Equilibrium sampling used to monitor malodors in a Swine waste lagoon

The concentrations of malodorous compounds in a 0.4-ha anaerobic lagoon that received waste from approximately 2000 sows were monitored during the late summer to late fall of 2006 to gain insight into the factors influencing their concentrations. Selected malodorous compounds were measured by the use of equilibrium samplers consisting of submersible stir plates and stir bar sorbtive sampling with polydimethylsiloxane-coated magnetic stir bars. During the same period, air and water temperatures, suspended solids, total organic carbon and nitrogen content, and wastewater pH were recorded. Concentrations of malodorous compounds were higher at the surface of the lagoon than at the middle or bottom of the lagoon. Skatole concentration, for instance, averaged 54, 24, and 38 microg L(-1) near the surface, in the middle, and at the lowest sampling depths, respectively. While the lagoon was being pumped down during field application of wastewater, concentrations of malodorous compounds fluctuated widely, increased 16-fold as compared with the sampling period before pumping, and continued to increase as fall progressed and temperatures cooled. Suspended solids, volatile suspended solids, and total organic carbon increased near the bottom of the lagoon during this same period. The increases in the concentrations of malodorous compounds in the wastewater during the fall could have been due to a combination of several factors. These factors include reduced degradation by lagoon bacteria, less wind stripping of volatile compounds from the lagoon surface due to lowering of the lagoon surface after crop application, and/or reduced evaporation of malodorous compounds due to falling temperatures.     

Denitrification in anaerobic lagoons used to treat swine wastewater

Anaerobic lagoons are commonly used for the treatment of swine wastewater. Although these lagoons were once thought to be relatively simple, their physical, chemical, and biological processes are very complex. This study of anaerobic lagoons had two objectives: (i) to quantify denitrification enzyme activity (DEA) and (ii) to evaluate the influence of lagoon characteristics on the DEA. The DEA was measured by the acetylene inhibition method. Wastewater samples and physical and chemical measurements were taken from the wastewater column of nine anaerobic swine lagoons from May 2006 to May 2009. These lagoons were typical for anaerobic swine lagoons in the Carolinas relative to their size, operation, and chemical and physical characteristics. Their mean value for DEA was 87 mg N2O-N m(-3) d(-1). In a lagoon with 2-m depth, this rate of DEA would be compatible with 1.74 kg N ha(-1) d(-1) When nonlimiting nitrate was added, the highest DEA was compatible with 4.38 kg N ha(-1) d(-1) loss. Using stepwise regression for this treatment, the lagoon characteristics (i.e., soluble organic carbon, total nitrogen, temperature, and NO3-N) provided a final step model R2 of 0.69. Nitrous oxide from incomplete denitrification was not a significant part of the system nitrogen balance. Although alternate pathways of denitrification may exist within or beneath the wastewater column, this paper documents the lack of sufficient denitrification enzyme activity within the wastewater column of these anaerobic lagoons to support large N2 gas losses via classical nitrification and denitrification.     

QBF法在污水处理场的应用研究

大港石化公司污水处理场废气处理装置采用QBF(Quick Bio Filter)法去除VOC(挥发性有机物)以及硫化氢等恶臭物质的二次污染治理问题,通过检测装置入、出口数据,计算其去除率并进行分析,实验结果表明,QBF法用于处理VOC切实可行,可作为污水处理场去除恶息的首先方法之一。     

废纸制浆造纸废水封闭循环处理工艺

本文介绍了废纸造纸制浆废水的特点、在零排放和废水封闭循环中遇到的问题以及解决措施，介绍了几种目前比较常用的废纸制浆连纸循环水处理工艺及其发展状况。     

Estrogenic activity in the environment: municipal wastewater effluent, river, ponds, and wetlands

Estrogenic activity of regional water samples was evaluated. Samples obtained from wetlands and ponds involved in various agricultural land uses, from three river sites over four seasons, and from municipal wastewater effluent held in storage lagoons were evaluated. The estrogen-responsive cell line MCF-7 BOS was used in the E-screen assay to determine 17beta-estradiol equivalents (E2 Eq) of water samples extracted by solid-phase extraction. Estrogenic activity in surrounding wetlands and ponds from different land uses was not different, with 10(-12) M E2 Eq (0.3 ppt). Estrogenic activity of Red River samples was within the same range as wetland-pond samples. The highest activity was found downstream from municipal wastewater treatment effluent discharge sites, in winter when river flow was lowest (approximately 6 x 10(-13) M E2 Eq). Results showed that 7 of 20 wetland-pond samples and 5 of 12 river samples were below the limits of quantitation (approximately 3 x 10(-14) M E2 Eq). Toxicity was found in fall and summer river samples upstream from municipal wastewater release sites. The timing of toxicity did not coincide to the presence of elevated fecal coliforms. Estrogenic activity in wastewater effluent from lagoons decreased over time (approximately 25 to 5 x 10(-13) M E2 Eq) with an apparent half-life of 8 d for one lagoon. The median concentration of detectable estrogenic activity in regional water samples was approximately 50-fold less than the median 17beta-estradiol concentration of estradiol detected in some U.S. streams in previous studies.     

