天津快速的经济发展造成的环境问题及具对策

直面冷峻的环境现状,每一个有理性与责任感的公民无不忧心如焚.蔽日的烟云、腥臭的污河、毒化的农田和振聋发聩的噪音一刻不歇地疯狂考验和鞭笞着人们从心灵到生理的忍耐极限.本文使用大量详实的数据还原出天津环保的真相,社会各界的高度关注、积极参与和成效卓著的努力让我们对天津山清水秀的明日充满了期待.     

浅析土壤环境中的镉的影响

由于工业的污染使土壤中镉的含量增加,从而直接导致对食物链的影响,文章以镉为例,进行研究.而研究高等植物是生态系统的重要组成部分,一个平衡、稳定的生态系统生产健康、优良的高等植物.因此,利用高等植物的生长状况诊断土壤污染,是土壤毒理诊断的重要方法之一.     

"难缠"意味着什么

一次,我国一家工厂想接一位德商的棉布袋订单.对方要求,棉布袋的材料必须是本色棉布,两面的图案须用6种颜色印刷,而且对袋子的尺寸和提手的针脚都作了严格的规定.德商没有当场与这家工厂的厂长签约,而是提出在做出符合标准的样品后,再谈今后的合作.     

中俄界河黑龙江沿岸地区自然保护区建设和管理研究

随着生产力水平的不断提高和世界经济一体化趋势的快速发展,国际河流已成为有关国家开发的热点,国际河流的生态保护与生态安全是国家维护自身生态安全的前沿.界河--黑龙江流域可持续发展,对边境地区的稳定.防止流域生态退化和保护黑龙江流域森林、黑土地、湿地等资源具有重要意义.界河沿岸地区的自然保护区在保护该地区的生态环境,生物多样性、生态系统功能和国土安全方面起到了非常重要的作用.文章介绍了界河沿岸地区自然保护区的发展状况以及数量、面积、类型、分布和管理等现状,分析了制约自然保护区发展的主要因素提出了因地制宜的建设该地区自然保护区的有效措施及发展方向.     

型煤使用效果的实验分析

近些年来,随着工企业的不断增多和经济的迅猛发展,环境的污染问题越来越受到人们的重视和关注,在这种情况下,导致了各种洁净性型煤的应运而生.那么,通过型煤与原煤燃烧的对比试验,对它的燃烧特性进行了测试,证明燃烧型煤可降低烟尘和SO2的排放,并提高炉膛的温度.     

循环经济:经济与环保的双赢

上世纪的80年代到90年代,循环经济已成为世界发达国家的经济经济发展的模式.现代循环经济作为一个完整的系统概念,最早是我国一些学者考察德国对废弃物管理的实践后于1998年引入的.     

加强领导开创环保工作的新局面

一、认清形势,增强做好环境保护工作的紧迫性和责任感 过去的一年,在各级党委、政府的正确领导和大力支持下,通过各级环保部门的积极努力,我区环境质量总体保持稳定,重点城市、重点区域和流域的环境质量有所好转,生态环境恶化的趋势初步得到遏制,环境保护工作取得明显进展.这些成绩是在自治区经济快速发展当中,资源、能源消耗较大的情况下取得的,困难多、难度大,成绩来之不易.借此机会,我代表自治区人民政府向辛勤工作在全区环保战线上的广大干部职工表示衷心的感谢和亲切的问候.     

电石渣综合利用研究进展

详细介绍了电石渣在生产建材,治理环境污染,生产化工产品等方面的利用,并对它们在处理效果,创造的经济效益及实际应用过程中遇到的问题进行了分析.提出了一种处理电石渣的有效方法--生产具备高附加值的纳米碳酸钙,在实现经济效益的同时,还能创造良好的环境效益及社会效益.     

室内环境污染问题浅析

室内环境质量是关系人们健康生活的重要问题之一,长期以来人们往往把目光更多的投向室外环境污染,但由于人的一生大部分时间是在室内度过的,因此,居室环境对人的日常生活有着重大影响,居室的选址、设计、建设以及传统的烹调和取暖造成的室内环境污染都会对人类健康产生重大影响.文章探讨并分析了室内环境主要污染物的种类.危害及其来源,同时针对室内环境污染的现状提出了控制室内污染的几点对策.     

