Development and analysis of high-performance green concrete in the urban infrastructure

Cement production accounts for approximately 5% of total global CO₂ emissions from all human activities. In addition, the consumption of virgin aggregates for concrete infrastructure has created virgin material scarcity issues in many areas of the USA. High-performance green concrete (HPGC) with fly ash and recycled aggregates can help reduce the demand for material inputs and reduce pollution outputs associated with bulk material flow of urban concrete. Structural and durability tests showed that HPGC containing fly ash and 50% recycled aggregate (100% of the coarse aggregate fraction) performed equally or better than 100% ordinary Portland cement concrete with the same cementitious content. Durability improvements were more significant with Class F than Class C fly ash. For both Class F and Class C fly ash, greater per cent replacement of Portland cement with fly ash led to slower and lower strength gain, but still within acceptable strength criteria for Colorado Department of Transportation Class B concrete. This paper quantifies the sustainability of HPGC in urban infrastructure by addressing structural performance, environmental, economic and resource depletion impacts.     

Properties of alkali-activated fly ash: high performance to lightweight

Alkali ash material (AAM) concrete is a unique material that is sustainable and cost-effective because it utilises waste fly ash, and has properties superior to other concrete products. The AAM concrete described here is produced from the addition of inexpensive chemicals to fly ash. AAM can be used to create a wide range of materials including high performance concrete (HPC-AAM) and lightweight (LW-AAM). The high performance AAM provides rapid strength gain along with high ultimate strengths of more than 110 MPa (16000 psi). LW-AAM can produce materials with densities ranging from 1200 to 2200 kg/m³ and compressive strengths from 2 (290 psi) to 65 MPa (9500 psi). Both HPC-AAM and LW-AAM have far better environmental resistance than Portland cement concrete, resisting attack from sulphuric acid (H₂SO₄), hydrochloric acid (HCl) and organic acids. AAMs resists freeze–thaw attack and high abrasion, possesses low chloride permeability and does not exhibit alkali silica reactivity.     

Recovery of copper from small grain size fractions of municipal solid waste incineration bottom ash by means of density separation

Small grain size fractions of municipal solid waste incineration (MSWI) bottom ash (BA) contain elemental and chemically bonded metals in appreciable amounts, especially copper. Investigations with a centrifugal concentrator were carried out using samples, which had been treated with different impact devices. Partly the impacts of single devices were visible in outlines, but mostly the surfaces of the metals were still covered with mineral residues. To generate copper rich fractions, parameters of the separation process should ensure mass yields <2%, best between 0.5 and 1%. The density of the concentrates is then generally >3.2 g/cm³. Best results were achieved with material from a special treatment train which is adapted to grain sizes <2 mm. Reliable copper contents between 20 and 40% (single runs >50%) could be realised. However, considering the required mass yields, referred to this subset only 150–170 g copper would be recovered from 1 Mg MSWI BA. Furthermore, this copper is only in parts present in elemental form. A dependable added value of such treatment step seems to be given only, if that enables a recycling of the mineral aggregates (tailings) in parallel to avoid landfill costs.     

Evaluation of Brasilia wastewater sludge as a biomass resource for the production of energy by gasification simulation

This work evaluated the sludge potential of the Wastewater Treatment Plant (ETA) in the city of Brasília to be used as a fuel by gasification. It is known that ETA sludge is a significant environmental liability, since current legislation restricts its final disposal. For this, the chemical characterisation of ETA sludge was performed by immediate and elemental analysis. No traces of heavy metals were observed, and the moisture (ω) and ash contents were 31.17 and 51.77%, respectively, different from those already reported in the literature because the composition depends on the water treatment technology employed. The gasification process was numerically simulated; once dry, it constitutes a residue with an energy content (HHV) of 22.4498 MJ kg^?1, comparable with other types of biomass currently used for large-scale energy generation by thermochemical processes (e.g. agricultural residues, wood and sugar cane bagasse). For the numerical simulation with an equivalence ratio (Φ) near 3, higher concentrations of CO and H₂ can only be achieved with ω lower than 15%. The results showed that gasification can be an attractive option for the disposal and use of a renewable waste resource, such as ETA sludge, in an environmentally safe way, and it is allowed by local legislation.     

