有机氯农药径流污染模拟试验研讨

采用人工径流的方法,选择有代表性的农药和有代表性地块进行污染摸拟试验。对研究非点源污染的有机氯农药的控制使用、施药方法、施药季节和施药条件选择等具有一定科学意义和实用价值。     

蚌埠市无公害食品产业现状及发展对策

无公害食品,指的是无污染、无毒害、安全优质的食品。无公害食品(绿色食品)分为AA级和A级两种,其主要区别是在生产过程中,AA级不使用任何农药、化肥和人工合成激素;A级则允许限量使用限定的农药、化肥和合成激素。     

人工湿地控制非点源污染的应用

随着点源污染的有效管理和控制，非点源污染已成为水环境污染的主要原因。人工湿地作为一种控制水环境非点源污染的有效工具，已被世界上很多国家所认可。本文首先简述了非点源污染的危害，其次对人工湿地的概念和类型进行了介绍，论述了人工湿地对非点源污染中氮、磷、重金属和农药等主要污染物的去除机理，最后对人工湿地处理系统的附属设施、水力因素、表土层以及植物收割等应用问题进行了探讨。     

四川省农药“三废”污染浅析

本文简介了四川省近几年来主要合成农药“三废”的基本情况。例举了有抗磷化合物,胺(?)化合物,酚类化合物,硝基化合物,氮化氢,硫化氢等有毒物对环境的危害,同时介绍了农药“三废”的一些治理技术,并提出了防治污染的措施和建议。     

人工湿地污水处理系统工艺设计研究

本文阐述了人工湿地污水处理系统工艺设计的主要内容及存在的若干问题，提出了开展人工湿地工艺设计研究的一些设想。人工湿地工艺设计研究包括人工湿地基质构建、植物群落构建和人工湿地构造与工程参数三个方面。目前，由于在污染物净化机理、系统水力学和污染物降解动力学等方面认识不足，制约了人工湿地工艺设计水平的提高，因此，深入研究污染物净化机理、开展人工湿地基质与植物筛选与组合研究、创建适合植物生长的人工生境、优化水力学模型和污染物降解动力学模型．将有利于提高人工湿地工艺设计水平。     

4亿元的土壤修复之路:武汉农药厂酿全国最大“毒地”退回案

正"蕴藏"毒气的黄金地段1959年建成并投产的武汉农药厂,位于长江、汉水交汇处的武汉三镇之一:汉阳市,它是一家从事合成农药及加工农药的中型国有企业,主要产品有除草剂、除虫剂、棉花病虫药等。武汉农药厂从1960年到1980年发展稳定,1985年后因经营状况不佳组建为轮胎厂,后破产。2003年,农药厂改制后,武汉市土地储备中心收储了这地块。     

红外图谱计算机解析研究

本文提供了被认为比较准确的32种有机分子特征基团红外光谱吸收范围;提出了红外仪扫描时计算机同时采集数据,红外扫描结束后,计算机不用人工干予自动利用有机分子基团的特征吸收峰的峰位、强度信息判断有机分子所含基团的图谱解析方法。并提供了程序设计框图。给出了40个较有代表性化合物的图谱解析实验结果。     

气相分子吸收光谱法测定油田废水中氨氮的改进

文章对气相分子吸收光谱法测定氨氮的国标推荐方法 HJ/T 195—2005《水质氨氮的测定气相分子吸收光谱法》进行了改进实验,提出用氨氮标准使用液绘制标准曲线更客观,验证了国标方法改进后的准确度和精密度(相对标准偏差为0.61%)满足实验室质控要求;通过对氨氮传统人工监测方法纳氏试剂法和气相分子吸收光谱法的比较,认为气相分子吸收光谱法适用于油田废水氨氮的测定。     