试论我国环境污染减排中经济制度的建立

建立环境污染减排经济制度的必要性 我国在环境污染治理方面至今没有开设独立的税种,环境税的缺位客观上有的3大不良后果:一方面不能筹集到污染减排需用的专项资金;另一方面不能调动污染者减排污染的积极性;再次减排没有税收的调节,造成实施污染方法产生的产品比污染减排的产品有价格优势,不利于消费者绿色消费观念的建立.     

Experimental investigation of the effect of sediment transport patterns on the adsorption of cadmium ions onto sediment particles

The mechanism of flow turbulence, sediment supply conditions, and sediment transport patterns that affect the adsorption of cadmium ions onto sediment particles in natural waters are experimentally simulated and studied in this study both in batch reactors and in a turbulence simulation tank. By changing the agitation conditions, the sediment transport in batch reactors can be categorized into bottom sediment-dominated sediment and suspended sediment-dominated sediment. It is found that the adsorption rate of bottom sediment is much less than that of suspended sediment, but the sediment transport pattern does not affect the final (equilibrium) concentration of dissolved cadmium. This result indicates that the parameters of an adsorption isotherm are the same regardless of the sediment transport pattern. In the turbulence simulation tank, the turbulence is generated by harmonic grid-stirred motions, and the turbulence intensity is quantified in terms of eddy diffusivity, which is equal to 9.84F(F is the harmonic vibration frequency) and is comparable to natural surface water conditions.When the turbulence intensity of flow is low and sediment particles stay as bottom sediment, the adsorption rate is significantly low, and the adsorption quantity compared with that of suspended sediment is negligible in the 6 h duration of the experiment. This result greatly favors the simplification of the numerical modeling of heavy metal pollutant transformation in natural rivers. When the turbulence intensity is high but bottom sediment persists, the rate and extent of descent of the dissolved cadmium concentration in the tank noticeably increase, and the time that is required to reach adsorption equilibrium also increases considerably due to the continuous exchange that occurs between the suspended sediment and the bottom sediment.A comparison of the results of the experiments in the batch reactor and those in the turbulence simulation tank reveals that the adsorption ability of the sediment, and in particular the adsorption rate, is greatly over-estimated in the batch reactor.     

Adsorption of phenolic compounds from aqueous solutions by aminated hypercrosslinked polymers

Two novel polymers （NJ-1 and N J-2） were synthesized by chemically modified a hypercrosslinked polymer NJ-0 with dimethylamine and trimethylamine, respectively. The comparison of the adsorption properties of the three polymers toward phenol, resorcin and phloroglucin was made. The study focused on the static equilibrium adsorption behaviors and the adsorption thermodynamics. Freundlich equation was found to fit the adsorption results well. The effect of amino groups introduced onto the surface of the resin and the structure of phenolic compounds on the adsorption were also studied. The hydrogen-bonding interaction and electrostatic interaction could happen between the amino groups and the adsorbates. The adsorption impetus increased as quantity of hydroxyl groups increased, but the adsorption capacity decreased due to the drop of the matching degree of the aperture of resins and the diameter of adsorbate molecules.     

厌氧氨氧化过程中COD及pH与基质浓度之间的关系

分析了上向流厌氧氨氧化生物滤池中氮素化合物浓度、COD和pH变化规律以及ANAMMOX活性和生物量的分布规律,利用数理统计的方法研究了厌氧氨氧化过程中COD和pH与氮素基质浓度之间的关系.结果表明,溶解氧和氮负荷的共同作用使得ANAMMOX活性和生物量的分布沿滤层深度呈"山脊"状不均匀分布;异养反硝化的存在和H+的消耗使得厌氧氨氧化过程中COD和pH分别呈降低和升高趋势;100 mg/L以下的有机物浓度对厌氧氨氧化菌的影响不大,且COD和pH与基质NH4+-N浓度之间呈良好的线性相关关系.本试验中COD-NH4+-N和pH-NH4+-N拟合直线的斜率分别为1.113 8±0.052 2和-0.111 3±0.001 2,置信度为95%,平均相关系数R2分别为0.982 3和0.985 0.     

