Phosphorus leaching under a restored tallgrass prairie and corn agroecosystems

Most studies of phosphorus (P) movement in soil have based their conclusions on patterns of extractable soil P as a function of depth, which has led to the assumption that no substantial leaching loss occurs because of high P-fixation capacity in mineral soils. Few studies have involved high-quality leachate samples collected below the root zone; rather, most have involved tile drainage systems. Equilibrium-tension lysimeters installed at a depth of 1.4 m were used to evaluate and compare P leaching from a restored tallgrass prairie and corn (Zea mays L.) agroecosystems on Plano silt loam soil (fine-silty, mixed, superactive, mesic Typic Argiudoll) in southcentral Wisconsin during a 5-yr period. The corn agroecosystem treatments included nitrogen (N)-fertilized (f) or N-unfertilized (nf) and no-tillage (NT) or chisel-plowed (CP). Mean volume-weighted molybdate-reactive phosphorus (MRP) and total dissolved phosphorus (TDP) concentrations were similar within replicate samples, but always higher in NTf corn than in the prairie or CPf corn systems, though drainage from the CPf corn was always higher than from the NTf corn system. Water-extractable soil P concentrations at any given depth were not positively correlated with leachate concentrations, suggesting that macropore flow causes infiltrating runoff to preferentially bypass the bulk of the soil matrix. Leachate-P concentrations from the natural and managed agroecosystems exceeded 0.01 mg P L(-1) and leaching losses were significantly higher from N-fertilized corn, regardless of tillage, than from the prairie or N-unfertilized corn systems, from which leachate-P concentrations and loads were similar. Increased root growth from N fertilization could cause more macropore formation, preferential flow, and P mineralization from decaying roots compared with N-unfertilized systems, which could contribute to a N-fertilization effect on P leaching.     

Nitrogen and carbon leaching in agroecosystems and their role in denitrification potential

The drainage of water and leaching of dissolved constituents represent major components of agroecosystem mass budgets that have been exceedingly difficult to measure. Equilibrium-tension lysimeters (ETLs) were used to monitor drainage, nitrogen (N), and carbon (C) leaching through Plano silt loam (fine-silty, mixed, superactive, mesic Typic Argiudoll) for a 4-yr period in a restored prairie and N-fertilized no-tillage and chisel-plowed maize (Zea mays L.) agroecosystems. Mean drainage recorded during 4 yr for the prairie, no-tillage, and chisel-plowed ecosystems totaled 461, 1,116, and 1,575 mm and represented 16, 33, and 47% of precipitation plus melting of drifted snow received, respectively. Total inorganic N leaching losses during the 4-yr period for the prairie, no-tillage, and chisel-plowed ecosystems were 0.6, 201, and 179 kg N ha(-1), respectively. Inorganic N leaching represented 26 and 24% of applied fertilizer N additions to the no-tillage and chisel-plowed agroecosystems. Total dissolved C leaching losses were 119, 435, and 502 kg C ha(-1) for the prairie, no-tillage, and chisel-plowed ecosystems, respectively. Sufficient dissolved organic carbon (DOC) and nitrate N (NO3- -N) existed in the prairie and agroecosystems to support subsoil denitrification. Potential denitrification, however, was limited by insufficient lengths of saturated soil conditions in all three ecosystems, the supply of DOC in the agroecosystems, and the supply of nitrate N in the prairie. Based on available DOC and nitrate N, the maximum contribution of denitrification below the root zone in the agroecosystems was less than 25% of the total amount of leached nitrate N and the probable contribution of denitrification was much less.     

Fertilizer source and tillage effects on yield-scaled nitrous oxide emissions in a corn cropping system