Nitrification and denitrification gene abundances in swine wastewater anaerobic lagoons

Although anaerobic lagoons are used globally for livestock waste treatment, their detailed microbial cycling ofN is only beginning to become understood. Within this cycling, nitrification can be performed by organisms that produce the enzyme ammonia monooxygenase. For denitrification, the reduction of nitrite to nitric oxide can be catalyzed by two forms of nitrite reductases, and N,O can be reduced by nitrous oxide reductase encoded by the gene nosZ The objectives of this investigation were to (i) quantify the abundance of the amoA, nirK, nirS, and nosZ genes; (ii) evaluate the influence of environmental conditions on their abundances; and (iii) evaluate their abundance relative to denitrification enzyme activity (DEA). Samples were analyzed via real-time quantitative polymerase chain reaction and collected from eight typical, commercial anaerobic, swine wastewater lagoons located in the Carolinas. The four genes assayed in this study were present in all eight lagoons. Their abundances relative to total bacterial populations were 0.04% (amoA), 1.33% (nirS), 5.29% (nirK), and 0.27% (nosZ). When compared with lagoon chemical characteristics, amoA and nirK correlated with several measured variables. Neither nirS nor nosZ correlated with any measured environmental variables. Although no gene measured in this study correlated with actual or potential DEA, nosZ copy numbers did correlate with the disparity between actual and potential DEA. Phylogenetic analysis ofnosZdid not reveal any correlations to DEA rates. As with other investigations, analyses of these genes provide useful insight while revealing the underlying greater complexity of N cycling within swine waste lagoons.     

Sustainability of wastewater treatment technologies

A set of indicators that incorporate environmental, societal, and economic sustainability were developed and used to investigate the sustainability of different wastewater treatment technologies, for plant capacities of <5 million gallons per day (MGD) or 18.9 x 10(3) cubic meters (m(3)/day). The technologies evaluated were mechanical (i.e., activated sludge with secondary treatment), lagoon (facultative, anaerobic, and aerobic), and land treatment systems (e.g., slow rate irrigation, rapid infiltration, and overland flow). The economic indicators selected were capital, operation and management, and user costs because they determine the economic affordability of a particular technology to a community. Environmental indicators include energy use, because it indirectly measures resource utilization, and performance of the technology in removing conventional wastewater constituents such as biochemical oxygen demand, ammonia nitrogen, phosphorus, and pathogens. These indicators also determine the reuse potential of the treated wastewater. Societal indicators capture cultural acceptance of the technology through public participation and also measure whether there is improvement in the community from the specific technology through increased job opportunities, better education, or an improved local environment. While selection of a set of indicators is dependent on the geographic and demographic context of a particular community, the overall results of this study show that there are varying degrees of sustainability with each treatment technology.     

Movement of lagoon-liquor constituents below four animal-waste lagoons

Movement of liquor constituents from animal-waste lagoons has the potential to degrade ground water quality. The depth of movement and concentrations of lagoon-liquor constituents in the soil underlying three cattle (Bos taurus)-waste retention lagoons and one swine (Sus scrofa)-waste lagoon were determined. Samples were taken by using a direct-push coring machine, dissected by depth, and analyzed for total N, organic C, CaCO3, pH, cation exchange capacity (CEC), texture, and extractable NO3, NH(4), P, Cl, Ca, Mg, K, and Na. Ammonium N concentrations were greatest in the upper 0.5 m of soil under all four lagoons with concentrations ranging from 94 to 1139 mg kg(-1). Organic N was determined to make up between 39 and 74% of the total N beneath all lagoons. The swine lagoon had 2.4 kg N m(-2) in the underlying soil whereas the cattle lagoon with highest quantity of N had 1.2 kg N m(-2) in the underlying soil. Although N concentrations decreased with depth, N was greater than expected background levels at the bottom of some cores, indicating that the sampling efforts did not reach the bottom of the N plume. Nitrate N concentrations were generally less than 5 mg kg(-1) immediately below the lagoon floor. In the uppermost 0.5 m of soil underlying the swine and three cattle lagoons, NH4+ occupied 44% and between 1 and 22% of the soil cation exchange sites, respectively. The depth of movement of N under these lagoons, as much as 4 m, may pose remediation difficulties at lagoon closure.     