The effects of FeCl3 on the distribution of the heavy metals Cd, Cu, Cr, and Zn in a simulated multimetal incineration system

Recognizing that waste-derived chlorine can enhance heavy metal emissions by forming volatile metallic chlorides during municipal solid waste (MSW) combustion, and that in Taiwan, FeCl3-containing sewage sludge may either be landfilled or coincinerated with other MSW, this study thus investigated the effects of FeCl3 on the speciation and partitioning of heavy metals in a multimetal incineration system by using a tubular furnace and FeCl3-spiked simulated wastes. The molar ratio of chlorine content to heavy metal content (referred to as the Cl/ M ratio), ranging from 3 to 200, was used as a parameter to evaluate the effects of chlorine on the movement of heavy metals between the incinerator discharges. Results indicate that speciation and partitioning were related to the affinity between the chlorine and the heavy metals and between chlorine and hydrogen in the combustion system. The effectiveness of increasing the Cl/M ratio to the formation potential of metallic chlorides and on the shift of heavy metals from the bottom ash to the fly ash and/or the flue gases was found to have in increasing order as follows: Zn>Cu>Cr, a phenomenon basically reflecting the volatility of the heavy metals and their chlorides formed during combustion.     

Effect of ozone pre-treatment on sludge production of aerobic digestion processes

The effect of ozone in a chemical sludge disintegration process was evaluated. Sludge solution chemical oxygen demand (COD), total suspended solids (TSS) and settling were investigated in single and sequential processes. A significant influence of ozone dose on sludge disintegration was observed: ozone was utilised to degrade the soluble organic matter and to destroy cell surfaces and release the cell liquids. For a single ozonation step, we found an optimum ozone dose in the range of 0.008–0.013 g O₃/g TSS to give the best COD and TSS removal efficiency. Disintegrated sludge was treated in a sequential process consisting of consecutive ozonation and bio-aeration (i.e. O₃ + biological treatment). The tendency was dependent on accumulated ozone, treatment time and operational conditions. An accumulated ozone dose of 0.055 g O₃/g TSS in two separate ozonation processes followed by biological treatments led to COD and TSS removal efficiency of 53 and 46.6%, respectively. The removal efficiency was improved by increasing aerobic treatment time and/or by mixing ozonated sludge with non-ozonated sludge. The settling ability of sludge was found to be fast at very low specific ozone doses. An observed tendency was the effect of ozone on cell disintegration and protein liberation. The use of sequential processes improved the settling tendency of sludge.     

Selection of an effective sludge dewatering system for a small wastewater treatment plant

The Jahra Plant was commissioned in 1981 as a secondary treatment plant employing the extended aeration process. The plant has been upgraded since that time by constructing additional tertiary filtration units to improve effluent quality. The plant has a design capacity of 66 000 m³/d. At present, the daily inflow to the plant is about 47 000 m³/d of domestic sewage. The sludge produced at the Jahra Plant can be classified as excess activated sludge which combines the primary and secondary solids. At present, there are 30 drying beds receiving about 100 m³ of sludge dally. Sewage-sludge production represents about 0.5% of the total flow treated at the plant and is increasing yearly with increases in population and water consumption. Present dewatering systems are not adequate to cope with expansion in sewage treatment. Increasing the capacity of the existing plant would require more drying beds that could exacerbate existing odor problems. Some dewatering systems, such as the belt filter press and the centrifuge, have been tested to determine the most effective one under local conditions. Appropriate polymer doses for thickening have been determined. This paper describes present sludge dewatering units and operating techniques which have been developed during the operation of this facility.     

Comparative analysis of land use and lake water quality in rural and urban zones of south Chennai, India

Chennai city, the capital of Tamil Nadu state in South India, has been experiencing rapid expansion since the last two decades, resulting in major changes in land use and degradation of wetlands. Small lakes in the peri-urban areas face severe strain on their environment due to transition of rural to urban conditions, leaving at stake their aquatic health and intended uses. This paper studies the role of urbanization and land use changes in the water quality of peri-urban (Rajakilpakkam) and rural (Vengaivasal) lakes. Water samples were collected and analysed for temperature, total dissolved solids, major ions, nutrients and biological oxygen demand as per standard methods. The temperature, pH and biological oxygen demand did not differ between lakes, while total dissolved solids (p = 0.008), alkalinity (p = 0.000), total hardness (p = 0.001) and phosphate (p = 0.000) were significantly higher in Rajakilpakkam. Seasonal and spatial variations in water quality between the lakes showed the direct impact of rapid and uncontrolled growth of built-up areas in the catchment area, in enhancing waste water inflows with inorganic salts and nutrients in Rajakilpakkam lake compared with Vengaivasal lake. Urbanization of the catchment and encroachments in Rajakilpakkam lake tends to reduce the social interdependence of lake and community and promote disuse, leading to decline in water quality. The impending environmental costs caused by urbanization to these lakes will only be tackled, if the main issues of domestic and industrial discharges and encroachments are addressed properly.     