Management practices such as fertilizer or tillage regime may affect nitrous oxide (N?O) emissions and crop yields, each of which is commonly expressed with respect to area (e.g., kg N ha or Mg grain ha). Expressing N?O emissions per unit of yield can account for both of these management impacts and might provide a useful metric for greenhouse gas inventories by relating N?O emissions to grain production rates. The objective of this study was to examine the effects of long-term (>17 yr) tillage treatments and N fertilizer source on area- and yield-scaled N?O emissions, soil N intensity, and nitrogen use efficiency for rainfed corn ( L.) in Minnesota over three growing seasons. Two different controlled-release fertilizers (CRFs) and conventional urea (CU) were surface-applied at 146 kg N ha(-1) several weeks after planting to conventional tillage (CT) and no-till (NT) treatments. Yield-scaled emissions across all treatments represented 0.4 to 1.1% of the N harvested in the grain. Both CRFs reduced soil nitrate intensity, but not N?O emissions, compared with CU. One CRF, consisting of nitrification and urease inhibitors added to urea, decreased N?O emissions compared with a polymer-coated urea (PCU). The PCU tended to have lower yields during the drier years of the study, which increased its yield-scaled N?O emissions. The overall effectiveness of CRFs compared with CU in this study may have been reduced because they were applied several weeks after corn was planted. Across all N treatments, area-scaled N?O emissions were not significantly affected by tillage. However, when expressed per unit yield of grain, grain N, or total aboveground N, N?O emissions with NT were 52, 66, and 69% greater, respectively, compared with CT. Thus, in this cropping system and climate regime, production of an equivalent amount of grain using NT would generate substantially more N?O compared with CT.     

Nitrate leaching beneath a containerized nursery crop receiving trickle or overhead irrigation

Container production of nursery crops is intensive and a potential source of nitrogen release to the environment. This study was conducted to determine if trickle irrigation could be used by container nursery producers as an alternative to standard overhead irrigation to reduce nitrogen release into the environment. The effect of overhead irrigation and trickle irrigation on leachate nitrate N concentration, flow-weighted nitrate N concentration, leachate volume, and plant growth was investigated using containerized rhododendron (Rhododendron catawbiense Michx. 'Album') supplied with a controlled-release fertilizer and grown outdoors on top of soil-monolith lysimeters. Leachate was collected over two growing seasons and overwinter periods, and natural precipitation was allowed as a component of the system. Precipitation accounted for 69% of the water entering the overhead-irrigated system and 80% of the water entering the trickle-irrigated system. Leachate from fertilized plants exceeded the USEPA limit of 10 mg L(-1) at several times and reached a maximum of 26 mg L(-1) with trickle irrigation. Average annual loss of nitrate N in leachate for fertilized treatments was 51.8 and 60.5 kg ha(-1) for the overhead and trickle treatments, respectively. Average annual flow-weighted concentration of nitrate N in leachate of fertilized plants was 7.2 mg L(-1) for overhead irrigation and 12.7 mg L(-1) for trickle irrigation. Trickle irrigation did not reduce the amount of nitrate N leached from nursery containers when compared with overhead irrigation because precipitation nullified the potential benefits of reduced leaching fractions and irrigation inputs provided under trickle irrigation.     

Nitrogen and phosphorus runoff losses from variable and constant intensity rainfall simulations on loamy sand under conventional and strip tillage systems

Further studies on the quality of runoff from tillage and cropping systems in the southeastern USA are needed to refine current risk assessment tools for nutrient contamination. Our objective was to quantify and compare effects of constant (Ic) and variable (Iv) rainfall intensity patterns on inorganic nitrogen (N) and phosphorus (P) losses from a Tifton loamy sand (Plinthic Kandiudult) cropped to cotton (Gossypium hirsutum L.) and managed under conventional (CT) or strip-till (ST) systems. We simulated rainfall at a constant intensity and a variable intensity pattern (57 mm h(-1)) and collected runoff continuously at 5-min intervals for 70 min. For cumulative runoff at 50 min, the Iv pattern lost significantly greater amounts (p < 0.05) of total Kjeldahl N (TKN) and P (TKP) (849 g N ha(-1) and 266 g P ha(-1) for Iv; 623 g N ha(-1) and 192 g P ha(-1) for Ic) than did the Ic pattern. However, at 70 min, no significant differences in total losses were evident for TKN or TKP from either rainfall intensity pattern. In contrast, total cumulative losses of dissolved reactive P (DRP) and NO3-N were greatest for ST-Ic, followed by ST-Iv, CT-Ic, and CT-Iv in diminishing order (69 g DRP ha(-1) and 361 g NO3-N ha(-1); 37 g DRP ha(-1) and 133 g NO3-N ha(-1); 3 g DRP ha(-1) and 58 g NO3-N ha(-1); 1 g DRP ha(-1) and 49 g NO3-N ha(-1)). Results indicate that constant-rate rainfall simulations may overestimate the amount of dissolved nutrients lost to the environment in overland flow from cropping systems in loamy sand soils. We also found that CT treatments lost significantly greater amounts of TKN and TKP than ST treatments and in contrast, ST treatments lost significantly greater amounts of DRP and NO3-N than CT treatments. These results indicate that ST systems may be losing more soluble fractions than CT systems, but only a fraction the total N (33%) and total P (11%) lost through overland flow from CT systems.     

