Characterization of the Leachate in an Urban Landfill by Physicochemical Analysis and Solid Phase Microextraction-GC/MS

The aim of this study is to evaluate extensively the characterization and identification of major pollutant parameters by paying attention to the organic chemical pollution for unregulated dumping site leachate in Eskişehir/Turkey. The study that is first and only one research has been very important data related with before new sanitary landfill site in Eskişehir city. For this purpose, in this study leachate samples were collected in-situ at monthly interval for a period of 8 months. Firstly, thirty three physicochemical parameters were monitored. Secondly, SPME technique was used for identification of organic pollutants. Meteorological data were also recorded for the same sampling period to correlate meteorological data and physicochemical parameters. Mean values are used in the correlation analysis. Correlation is shown only for the relationship between air temperature and NO₃ ⁻. No correlation has been found between rain and leachate quality parameters since the amount of rain was very low during the sampling period. However, analysis results were generally decreased in winter season when each parameter and each sampling point are examined separately. According to correlation between every parameter, especially solid content and dissolved oxygen concentration of leachate is affecting to other parameters. Also, sodium and potassium are changing proportionally with same parameters (suspended solids, fixed solids, dissolved oxygen) and high correlation between chloride and heavy metal concentration is showing. The results were statistically evaluated by use of SPSS 10.0 program. Second part of the study, the leachate was extracted by Solid Phase Microextraction (SPME) technique and then analyzed. Of the methodologies tested in this study, the best one selected was based on 100 μ m polydimethylsiloxane coated fiber (PDMS), headspace with heating (Δ HS) sampling mode and an extraction time of 15 min. at a temperature of 50 ^o C. Thirty three organic compounds in leachate were identified by GC/MS.     

Environmental Monitoring and Impact Assessment of a Solid Waste Disposal Site

The objective of this study is an attempt to conduct an environmentalmonitoring and impact assessment of the On-Nooch solid waste disposal sitein Bangkok, Thailand. Four water and five air sampling stations (2 upwindand 3 downwind directions) were established at the site. Grab water samplesfrom leachate treatment plant and Khlong Song Hong, a nearby stream, werecollected during the rainy and dry seasons. Analytical results of the wastewater discharged by the leachate treatment plant, during dry season showedchemical oxygen demand: 618 mg/l; biochemical oxygen demand: 80 mg/l;suspended solid: 101 mg/l; Total Kjeldahl Nitrogen: 283 mg/l, which werestill higher than standard limit for effluents in Thailand. During the dryseason, results also showed widespread heavy metal pollution from leachate(chromium: 1.03 mg/l; manganese: 1.07 mg/l; mercury: 0.025 mg/l) and werehigher than the allowable level of heavy metals for the Industrial EffluentStandard in Thailand. The direct discharge of untreated leachate into inlandwater will cause considerable water pollution in the study area. Compositeair samples in this study area were collected during the rainy and dryseasons and were analyzed for methane (CH₄), carbon dioxide(CO₂), carbon monoxide (CO), sulphur dioxide(SO₂), nitrogen dioxide (NO₂) andsuspended particulate matter (SPM). The average concentration of SPM rangedbetween 0.1–0.36 mg/m³ for 24-hour average, dependingupon the season. The level of CH₄ and CO₂ inthe ambient air of the study area were found to be 3.48–65.71mg/m³ and 886-1758 mg/m³ respectively which weremuch higher than the normal concentration of CH₄ andCO₂ in the air (CH₄: 2.41 mg/m³;CO₂: 585 mg/m³). Hence, adverse health andenvironmental effects could be expected from water and air pollution.     

Assessment of Pollution Near Landfill Site in Nagpur, India by Resistivity Imaging and GPR

Groundwater pollution in the vicinity of a landfill site in Nagpur, India is assessed with the help of resistivity imaging and GPR tools. The resistivity imaging survey indicates high conductive anomalies in the topsoil as well as the underlying fractured rocks. Significant reflections from the GPR records known as radargrams are extracted with the help of maximum peak module and Hilbert transform module in RADAN 6. These reflections can be attributed to presence of fractures, which are potential pathways for migration of the fluid. The geophysical findings are strengthened by the results of groundwater analysis from wells located close to the profile where resistivity and GPR survey have been carried out. The study has indicated the vulnerability of the unconfined aquifer underlying the predominantly clay layer.     

