Assessment of arsenic level in the hair of the nonoccupational Egyptian population: pilot study.

Arsenic level of hair samples of apparently healthy Egyptian was measured by means of hydride atomic absorption spectrophotometery. It ranged between 0.04 and 1.04 mg As/kg hair, about 55% of the analysed hair samples were within the range of allowable values (0.08-0.25 mg As/kg hair), but 45% were not. There were no considerable sex-related differences (0.303 and 0.292 mg As/kg hair for males and females, respectively). Different educational levels did not influence it either, when the effect of the age had been excluded. Children and adolescents proved to be more susceptible to arsenic as their mean levels (0.353 microg/g), and were significantly higher than those in the adults (0.233 microg/g). Smoking and some dietary habits had an important role in the elevation of arsenic levels among the nonoccupational Egyptian population: 60% of smokers and 66.7% of indoor passive smokers had arsenic levels >0.25 mg As/kg hair. Arsenic levels were also dependent on the kind of smoking, as hair arsenic of the subject smoking molasses tobacco was found to be significantly higher than that of cigarette smokers (0.459 and 0.209 mg As/kg hair, respectively). The frequency of meat and fish consumption per week was also found to be positively, significantly correlated with arsenic levels. On the other hand, the frequency of consumption of fruits, fresh and cooked vegetables, milk and milk products per week beneficially influenced the arsenic level of the hair samples examined. Arsenic content of the consumed water in Egypt was 0.001 mg/l, which is below the maximum drinking water level allowed by World Health Organisation (WHO). Therefore, the arsenic content of domestic tap water hardly contributed to the arsenic exposure of the Egyptian population in the regions of the study. It is likely that exposure routes by smoking, fish and animal protein consumption are the principal cause of arsenic accumulation in the general Egyptian population.     

Arsenic contamination of groundwater in the Terai region of Nepal: an overview of health concerns and treatment options

A review of published information on the arsenic contamination of groundwater in the Terai regions of Nepal showed that the source was mainly geogenic due to the dissolution of the arsenic-bearing minerals. Clinical observations of patients in the arsenic affected districts revealed chronic arsenic poisoning from drinking water. Half a million people inhabiting the region are believed to have been exposed to arsenic levels greater than 50 microg/L in their drinking water. Thirty-one percent of the population (3.5 million) in the region are estimated to have been exposed to arsenic levels between 10 and 50 microg/L. Iron assisted biosand filters currently distributed and in operation are a suitable alternative to mitigate the interim arsenic standard of 50 microg/L, as set by the Nepal Government. Arsenic biosand filters were also effective in removing bacteria and viruses from drinking water in laboratory and field tests. However, groundwater treatment targeting cluster communities in the Terai region is the sustainable way of mitigating the arsenic problem.     

Contamination of groundwater and risk assessment for arsenic exposure in Ha Nam province, Vietnam

The characteristics of arsenic-contaminated groundwater and the potential risks from the groundwater were investigated. Arsenic contamination in groundwater was found in four villages (Vinh Tru, Bo De, Hoa Hau, Nhan Dao) in Ha Nam province in northern Vietnam. Since the groundwater had been used as one of the main drinking water sources in these regions, groundwater and hair samples were collected in the villages. The concentrations of arsenic in the three villages (Vinh Tru, Bo De, Hoa Hau) significantly exceeded the Vietnamese drinking water standard for arsenic (10 microg/L) with average concentrations of 348, 211, and 325 microg/L, respectively. According to the results of the arsenic speciation testing, the predominant arsenic species in the groundwater existed as arsenite [As(III)]. Elevated concentrations of iron, manganese, and ammonium were also found in the groundwater. Although more than 90% of the arsenic was removed by sand filtration systems used in this region, arsenic concentrations of most treated groundwater were still higher than the drinking water standard. A significant positive correlation was found between the arsenic concentrations in the treated groundwater and in female human hair. The risk assessment for arsenic through drinking water pathways shows both potential chronic and carcinogenic risks to the local community. More than 40% of the people consuming treated groundwater are at chronic risk for arsenic exposure.     