松乳菇母种培养基及松乳菇人工栽培方法

松乳菇的母种培养基主要由酵母 2 ｇ～ 1 0 ｇ、尼克酸 1ｍｇ～ 1 0ｍｇ、叶酸 2ｍｇ～ 8ｍｇ及生物素 1ｍｇ～ 8ｍｇ等组成。用该培养基进行菌种培养 ,选用马尾松种子与菌种培养成菌根合成苗 ,将菌根合成苗在常规条件下种植 2年～ 3年即可出菇。利用本发明提供的母种培养基和人工栽培方法可实现松乳菇的产业化生产。 (ＣＮ 1 2 4 0 572Ａ)松乳菇母种培养基及松乳菇人工栽培方法     

人工湿地系统在垃圾渗滤液处理中的应用

介绍了人工湿地的组成和类型,人工湿地去除渗滤液中有机物、氮、磷和重金属的机制。分析了影响人工湿地处理渗滤液效率的因子,并且结合人工湿地设计和运行维护提出了相关建议。根据国内外成功的工程实例,分析了人工湿地处理垃圾渗滤液的经济优势、生态优势,展示了该处理技术广泛的应用前景,对以后的研究进行了展望。     

Fate of pesticides in combined paddy rice-fish pond farming systems in northern Vietnam

During the last decades, high population growth and export-oriented economics in Vietnam have led to a tremendous intensification of rice production, which in turn has significantly increased the amount of pesticides applied in rice cropping systems. Since pesticides are toxic by design, there is a natural concern on the impact of their presence in the environment on human health and environmental quality. The present study was designed to examine the water regime and fate of pesticides (fenitrothion, dimethoate) during two consecutive rice crop seasons in combined paddy rice-fish pond farming systems in northern Vietnam. Major results revealed that 5 and 41% (dimethoate), and 1 and 17% (fenitrothion) of the applied mass of pesticides were lost from the paddy field to the adjacent fish pond during spring and summer crop seasons, respectively. The decrease of pesticide concentration in paddy surface water was very rapid with dissipation half-life values of 0.3 to 0.8 and 0.2 d for dimethoate and fenitrothion, respectively. Key factors controlling the transport of pesticides were water solubility and paddy water management parameters, such as hydraulic residence time and water holding period. Risk assessment indicates that the exposure to toxic levels of pesticides for aquaculture (, ) is significant, at least shortly after pesticide application.     

农药在土壤中的结合残留及其生态风险

农药等有机物在施用后可以通过物理、化学和生物等作用形成结合残留。农药结合残留的形成,可以降低其活性,但也存在重新释放的可能性。文章从结合残留的定义、形成机制、分析方法和可能存在的生态风险等方面进行了综述,并对以后需要深入研究的内容做一展望。     

ECONOMICS OF SCREENING FOR PESTICIDES IN GROUND WATER1

ABSTRACT: In the United States, millions of dollars are currently spent to monitor water quality for a whole suite of organic compounds. However, results of several surveys conducted in the past decade indicate that only a few pesticides occur in a small proportion of wells. Screening methods based on historical evidence of contamination patterns and knowledge of the locales will have significant potential to reduce these costs and effectively identify contamination problems. In this paper, the economics of utilizing two screening methods, sequential analysis and sample compositing, in the design of monitoring strategies is captured In the form of mathematical models and illustrated for a state-level monitoring program. When the two methods are adopted, the total analytical cost to conclusively identify contaminated wells in a network of 4,000 wells is shown to range from $12,500 to $1,575,000 depending on the extent of contamination. In contrast, the total analytical cost of a conventional program where all the wells in the network are sampled and tested for a standard suite of pesticides at a cost of $250/sample is one million dollars. Given such wide range in costs, it is prudent to incorporate the screening concepts presented in this paper in the development of cost-effective monitoring programs.     