Heavy equipment maintenance wastes and environmental management in the mining industry

Maintenance wastes, if not managed properly, represent significant environmental issues for mining operations. Petroleum hydrocarbon liquid wastes were studied at an Australian site and a review of the literature and technology vendors was carried out to identify oil/water separation technologies. Treatment technologies and practices for managing oily wastewater, used across the broader mining industry in the Asia-Pacific region, were also identified. Key findings from the study were: (1) primary treatment is required to remove grease oil contamination and to protect secondary oily wastewater treatment systems from being overloaded; (2) selection of an effective secondary treatment system is dependent on influent oil droplet size and concentration, suspended solids concentration, flow rates (and their variability), environmental conditions, maintenance schedules and effectiveness, treatment targets and costs; and (3) oily wastewater treatment systems, based on mechanical separation, are favoured over those that are chemically based, as they simplify operational requirements. Source reduction, through housekeeping, equipment and reagent modifications, and segregation and/or consolidation of hydrocarbon waste streams, minimizes treatment costs, safety and environmental impact.     

秦皇岛市水环境现状与恢复

秦皇岛地区原始自然环境优越,多年来,不正当的人为活动、环境恶化趋势明显,也直接干扰与影响着水的良性循环。现状水环境:河流基流渐小,并季节性断流,坑塘减少,湿地萎缩水土流失,洪径增大。地下水位下降,水量减少,承压水无序开采,污净比失衡,河流承栽力降低。地下水垂直污染面扩大,点、面、垃圾污染源趋重。联通青一洋、石一起,实施水资源再分配。优化配置城乡用水。重视地下水源地建设,联合调度地表、地下水源。谨慎开发承压水。植树造林、涵养水分。注重防风林带建设,改善田间小气候。严控地下水采量,防止土壤旱化。搞好坑塘建设,解决乡镇污水出路与净化。保护湿地,促进水的良性循环。深度处理废污水.使之资源化。从源头抓好城市三大水源地污染源.察勘储备新地下水源地。改良恢复水环境,保障水资源循环利用。     

重金属废水处理技术研究进展

总结近年来重金属废水主要处理技术,指出重金属废水污染治理与重金属的回收利用相结合是未来治理的发展之路,也是技术开发与应用的方向。     

绿色水处理技术的应用与发展

采用绿色水处理技术是实现水资源可持续发展、环境保护和生态安全的重要措施。文章列举了膜分离、绿色氧化、绿色絮凝以及超声波、微波、电磁场等环保水处理技术,以及在国内外的研究应用现状探讨了绿色水处理技术的发展趋势。     

A comparative analysis of methods to represent uncertainty in estimating the cost of constructing wastewater treatment plants

Prediction of construction cost of wastewater treatment facilities could be influential for the economic feasibility of various levels of water pollution control programs. However, construction cost estimation is difficult to precisely evaluate in an uncertain environment and measured quantities are always burdened with different types of cost structures. Therefore, an understanding of the previous development of wastewater treatment plants and of the related construction cost structures of those facilities becomes essential for dealing with an effective regional water pollution control program. But deviations between the observed values and the estimated values are supposed to be due to measurement errors only in the conventional regression models. The inherent uncertainties of the underlying cost structure, where the human estimation is influential, are rarely explored. This paper is designed to recast a well-known problem of construction cost estimation for both domestic and industrial wastewater treatment plants via a comparative framework. Comparisons were made for three technologies of regression analyses, including the conventional least squares regression method, the fuzzy linear regression method, and the newly derived fuzzy goal regression method. The case study, incorporating a complete database with 48 domestic wastewater treatment plants and 29 industrial wastewater treatment plants being collected in Taiwan, implements such a cost estimation procedure in an uncertain environment. Given that the fuzzy structure in regression estimation may account for the inherent human complexity in cost estimation, the fuzzy goal regression method does exhibit more robust results in terms of some criteria. Moderate economy of scale exists in constructing both the domestic and industrial wastewater treatment plants. Findings indicate that the optimal size of a domestic wastewater treatment plant is approximately equivalent to 15,000 m3/day (CMD) and higher in Taiwan. Yet the optimal size of an industrial wastewater treatment plant could fall in between 6000 CMD and 20,000 CMD.     

Bioreactor applications in waste treatment

An overview of bioreactor applications in treatment of gaseous, liquid and solid wastes is presented with emphasis on newer technologies. Waste treatment is considered in a broad context including concentration by bioaccumulation, degradation to substances with reduced environmental impact and upgrading to such useful products as feeds, foods and fuels. Biofilters and bioscrubbers for gaseous pollutants, high-rate municipal and industrial wastewater treatment in airlift bioreactors, reactor-based soil bioremediation, artificial wetland filters for liquid effluents, and protein enrichment of agricultural solid residues are some of the technologies reviewed. The various treatment strategies are illustrated with examples. The developments discussed point to an increasing role for bioreactor based processes in waste treatment and reuse.     