Carbon dioxide efflux from soil with poultry litter applications in conventional and conservation tillage systems in northern Alabama

Increased CO2 release from soils resulting from agricultural practices such as tillage has generated concerns about contributions to global warming. Maintaining current levels of soil C and/or sequestering additional C in soils are important mechanisms to reduce CO2 in the atmosphere through production agriculture. We conducted a study in northern Alabama from 2003 to 2006 to measure CO2 efflux and C storage in long-term tilled and non-tilled cotton (Gossypium hirsutum L.) plots receiving poultry litter or ammonium nitrate (AN). Treatments were established in 1996 on a Decatur silt loam (clayey, kaolinitic thermic, Typic Paleudults) and consisted of conventional-tillage (CT), mulch-tillage (MT), and no-tillage (NT) systems with winter rye [Secale cereale (L.)] cover cropping and AN and poultry litter (PL) as nitrogen sources. Cotton was planted in 2003, 2004, and 2006. Corn was planted in 2005 as a rotation crop using a no-till planter in all plots, and no fertilizer was applied. Poultry litter application resulted in higher CO2 emission from soil compared with AN application regardless of tillage system. In 2003 and 2006, CT (4.39 and 3.40 micromol m(-2) s(-1), respectively) and MT (4.17 and 3.39 micromol m(-2) s(-1), respectively) with PL at 100 kg N ha(-1) (100 PLN) recorded significantly higher CO2 efflux compared with NT with 100 PLN (2.84 and 2.47 micromol m(-2) s(-1), respectively). Total soil C at 0- to 15-cm depth was not affected by tillage but significantly increased with PL application and winter rye cover cropping. In general, cotton produced with NT conservation tillage in conjunction with PL and winter rye cover cropping reduced CO2 emissions and sequestered more soil C compared with control treatments.     

Leachate chemistry of field-weathered spent mushroom substrate

Passive leaching by rainfall and snowmelt is a popular method to treat piles of spent mushroom substrate (SMS) before its reuse. During this field weathering process, leachate percolates into the underlying soils. A field study was conducted to examine the chemistry of SMS leachate and effects of infiltration. Two SMS piles were deposited (90 and 150 cm in height) over a Typic Hapludult and weathered for 24 mo. Leachate was collected biweekly using passive capillary samplers. The SMS leachate contained high concentrations of dissolved organic carbon (DOC; 0.8-11.0 g L(-1)), dissolved organic nitrogen (DON; 0.1-2 g L(-1)), and inorganic salts. The pH, electrical conductivity, and acid neutralizing capacity were 6.6 to 9.0, 21 to 66 ds m(-1), and 10 to 75 mmolc L(-1), respectively. Inorganic chemistry of the leachate was dominated by K+, Cl-, and SO24-. Leachate DOC was predominantly low molecular weight (<1000 Da) organic acids. During 2 yr of weathering, the 90-cm SMS pile released (per cubic meter of SMS) 3.0 kg of DOC, 1.6 kg of dissolved N, and 26.6 kg of inorganic salts. The 150-cm pile released (per cubic meter of SMS) 2.8 kg of DOC, 0.7 kg of dissolved N, and 13.6 kg of inorganic salts. The 150 cm pile retained more water and exhibited lower net nitrification compared with the 90-cm pile. The top 90 cm of soil retained 20 to 89% of the leachate solutes. Weathering of SMS in piles of 90 cm depth or greater may adversely affect ground water quality.     

