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非均相Fenton反应技术研究进展 总被引:7,自引:0,他引:7
Fenton氧化法是较为常用的一种高级氧化技术。非均相Fenton反应适用的pH值范围较宽,能避免均相Fenton反应产生铁泥沉淀的缺点,成为近年来Fenton反应的重要研究方向。本文对非均相Fenton氧化技术的研究现状及发展动态进行较为详尽的评述。 相似文献
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在初始pH=3的条件下研究了甲基橙在非均相Fenton体系和非均相US-Fenton体系中的降解动力学。研究内容包括表观动力学方程和活化能。研究表明,超声的引入可以提高甲基橙的降解效率和降解速率。对比非均相Fenton和非均相US-Fenton体系中的表观动力学方程表明超声的引入可以提高反应速率常数,此外,还可以提高H2O2的利用率。通过对比分析,超声的引入可以降低反应所需的活化能,在超声的存在下,甲基橙的氧化活化能为25.12 kJ/mol,而在没有超声的条件下,需要的活化能为41.49 kJ/mol。 相似文献
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采用浸渍法制备载铁凹凸棒土,并用其作为非均相Fenton催化剂处理模拟苯酚废水,研究该体系中各影响因素对模拟苯酚废水处理效果的影响,确定适宜反应条件,并对载铁凹凸棒土进行简单造粒研究。结果表明,载铁凹凸棒土与原凹凸棒土相比吸附能力有所增强,是一种良好的非均相Fenton催化剂。对于50 mL质量浓度为500 mg/L的模拟苯酚废水,适宜的非均相Fenton反应条件为载铁凹凸棒土14g/L、H_2O_2 1.0mL,在此条件下反应2.5h后苯酚及总有机碳(TOC)的去除率分别在98%、56%以上,非均相Fenton反应在一定程度上拓宽了Fenton反应的pH范围。将载铁凹凸棒土手工制成2~3mm颗粒,重复使用8次仍具有较高的活性,铁溶量低,具有良好的稳定性和回收性。 相似文献
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以三氯生为目标污染物,研究了黄铁矿催化H2O2非均相类Fenton体系对污染物的去除效果,并利用SEM、EDS等手段对天然黄铁矿进行了表征。考察了催化剂、H2O2投加量、溶液初始pH、反应时间等重要因素对催化氧化反应的影响。在H2O2投加量5 mg/L,黄铁矿用量0.1 g/L,溶液初始pH为8,反应10 min后,三氯生的去除率达90%以上。相对于传统Fenton反应,pH对本非均相催化反应的影响较小,在2~10的pH范围内,仍有较高的催化活性。利用GC-MS分析显示,三氯生降解过程能够产生包括2,4-二氯苯酚在内的多种中间产物。 相似文献
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新型类Fenton催化剂用于酸性红B染料废水处理的研究 总被引:3,自引:0,他引:3
为了解决Fenton试剂反应前后需要调节pH值、催化剂不能重复利用的问题,本实验以酸性红B溶液作为模拟染料废水,探索以硫铁矿烧渣作为非均相催化剂进行类Fenton反应的催化活性,研究了H2O2投加量、催化剂投加量、pH值、反应时间对酸性红B去除效果的影响。在双氧水(H2O2质量分数为30%)投加量为30 mL/L、催化剂投加量为30 g/L、pH值在1~11范围内,反应4 h,浓度为200 mg/L的酸性红B去除率均达到95%以上,且反应后pH值在中性范围。实验结果表明,该非均相类Fenton反应体系对pH的适用范围广,且催化剂易于沉淀分离,反应数次后依然保持较高催化活性,能重复利用。 相似文献
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采用浸渍固化法制备非均相Fenton催化剂载铁活性炭处理模拟铅锌选矿废水,确定催化剂最佳制备条件:食品级粉末活性炭为载体,用质量分数为5%的Fe_2(SO_4)_3溶液浸渍载体10h,固化温度120℃,固化时间2h。在非均相Fenton氧化降解实验中,当H_2O_2用量为0.4g/L、催化剂用量为1.4g/L、初始pH为5时,反应40 min后对模拟铅锌选矿废水COD去除率可达85.74%,出水COD为37.08mg/L,达到《铅、锌工业污染物排放标准》(GB 25466—2010)中的直接排放标准。制得的催化剂具有一定的重复使用能力,重复使用3次后COD去除率仍达到75%以上,但继续重复使用催化效果下降显著。机理分析显示,非均相Fenton反应主要通过铁离子催化及吸附作用共同使有机物去除。 相似文献
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利用Ce-Fe/Al2O3为催化剂的非均相光Fenton体系降解阳离子红GTL模拟废水,考察了H2O2浓度、催化剂用量、初始pH值及不同工艺过程对降解效果的影响,通过紫外-可见漫反射光谱、红外光谱、XPS手段研究铁在反应中的价态变化.结果表明,在11 W低压汞灯照射下,非均相光Fenton体系能够有效地降解结构稳定的阳离子红GTL,在pH 6,反应温度20℃,时间90 min,Ce-Fe/Al2O3 2 g/L,H2O2浓度340 mg/L,含50 mg/L阳离子红GTL模拟废水TOC去除率为92.40%;光Fenton反应中Fe(Ⅲ)转化为Fe(Ⅱ). 相似文献
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Glucose oxidase is a well-known enzyme that catalyzes the oxidation of β-d-glucose to produce gluconic acid and hydrogen peroxide. Fenton reaction is a powerful oxidation technology used for the oxidation of groundwater pollutants. For the application of Fenton reaction in groundwater remediation, successful operation of Fenton reaction near neutral pH, and on-site generation of both H2O2 and chelate will be beneficial. The focus of this experimental study was to couple the glucose oxidation reaction with chelate-based Fenton reaction. The idea was to use the hydrogen peroxide and chelate gluconic acid generated during glucose oxidation for the dechlorination of 2,4,6-trichlorophenol (TCP) by Fenton reaction. The oxidation of glucose was achieved using the enzyme in free and immobilized forms. The rate of production of hydrogen peroxide was determined for each system, and was used to estimate the time required for complete consumption of glucose during the process, thus avoiding any traces of glucose in the Fenton reaction. In the case of free enzyme reaction, separation of the enzyme was achieved using an ultrafiltration membrane before initiating the Fenton reaction. The oxidation of TCP by Fenton reaction was performed at varying ratios of gluconic acid/Fe, and its effect on the decomposition of TCP and H2O2 was studied. TCP degradation was studied both in terms of parent compound degradation and free chloride generation. 相似文献
