REGIONAL CHEMISTRY OF LAKES IN MASSACHUSETTS 1

ABSTRACT: We surveyed over 2000 lakes in the State of Massachusetts (1983–1984) to examine the spatial variations in their acid-base chemistry. Our survey differed from previous surveys by including small lakes and nonpristine urban lakes. For samples collected in October 1983 and 1984, the median acid neutralizing capacity (ANC) was 184 μeq L^?1 and 5.9 percent were acidic (ANC≤O). Small lakes (<4 ha) were more likely to be acidic than large lakes. Generally, sulfate was the dominant acidifying agent, although organic anions were dominant in some of the lakes in the Cape Cod Region. The ionic composition of the lakes showed strong regional patterns which appear to be related to geology and human population density. An analysis of variance of ANC shows the six regional categories in the state explain 51 percent of the variance, while a combined general linear model of lake drainage type, color, elevation, size, silica, and hydrogen ion deposition could explain only 4.9 percent of the variation in ANC. Calcium rich, high ionic strength lakes were present in the marble bedrock in the west, and relatively dilute lakes dominated by sodium and chloride were found near the coast. Chloride concentrations were also related to population density, suggesting road salt as a likely contributing source.     

DEFINING REGIONAL POPULATIONS OF LAKES FOR THE ASSESSMENT OF SURFACE WATER QUALITY1

ABSTRACT: Topographic maps are commonly used to define populations of lakes in regional surveys of surface water quality. To illustrate the effect of different maps on that process, we compared the lakes represented on the 1:250,000-scale maps used for the Northeast Region of the Eastern Lake Survey—Phase I (ELS-I) to the lakes on a sample of large-scale maps (1:24,000 or 1:62,500). Lake areas at or near the lower limit of representation delimited “smallest-lake” values for the compared 1:250,000-scale maps. The regional median for these values was 4.5 hectares (ha) and ranged from 0.6 to 24.8 ha. Lake representation is influenced by cartographic limitations such as map scale, age, and complexity as well as the inherent variability of waterbodies (e.g., water level fluctuations or the creation of reservoirs, beaver impoundments, and oxbows). The total number of lakes on large-scale maps increased markedly as lake area decreased. Approximately 15,700 of the estimated 29,000 lakes in the EPA's Northeast Region were 1 to 4 ha in area. Because maps affect the size distribution of lakes included in a regional survey and because lake areas are thought to modify lake chemistry, maps ultimately affect the estimates of regional surface water quality.     

Chronic and episodic acidification of Adirondack streams from acid rain in 2003-2005

Limited information is available on streams in the Adirondack region of New York, although streams are more prone to acidification than the more studied Adirondack lakes. A stream assessment was therefore undertaken in the Oswegatchie and Black River drainages; an area of 4585 km(2) in the western part of the Adirondack region. Acidification was evaluated with the newly developed base-cation surplus (BCS) and the conventional acid-neutralizing capacity by Gran titration (ANC(G)). During the survey when stream water was most acidic (March 2004), 105 of 188 streams (56%) were acidified based on the criterion of BCS < 0 microeq L(-1), whereas 29% were acidified based on an ANC(G) value < 0 microeq L(-1). During the survey when stream water was least acidic (August 2003), 15 of 129 streams (12%) were acidified based on the criterion of BCS < 0 microeq L(-1), whereas 5% were acidified based on ANC(G) value < 0 microeq L(-1). The contribution of acidic deposition to stream acidification was greater than that of strongly acidic organic acids in each of the surveys by factors ranging from approximately 2 to 5, but was greatest during spring snowmelt and least during elevated base flow in August. During snowmelt, the percentage attributable to acidic deposition was 81%, whereas during the October 2003 survey, when dissolved organic carbon (DOC) concentrations were highest, this percentage was 66%. The total length of stream reaches estimated to be prone to acidification was 718 km out of a total of 1237 km of stream reaches that were assessed.     