Nitrous oxide emissions from a Northern Great Plains soil as influenced by nitrogen management and cropping systems

Field measurements of N2O emissions from soils are limited for cropping systems in the semiarid northern Great Plains (NGP). The objectives were to develop N2O emission-time profiles for cropping systems in the semiarid NGP, define important periods of loss, determine the impact of best management practices on N2O losses, and estimate direct N fertilizer-induced emissions (FIE). No-till (NT) wheat (Triticum Aestivum L.)-fallow, wheat-wheat, and wheat-pea (Pisum sativum), and conventional till (CT) wheat-fallow, all with three N regimes (200 and 100 kg N ha(-1) available N, unfertilized control); plus a perennial grass-alfalfa (Medicago sativa L.) system were sampled over 2 yr using vented chambers. Cumulative 2-yr N2O emissions were modest in contrast to reports from more humid regions. Greatest N2O flux activity occurred following urea-N fertilization (10-wk) and during freeze-thaw cycles. Together these periods comprised up to 84% of the 2-yr total. Nitrification was probably the dominant process responsible for N2O emissions during the post-N fertilization period, while denitrification was more important during freeze-thaw cycles. Cumulative 2-yr N2O-N losses from fertilized regimes were greater for wheat-wheat (1.31 kg N ha(-1)) than wheat-fallow (CT and NT) (0.48 kg N ha(-1)), and wheat-pea (0.71 kg N ha(-1)) due to an additional N fertilization event. Cumulative losses from unfertilized cropping systems were not different from perennial grass-alfalfa (0.28 kg N ha(-1)). Tillage did not affect N2O losses for the wheat-fallow systems. Mean FIE level was equivalent to 0.26% of applied N, and considerably below the Intergovernmental Panel on Climate Change mean default value (1.25%).     

Modeling nitrogen and water management effects in a wheat-maize double-cropping system

Excessive N and water use in agriculture causes environmental degradation and can potentially jeopardize the sustainability of the system. A field study was conducted from 2000 to 2002 to study the effects of four N treatments (0, 100, 200, and 300 kg N ha(-1) per crop) on a wheat (Triticum aestivum L.) and maize (Zea mays L.) double cropping system under 70 +/- 15% field capacity in the North China Plain (NCP). The root zone water quality model (RZWQM), with the crop estimation through resource and environment synthesis (CERES) plant growth modules incorporated, was evaluated for its simulation of crop production, soil water, and N leaching in the double cropping system. Soil water content, biomass, and grain yield were better simulated with normalized root mean square errors (NRMSE, RMSE divided by mean observed value) from 0.11 to 0.15 than soil NO(3)-N and plant N uptake that had NRMSE from 0.19 to 0.43 across these treatments. The long-term simulation with historical weather data showed that, at 200 kg N ha(-1) per crop application rate, auto-irrigation triggered at 50% of the field capacity and recharged to 60% field capacity in the 0- to 50-cm soil profile were adequate for obtaining acceptable yield levels in this intensified double cropping system. Results also showed potential savings of more than 30% of the current N application rates per crop from 300 to 200 kg N ha(-1), which could reduce about 60% of the N leaching without compromising crop yields.     

Phosphorus and nitrogen sorption to soils in the presence of poultry litter-derived dissolved organic matter

Two environmental aspects associated with land application of poultry litter that have not been comprehensively evaluated are (i) the competition of dissolved organic matter (DOM) and P for soil sorption sites, and (ii) the sorption of dissolved organic nitrogen (DON) relative to inorganic nitrogen species (e.g., NO(3)(-) and NH(4)(+)) and dissolved organic carbon (DOC). The competition between DOM and P for sorption sites has often been assumed to increase the amount of P available for plant growth; however, elevating DOM concentrations may also increase P available for transport to water resources. Batch sorption experiments were conducted to (i) evaluate soil properties governing P sorption to benchmark soils of Southwestern Missouri, (ii) elucidate the impact of poultry litter-derived DOM on P sorption, and (iii) investigate DON retention relative to inorganic N species and DOC. Soils were reacted for 24 h with inorganic P (0-60 mg L(-1)) in the presence and absence of DOM (145 mg C L(-1)) using a background electrolyte solution comparable to DOM extracts (I = 10.8 mmol L(-1); pH 7.7). Soil P sorption was positively correlated with metal oxide (r(2) = 0.70) and clay content (r(2) = 0.79) and negatively correlated with Bray-1 extractable P (r(2) = 0.79). Poultry litter-derived DOM had no significant negative impact on P sorption. Dissolved organic nitrogen was preferentially removed from solution relative to (NO(3)(-)-N + NO(2)(-)-N), NH(4)(+)-N, and DOC. This research indicates that poultry litter-derived DOM is not likely to enhance inorganic P transport which contradicts the assumption that DOM released from organic wastes increases plant-available P when organic amendments and fertilizer P are co-applied. Additionally, this work demonstrates the need to further evaluate the fate and transport of DON in agroecosystem soils receiving poultry litter applications.     