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Ji-Feng Yang Shi-Biao Zhou An-Guo Xiao Wen-Jun Li Guang-Guo Ying 《Journal of environmental science and health. Part. B》2013,48(12):909-916
This paper investigated sulfadiazine oxidation by the Fenton process under various reaction conditions. The reaction conditions tested in the experiments included the initial pH value of reaction solutions, and the dosages of ferrous ions and hydrogen peroxide. Under the reaction conditions with pH 3, 0.25 mM of ferrous ion and 2 mM of hydrogen peroxide, a removal efficiency of nearly 100% was achieved for sulfadiazine. A series of intermediate products including 4-OH-sulfadiazine/or 5-OH-sulfadiazine, 2-aminopyrimidine, sulfanilamide, formic acid, and oxalic acid were identified. Based on these products, the possible oxidation pathway of sulfadiazine by Fenton's reagent was proposed. The toxicity evaluation of reaction solutions showed increased antimicrobial effects following the Fenton oxidation process. The results from this study suggest that the Fenton oxidation process could remove sulfadiazine, but also increase solution toxicity due to the presence of more toxic products. 相似文献
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MnO2催化Fenton试剂降解苯酚废水 总被引:2,自引:1,他引:1
实验对MnO2催化Fenton试剂氧化高浓度苯酚废水的动力学特性和去除效果进行了研究。结果表明,MnO2可以提高Fenton试剂体系对苯酚的降解率以及COD的去除率;Fenton试剂以及MnO2催化Fenton试剂氧化苯酚废水体系中苯酚的降解都符合拟一级动力学模型。在MnO2催化Fenton试剂氧化体系中,苯酚的降解速率常数有明显提高,反应活化能也有所降低,说明MnO2的加入可以使反应容易进行。废水降解前后紫外可见吸收光谱和红外谱图表明,Fenton试剂法将苯酚可能降解为羧酸、烯烃等有机物中间体。 相似文献
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This paper evaluates the Fenton process, involving oxidation and coagulation, for the removal of color and chemical oxygen demand (COD) from synthetic textile wastewater containing polyvinyl alcohol and a reactive dyestuff, R94H. The experimental variables studied include dosages of iron salts and hydrogen peroxide, oxidation time, mixing speed and organic content. The results show that color was removed mainly by Fenton oxidation. The color removal reached a maximum of 90% at a reaction time of 5 min under low dosages of H2O2 and Fe2+. In contrast, the COD was removed primarily by Fenton coagulation, rather than by Fenton oxidation. The ratio of removal efficiency between Fenton process and ferric coagulation was 5.6 for color removal and 1.2 for COD removal. It is concluded that Fenton process for the treatment of textile wastewater favors the removal of color rather than COD. 相似文献
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Impact of radical versus non-radical pathway in the Fenton chemistry on the iron redox cycle in clouds 总被引:2,自引:0,他引:2
Modeling studies have shown that the Fenton reaction of iron(II) with H2O2 can contribute, in a significant amount, to OH radicals production in cloud droplets. However, the destruction mechanism of hydrogen peroxide by iron(II) is still uncertain. Two reaction pathways for the first step of Fenton chemistry have been advanced: a radical pathway which considers an OH radical production and a non-radical pathway considering ferryl ion production. The aim of this work is to evaluate the impact of these two possible reaction pathways for Fenton chemistry on the iron redox cycle in cloud droplets. For this purpose, the numerical model of multiphase chemistry M2C2 has been applied to a rural chemical scenario representative of continental conditions. This study highlights that the iron redox cycling is driven by Fenton reaction whatever Fenton mechanism is considered. The ferryl ion chemistry becomes significant in the iron redox cycling when this species is considered as an active intermediate in Fenton chemistry and under night time conditions the iron redox chemistry is controlled by the ferryl ion reactivity. The partitioning of iron between its two main oxidation states (+II and +III) in cloud droplets, which is the indicator of the iron oxido-reduction potential, does not change significantly between the two cases. However, for the non-radical case, the ferryl ion concentration is up to four orders of magnitude higher than the OH concentration highlighting its potential role in oxidative capacity of cloud droplets. 相似文献