CHEMICAL COMPOSITION OF SOFTWATER FLORIDA LAKES AND THEIR SENSITIVITY TO ACID PRECIPITATION1

ABSTRACT: Based on alkalinity data for 596 lakes, 31 percent of Florida's 7300 lakes have < 100 μeq/l alkalinity and are sensitive to acid depostion. More than two-thirds of the lakes in 12 northern Florida counties fit this criterion. Increasing aluminum and decreasing nutrient and chlorophyll a concentrations were observed with decressing pH in a survery of 20 softwater lakes. Maximum measured aluminum values (100-150 μg/L) are below levels asociated with fish toxicity. Factor analysis showed that lake chemistry was related to three principal factors, representing three major processes: watershed weathering, acidification, and nutrient inputs. An acidification index defined as the difference between excess SO₄^2- and excess (Ca²⁺+Mg²⁺) accounted for 74 percent of the variance in lake pH. Comparison of historical (late 1950a) and present data for pH, alkalinity, and excess SO₄^2- indicated loss of alkalinity (>25 μeq/L) and increase in excess SO₄^2- (16-34 μeq/L) in several softwater lakes.     

Use of stream chemistry for monitoring acidic deposition effects in the Adirondack region of New York

Acid-neutralizing capacity (ANC) and pH were measured weekly from October 1991 through September 2001 in three streams in the western Adirondack Mountain region of New York to identify trends in stream chemistry that might be related to changes in acidic deposition. A decreasing trend in atmospheric deposition of SO4/2- was observed within the region over the 10-yr period, although most of the decrease occurred between 1991 and 1995. Both ANC and pH were inversely related to flow in all streams; therefore, a trend analysis was conducted on (i) the measured values of ANC and pH and (ii) the residuals of the concentration-discharge relations. In Buck Creek, ANC increased significantly (p < 0.05) over the 10 yr, but the residuals of ANC showed no trend (p > 0.10). In Bald Mountain Brook, ANC and residuals of ANC increased significantly (p < 0.01), although the trend was diatonic-a distinct decrease from 1991 to 1996 was followed by a distinct increase from 1996 to 2001. In Fly Pond outlet, ANC and residuals of ANC increased over the study period (p < 0.01), although the trend of the residuals resulted largely from an abrupt increase in 1997. In general, the trends observed in the three streams are similar to results presented for Adirondack lakes in a previous study, and are consistent with the declining trend in atmospheric deposition for this region, although the observed trends in ANC and pH in streams could not be directly attributed to the trends in acidic deposition.     

Landscape-Based Assessment of Human Disturbance for Michigan Lakes

Assessment of lake impairment status and identification of threats’ type and source is essential for protection of intact, enhancement of modified, and restoration of impaired lakes. For regions in which large numbers of lakes occur, such assessment has usually been done for only small fractions of lakes due to resource and time limitation. This study describes a process for assessing lake impairment status and identifying which human disturbances have the greatest impact on each lake for all lakes that are 2 ha or larger in the state of Michigan using readily available, georeferenced natural and human disturbance databases. In-lake indicators of impairment are available for only a small subset of lakes in Michigan. Using statistical relationships between the in-lake indicators and landscape natural and human-induced measures from the subset lakes, we assessed the likely human impairment condition of lakes for which in-lake indicator data were unavailable using landscape natural and human disturbance measures. Approximately 92% of lakes in Michigan were identified as being least to marginally impacted and about 8% were moderately to heavily impacted by landscape human disturbances. Among lakes that were heavily impacted, more inline lakes (92%) were impacted by human disturbances than disconnected (6%) or headwater lakes (2%). More small lakes were impacted than medium to large lakes. For inline lakes, 90% of the heavily impacted lakes were less than 40 ha, 10% were between 40 and 405 ha, and 1% was greater than 405 ha. For disconnected and headwater lakes, all of the heavily impacted lakes were less than 40 ha. Among the anthropogenic disturbances that contributed the most to lake disturbance index scores, nutrient yields and farm animal density affected the highest number of lakes, agricultural land use affected a moderate number of lakes, and point-source pollution and road measures affected least number of lakes. Our process for assessing lake condition represents a significant advantage over other routinely used methods. It permits the evaluation of lake condition across large regions and yields an overall disturbance index that is a physicochemical and biological indicator weighted sum of multiple disturbance factors. The robustness of our approach can be improved with increased availability of high-resolution disturbance datasets.     