Nitrogen- vs. phosphorus-based dairy manure applications to field crops: nitrate and phosphorus leaching and soil phosphorus accumulation

Management of animal manures to provide nutrients for crop growth has generally been based on crop N needs. However, because manures have a lower N/P ratio than most harvested crops, N-based manure management often oversupplies the crop-soil system with P, which can be lost into the environment and contribute to eutrophication of water bodies. We examined the effects of N- vs. P-based manure applications on N and P uptake by alfalfa (Medicago sativa L.), corn (Zea mays L.) for silage, and orchardgrass (Dactylis glomerata L.), leaching below the root zone, and accumulation of P in soil. Treatments included N- and P-based manure rates, with no nutrient input controls and inorganically fertilized plots for comparison. Nitrate concentrations in leachate from inorganic fertilizer or manure treatments averaged 14 mg NO(3)-N L(-1), and did not differ by nutrient treatment. Average annual total P losses in leachate did not exceed 1 kg ha(-1). In the top 5 cm of soil in plots receiving the N-based manure treatment, soil test P increased by 47%, from 85 to 125 mg kg(-1). Nitrogen- and P-based manure applications did not differ in ability to supply nutrients for crop growth, or in losses of nitrate and total P in leachate. However, the N-based manure led to significantly greater accumulation of soil test P in the surface 5 cm of soil. Surface soil P accumulation has implications for increased risk of off-field P movement.     

Biochar and earthworm effects on soil nitrous oxide and carbon dioxide emissions

Biochar is the product of pyrolysis produced from feedstock of biological origin. Due to its aromatic structure and long residence time, biochar may enable long-term carbon sequestration. At the same time, biochar has the potential to improve soil fertility and reduce greenhouse gas (GHG) emissions from soils. However, the effect of biochar application on GHG fluxes from soil must be investigated before recommendations for field-scale biochar application can be made. A laboratory experiment was designed to measure carbon dioxide (CO) and nitrous oxide (NO) emissions from two Irish soils with the addition of two different biochars, along with endogeic (soil-feeding) earthworms and ammonium sulfate, to assist in the overall evaluation of biochar as a GHG-mitigation tool. A significant reduction in NO emissions was observed from both low and high organic matter soils when biochars were applied at rates of 4% (w/w). Earthworms significantly increased NO fluxes in low and high organic matter soils more than 12.6-fold and 7.8-fold, respectively. The large increase in soil NO emissions in the presence of earthworms was significantly reduced by the addition of both biochars. biochar reduced the large earthworm emissions by 91 and 95% in the low organic matter soil and by 56 and 61% in the high organic matter soil (with and without N fertilization), respectively. With peanut hull biochar, the earthworm emissions reduction was 80 and 70% in the low organic matter soil, and only 20 and 10% in the high organic matter soil (with and without N fertilization), respectively. In high organic matter soil, both biochars reduced CO efflux in the absence of earthworms. However, soil CO efflux increased when peanut hull biochar was applied in the presence of earthworms. This study demonstrated that biochar can potentially reduce earthworm-enhanced soil NO and CO emissions. Hence, biochar application combined with endogeic earthworm activity did not reveal unknown risks for GHG emissions at the pot scale, but field-scale experiments are required to confirm this.     