Contamination of drinking water resources in the Mekong delta floodplains: arsenic and other trace metals pose serious health risks to population

This study presents a transnational groundwater survey of the 62,000 km(2) Mekong delta floodplain (Southern Vietnam and bordering Cambodia) and assesses human health risks associated with elevated concentrations of dissolved toxic elements. The lower Mekong delta generally features saline groundwater. However, where groundwater salinity is <1 g L(-)(1) Total Dissolved Solids (TDS), the rural population started exploiting shallow groundwater as drinking water in replacement of microbially contaminated surface water. In groundwater used as drinking water, arsenic concentrations ranged from 0.1-1340 microg L(-)(1), with 37% of the studied wells exceeding the WHO guidelines of 10 microg L(-)(1) arsenic. In addition, 50% exceeded the manganese WHO guideline of 0.4 mg L(-)(1), with concentrations being particularly high in Vietnam (range 1.0-34 mg L(-)(1)). Other elements of (minor) concern are Ba, Cd, Ni, Se, Pb and U. Our measurements imply that groundwater contamination is of geogenic origin and caused by natural anoxic conditions in the aquifers. Chronic arsenic poisoning is the most serious health risk for the ~2 million people drinking this groundwater without treatment, followed by malfunction in children's development through excessive manganese uptake. Government agencies, water specialists and scientists must get aware of the serious situation. Mitigation measures are urgently needed to protect the unaware people from such health problems.     

Impacts of arsenic contamination in groundwater: case study of some villages in Bangladesh

The contamination of groundwater in Bangladesh by arsenic is a widespread and serious environmental problem, affecting mainly the rural population who rely extensively on groundwater for drinking and cooking. The study conducted survey work in a few affected villages of the Northwest region in Bangladesh. The household survey gathered information on the respondents (affected by arsenic) water usage and sources, knowledge of the arsenic problem, changes in the source of water for drinking and cooking, arsenic mitigation technologies and socio-economic information on the households. The survey work shows that percentage of male patient is higher than female patient among the same level of household income in each study villages. Prevalence of arsenicosis is more among poorer sections and it is directly related to the poverty situation of the community. People know more about the health problems caused by arsenicosis but lack knowledge about mitigation aspects. In one of the study areas, every year an extra 4% tubewell is getting contaminated by arsenic. Arsenic contamination in groundwater also affects the environment and the ecology negatively. The NGOs have been found contributing to a knowledge creation process in the village community as the villagers are showing marked behavioral changes in water-use practice.

Recent advances in the bioremediation of arsenic-contaminated groundwater

The biological treatment of groundwater is used primarily to remove electron donors from water sources, providing (biologically) stable drinking water, which preclude bacterial regrowth during subsequent water distribution. To the electron donors belong also the dissolved metal cations of ferrous iron and manganese, which are common contaminants found in most (anaerobic) groundwater. The removal of iron and manganese is usually accomplished by the application of chemical oxidation and filtration. However, biological oxidation has recently gained increased importance and application due to the existence of certain advantages, over the conventional physicochemical treatment. The oxidation of iron and manganese is accelerated by the presence of certain indigenous bacteria, the so-called "iron and manganese oxidizing bacteria." In the present paper, selected long-term experimental results will be presented, regarding the bioremediation of natural groundwater, containing elevated concentrations of iron and arsenic. Arsenic is considered as a primary pollutant in drinking water due to its high toxicity. Therefore, its efficient removal from natural waters intended for drinking water is considered of great importance. The application of biological processes for the oxidation and removal of dissolved iron was found to be an efficient treatment technique for the simultaneous removal of arsenic, from initial concentrations between 60 and 80 microg/l to residual (effluent) arsenic concentrations lower than the limit of 10 microg/l. The paper was focused on the removal of As(III) as the most common species in anaerobic groundwater and generally is removed less efficiently than the oxidized form of As(V). To obtain information for the mechanism of As(III) removal, X-ray photoelectron spectroscopy (XPS) analyses were applied and it was found that As(III) was partially oxidized to As(V), which enabled the high arsenic removal efficiency over a treatment period of 10 months.     