Explaining human settlement patterns in a recreational lake district: Vilas County,Wisconsin, USA

Lakeshore development in Vilas County, northern Wisconsin (USA) is heterogeneous, ranging from lakes that are surrounded by homes and commercial establishments to lakes that have no buildings on their shorelines. Development in this recreational area has increased, and since the 1960s over half of new homes have been built on the lakeshore. We examined building density around lakes in relationship to 11 variables, including in-lake, shoreline, and social characteristics. Buildings in many parts of northern Wisconsin tend to be concentrated around shorelines; in Vilas County 61% of all medium-sized buildings (our proxy for residential development) on private land were ≤100 m of a lake. The probability of development on a lake was largely related to lake surface area, with larger, more accessible lakes showing a higher probability of development. Building density along shorelines varied with travel cost, lake surface area, presence of wetlands, and extent of public land ownership. Building density was greater on larger, more accessible lakes that were surrounded by forest (as opposed to wetlands) and public lands. Gaining a more precise understanding of human settlement patterns can help direct planning and resource protection efforts to lakes most likely to experience future development.     

Multiscale Drivers of Water Chemistry of Boreal Lakes and Streams

The variability in surface water chemistry within and between aquatic ecosystems is regulated by many factors operating at several spatial and temporal scales. The importance of geographic, regional-, and local-scale factors as drivers of the natural variability of three water chemistry variables representing buffering capacity and the importance of weathering (acid neutralizing capacity, ANC), nutrient concentration (total phosphorus, TP), and importance of allochthonous inputs (total organic carbon, TOC) were studied in boreal streams and lakes using a method of variance decomposition. Partial redundancy analysis (pRDA) of ANC, TP, and TOC and 38 environmental variables in 361 lakes and 390 streams showed the importance of the interaction between geographic position and regional-scale variables. Geographic position and regional-scale factors combined explained 15.3% (streams) and 10.6% (lakes) of the variation in ANC, TP, and TOC. The unique variance explained by geographic, regional, and local-scale variables alone was <10%. The largest amount of variance was explained by the pure effect of regional-scale variables (9.9% for streams and 7.8% for lakes), followed by local-scale variables (2.9% and 5.8%) and geographic position (1.8% and 3.7%). The combined effect of geographic position, regional-, and local-scale variables accounted for between 30.3% (lakes) and 39.9% (streams) of the variance in surface water chemistry. These findings lend support to the conjecture that lakes and streams are intimately linked to their catchments and have important implications regarding conservation and restoration (management) endeavors.     

Geospatial and Temporal Analysis of a 20‐Year Record of Landsat‐Based Water Clarity in Minnesota's 10,000 Lakes

A large 20‐year database on water clarity for all Minnesota lakes ≥8 ha was analyzed statistically for spatial distributions, temporal trends, and relationships with in‐lake and watershed factors that potentially affect lake clarity. The database includes Landsat‐based water clarity estimates expressed in terms of Secchi depth (SD_Landsat), an integrative measure of water quality, for more than 10,500 lakes for time periods centered around 1985, 1990, 1995, 2000, and 2005. Minnesota lake clarity is lower (more turbid) in the south and southwest and clearer in the north and northeast; this pattern is evident at the levels of individual lakes and ecoregions. Temporal trends in clarity were detected in ~11% of the lakes: 4.6% had improving clarity and 6.2% had decreasing clarity. Ecoregions in southern and western Minnesota, where agriculture is the predominant land use, had higher percentages of lakes with decreasing clarity than the rest of the state, and small and shallow lakes had higher percentages of decreasing clarity trends than large and deep lakes. The mean SD_Landsat statewide remained stable from 1985 to 2005 but decreased in ecoregions dominated by agricultural land use. Deep lakes had higher clarity than shallow lakes statewide and for lakes grouped by land cover. SD_Landsat decreased as the percentage of agriculture and/or urban area increased at county and catchment levels and it increased with increasing forested land.     

The Potential Use of Synthetic Aperture Radar for Estimating Methane Ebullition From Arctic Lakes1

Abstract: Arctic lakes are significant emitters of methane (CH₄), a potent greenhouse gas, to the atmosphere; yet no rigorous quantification of the magnitude and variability of pan‐Arctic lake emissions exists. In this study, we demonstrate the potential for a new method using synthetic aperture radar (SAR) imagery to detect methane bubbles in lake ice to scale up whole‐lake measurements of CH₄ ebullition (bubbling) to regional scales. We estimated ebullition from lakes, which is often the dominant mode of lake emissions, by mapping the distribution of bubble clusters frozen in early winter ice across surfaces of seven tundra lakes and one boreal forest lake in Alaska. Applying previously measured ebullition rates associated with four distinct classes of bubble clusters found in lake ice, we estimated whole‐lake emissions from individual lakes. The percent surface area of lake ice covered with bubbles (R² = 0.68) and CH₄ ebullition rates from lakes (R² = 0.59) and were correlated with radar return values from RADARSAT‐1 Standard Beam mode 3 for the tundra lakes, suggesting that with appropriate scaling and consideration for variability in lake‐ice conditions, this technique has the potential to be used for estimating broader‐scale regional and pan‐Arctic lake methane emissions.     