Influence of lactic acid on the two-phase anaerobic digestion of kitchen wastes

To evaluate the influence of lactic acid on the methanogenesis, anaerobic digestion of kitchen wastes was firstly conducted in a two-phase anaerobic digestion process, and performance of two digesters fed with lactic acid and glucose was subsequently compared. The results showed that the lactic acid was the main fermentation products of hydrolysis-acidification stage in the two-phase anaerobic digestion process for kitchen wastes. The lactic acid concentration constituted approximately 50% of the chemical oxygen demand （COD） concentration in the hydrolysis-acidification liquid. The maximum organic loading rate was lower in the digester fed with lactic acid than that fed with glucose. Volatile fatty acids （VFAs） and COD removal were deteriorated in the methanogenic reactor fed with lactic acid compared to that fed with glucose. The specific methanogenic activity （SMA） declined to 0.343 g COD/（gVSS-d） when the COD loading were designated as 18.8 g/（L-d） in the digester fed with lactic acid. The propionic acid accumulation occurred due to the high concentration of lactic acid fed. It could be concluded that avoiding the presence of the lactic acid is necessary in the hydrolysis-acidification process for the improvement of the two-phase anaerobic digestion process of kitchen wastes.     

Composition analysis of colored dissolved organic matter in Taihu Lake based on three dimension excitation-emission fluorescence matrix and PARAFAC model, and the potential application in water quality monitoring

Taihu Lake is one of the five biggest lakes in China. Surface water samples from 26 sampling sites of Taihu Lake were collected. Furthermore wet chemical analysis （CODCr and BOD5） and measurement of three dimensional excitation-emission matrix （3DEEM） spectra in the laboratory have been conducted. Using parallel factor analysis （PARAFAC） model, three components of colored dissolved organic matter （CDOM） have been identified successfully, based on the analysis of 3DEEM data. The characteristics of the three components also have been described by comparing them to some components of CDOM, identified in earlier researches. Meanwhile, spatial variations of concentration for the three components in Taihu Lake have been analyzed, and the result indicates that the concentration of component 1 depends more on the situation of wastewater pollution and can be used as the indicator of wastewater pollution. The relationship between the concentrations of the three components and results of the wet chemical analysis show that none of the three components can be used as indicators of gross organic matter in water. However, the concentrations of all the three components have obvious linear relationships with the BOD5 value, especially for component 1 （r = 0.72878）. Finally, the potential applications of the composition analysis based on 3DEEM and PARAFAC model in water quality monitoring have been illuminated.     

Bioaccumulation of heavy metals in fishes from Taihu Lake, China

The Cr,Zn,Cu,Cd,Pb contents were determined in Cyprinus carpio Linnaeus,Carassius auratus Linnaeus,Hypophthalmichthys molitrix and Aristichthys nobilis,which were caught from Meiliang Bay,Taihu Lake,a large,shallow and eutrophic lake of China.The results showed that:(1)the Cr,Cu,Pb,Cd contents in the edible parts of the four fish species were much lower than Chinese Food Health Criterion(1994),but the Zn contents were higher than the Criterion;(2)Cd contents were the highest in the liver of fish,Pb contents were almost the same in all organs of fish,Cr contents mainly enriched in the skin and gonads,Zn contents were the highest in the gonad(♀),and Cu contents were the highest in the liver;(3)the total metal accumulation was the greatest in the liver and the lowest in the muscle.The total metal accumulation was the highest in C.auratus L.This investigation indicated that fish products in Taihu Lake were still safe for human consumption,but the amount consumed should be controlled under the Chinese Food Health Criterion to avoid excessive intake of Zn.     

