职业卫生监督存在的问题及对策

目前我国职业卫生监督存在的主要问题是管理模式、监测手段滞后,技术力量薄弱,监督人员结构不合理.企业职业卫生法制意识淡薄,有毒有害作业场所缺乏卫生防护设施,不重视个人防护、定期监测和健康体检.今后应建立高效的职业安全卫生一体化管理体制,强化政府职业卫生监督管理职能.监督的重点放在作业场所,并逐渐由监督检查向服务转变.应增强监督机构的技术力量,加强职业卫生法律法规的宣传和职业卫生培训,建立监督规范、标准体系,促使职业卫生监督向规范化、程序化、专业化发展.     

浅谈我国职业病防治现状及其对策

针对目前我国职业病高发的现状,从企业职业病危害因素的产生、相关部门监督及职业卫生人才短缺等环节存在的问题进行剖析,探讨下一步职业卫生管理努力的方向及对策.     

某石化企业职业卫生检测现状分析

通过收集某石化企业近两年的日常检测数据,并结合企业的职业卫生管理及防护设施运行情况,分析了该企业的职业卫生检测现状.     

炼化企业重点岗位职业卫生管理探讨

炼化企业职业危害种类多、分布范围广，但是职业卫生管理人员特别是专业专职管理人员较少，职业卫生管理难度大。要想做好炼化企业的职业卫生工作，就需要针对重点岗位，进行分级管理、重点管理，利用有限的管理资源，抓住主要矛盾，控制职业病的发生。本文以炼化企业毒物、粉尘、噪声等职业危害因素比较突出的化验岗位、热电燃料岗位和汽轮机岗位为例，探讨重点岗位的职业卫生管理。     

炼化企业承包商职业卫生管理存在问题及对策分析

“以人为本”、“体面工作,健康生活,让每个劳动者有尊严地活着”等和谐发展理念对企业职业卫生管理工作提出了更高的标准和要求,尤其对承包商的职业卫生管理,足当前企业抓好职业卫生管理工作必须面临的重要课题。通过对承包商职业卫生管理工作的分析和探讨,查找存在的主要问题,提出对策措施,加强对承包商的职业卫生管理,可以提升管理水平,创造和偕发展、健康发展的良好局面。     

石化企业HSE管理体系审核中有关“职业健康”的审核要点

依据《中华人民共和国职业病防治法》及有关法律法规、标准规范的要求,逐一分解了中国石化HSE管理体系各要素中"职业健康"的审核要点,为企业内审员、职业卫生管理人员全面、准确地进行职业健康日常监督和内部审核提供参考。     

石化企业职业危害风险评估与控制系统工具开发及应用

依据石化企业职业危害风险评估方法,参考国外职业危害风险评估工具,开发一套石化企业职业危害风险评估与控制系统工具,介绍了系统工具各部分的设计,并进行了应用举例。该工具可以对作业场所、作业活动的职业危害进行风险评估,为企业及职业卫生管理部门提供技术支持。     

某石油化工企业橡胶生产装置职业病危害现状评价

采用职业卫生调查法、检测检验法、工程分析法对某石油化工企业橡胶生产装置工作场所职业病危害因素进行识别、分析和评价,确定了职业病危害关键控制点,对企业的职业卫生管理提出了建议。     

职业卫生与安全─—化工企业发展的优先任务

1职业卫生与安全工作的基本概念职业卫生与安全的概念主要来自英美等资本主义的国家，我国随着改革开放的深人发展和企业现代化管理的实现，安全与卫生（甚至包括环保）之间的内在联系更为密切，职业卫生成为职业安全工作的主要内容。因为燃烧、爆炸、泄漏等安全问题已纳入工程标准，通过预先制订安全操作规程，使安全操作的管理目标非常明确。而职业卫生问题不易被识别，对其认识有一个漫长的过程，而且会随着科学的发展不断有新的认识，因而不容易得到控制。加上职业卫生涉及学科范围广（毒理学、流行病学、人机工效学、生物物理学等），…     

某石化企业实验室职业病危害因素控制

分析了某石化企业质量管理中心实验室职业卫生状况及职业病危害因素产生途径,提出职业病危害因素监测、职业卫生隐患治理、职业健康监护、劳动保护用品使用等控制措施.     

Exploration of relationships between phytoplankton biomass and related environmental variables using multivariate statistic analysis in a eutrophic shallow lake： A S-year study