STREAM CHEMISTRY IN THE SOUTHERN BLUE RIDGE: FEASIBILITY OF A REGIONAL SYNOPTIC SAMPLING APPROACH1

ABSTRACT: A pilot study, which was conducted in the Southern Blue Ridge geographical province of the Southeastern U.S., demonstrated the feasibility of a probability-based regional synoptic design for the National Stream Survey, which is a project aimed at estimating the number and percentage of streams in various regions of the U.S. that are acidic or at risk from acid deposition. Estimated population distributions for key chemical variables were not appreciably affected by week-to-week variability in stream chemistry during the spring index period chosen for the study. Differences were observed in estimated acid neutralizing capacity (ANC), nitrate, and pH frequency distributions between spring and summer. Observations made at the downstream node did not represent the chemistry of the entire reach for some variables (ANC and nitrate) as indicated by differences in chemical concentrations between upstream and downstream sampling locations. Coefficients of variation in chemical species were low enough to provide a reasonably stable classification of streams based on ANC. Although median ANC, sulfate, and nitrate concentrations were quite low in the region, the probability of finding streams with ph < 6.3 is less than 1.3 percent at the α= 0.05 confidence level.     

Mesoscale survey of western and northwestern Irish lakes – Spatial and aestival patterns in trophic status and phytoplankton community structure

Inland water bodies are considered as integrated parts of the landscape and the monitoring of water quality and aquatic resources need to be addressed on a regional basis for optimal assessment and management. In this study, a simple stratified sampling scheme was applied to a mesoscale survey of western and northwestern Irish lakes, which was carried out to identify, based on the distribution patterns of phytoplankton biomass, potential associations between lake trophic state and land cover attributes. Phytoplankton community analysis was also performed to determine whether taxa associations reflected meteorology-linked aestival succession or specific spatial distributions. The assessment was based on the typology of hydrogeomorphological and land cover attributes of river catchments through ArcGIS analysis. Sampling was carried out in 50 lakes and during a 15-week period in summer 2009. Results showed a general longitudinal gradient in the trophic status of the lakes sampled, with a greater frequency of mesotrophic lakes in the eastern part of the study area where land cover is dominated by agricultural surfaces. Significant relationships (p < 0.010) were found between chlorophyll-a concentration and the proportion of river catchment surface covered by agriculture land and wetlands, findings which might be considered further as proxies for developing an eutrophication risk index. Multivariate analysis of phytoplankton community data clustered the sampled lakes into three assemblages, with ordination along axis 1 being significantly correlated to time and temperature (p < 0.006). There was greater frequency of occurrence of diatoms in lakes from cluster III (Kruskal–Wallis, p < 0.05, H = 6.34, df = 2, n = 49), concomitant to lower chlorophyll-a concentrations, lake surface temperatures and Secchi depths, reflecting meteorological conditions dominated by precipitations. Those results support the potential of mesoscale surveys to assess water quality variables and detect environmental patterns at regional scales.     

Limnological effects of wood ash application to the subcatchments of boreal,humic lakes

To assess environmental risks of wood ash, limnological effects of ash application to the drainage basins of two small, humic lakes and one reference lake in southern Finland were examined in this three-year study. Treated areas corresponded to 12 and 19% of the total catchment and the amount of wood ash added was 6400 kg ha(-1). Immediate effects of wood ash on lake water were investigated in three tank experiments each lasting 1.5 wk. In tank experiments, addition of wood ash increased pH, alkalinity, conductivity, and Ca and P concentrations of humic lake water, while growth of phytoplankton decreased. After wood ash application to the subcatchments, pH, alkalinity, conductivity, and concentrations of K+, SO4(2-), and Cl- slightly increased, both in inflowing waters and in the lakes, but no increased leaching of Ca, N, or P from the treated subcatchments occurred. Phytoplankton biomass increased in both experimental lakes in comparison with the reference lake. In the lake with 19% application rate to the catchment, zooplankton biomass also increased. The results indicate that, over the short term, a small-scale ash treatment to a forested drainage basin will not necessarily cause significant changes in the water quality of boreal humic lakes, but at higher application rates, changes in water chemistry and biology are more evident.     