Wastewater management and the east-bound growth of the city of Kolkata: a compatibility analysis

Kolkata, home of 4.5 million people, is generating 1112 million liters of sewage per day and facing the challenge of managing this wastewater. The 125 km² wide wetland on the eastern fringe of the city, popularly known as the East Kolkata Wetlands is serving as a natural sewage treatment plant for more than a century where nearly 78 % of city sewage goes through an intricately designed canal network. This wetland is a designated RAMSAR site where the sewage treatment process is a rare example of an intertwined symbiotic relation between wastewater treatment and wetland aquaculture, where livelihood dependence of the local people on sewage-fed fisheries becomes of strategic importance in sustainable performance of the system. An aggressive urban expansion in the eastern fringe of the city is disturbing this age-old eco-balance by making this sewage water pisciculture less profitable. There is push factor due to reduced attraction of the wastewater fisheries and a pull factor due to emergence of alternative livelihood options through rapid urbanization. To protect wetland in its original form, the civil society and the administrative authorities are designing active interventions. However, these are not generating expected results as these instruments are targeting to mitigate the push factor only without paying much heed to the push–pull interactions.     

The stabilization of sewage sludge by pulverized fuel ash and related materials

In Hong Kong, with the implementation of the Strategic Sewage Disposal Strategy (SSDS), there will be a substantial increase in the generation of sewage sludge. An alternative method using pulverized fuel ash (PFA) generated from a local coal fire power station and lime to stabilize the sludge for potential beneficial uses is studied. The effects of the stabilizing agents on the leaching of heavy metals and pasturing of coliform are studied. The results show that PFA together with a small percentage of lime addition has the potential to reduce heavy metal leaching and reduce the total coliform content of the stabilized sewage sludge.     

Energy and exergy analysis of solar hybrid adsorption refrigeration system

In this paper, performance of a solar hybrid adsorption refrigeration (AR) system is investigated experimentally. Such a system was built and tested under the conditions at National Institute of Technology Calicut, Kerala, India. The hybrid system has been designed for heating 50 l of water from 25 to 90°C as well as cooling 10 l of water from 25 to 10°C. The experimental results demonstrate that the refrigerator has a cooling capacity of 47–78 W with a cycle coefficient of performance (COP) of 0.19 and maximum possible COP of 0.45. In exergy analysis of the system, the irreversibility and exergetic efficiency of each component of the system have been calculated. The exergy analysis reveals that the main source of irreversibility is the adsorbent bed of the AR system, emphasising that the input heat energy is not utilised efficiently due to material constraints. The exergetic efficiencies of condenser, expansion device, evaporator and adsorbent bed are found as 42.3%, 79.8%, 54.7% and 11%, respectively.     

Valuable utilisation of spray dryer ash and its performance in structural concrete

This paper focuses on the valuable utilisation of spray dryer ash (SDA) and investigates its performance in concrete for structural applications. Based on the challenges associated with the disposal of coal combustion products (including SDA) and the economic costs linked to cement production, this research seeks to provide an environmentally friendly and more cost-effective concrete product by utilising SDA in partial replacement of cement in concrete. With the exception of a relatively high-sulphur content, SDA exhibits very useful properties that are closely related to Class C fly ash and Portland cement.

Experimental tests were carried out to determine the effect of SDA replacement of Portland cement (ranging from 0 to 50% replacement) on the compressive strength, bond strength, freeze-thaw performance and corrosion resistance of concrete. The addition of SDA in non-air entrained concrete provided a general increase in its strength with optimal limits ranging between 25 and 35% replacement. The addition of SDA produced a negligible effect on the freeze-thaw durability of the concrete (air entrained). Results for corrosion performance were not as definitive, but indicate that the use of SDA does not significantly change the likelihood of reinforcing bar corrosion.     

贵州省城市污泥重金属组成特征与农用风险评价

分别选取了贵州省7个主要城市的10个典型污水处理厂脱水污泥样品进行检测，统计了2009~2012年污泥中重金属Cu、Zn、Pb、Cd、Ni、Cr、As、Hg的含量。结果表明，城市污泥中重金属含量受到各地区工矿业发展的影响，部分重金属在某一污水处理厂出现了远大于其它地区的极值，具有明显的地域特征。2009~2012年贵州省城市污泥重金属的变化表现为As、Hg呈升高趋势，其它重金属变化趋势不明显，As、Hg升高可能是因为贵州省近年来燃煤消耗量增加，烟气排放污染所致。对污泥重金属的农用风险评价显示，贵阳中部（S2）、黔西地区(S9)污泥农用重金属的生态风险较高，不推荐直接施用，其它各地区污泥农用风险较低，可以进行农用，建议各污水处理厂应根据本地区污泥重金属特征制定合理的污泥处置措施     