Fertilizer, tillage, and dairy manure contributions to nitrate and herbicide leaching

Few studies have examined the water quality impact of manure use in no-tillage systems. A lysimeter study in continuous corn (Zea mays L.) was performed on Maury silt loam (fine, mixed, semiactive, mesic Typic Paleudalf) to evaluate the effect(s) of tillage (no-till [NT] and chisel-disk [CD]), nitrogen fertilizer rate (0 and 168 kg N ha(-1)), and dairy manure application timing (none, spring, fall, or fall plus spring) on NO3-N, atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-triazine), and alachlor [2-chloro-2'-6'-diethyl-N-(methoxymethyl)acetanilide] concentrations in leachate collected at a 90-cm depth. Herbicides were highest immediately after application, declining to less than 4 mug L(-1) in about two months. Manure and manure timing by tillage interactions had little effect on leachate herbicides; rather, the data suggest that macropores rapidly transmitted atrazine and alachlor through the soil. Tillage usually did not significantly affect leachate NO3-N, but no-tillage tended to cause higher NO(3)-N. Manuring caused higher NO3-N concentrations; spring manuring had more impact than fall, but fall manure contained about 78% of the N found in spring manure. Nitrate under spring "only fertilizer" treatment exceeded 10 mg L(-1) 38% of the time, compared with 15% for spring only manure treatment. After three years, manured soil leachate NO3-N exceeded that for soil receiving only N fertilizer. Soil profile (90 cm) NO3-N after corn harvest exceeding 22 kg N ha(-1) was associated with winter leachate NO3-N greater than 10 mg N L(-1). Manure can be used effectively in conservation tillage systems on this and similar soils. Accounting for all N inputs, including previous manure applications, will be important.     

Habitat-associated changes in some metabolic dehydrogenases and proteins of tropical earthworms

Impacts of different habitats on specific activities of LDH, cMDH, mMDH, cytoplasmic and mitochondrial proteins of M. posthuma, P. sansibaricus, L. mauritii were studied. Maximum specific activity of LDH of the earthworm M. posthuma and L. mauritii was observed in garden. In case of P. sansibaricus, maximum LDH specific activity was found in sewage. Minimum specific activity of LDH of the earthworm M. posthuma was found in non-cultivated field. However, P. sansibaricus and L. mauritii exhibited minimum activity in orchard and cultivated pedoecosystem, respectively. The maximum specific activity of cMDH and mMDH in earthworms from sewage and minimum from non-cultivated field (in case of M. posthuma), garden (in P. sansibaricus) and cultivated land (in L. mauritii) may be due to availability of more organic matter and nitrogen content in the former than in the later cases. Variations in specific activities of these metabolic enzymes due to changes in their pedoecological habitats clearly demonstrate the impact of pedoecosystem on respiratory capacity of the earthworms. Earthworms from pedoecosystem richer in organic matter and nitrogen showed elevated levels of cytoplasmic and mitochondrial protein. The changes in enzyme-specific activity and protein profiles were habitat specific.     

Nitrogen, tillage, and crop rotation effects on nitrous oxide emissions from irrigated cropping systems

We evaluated the effects of irrigated crop management practices on nitrous oxide (N(2)O) emissions from soil. Emissions were monitored from several irrigated cropping systems receiving N fertilizer rates ranging from 0 to 246 kg N ha(-1) during the 2005 and 2006 growing seasons. Cropping systems included conventional-till (CT) continuous corn (Zea mays L.), no-till (NT) continuous corn, NT corn-dry bean (Phaseolus vulgaris L.) (NT-CDb), and NT corn-barley (Hordeum distichon L.) (NT-CB). In 2005, half the N was subsurface band applied as urea-ammonium nitrate (UAN) at planting to all corn plots, with the rest of the N applied surface broadcast as a polymer-coated urea (PCU) in mid-June. The entire N rate was applied as UAN at barley and dry bean planting in the NT-CB and NT-CDb plots in 2005. All plots were in corn in 2006, with PCU being applied at half the N rate at corn emergence and a second N application as dry urea in mid-June followed by irrigation, both banded on the soil surface in the corn row. Nitrous oxide fluxes were measured during the growing season using static, vented chambers (1-3 times wk(-1)) and a gas chromatograph analyzer. Linear increases in N(2)O emissions were observed with increasing N-fertilizer rate, but emission amounts varied with growing season. Growing season N(2)O emissions were greater from the NT-CDb system during the corn phase of the rotation than from the other cropping systems. Crop rotation and N rate had more effect than tillage system on N(2)O emissions. Nitrous oxide emissions from N application ranged from 0.30 to 0.75% of N applied. Spikes in N(2)O emissions after N fertilizer application were greater with UAN and urea than with PCU fertilizer. The PCU showed potential for reducing N(2)O emissions from irrigated cropping systems.     