An Interval-Parameter Fuzzy-Stochastic Programming Approach for Municipal Solid Waste Management and Planning

In this study, an integrated fuzzy-stochastic linear programming model is developed and applied to municipal solid waste management. Methods of chance-constrained programming and fuzzy linear programming are incorporated within a general interval-parameter mixed-integer linear programming framework. It improves upon the existing optimization methods with advantages in uncertainty reflection, data availability, and computational requirement. The model can be used for answering questions related to types, times and sites of solid waste management practices, with the objective of minimizing system costs over the planning horizon. The model can effectively reflect dynamic, interactive, and uncertain characteristics of municipal waste management systems. In its solution process, the model is transformed into two deterministic submodels, corresponding to upper and lower bounds of the desired objective function values under a given significance level, based on an interactive algorithm. Results of the method's application to a hypothetical case indicate that reasonable outputs have been obtained. It demonstrates the practical applicability of the proposed methodology.     

Accumulation of Heavy Metals in Epiphytic Lichens Near a Municipal Solid Waste Incinerator (Central Italy)

The epiphytic lichen Parmelia caperata was usedas biomonitor in the area of a municipal solid wasteincinerator (Poggibonsi, central Italy) to investigatethe levels and the spatial distribution of the heavymetals Al, Cd, Cr, Cu, Fe, Hg, Pb and Zn. Levels ofAl, Cu and Hg were similar to those in unpollutedareas, whereas high values were found for Cr, Zn andespecially Cd. The distribution pattern of the lastthree metals and the exponential relationship of theirconcentrations with distance from the incinerator,showed that the disposal plant is a local source ofatmospheric pollution due to Cd, Cr and Zn. For thesemetals, long-term hazard should be seriously taken into account.     

固体废弃物浸出毒性特性及美国EPA的实验室测定(续完)

围绕固体废弃物浸出毒性特性这个中心,综述了它在有害废弃物的鉴别和管理,在执行陆地处置限制法规过程中的重要作用。以及在保护水资源,特别是地下水资源方面的重要意义,并简要介绍和评论了美国固体废弃物浸出毒性的实验室测定方法ETP和TCLP。     

Assessment of Ground Water Vulnerability and its Application to the Development of Protection Strategy for the Water Supply Aquifer in Owerri, Southeastern Nigeria

Pollution vulnerability of theOwerri regional water supply aquifer wasevaluated as a basis for developing appropriateprotection strategy for the groundwaterresource. The assessment was accomplished usingLegrand, GOD, Siga and DRASTIC models.Techniques of the models generally involvedparameters rating and point count systems, whichare based on the evaluation of various parameterin relation to their capacity for enhancing orattenuating contaminants in the groundwatersystem. Field and laboratory evaluations of theparameters indicate that the Owerri areagenerally occupies a nearly, flat topographywith a relatively high groundwater recharge. Thearea is underlain by predominantly sandyfacies in the Northern area which grades intogravelly sequences towards the southwest. TheSoutheastern area is distinguished by thickclayey facies that thin westwards towards theOwerri metropolis. Effective hydraulicconductivity (Kz) in the downward directionranges from 1.44 × 10^-3 to 5.6 × 10^-9 m s^-1; with the upper limits reflecting coarsesands and gravelly units. The amount of clay andclay-size particles in the sandy and gravellyunits is negligible, suggesting that thesorptive capacity of the units is low. Depth towater table decreases southwards while hydraulichead gradients vary between 0.09 and 0.22.Groundwater occurs in unconfined conditions inmost places except in the southeastern zonewhere it is semi-confined due to the presence ofa clayey unit. The groundwater vulnerabilitymap developed on the basis of the models andseveral other thematic maps shows that theOwerri metropolis and the southwest area ofOwerri have high vulnerability, indicatinggroundwater pollution. The existing wastedisposal sites in these sub-areas should beabandoned and rehabilitated to forstall furtherpollution of the groundwater system. Areas tothe North and Southeast of Owerri have moderateand low vulnerabilities, respectively,indicating the relatively lower sensitivity ofthe groundwater system in the sub-areas tocontamination. The lower sensitivity couldfurther be matched with properly engineeredsanitary landfills in the event of choice ofsites, as an additional protective strategy forthe groundwater system.