灰的原因分析及处理措施

介绍了某电厂空预器的设计特点,该空预器运行过程中出现了一、二次风压与炉膛压力周期性波动、进出口差压偏大的问题.对该空预器实际运行情况的分析研究表明：燃用煤种含硫量超标、吹灰蒸汽带水、冬天暖风器投用不及时以及蓄热元件布置紧密是造成空预器堵灰的关键问题.通过控制入炉煤含硫量、加强吹灰、提高综合冷端温度和蓄热元件改造等措施,保证了空预器安全经济运行.     

Production of hydrogen by steam gasification of dehydrochlorinated poly(vinyl chloride) or activated carbon in the presence of various alkali compounds

Steam gasification of dehydrochlorinated poly(vinyl chloride) (PVC) or activated carbon was carried out in the presence of various alkali compounds at 3.0 MPa and 560°C–660°C in a batch reactor or in a semi-batch reactor with a flow of nitrogen and steam. Hydrogen and sodium carbonate were the main products, and methane and carbon dioxide were the minor products. Yields of hydrogen were high in the presence of sodium hydroxide and potassium hydroxide. The acceleration effect of the alkali compounds on the gasification reaction was as follows: KOH > NaOH > Ca(OH)₂ > Na₂CO₃. The rate of gasification increased with increasing partial steam pressure and NaOH/C molar ratio. However, the rate became saturated at a molar ratio of NaOH/C greater than 2.0.     

The potential of SO2 for reducing corrosion in WtE plants

Due to the high-temperature boiler corrosion induced by chloride-rich fly ash deposits, steam generation in today’s Waste-to-Energy (WtE) plants is typically designed only for 40 bar/400 °C as an economic compromise between acceptable corrosion rate and maximum power generation. The high-corrosive metal chlorides in the fly ash can react with SO₂ forming low-corrosive sulfates. The sulfation efficiency is enhanced by high SO₂ levels and sufficient residence time of the flue gas at high-temperatures (700–900 °C). The fly ash sulfation was tested in full scale in a Swedish WtE plant by applying the economic sulfur recirculation method. Probes of several alloys (16Mo3, Inconel 625, Sanicro 28) were exposed for 1000 h at controlled material temperatures in the superheater position, at normal and during sulfating operation respectively. Analyses of the fly ash showed that the molar Cl/S was decreased to values well below 1 and the corresponding corrosion rates of the individual material samples were less than half when sulfur recirculation was in operation. These positive findings demonstrate that the sulfur recirculation process has high potential for low-corrosive high-temperature steam generation (T ≈ 500 °C) and improved electricity production. Further steam superheating can be realized by staged superheating using small amounts of secondary fuel.     

Augmenting in-situ remediation by soil vapor extraction with six-phase soil heating

The use and performance of soil vapor extraction (SVE) as an in-situ remedial technology has been limited at numerous sites because of both geologic and chemical factors. SVE systems are not well suited to sites containing low permeability soils or sites contaminated with recalcitrant compounds. Six-phase soil heating (SPSH) has been developed by the Battelle Pacific Northwest Laboratories (Battelle) to enhance SVE systems. The technology utilizes resistive soil heating to increase the vapor pressure of subsurface contaminants and to generate an in-situ source of steam. The steam strips contaminants sorbed onto soil surfaces and acts as a carrier gas, providing an enhanced mechanism by which the contaminants can reach an extraction well. Full-scale applications of SPSH have been performed at the U.S. Department of Energy's Savannah River Site in Aiken, South Carolina; at a former fire training site in Niagara Falls, New York; and at Fort Richardson near Anchorage, Alaska. At each site, chlorinated solvents were present in low permeability soils and SPSH was applied in conjunction with SVE. The results of the three applications showed that SPSH is a cost-effective technology that can reduce the time required to remediate a site using only conventional SVE.     

Laboratory development and field demonstration of self-sealing/self-healing landfill liner

The self-sealing/self-healing (SS/SH) barrier concept is based on the principle that two or more parent materials placed in vertical or horizontal layers will react at their interfaces to form insoluble reaction products. These products constitute a seamless impermeable seal, which is resistant to the transmission of leachate and contaminants. A SS/SH liner formulation was developed in the laboratory and demonstrated at the Sudokwon landfill site in South Korea. Laboratory testing results indicated that a seal with a hydraulic conductivity less than 10(-9) m/s formed after two to four weeks of curing at room temperature, and the seal healed itself after it was fractured. The use of the soil from the Sudokwon landfill site instead of sand as the matrix of the parent materials in the SS/SH liner retarded the sealing and healing of the seal, but did not show an obvious effect on the overall sealing and healing capacity of the seal at early stages. The construction and installation of the field demonstration SS/SH liner were carried out in the same way as for a soil cement liner. The quality of the liner was ensured by the enforcement of quality analysis/quality control procedures during installation. A single sealed ring infiltration test was performed on the field demonstration liner 36 days after the installation was completed. The measurement of water infiltration rate indicated that the liner healed after it was fractured. However, the long-term sealing and healing capacity needs to be further investigated.