Management of Fly Ash Through Vermicomposting: A Rational Approach

Fly ash is a by‐product of coal combustion in thermal power plants. Its generation poses several environmental problems, the most important ones being its capacity for causing pollution and the need for large storage areas to keep it out of the environment. Fly ash management remains a major concern in the 21st century; however, despite these challenges, the material has great potential for beneficial use in agriculture due to its efficacy in modifying and improving soil health and improving crop performance. Vermicomposting is an excellent technique for reducing the toxic heavy metals in fly ash through the introduction of earthworms. The activities of several earthworm species minimize the solubility of heavy metals and increase the bioavailability of major nutrient elements such as phosphorous (P) and nitrogen (N). This article provides a comprehensive review of the scope and benefits of vermiremediating fly ash, demonstrating the abilities of different species of earthworms to accumulate heavy metals and increase the availability of plant nutrients. On the basis of a literature survey, the authors have concluded that adopting vermicomposting technology promises increased, effective fly ash utilization for agricultural benefits.     

Tillage, cropping systems, and nitrogen fertilizer source effects on soil carbon sequestration and fractions

Quantification of soil carbon (C) cycling as influenced by management practices is needed for C sequestration and soil quality improvement. We evaluated the 10-yr effects of tillage, cropping system, and N source on crop residue and soil C fractions at 0- to 20-cm depth in Decatur silt loam (clayey, kaolinitic, thermic, Typic Paleudults) in northern Alabama, USA. Treatments were incomplete factorial combinations of three tillage practices (no-till [NT], mulch till [MT], and conventional till [CT]), two cropping systems (cotton [Gossypium hirsutum L.]-cotton-corn [Zea mays L.] and rye [Secale cereale L.]/cotton-rye/cotton-corn), and two N fertilization sources and rates (0 and 100 kg N ha(-1) from NH(4)NO(3) and 100 and 200 kg N ha(-1) from poultry litter). Carbon fractions were soil organic C (SOC), particulate organic C (POC), microbial biomass C (MBC), and potential C mineralization (PCM). Crop residue varied among treatments and years and total residue from 1997 to 2005 was greater in rye/cotton-rye/cotton-corn than in cotton-cotton-corn and greater with NH(4)NO(3) than with poultry litter at 100 kg N ha(-1). The SOC content at 0 to 20 cm after 10 yr was greater with poultry litter than with NH(4)NO(3) in NT and CT, resulting in a C sequestration rate of 510 kg C ha(-1) yr(-1) with poultry litter compared with -120 to 147 kg C ha(-1) yr(-1) with NH(4)NO(3). Poultry litter also increased PCM and MBC compared with NH(4)NO(3). Cropping increased SOC, POC, and PCM compared with fallow in NT. Long-term poultry litter application or continuous cropping increased soil C storage and microbial biomass and activity compared with inorganic N fertilization or fallow, indicating that these management practices can sequester C, offset atmospheric CO(2) levels, and improve soil and environmental quality.     