Microbial remediation of nitro-aromatic compounds: an overview

Nitro-aromatic compounds are produced by incomplete combustion of fossil fuel or nitration reactions and are used as chemical feedstock for synthesis of explosives, pesticides, herbicides, dyes, pharmaceuticals, etc. The indiscriminate use of nitro-aromatics in the past due to wide applications has resulted in inexorable environmental pollution. Hence, nitro-aromatics are recognized as recalcitrant and given Hazardous Rating-3. Although several conventional pump and treat clean up methods are currently in use for the removal of nitro-aromatics, none has proved to be sustainable. Recently, remediation by biological systems has attracted worldwide attention to decontaminate nitro-aromatics polluted sources. The incredible versatility inherited in microbes has rendered these compounds as a part of the biogeochemical cycle. Several microbes catalyze mineralization and/or non-specific transformation of nitro-aromatics either by aerobic or anaerobic processes. Aerobic degradation of nitro-aromatics applies mainly to mono-, dinitro-derivatives and to some extent to poly-nitro-aromatics through oxygenation by: (i) monooxygenase, (ii) dioxygenase catalyzed reactions, (iii) Meisenheimer complex formation, and (iv) partial reduction of aromatic ring. Under anaerobic conditions, nitro-aromatics are reduced to amino-aromatics to facilitate complete mineralization. The nitro-aromatic explosives from contaminated sediments are effectively degraded at field scale using in situ bioremediation strategies, while ex situ techniques using whole cell/enzyme(s) immobilized on a suitable matrix/support are gaining acceptance for decontamination of nitrophenolic pesticides from soils at high chemical loading rates. Presently, the qualitative and quantitative performance of biological approaches of remediation is undergoing improvement due to: (i) knowledge of catabolic pathways of degradation, (ii) optimization of various parameters for accelerated degradation, and (iii) design of microbe(s) through molecular biology tools, capable of detoxifying nitro-aromatic pollutants. Among them, degradative plasmids have provided a major handle in construction of recombinant strains. Although recombinants designed for high performance seem to provide a ray of hope, their true assessment under field conditions is required to address ecological considerations for sustainable bioremediation.     

QuEChERS提取法在农产品农药残留检测中的应用进展

食品中的农药残留检测长期以来一直是一项艰巨的挑战,其杂质干扰多,残留含量低,传统的提取方法常常因为无法将杂质分离而影响检测结果。由于食品中杂质种类众多,农药的种类繁多且理化性质各异,新型农药日益涌现,所以对样品的前处理提出了更高的要求。近年来,QuEchERs（Quick,Easy,Cheap,Effective,RuggedandSafe）作为一种新型的提取方法,由于具有快速、简单、廉价、有效、可靠、安全的特点,成为国内外广泛采用的样品前处理新技术,在多种农药、医药、兽药的气相或液相色谱分析中已经得到广泛应用。本文就国内外对QuEChERS法在各类食品以及其他动植物性农产品的农药残留检测中的应用和方法的改进进行了综述,并对QuEChERS法在今后农药残留检测的应用前景以及发展方向进行了展望。     

ATFITUDES TOWARDS ARTIFICIAL WETLANDS IN ONTARIO FOR STORMWATER CONTROL AND WATERFOWL HABITAT1

ABSTRACT: The objective was to survey individuals from different interest groups in Ontario to ascertain attitudes towards the use of artificial wetlands for stormwater management and to provide waterfowl habitat. In total, 166 questionnaires were distributed and 124 cempleted returns were received. The results of the survey show that the provision of wetlands as waterfowl habitats in the context of stormwater impoundments is severely limited and is not considered an important management option. The overwhelming rejection of this integrated approach seems to be due to a lack of understanding and its comparative newness. Some of the perceived problems and concerns could be addressed by improvements in the design of the artificial wetlands. The design and implementation of an artificial wetland prototype as part of an education program in Ontario is recommended. A few research opportunities also are outlined.     