Understanding the process of the changing phytoplankton patterns can be particularly useful in water quality improvement and management decisions. However, it is generally not easy to illustrate the interactions between phytoplankton biomass and related environmental variables given their high spatial and temporal heterogeneity. To elucidate relationships between them, in a eutrophic shallow lake, Taihu Lake, relative long-term data set of biotic and abiotic parameters of water quality in the lake were conducted using multivariate statistical analysis within seasonal periodicity. The results indicate that water temperature and total phosphorus （TP） played governing roles in phytoplankton dynamics in most seasons （i.e. temperature in winter, spring and summer; TP in spring, summer and autumn）; COD （chemical oxygen demand） and BOD （biological oxygen demand） presented significant positive relationships with phytoplankton biomass in spring, summer and autumn. However, a complex interplay was found between phytoplankton biomass and nitrogen considering significant positive relationships occurring between them in spring and autumn, and conversely negative ones in summer. As the predatory factor, zooplankton presented significant grazing-pressure on phytoplankton biomass during summer in view of negative relationship between them in the season. Significant feedback effects of phytoplankton development were identified in summer and autumn in view that significant relationships were obser,qed between phytoplankton biomass and pH, Trans （transparency of water） and DO. The results indicate that interactions between phyto：plankton biomass and related environmental variables are highly sensitive to seasonal periodicity, which improves understanding of different roles of biotic and abiotic variables upon phytoplankton variability, and hence, advances management methods for eutrophic lakes.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Intraspecific differences in effects of co-contamination of cadmium and

A hydroponic experiment was carried out to study intraspecific differences in the effects of different concentrations of cadmium (Cd)(0-10 mg/L) and arsenate (As(V)) (0-8 mg/L) on the growth parameters and accumulation of Cd and As in six wheat varieties Jing-9428, Duokang-1, Jingdong-11, Jing-411, Jingdong-8 and Zhongmai-8. The endpoints of wheat seedlings, including seed germination,biomass, root length and shoot height, decreased with increasing the Cd and As concentrations. Significant differences in seed germination, biomass, root length, shoot height and the accumulation of Cd and As were observed between the treatments and among the varieties (p ＜ 0.05). The lethal dosage 50% were about 20, 80, 60, 60, 80 and 20 mg As/L for Jing-9428, Duokang-1, Jingdong-11,Jing-411, Jingdong-8 and Zhongmai-8, respectively, and the corresponding values for Cd were about 30, 80, 20, 40, 60 and 10 mg Cd/L, respectively. Among the six varieties, Duokang-1 was found to be the most resistant to Cd and As toxicity, and Zhongmai-8 was the most sensitive to Cd and As co-contamination. The resistance of the six varieties was found dependant on the seedling uptake of Cd and As. Duokang-1 was the most suitable for cultivation in Cd and As co-contaminated soils.     

Nitrogen cycling of atmosphere-plant-soil system in the typical Calamagrostis angustifolia wetland in the Sanjiang Plain, Northeast China

The nitrogen (N) distribution and cycling of atmosphere-plant-soil system in the typical meadow Calamagrostis angustifolia wetland (TMCW) and marsh meadow Calamagrostis angustifolia wetland (MMCW) in the Sanjiang plain were studied by a compartment model. The results showed that the N wet deposition amount was 0.757 gN/(m2·a), and total inorganic N (TIN) was the main body (0.640 gN/(m2·a)). The ammonia volatilization amounts of TMCW and MMCW soils in growing season were 0.635 and 0.687 gN/m2, and the denitrification gaseous lost amounts were 0.617 and 0.405 gN/m2, respectively. In plant subsystem, the N was mainly stored in root and litter. Soil organic N was the main N storage of the two plant-soil systems and the proportions of it were 93.98% and 92.16%, respectively. The calculation results of N turnovers among compartments of TMCW and MMCW showed that the uptake amounts of root were 23.02 and 28.18 gN/(m2·a) and the values of aboveground were 11.31 and 6.08 gN/(m2·a), the re-translocation amounts from aboveground to root were 5.96 and 2.70 gN/(m2·a), the translocation amounts from aboveground living body to litter were 5.35 and 3.38 gN/(m2·a), the translocation amounts from litter to soil were larger than 1.55 and 3.01 gN/(m2·a), the translocation amounts from root to soil were 14.90 and 13.17 gN/(m2·a), and the soil (0-15cm) N net mineralization amounts were 1.94 and 0.55 gN/(m2·a), respectively. The study of N balance indicated that the two plant-soil systems might be situated in the status of lacking N, and the status might induce the degradation of C. angustifolia wetland.     

基于电子鼻土壤与地下水污染修复现场TVOC和恶臭的评估

根据上海某土壤与地下水污染修复现场情况,应用自主研发的电子鼻系统(iSA-M1)分别对未修复及修复过程中的土壤和地下水、修复场地上空及周边空气中的VOCs和恶臭类气体进行检测.结合前期研究所得TPI和OPI公式,求得各点的值,并将其用图表示.结果表明:①修复后TVOC和恶臭的浓度总体呈下降趋势;②在土壤和地下水修复过程中,VOCs和恶臭的挥发受气象要素和作业的影响,其浓度在总体下降的过程中伴随着阶段性上升现象;③结合GIS技术,电子鼻能初步用于评估土壤和地下水修复现场造成的空间污染情况及对周围居民产生的影响.但造成影响程度的具体细化分级还需要进一步研究.     