砷污染与生态环境的关系

砷为广泛存在于自然界中的一种元素,在环境中表现出复杂的地球化学性质,不同形态的砷在大气、土壤及水体中的迁移和富集受许多物理化学因素的制约,并产生毒害程度不同的环境效应。总结砷的来源、其在不同环境介质中的存在状态及砷污染对生态环境的影响,提出应在了解不同介质环境中砷的赋存状态后,采用不同的治理方法有效地去除砷,以最大程度地降低砷对人体健康及生态环境造成的危害。     

Elevated childhood exposure to arsenic despite reduced drinking water concentrations — A longitudinal cohort study in rural Bangladesh

ObjectivesThe aim of this study was to evaluate the massive efforts to lower water arsenic concentrations in Bangladesh.MethodsIn our large mother–child cohort in rural Matlab, we measured the arsenic concentrations (and other elements) in drinking water and evaluated the actual exposure (urinary arsenic), from early gestation to 10 years of age (n = 1017).ResultsMedian drinking water arsenic decreased from 23 (2002–2003) to < 2 μg/L (2013), and the fraction of wells exceeding the national standard (50 μg/L) decreased from 58 to 27%. Still, some children had higher water arsenic at 10 years than earlier. Installation of deeper wells (> 50 m) explained much of the lower water arsenic concentrations, but increased the manganese concentrations. The highest manganese concentrations (~ 900 μg/L) appeared in 50–100 m wells. Low arsenic and manganese concentrations (17% of the children) occurred mainly in > 100 m wells. The decrease in urinary arsenic concentrations over time was less apparent, from 82 to 58 μg/L, indicating remaining sources of exposure, probably through food (mean 133 μg/kg in rice).ConclusionDespite decreased water arsenic concentrations in rural Bangladesh, the children still have elevated exposure, largely from food. Considering the known risks of severe health effects in children, additional mitigation strategies are needed.     

Evaluation of nitrate and trace elements concentration in drinking water:Bottled,tap and well

Concentrations of nitrate and trace elements such as arsenic,cadmium,chromium,copper,manganese,nickel,lead,selenium,antimony and mercury in 18 different brands of bottled water were investigated.For comparison,samples of tap and well water from three different places of Tehran were also analyzed.UV/VIS spectrophotometer and Graphite Furnace Atomic Absorption Spectrometer were used for the analysis of nitrate and trace elements,respectively.Results obtained were compared to Iranian,World Health Organization(WHO)and Environmental Protection Agency(EPA)guideline for drinking water.Nitrate concentration in bottled,tap and well water samples were in maximum safe nitrate concentration of Iranian and WHO standards.However,70%of bottled water samples and one sample of tap water were below the standard level proposed by EPA and probably remedial action should be taken.Concentration levels of all analyzed elements investigated in all examined water samples were below the maximum contaminant level prescribed by Iranian,WHO and EPA regulations.     

Analysis of climate trends in North Carolina (1949-1998)

North Carolina has one of the most complex climates in the United States (U.S.). Analysis of the climate in this state is critical for agricultural and planning purposes. Climate patterns and trends in North Carolina are analyzed for the period 1949-1998. Precipitation, minimum temperature, and maximum temperature are analyzed on seasonal and annual time scales using data collected from the National Weather Service Cooperative Observer Network. Additionally, changes in patterns of occurrence of the last spring freeze and first fall freeze are investigated. Linear time series slopes are analyzed to investigate the spatial and temporal trends of climate variability in North Carolina. Spatial analysis of climate variability across North Carolina is performed using a geographic information system.While most trends are local in nature, there are general statewide patterns. Precipitation in North Carolina has increased over the past 50 years during the fall and winter seasons, but decreased during the summer. Temperatures during the last 10 years are warmer than average, but are not warmer than those experienced during the 1950s. The warm season has become longer, as measured by the dates of the last spring freeze and first fall freeze. Generally, the last 10 years were the wettest of the study period.These conclusions are consistent with earlier studies that show that the difference between the maximum and minimum temperatures is decreasing, possibly due to increased cloud cover and precipitation. Similarly, these results show that temperature patterns are in phase with the North Atlantic Oscillation and precipitation patterns appear to be correlated with the Pacific Decadal Oscillation.     

Spatial distribution of arsenic in the intertidal sediments of River Scheldt, Belgium

A study was carried out to assess the spatial distribution of arsenic in the intertidal sediments of the River Scheldt in Belgium. Sediment samples were collected from different locations along the River Scheldt up to 100 cm depth and analysed for the major physicochemical properties. The study reveals that the arsenic contents in the sediment samples vary in a wide range, from 2.3 to 140.2 mg kg(-1) dry weight. Moreover, the arsenic concentrations are generally below the background concentrations and remediation thresholds of arsenic in Flanders, Belgium. The occurrence of arsenic is found closely related to some physicochemical properties of the sediments. Arsenic has a strong positive correlation with organic matter and clay contents. On the contrary, a negative correlation exists between arsenic, sand and pH. It is recommended to develop and use organic matter control practices for lowering further accumulation of arsenic within the sediments.     