Adsorption of pesticides onto quartz, calcite, kaolinite, and alpha-alumina

The fate of pesticides in aquifers is influenced by the small but not insignificant adsorption of pesticides to mineral surfaces. Batch experiments with five pesticides and four minerals were conducted to quantify the contributions to adsorption from different mineral surfaces and compare adsorption characteristics of selected pesticides. Investigated mineral phases included quartz, calcite, kaolinite, and alpha-alumina. Selected pesticides comprised atrazine (6-chloro-N2-ethyl-N4-isopropyl-1,3,5-triazine-2,4-diamine), isoproturon [3-(4-isopropylphenyl)-1,1-dimethylurea)], mecoprop [(RS)-2-(4-chloro-2-methylphenoxy)propionic acid], 2,4-D (2,4-dichlorophenoxyacetic acid), and bentazone [3-isopropyl-1H-2,1,3-benzothiadiazin-4-(3H)-one 2,2-dioxide]. Specific surface area and mineral surface charge proved to be important for the adsorption of these pesticides. Detectable adsorption of the anionic pesticides (mecoprop, 2,4-D, and bentazone) was only measured when positive sites were present on the mineral surface. However, when CaCl2 was added as an electrolyte, a detectable adsorption of mecoprop and 2,4-D was also measured on kaolinite (which exhibits a negative surface charge), probably due to formation of Ca-pesticide--surface complexes. Adsorption of the uncharged pesticides (atrazine and isoproturon) was detected only on kaolinite. The lack of adsorption on alpha-alumina indicates that the uncharged pesticides have a greater affinity for the silanol surface sites (=SiOH) than for the aluminol surface sites (=AlOH) in kaolinite. No measurable effect of ionic strength was found for the uncharged pesticides. The results indicate that quartz and calcite play a smaller role than clay minerals.     

OCCURRENCE OF PESTICIDES IN GROUND WATER OF THE OZARK PLATEAUS PROVINCE1

ABSTRACT: Pesticides were detected in ground-water samples collected from 20 springs and nine wells in the Ozark Plateaus Province of Arkansas, Kansas, Missouri, and Oklahoma. From April through September 1993, water samples were collected from 50 shallow domestic wells and 50 springs in the Springfield Plateau and Ozark aquifers and analyzed for 47 pesticides and metabolites. Pesticides were detected in 17 water samples from the Springfield Plateau aquifer and 12 water samples from the Ozark aquifer. Fourteen pesticides were detected, with a maximum of four pesticides detected in any one sample. The most commonly detected pesticides were atrazine (14 detections), prometon (11 detections), and tebuthiuron (seven detections). P, P' DDE, a metabolite of DDT, was detected in water samples from three wells and one spring. The remaining pesticides were detected in three or less samples. The occurrence and distribution of pesticides probably are related to the local land use near a sampling site. Pesticide detections were significantly related to aquifer, site type, and discharge of springs.     

Comparison of Two Parametric Methods to Estimate Pesticide Mass Loads in California’s Central Valley1

Saleh, Dina K., David L. Lorenz, and Joseph L. Domagalski, 2010. Comparison of Two Parametric Methods to Estimate Pesticide Mass Loads in California’s Central Valley. Journal of the American Water Resources Association (JAWRA) 00(0):1‐11. DOI: 10.1111/j.1752‐1688.2010.00506.x Abstract: Mass loadings were calculated for four pesticides in two watersheds with different land uses in the Central Valley, California, by using two parametric models: (1) the Seasonal Wave model (SeaWave), in which a pulse signal is used to describe the annual cycle of pesticide occurrence in a stream, and (2) the Sine Wave model, in which first‐order Fourier series sine and cosine terms are used to simulate seasonal mass loading patterns. The models were applied to data collected during water years 1997 through 2005. The pesticides modeled were carbaryl, diazinon, metolachlor, and molinate. Results from the two models show that the ability to capture seasonal variations in pesticide concentrations was affected by pesticide use patterns and the methods by which pesticides are transported to streams. Estimated seasonal loads compared well with results from previous studies for both models. Loads estimated by the two models did not differ significantly from each other, with the exceptions of carbaryl and molinate during the precipitation season, where loads were affected by application patterns and rainfall. However, in watersheds with variable and intermittent pesticide applications, the SeaWave model is more suitable for use on the basis of its robust capability of describing seasonal variation of pesticide concentrations.