THE RESTON (VIRGINIA) LAKE-USE SURVEY: PUBLIC PERCEPTIONS AND MANAGEMENT IMPLICATIONS1

ABSTRACT: A public attitude survey was developed by a citizen committee and mailed to all residences (14,747) in the planned, suburban community of Reston, Virginia, which is responsible for maintaining four small, recreational impoundments. Over 18 percent of survey forms were returned, and characteristics of the survey sample suggest that the suite of respondents was representative of the Reston community as a whole. Of those respondents indicating a preferred lake use, 48 percent chose walking or looking as most important; boating as second at 27 percent; and fishing was third, favored by only 8 percent. Citizens feel strongly (94 percent) that the lakes are valuable community assets. Appearance was the characteristic most valued by 62 percent of respondents, and 58 percent considered degradation of water quality either the first or second most important ecological issue affecting local lakes. These findings provide a decisive public mandate for lake management activities related to visual quality. In response to this survey, the Reston Association, a homeowners' organization responsible for the lakes, increased public access of visual enjoyment, intensified litter control, expanded activities in public education on lake management and ecology, and continued a long-term program of water quality monitoring.     

Usefulness of natural regions for lake management: Analysis of variation among lakes in northwestern Wisconsin,USA

A map of summer total phosphorus in lakes was compiled recently for a three-state area of the upper Midwest for purposes of identifying regional patterns of total phosphorus in lakes and attainable lake trophic state. Spatial patterns in total phosphorus from approximately 3000 lakes were studied in conjunction with maps of geographic characteristics that tend to affect phosphorus balance in lakes to identify regions of similarity in phosphorus concentrations in lakes or similarity in the mosaic of values as compared to adjacent areas. While degrees of relative homogeneity are apparent at many scales, the map was designed at a scale that would yield regions with sufficient homogeneity to be useful for lake management throughout the area. In this study, data from 210 lakes in a 1560-mi² area in northwestern Wisconsin, sampled by the Wisconsin Department of Natural Resources in the spring of 1988 (subsequent to the compilation of the phosphorus map), were examined to: (1) substantiate the existence of the regions depicted on the map in northwest Wisconsin, (2) determine the nature and relative precision of the regional boundaries, (3) determine the relative importance of natural and anthropogenic watershed characteristics, lake types, lake area, and lake depth in explaining within-region differences in lake phosphorus, and (4) demonstrate how the regions might be used by local lake managers.     

Modeling surface water critical loads with PROFILE: possibilities and challenges

The critical load concept has become a valuable tool for policymakers in the European negotiations on emission reductions. Despite the international acceptance, ongoing validation of critical load methodology is of the utmost importance to avoid a situation where the calculation results are difficult to defend. In this paper we explore the potential of using the steady state soil chemistry model PROFILE as an alternative to the Steady State Water Chemistry (SSWC) method for calculating critical loads of acidity. The hypothesis is that the uncertainty in prediction of preindustrial leaching of base cations is reduced when soil properties instead of lake chemistry are used as input data. Paleolimnological reconstructions of preindustrial lake chemistry are used to test PROFILE. As PROFILE requires soil data that are not generally available on a catchment level, we used distributions of crucial parameters from soil survey data within the vicinity of five lakes for which paleoecological pH reconstructions were available. An important concern is the characterization of catchment hydrology. A calibration of the "effective" soil depth, needed to give PROFILE predictions that coincided with paleolimnology, suggested that approximately 0.6 m of the total soil depth was hydrologically active in supplying acid neutralizing capacity (ANC) to runoff through weathering. At present, there is insufficient evidence to either recommend or reject the PROFILE model for surface water critical loads. Before such a judgement can be made, the approach presented here has to be tested for other regions, and the definition of catchment hydrology needs to be investigated further.     