Assessment of physicochemical characteristics of Ganga Canal water quality in Uttarakhand

Assessment of physicochemical parameters of Ganga Canal water was carried out during 2012–2013 at Haridwar (Uttarakhand) with two different sites, i.e., Bhimgoda Barrage (site 1—control site) and Bahadrabad (site 2—contaminated site), where canal water flows with loads of pollution from highly commercial and industrial areas. During investigation, maximum turbidity (287.72 ± 56.28 JTU), total solids (1167.60 ± 303.90 mg l^?1), free CO₂ (1.88 ± 0.22 mg l^?1), total hardness (60.14 ± 1.13 mg l^?1), pH (7.1 ± 0.13), nitrate (0.048 ± 0.010), nitrite (0.019 ± 0.001), biochemical oxygen demand (2.866 ± 1.098), chemical oxygen demand (6.8 ± 2.61) and phosphate (0.087 ± 0.015), while minimum velocity (1.71 ± 0.19 ms^?1), transparency (0.12 ± 0.08 m) and dissolved oxygen (7.95 ± 0.44 mg l^?1) were recorded in monsoon season at site 2 in comparison with site 1. The mean values of these parameters were compared with WHO and ISI standards and found significant differences (p < 0.05) in the mean values of turbidity, total solids, pH, dissolved oxygen, free CO₂ and total hardness with sampling sites. The turbidity of both the sites 1 and 2 was recorded above the permissible limit. Turbidity of site 2 is much higher than of site 1, so it is counted as more polluted. The values of the studied parameters were more during monsoon season and summer season at site 2 as compared to site 1. The results indicated that most of the physicochemical parameters from Ganga Canal system were within or at periphery in comparison with permissible limit of ISI and WHO for drinking water and therefore may be suitable for domestic purposes, but it requires perceptible consideration due to intense changes in climate and increase in pollution.     

Assessment of polychlorinated dibenzo-p-dioxins and dibenzofurans in sludges according to the European environmental policy

The amount of sewage sludge generated in Europe is expected to surpass the 10 million tons/year in 2006 as a result of the waste water treatment process according to the Water Policy in European Union. Sewage sludge is what is left behind after water is cleaned in waste treatment plants and is characterized for this high content in nitrogen and phosphorous that could be of great importance in agriculture as fertilizer or soil conditioner. On the other hand, pollutants like metals and organic contaminants are usually removed from water and are accumulated in the sewage sludge, reaching the food chain if their concentrations are not below the safe limits established by the European legislation. The latter issue is of great concern nowadays and in this sense, different works alert against the use of the sewage sludge in agriculture arguing that serious illnesses, even resulting in death as well as adverse environmental impacts are associated to the application of sewage sludge. This work is a continuation of a former comprehensive survey on of priority organic pollutant in sludges for agricultural purposes carried out by our group in Catalonia and this time is focused on the polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F), one of the most toxic group of organic compounds listed in the Work Document on Sludge which is the reference tool in this field in Europe and is also included in the Stockholm Convention. Eighty eight samples were collected from the end of 2003 to April 2006 and the concentrations detected were lower than the 100 ng/kg I-TEQ limit recommended by the European legislation (EC, 2000). Thus, sewage sludges generated in Catalonia do not represent a threat to human health if they are used as fertilizers in agriculture.     

Preliminary experiment on fuel consumption and emission reduction in SI engine using blended bioethanol–gasoline and radiator tube-heater

The objective of this research is to investigate the reduction in fuel consumption and emission in spark ignition engine using blended bioethanol-gasoline and novel radiator-tube heater. Different percentages of ethanol – 0, 5, 10, 15, 20, 25 and 30% – are employed. The blended fuel is then pre-heated by sending it into a tube-heater-installed upper tank radiator which has different shape. The results show a significant reduction in fuel consumption and emission in engine. The best economical fuel consumption occurs in the tube-heater with a fin pipe of 10 mm space at 2.153 × 10^?3 cc per cycle or 5.632%. However, the most economical fuel consumption occurs when 25% of bioethanol is added to fuel at 3.175?×?10^?3 per cycle. This decreases fuel consumption by 8.306%. The highest decrease in fuel consumption occurs when fuel blended with 25% of bioethanol and tube-heater of 10 mm 6.236?×?10^?3 cc per cycle or 16.313% is combined. In terms of emission reduction, the tube-heater with a space of 20 mm between fins (Tube 20) using a fuel mixture of 25% ethanol and 75% gasoline produced the lowest CO emissions.     