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Mineralization of dinitrotoluenes and trinitrotoluene of spent acid in toluene nitration process by Fenton oxidation 总被引:1,自引:0,他引:1
Fenton's reagent, UV/H2O2 and UV/Fenton's reagent were employed to mineralize dinitrotoluene (DNT) isomers and 2,4,6-trinitrotoluene (TNT) of spent acid in toluene nitration process. The bench-scale experiments were conducted to elucidate the influence of various operating variables on the performance of removal of total organic compounds (TOC) from spent acid, including reaction temperature, concentration of ferrous ion and H2O2 dosage. It is remarkable that organic compounds were completely mineralized by Fenton oxidation, of which removal efficiency is superior to that of UV/H2O2. Nevertheless, it makes slight difference between Fenton oxidation and UV/Fenton oxidation. According to the spectra identified by gas chromatograph/mass spectrometer (GC/MS), it is proposed that oxidative degradation of DNT isomers leads to o-, m-, p-mononitrotoluene (MNT) and 1,3-dinitrobenzene respectively. Besides, the oxidation of 2,4,6-TNT gives the 1,3,5-trinitrobenzene intermediate. Apparently, Fenton oxidation is promising for purification of spent acid industrially. 相似文献
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Fenton试剂对富营养化湖水黑臭的氧化降解作用 总被引:3,自引:0,他引:3
通过室内实验,研究Fenton试剂对富营养化水体黑臭物质氧化降解作用。实验结果表明,在黑臭的富营养化水中投加Fenton试剂20 min后,水体臭味明显降低,90 min后水体臭味全部消除;水体浊度、色度有显著改善,水体浊度、色度去除率分别达73.73%和93.11%,显著高于对照组的53.4%和22%;水体溶解氧量显著提高;水体的pH值保持在7左右。鱼类毒理实验结果表明,最佳剂量的Fenton试剂对实验鱼类无急性毒性作用。 相似文献
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Photocatalytic degradation of 5-nitro-1,2,4-triazol-3-one NTO in aqueous suspension of TiO2. Comparison with Fenton oxidation 总被引:1,自引:0,他引:1
5-nitro-1,2,4-triazol-3-one (NTO) is a powerful insensitive explosive, present in industrial waste waters. A remediation method based on photochemical decomposition and Fenton oxidation of NTO has been evaluated by monitoring the mineralization of 14C-labelled NTO. The TiO2-catalyzed photodegradation (lambda > 290 nm, TiO2 0.4 g/l, NTO 150 mg/l)) leads to the complete mineralization of NTO in 3 hours. This degradation involves a simultaneous denitrification and ring scission of NTO leading to nitrites, nitrates and carbon dioxide. No significant photo-degradation of NTO was detected in the absence of the catalyst. Long term irradiation over one week, leads to a complete degradation of concentrated NTO (5 g/l), suggesting that this method could be useful to clean-up NTO wastes. Fenton oxidation offers an efficient cost-effective method for NTO remediation. This reaction is faster that the TiO2 catalyzed photolysis and find application on the mineralization of high concentrations of NTO (15 g/l). Fenton oxidation provokes ring cleavage and subsequent elimination of the two carbon atoms of NTO as CO2. During this reaction, the nitro group is completely transformed into nitrates. 相似文献
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对絮凝预处理后的垃圾渗滤液进行Fenton氧化处理。通过微分法对Fenton氧化的反应级数进行求解,确定其反应级数为2,并初步建立了Fenton氧化的动力学模型,即1/c=1/c0+kt,由此建立起来的降解的动力学模型与实验数据相吻合;在4个实验基准条件下———初始COD浓度为960 mg/L、pH值4、H2O2投加量0.4 mol/L、nH2O2/nFe2+3∶1,探讨了其中某一变量对反应速率的影响。实验水样为絮凝反应出水,进水COD浓度为912~960 mg/L,出水COD浓度为80~112 mg/L,COD去除率在87%~92%之间,表明Fenton试剂能够有效地处理垃圾渗滤液。 相似文献