Characteristics of indoor/outdoor PM2.5 and elemental components in generic urban, roadside and industrial plant areas of Guangzhou City, China

Quantitative information on mass concentrations and other characteristics, such as spatial distribution, seasonal variation, indoor/outdoor （I/O） ratio, correlations and sources, of indoor and outdoor PM2.5 and elemental components in Guangzhou City were provided. Mass concentration of PM2.5 and elemental components were determined by standard weight method and proton-induced X-ray emission （PIXE） method. 18 elements were detected, the results showed positive results. Average indoor and outdoor PM2.5 concentrations in nine sites were in the range of 67.7-74.5μg/m^3 for summer period, and 109.9-123.7 μg/m^3 for winter period, respectively. The sum of 18 elements average concentrations were 5362.6-5533.4 ng/m^3 for summer period, and 8416.8-8900.6 ng/m^3 for winter period, respectively. Average concentrations of PM2.5 and element components showed obvious spatial characteristic, that the concentrations in roadside area and in industrial plant area were higher than those in generic urban area. An obvious seasonal variation characteristic was found for PM2.5 and elemental components, that the concentrations in winter were higher than that in summer. The I/O ratio of PM2.5 and some elemental components presented larger than 1 sometimes. According to indoor/outdoor correlation of PM2.5 and element concentrations, it was found that there were often good relationships between indoor and outdoor concentrations. Enrichment factors were calculated to evaluate anthropogenic versus natural elements sources.     

厌氧氨氧化过程中COD及pH与基质浓度之间的关系

分析了上向流厌氧氨氧化生物滤池中氮素化合物浓度、COD和pH变化规律以及ANAMMOX活性和生物量的分布规律,利用数理统计的方法研究了厌氧氨氧化过程中COD和pH与氮素基质浓度之间的关系.结果表明,溶解氧和氮负荷的共同作用使得ANAMMOX活性和生物量的分布沿滤层深度呈"山脊"状不均匀分布;异养反硝化的存在和H+的消耗使得厌氧氨氧化过程中COD和pH分别呈降低和升高趋势;100 mg/L以下的有机物浓度对厌氧氨氧化菌的影响不大,且COD和pH与基质NH4+-N浓度之间呈良好的线性相关关系.本试验中COD-NH4+-N和pH-NH4+-N拟合直线的斜率分别为1.113 8±0.052 2和-0.111 3±0.001 2,置信度为95%,平均相关系数R2分别为0.982 3和0.985 0.     

Effects of two sludge application on fractionation and phytotoxicity of zinc and copper in the soil

The potential harm of heavy metals is a primary concern in application of sludge to the agricultural land. A pot experiment was conducted to evaluate the effect of two sludges on fractionation of Zn and Cu in soil and their phytotoxicity to pakchoi. The loamy soil was mixed with 0%, 20%, 40%, 60% and 80% (by weight) of digested sewage sludge (SS) and composted sludge (SC). The additions of both sludges caused a significant raise in all fractions, resulting in that exchangeable (EXCH) and organic bound (OM) became predominance of Zn and organic bound Cu occupied the largest portion. There was more available amount of Zn and Cu in SS treatments than SC treatments. During the pot experiment, the concentration of Zn in EXCH, carbonate (CAR) and OM and Cu in EXCH and OM fractions decreased in all treatments, so their bioavailability reduced. Germination rate and plant biomass decreased when the addition rate was high and the best yield appeared in 20% mixtures at the harvest of pakchoi. The two sludges increased tissue contents of Zn and Cu especially in the SS treatments. Zn in pakchoi was not only in relationship to ΔEXCH and ΔCAR forms but also in ΔOM forms in the sludge-soil mixtures. Tissue content of Cu in pakchoi grown on SC-soils could not be predicted by ΔEXCH. These correlation rates between Zn and Cu accumulation in pakchoi and variation of different fractions increased with time, which might indicate that sludges represented stronger impacts on the plant in long-term land application.     

污泥超高温好氧发酵去除氟喹诺酮类抗生素及其降解产物

对比分析了污泥传统高温好氧发酵(TC)和超高温好氧发酵(HTC)对诺氟沙星(NOR)、氧氟沙星(OFL)及其降解产物的去除性能.结果表明,超高温好氧与高温好氧发酵25d时NOR去除率分别为91.8％,92.1％,产物诺氟沙星脱乙基(NORP)残留含量分别为628,668μg/kg;OFL去除率分别为92.1％、88.1...     

北京市夏季O3、 NOx等污染物“周末效应”研究

采用了2000-06-25~2000-07-07以及2000-07-26~2000-08-22在北京325 m气象塔观测平台观测到的O3、NOx(NO和NO2)、CO和SO2数据,分析了周末与工作日O3、NOx、NO、NO2、CO和SO2浓度变化的差异及成因.结果表明,除SO2之外,O3、NOx、NO、NO2和CO的周末浓度与对应工作日浓度相关性显著,均通过了显著性水平α=0.05的t检验,相关系数(R)依次为0.99、0.61、0.56、0.80和0.61.交通高峰时段(06:00~08:00)NOx和CO的周末浓度明显低于工作日浓度,该时段NOx和CO的周末浓度与工作日浓度的平均偏差分别为-28%和-9%.O3周末浓度与工作日浓度的回归系数为1.25±0.02.此外,周末O3的最大小时浓度值与最大8 h平均浓度值分别比工作日高23%和26%,表现出十分明显的"周末效应".