Emissions of SO2, NO and N2O in a circulating fluidized bed combustor during co-firing coal and biomass

This paper presents the experimental investigations of the emissions of SO2, NO and N2O in a bench scale circulating fluidized bed combustor for coal combustion and co-firing coal and biomass. The thermal capacity of the combustor is 30 kW. The setup is electrically heated during startup. The influence of the excess air, the degree of the air staging, the biomass share and the feeding position of the fuels on the emissions of SO2, NO and N2O were studied. The results showed that an increase in the biomass shares resulted in an increase of the CO concentration in the flue gas, probably due to the high volatile content of the biomass. In co-firing, the emission of SO2 increased with increasing biomass share slightly, however, non-linear increase relationship between SO2 emission and fuel sulfur content was observed. Air staging significantly decreased the NO emission without raising the SO2 level. Although the change of the fuel feeding position from riser to downer resulted in a decrease in the NO emission level, no obvious change was observed for the SO2 level. Taking the coal feeding position R as a reference, the relative NO emission could significantly decrease during co-firing coal and biomass when feeding fuel at position D and keeping the first stage stoichiometry greater than 0.95. The possible mechanisms of the sulfur and nitrogen chemistry at these conditions were discussed and the ways of simultaneous reduction of SO2, NO and N2O were proposed.     

Adsorption thermodynamics and kinetic investigation of aromatic amphoteric compounds onto different polymeric adsorbents

The adsorption behavior of p-aminobenzoic acid and o-aminobenzoic acid onto the different polymeric adsorbents was systematically investigated as a function of the solution concentration and temperature.Experimental results indicated that the equilibrium adsorption data of the four polymeric adsorbents fitted well in the Freundlich isotherm.The adsorption capacity of multi-functional polymeric adsorbent NJ-99 was the highest,which might be attributed to the strong hydrogen-bonding interaction between the amino groups on the resin and the carboxyl group of aminobenzoic acid.The adsorption capacity of o-aminobenzoic acid onto any adsorbent was higher than p-aminobenzoic acid.Thermodynamic studies suggested the exothermic,spontaneous physical adsorption process.Adsorption kinetics results showed that the adsorption followed the pseudo-second-order kinetics model and the intraparticle mass transfer process was the rate-controlling step.     

Sorption and cosorption of the nonionic herbicide mefenacet and heavy metals on soil and its components

Sorption and cosorption of the nonionic herbicide mefenacet and two typical metals (copper and silver) on black soil and its components (kaolinite and humic acid) were investigated. It was found that because of their different valences and properties, Cu²⁺and Ag⁺ presented different effects on the sorption of mefenacet. Due to the competition of Cu²⁺, along with the shells of dense water formed by its surface complexation, for sorption surface area with mefenacet, the addition of Cu²⁺ decreased the sorption amount of mefenacet on soil and its components, especially on humic acid. However, the addition of Ag⁺ significantly enhanced the sorption of mefenacet, which was attributed to the softness of the cation that weakened the hydrophilicity of the local region around Ag⁺-complexed functionalities, and thus mitigated the competitive sorption of water. In addition, the sorption of mefenacet on soil with or without the two metals was generally decreased with increasing pH, which was caused by the hydrolysis of carbonyl and carboxyl groups on the surface of the sorbents, π-π interaction between mefenacet and the soil organic matter, and so on. On the other hand, the presence of mefenacet seemed to have little effect on the sorption of Cu²⁺ and Ag⁺, indicating that Cu²⁺ and Ag⁺ might be sorbed strongly on the tested sorbents and the mefenacet added was too low in concentration to affect the sorption of the metals.     

基于电子鼻土壤与地下水污染修复现场TVOC和恶臭的评估

根据上海某土壤与地下水污染修复现场情况,应用自主研发的电子鼻系统(iSA-M1)分别对未修复及修复过程中的土壤和地下水、修复场地上空及周边空气中的VOCs和恶臭类气体进行检测.结合前期研究所得TPI和OPI公式,求得各点的值,并将其用图表示.结果表明:①修复后TVOC和恶臭的浓度总体呈下降趋势;②在土壤和地下水修复过程中,VOCs和恶臭的挥发受气象要素和作业的影响,其浓度在总体下降的过程中伴随着阶段性上升现象;③结合GIS技术,电子鼻能初步用于评估土壤和地下水修复现场造成的空间污染情况及对周围居民产生的影响.但造成影响程度的具体细化分级还需要进一步研究.