NITROGEN AND ORGANIC MATTER LOSSES IN NO‐TILL CORN CROPPING SYSTEMS1

ABSTRACT: Intensive cropping systems based on mechanical movement of soil have induced land degradation in most agricultural areas due to soil erosion and soil fertility losses. Thus, farmers have been increasing fertilization rates to maintain an economically competitive crop yield. This practice has resulted in water quality degradation and lake eutrophication in many agricultural watersheds. Research was conducted in the Patzcuaro watershed in central Mexico to develop appropriate technology that prevents nonpoint source pollution from fertilizers. Organic matter (OM) and nitrogen (N) losses in runoff and nitrate (NO₃‐N) percolation in Andisols with corn under conventional till (CT) and no‐till (NT) treatments using variable percentages of crop residue as soil cover were investigated for steep‐slope agriculture. USLE type runoff plots were used to collect water runoff, while suction tubes with porous caps at 30, 60, and 90 cm depth were used to sample soil water solutes for NO₃‐N analyses. Results indicated a significant reduction of N and OM losses in runoff as residue cover increased in the NT treatments. Inorganic N in runoff was 25 kg/ha for NT without residue cover (NT‐0) and 6 kg/ha for the NT with 100 percent residue cover (NT‐100). Organic matter losses in runoff were 157 and 24 kg/ha for the NT‐0 and NT‐100 treatments, respectively. Nitrate‐N percolation was evident in CT and NT with 100 percent residue cover (NT‐100). However, NT‐100 had higher NO₃‐N concentration at the root zone, suggesting the possibility of reducing fertilization rates with the use of NT treatments.     

Integrated BIosphere Simulator (IBIS) yield and nitrate loss predictions for Wisconsin maize receiving varied amounts of nitrogen fertilizer

Agriculture in the U.S. Midwest faces the formidable challenge of improving crop productivity while simultaneously mitigating the environmental consequences of intense management. This study examined the simultaneous response of nitrate nitrogen (NO3-N) leaching losses and maize (Zea mays L.) yield to varied fertilizer N management using field observations and the Integrated BIosphere Simulator (IBIS) model. The model was validated against six years of field observations in chisel-plowed maize plots receiving an optimal (180 kg N ha(-1)) fertilizer N application and in N-unfertilized plots on a silt loam soil near Arlington, Wisconsin. Predicted values of grain yield, harvest index, plant N uptake, residue C to N ratio, leaf area index (LAI), grain N, and drainage were within 20% of observations. However, simulated NO3-N leaching losses, NO3-N concentrations, and net N mineralization exhibited less interannual variability than observations, and had higher levels of error (20-65%). Potential effects of 30% higher (234 kg N ha(-1)) and 30% lower (126 kg N ha(-1)) fertilizer N use (from optimal) on NO3-N leaching loss and maize yield were simulated. A 30% increase in fertilizer N use increased annual NO3-N leaching by 56%, while yield increased by only 1%. The NO3-N concentration in the leachate solution at 1.4 m below the soil surface was 30.7 mg L(-1). When fertilizer N use was reduced by 30% (from optimal), annual NO3-N leaching losses declined by 42% after seven years, and annual average yield only decreased by 8%. However, NO3-N concentration in the leachate solution remained above 10 mg L(-1) (11.3 mg L(-1)). Clearly, nonlinear relationships existed between changes in fertilizer use and NO3-N leaching losses over time. Simulated changes in NO3-N leaching were greater in magnitude than fertilizer N use changes.     

Free-air CO2 enrichment of sorghum: soil carbon and nitrogen dynamics

The positive impact of elevated atmospheric CO(2) concentration on crop biomass production suggests more carbon inputs to soil. Further study on the effect of elevated CO(2) on soil carbon and nitrogen dynamics is key to understanding the potential for long-term carbon storage in soil. Soil samples (0- to 5-, 5- to 10-, and 10- to 20-cm depths) were collected after 2 yr of grain sorghum [Sorghum bicolor (L.) Moench.] production under two atmospheric CO(2) levels: (370 [ambient] and 550 muL L(-1) [free-air CO(2) enrichment; FACE]) and two water treatments (ample water and limited water) on a Trix clay loam (fine, loamy, mixed [calcareous], hyperthermic Typic Torrifluvents) at Maricopa, AZ. In addition to assessing treatment effects on soil organic C and total N, potential C and N mineralization and C turnover were determined in a 60-d laboratory incubation study. After 2 yr of FACE, soil C and N were significantly increased at all soil depths. Water regime had no effect on these measures. Increased total N in the soil was associated with reduced N mineralization under FACE. Results indicated that potential C turnover was reduced under water deficit conditions at the top soil depth. Carbon turnover was not affected under FACE, implying that the observed increase in soil C with elevated CO(2) may be stable relative to ambient CO(2) conditions. Results suggest that, over the short-term, a small increase in soil C storage could occur under elevated atmospheric CO(2) conditions in sorghum production systems with differing water regimes.