RESPONSE OF NORTH AMERICAN FRESHWATER LAKES TO SIMULATED FUTURE CLIMATES1

ABSTRACT: We apply a physically based lake model to assess the response of North American lakes to future climate conditions as portrayed by the transient trace-gas simulations conducted with the Max Planck Institute (ECHAM4) and the Canadian Climate Center (CGCM1) atmosphere-ocean general circulation models (A/OGCMs). To quantify spatial patterns of lake responses (temperature, mixing, ice cover, evaporation) we ran the lake model for theoretical lakes of specified area, depth, and transparency over a uniformly spaced (50 km) grid. The simulations were conducted for two 10-year periods that represent present climatic conditions and those around the time of CO₂ doubling. Although the climate model output produces simulated lake responses that differ in specific regional details, there is broad agreement with regard to the direction and area of change. In particular, lake temperatures are generally warmer in the future as a result of warmer climatic conditions and a substantial loss (> 100 days/yr) of winter ice cover. Simulated summer lake temperatures are higher than 30°C over the Midwest and south, suggesting the potential for future disturbance of existing aquatic ecosystems. Overall increases in lake evaporation combine with disparate changes in A/OGCM precipitation to produce future changes in net moisture (precipitation minus evaporation) that are of less fidelity than those of lake temperature.     

Bottomfast Ice Mapping and the Measurement of Ice Thickness on Tundra Lakes Using C‐Band Synthetic Aperture Radar Remote Sensing1

Abstract: Industrial activity in Canada’s north is increasing, placing demands on the use of water from lakes to build ice roads. Winter water withdrawal from these lakes has the potential to impact overwintering fish. Removal of water from small lakes can decrease oxygen and habitat available to fish. To address this issue, a protocol has been developed by the Department of Fisheries and Oceans outlining water withdrawal thresholds. Bathymetric surveys are the traditional method to determine lake depth, but are costly given the remoteness of northern lakes. This paper investigates the use of satellite C‐band synthetic aperture radar (SAR) remote sensing technology as a potential alternative or complement to traditional survey methods. Previous research has shown that a SAR can detect the transition from grounded to floating ice on lakes, or if a lake is completely frozen. Grounded ice has a dark signature while floating ice appears very bright in contrast. Similar results were observed for the datasets acquired in the study area. This suggests that lakes that freeze completely to the bottom can be identified using SAR. Such water bodies would not be viable fish overwintering habitat and can therefore be used as water sources without thresholds necessary. However, attempts to accurately calculate the depth of the ice at the grounded‐floating ice boundary using bathymetric profiles acquired in the summer and lake ice thickness measurements from a reference lake near Inuvik proved to be unreliable.     

The Contribution of Marsh Zones to Water Quality in Dutch Shallow Lakes: A Modeling Study

Many lakes have experienced a transition from a clear into a turbid state without macrophyte growth due to eutrophication. There are several measures by which nitrogen (N) and phosphorus (P) concentrations in the surface water can be reduced. We used the shallow lake model PCLake to evaluate the effects of three measures (reducing external nutrient loading, increasing relative marsh area, and increasing exchange rate between open water and marsh) on water quality improvement. Furthermore, the contribution of different retention processes was calculated. Settling and burial contributed more to nutrient retention than denitrification. The model runs for a typical shallow lake in The Netherlands showed that after increasing relative marsh area to 50%, total phosphorous (TP) concentration in the surface water was lower than the Maximum Admissible Risk (MAR, a Dutch government water quality standard) level, in contrast to total nitrogen (TN) concentration. The MAR levels could also be achieved by reducing N and P load. However, reduction of nutrient concentrations to MAR levels did not result in a clear lake state with submerged vegetation. Only a combination of a more drastic reduction of the present nutrient loading, in combination with a relatively large marsh cover (approximately 50%) would lead to such a clear state. We therefore concluded that littoral marsh areas can make a small but significant contribution to lake recovery.     

COMPARATIVE WATER CHEMISTRY OF FOUR LAKES IN ROCKY MOUNTAIN NATIONAL PARK1

ABSTRACT: The inorganic chemistry of two pairs of lakes in Rocky Mountain National Park was studied to determine reasons for their similarities and differences. The pairs were located on differing geologic units. It was expected that weathering from the different types of parent material would cause differing cation concentrations between the pairs. This was verified by dissimilar concentrations of those cations which are products of primary weathering. Unexpected was a significant difference in anion concentrations between members of one pair having the same bedrock geology. This difference has been attributed to the presence of a wet sedge meadow above one of the lakes which serves as a biological filter for anions, particularly nitrate and sulfate. It is shown that small scale drainage characteristics which can alter regional atmospheric contributions are important contributors to lake chemistry.