Biomass production for bioenergy using recycled wastewater in a natural waste treatment system

Bioenergy production from biomass is proposed as a method to solve part of the nation's energy problem. However, biomass and bioenergy production is questioned as an environment-friendly approach due to the potential increase of water pollution and the potential decrease of available water resource. A conceptual model of an integrated natural waste treatment system that produces biogas and biomass for bioenergy, treat waste and wastewater, conserve fresh water, and decrease the potential water pollution is presented. The potential biomass production from water hyacinth, duckweed, cattail, and knotgrass was investigated using recycling wastewater from an integrated natural waste treatment system from 2005 to 2008. Although the biomass production from recycling wastewater was not controlled for maximum production, this research identified the large potential impact that could be made if these systems were implemented. The overall average water hyacinth growth rate was high to 0.297 kg wet wt./m²/day during a research period of over 500 days, including both the active and non-active growing seasons. The average daily growth rates of duckweed, cattail, and knotgrass were 0.099-0.127, 0.015, and 0.018 kg wet wt./m², respectively. This research illustrated that water hyacinth was a more promising aquatic plant biomass for bioenergy production when wastewater effluent was recycled as water and nutrient sources from an integrated natural waste treatment system.     

COST ANALYSIS OF WATER AND WASTE WATER TREATMENT PROCESSES IN DEVELOPING COUNTRIES1

ABSTRACT: Mathematical modeling techniques are used to develop predictive equations for cost of water and waste water treatment processes in developing countries utilizing socioeconomic, environmental, and technological indicators. Predictive equations are developed for each of the three regions (Africa, Asia, and Latin America) for construction, operation, and maintenance costs of slow sand filter, rapid sand filter, stabilization lagoon, aerated lagoon, activated sludge, and trickling filter. Data analysis indicated that cost of water treatment processes is a function of technological indicator (percentage of imported materials), population, and the design capacity. The variables which gave the best correlation for waste water treatment cost were population, design flow, and the percentage of imported waste water disposal materials.     

Uncertainty analysis of the water balance technique for measuring seepage from animal waste lagoons

Water balance measurements can be used to estimate seepage rates from animal waste lagoons and earthen storages. This method requires detailed measurements of depth changes and cumulative evaporation during 5- to 10-d periods. Quantifying the uncertainty surrounding the measurements is crucial if data from seepage tests are used to determine if lagoons are meeting engineering specifications and operating within regulatory guidelines. Uncertainty analyses, using a 95% confidence interval, were applied to field data collected during studies of animal waste lagoons in Kansas and Oklahoma. Changes in depth were measured with float-based recorders and evaporation was estimated from meteorological observations. Results showed that rate changes in depth could be measured to within +/-0.28 mm d(-1) or better when wind speeds at the start and end of the test were less than 4 m s(-1). Uncertainty in evaporation was the most significant factor affecting the seepage estimate, and surface temperature and relative humidity were the main sources of imprecision in the evaporation calculations. Evaporation could be estimated to within 10 to 20%, with the largest uncertainty occurring during windy conditions. Uncertainty in the calculated seepage rate increased as evaporation increased. When evaporation rates are low (e.g., <4 mm d(-1)), seepage can be estimated to within +/-0.5 mm d(-1) with 95% confidence. A precision of +/-0.25 mm d(-1) is possible when research-grade instruments are deployed under favorable weather conditions. A measurement duration of 5 d is adequate for most water balance tests. In many cases, precision of the water balance technique will be sufficient in determining if a working lagoon is within regulatory guidelines.     

高级组合塘处理污水系统简介

氧化塘处理污水的全过程与天然水体自净相似,因此具有处理成本低、运行稳定等优点,但由于它所存在的缺点,如负荷低、占地大、恶化周围环境等,限制了它的使用,为解决这些缺点,产生了一些新型塘及塘系统,本文介绍了其中的一种,即高级组合塘系统。     

硫磺回收装置脱硫废液处理的试验研究

采用将脱硫废液与炼油废水按比例混合之后对其进行处理的方法,通过批式试验,考查混合废液的BOD5/COD指标及其COD、NH3-N、S2-的去除率。筛选合适的混合液配比,分别对500︰1和800︰1的混合废液进行了模型试验,分析了COD去除效果。结果表明:800︰1的混合废液在10d之后,出水COD为134mg/L,达到了《污水综合排放标准》(GB8978—1996)二级标准要求。最终确定炼油废水与脱硫废液混合的合适比例应不低于800︰1。     

井下作业清洁生产工艺技术应用

推行井下作业清洁生产势在必行。文章根据目前油田企业推行清洁生产中的实际情况,对井下作业各种施工中落地原油、污水和各种废液产生的原因、方式进行了分析,针对性地研制了接油漏斗、U型污水回流管、分离式汽化水放喷罐等配套新技术、新工艺。应用这些新技术、新工艺在处理井下作业施工造成的环境污染中取得了很好的效果,实现了清洁生产的目标。