Climate change impacts on a pine stand in Central Siberia

The objective of this paper is to analyse the impacts of climate change on a pine forest stand in Central Siberia (Zotino) to assess benefits and risks for such forests in the future. We use the regional statistical climate model STARS to develop a set of climate change scenarios assuming a temperature increase by mid-century of 1, 2, 3 and 4 K. The process-based forest growth model 4C is applied to a 200-year-old pine forest to analyse impacts on carbon and water balance as well as the risk of fire under these climate change scenarios. The climate scenarios indicate precipitation increases mainly during winter and decreases during summer with increasing temperature trend. They cause rising forest productivity up to about 20 % in spite of increasing respiration losses. At the same time, the water-use efficiency increases slightly from 2.0 g C l^?1 H₂O under current climate to 2.1 g C l^?1 H₂O under 4 K scenario indicating that higher water losses from increasing evapotranspiration do not appear to lead to water limitations for the productivity at this site. The simulated actual evaporation increases by up to 32 %, but the climatic water balance decreases by up to 20 % with increasing temperature trend. In contrast, the risk of fire indicated by the Nesterov index clearly increases. Our analysis confirms increasing productivity of the boreal pine stand but also highlights increasing drought stress and risks from abiotic disturbances which could cancel out productivity gains.     

江苏省化工园区污水处理厂污泥重金属污染及生态风险评价

污水处理厂的排放污泥是诸多污染物的最终环境归宿之一,其环境影响值得重视。在江苏省全境调查了49家化工园区集中式污水处理厂,对其外排污泥及其浸出液中的5种重金属(砷、镉、铬、汞和铅)含量进行了测定,采用Hakanson潜在生态危害指数法评价了污泥中重金属生态风险。结果表明:49家化工园区污泥浸出液中5种重金属均不超标,但污泥中的砷、铬、汞含量超标,超标率分别为24.5%、6.1%和4.1%,最大超标倍数分别为131、2.12和0.41。污泥中砷含量显著高于我国城市污泥,潜在生态风险程度呈现汞砷铬。从地域分布来看,苏北地区化工园区污泥重金属风险更大。     

Assessment of hydrothermally modified fly ash for the treatment of methylene blue dye in the textile industry wastewater

Dyes and pigments are one of the major water pollutants and if not discharged properly cause ecological disturbance. Considering this, the current study investigates the application of thermal power plant by-product, i.e., fly ash for the elimination of a hazardous methylene blue dye from its synthetic aqueous solution. Experiments were conducted in batch mode to study the effect of pH, temperature, adsorbent dose and contact time. Highest dye removal (94.3%) was achieved at pH 10 using adsorbent dose of 10 g/L in 90 min of contact time at 40 °C. However, for cost-effective operation at neutral pH and room temperature (30 °C), it yields 89.3% dye removal having similar dose and contact time. Equilibrium isotherms for adsorption were analyzed by Langmuir and Freundlich, Temkin and Dubinin–Radushkevich isotherm equations. The results revealed that the best fit model of adsorption closely followed Langmuir adsorption. Based on adsorption isotherm models, thermodynamics parameters ΔG, ΔH and ΔS were calculated. The negative value of ΔG and ΔH revealed that adsorption process was exothermic, spontaneous and physical. The present work suggests that through simple process hydrothermally modified fly ash has the potential to be used as cost-effective and efficient adsorbent for the treatment of wastewater from textile industries.     

Management of sludge from fish ponds at the edge of the Itaparica Reservoir (Brazil): an alternative to improve agricultural production

Sludge generated in intensively managed tilapia fingerling breeding ponds near the Itaparica Dam in the semi-arid Brazilian northeastern region was tested as a soil conditioner to produce lettuce in an effort to mitigate the present environmental impact of the deposition of this sludge, thereby giving it a productive destiny. A greenhouse experiment was performed by mixing the sludge with a Haplic Planosol topsoil, a characteristic soil of the region, so that the sludge corresponded to 0, 25, 50, 75, and 100% of the mixture (substrate). The experiment was set up as a randomized block design with five blocks, each with three pots (5-kg substrate per pot) of the five sludge proportion treatments. One lettuce plant was transplanted into each pot, maintained under greenhouse conditions, and harvested 35 days after transplanting. Sludge, soil, and the substrates were evaluated for nutrient concentration and physical characteristics. Green and dry weights, stem diameter, and nitrogen, phosphorus, and potassium concentrations in the aboveground parts of the lettuce plants were determined. Sludge incorporation into the substrate improved its chemical and physical characteristics. The lettuce plants grew best in the substrate with 75% sludge, increasing its biomass production by 50% and more than doubling its nitrogen uptake.