Study of 222Rn concentrations in drinking water in the north-eastern hydroregions of Poland

This paper presents the results of radon concentration measurements in the drinking water from the municipal water supply system and private wells located in the north-eastern part of Poland. The measurements were carried out on 643 samples using a liquid scintillation method. The mean value was found to be 5262 Bq m-3 with a maximum of 38347 Bq m-3. The samples were obtained from different water-bearing levels, i.e. surface water, deep borehole water and well water and have respective mean values of 3398, 5178 and 6155 Bq m-3. In 57 water samples, a guideline maximum level of 11,000 Bq m-3 was found to be exceeded. The observed radon concentration in water can contribute to a 2% increase in indoor radon concentration.     

Arsenic geochemistry and health

Arsenic occurs naturally in the earth's crust and is widely distributed in the environment. Natural mineralization and activities of microorganisms enhance arsenic mobilization in the environment but human intervention has exacerbated arsenic contamination. Although arsenic is useful for industrial, agricultural, medicinal and other purposes, it exerts a toxic effect in a variety of organisms, including humans. Arsenic exposure may not only affect and disable organs of the body, especially the skin, but may also interfere with the proper functioning of the immune system. This paper, therefore, generally highlights the toxic effects of arsenic as well as its mobilization in the natural environment and possible controls. It also briefly attempts to outline the impact of arsenic on the immune system, whose alteration could lead to viral/bacterial infections.     

苏州地区地下水资源城市应急利用适宜性研究

随着太湖水体富营养化程度的不断加剧,建立安全、稳定、可靠的应急备用水源日益重要。利用2005~2009年苏州地区地下水水质连续监测和补充监测资料,对第Ⅱ承压含水层进行了应急利用(生活饮用和工业利用)的水质适宜性和安全性评价分析。研究结果表明:第Ⅱ承含水层主要水化学类型为Na-HCO3、Ca-HCO3和Na-CaHCO3型,水质总体稳定,年际差异很小;地下水水质指数(WQI)均值较低(位于49.98~68.75之间),地下水没有受到有机物污染,可作为应急利用水源;WQI的水质指标贡献率表明,As、Fe、pH和Mn指标的贡献率最大,局部区域As、Fe、Mn及氨氮和亚硝酸盐含量较高,应急利用时应进行处理。朗格里尔饱和指数(LSI)和拉森比(LnR)评价结果表明,该水源易结垢,具有轻微腐蚀倾向,作为工业备用水源时应进行适当的处理。为苏州地区地下水应急水源建设和安全利用提供了科学依据和参考。     

Assessment of groundwater contamination in a suburban area of Chennai,Tamil Nadu,India

Groundwater source is the major source of drinking water in most of the suburban areas of India. Groundwater quality was analyzed for pH, TDS, hardness, chloride, fluoride, nitrate, ammonia, phosphate, total coliform and E. coli for the period of January–December 2013. Samples were collected from 10 locations that include 10 shallow wells and 10 deep wells in each location. The quality variation between both shallow and deep wells during pre- and post-monsoon was analyzed. The improper disposal of solid waste and the distance of septic tank were pronounced on E. coli count. The analysis reveals that groundwater contamination is influenced by seasonal changes, environmental condition of the well and maintenance of the well. The high contamination was observed in the wells which are near to the Pallikaranai marsh, and during post-monsoon season, the total dissolved solids and nitrite parameters are slightly increased, whereas chloride increases during pre-monsoon season. Correlation analysis reveals that the chloride and nitrite have a significant relation. The results suggested that the groundwater immediately needs broader protection.     

Monitoring and evaluation of shallow well water quality near a waste disposal site

This study identifies shallow well water contamination sources near the Mae-Hia waste disposal site and the clarification of the extent of well water contamination caused by leachate generated from the disposal site. The water of 40 shallow wells around the Mae-Hia disposal site, where three potential sources of groundwater pollution exist, was sampled and analyzed for physical, chemical, and biological characteristics. Water samples were taken every month from June 1989 to May 1990 along with a measurement of well water levels in order to estimate the groundwater flow direction. Comparison with the drinking water standards/guidelines showed that well water in the study area was not suitable for drinking due to the high contamination of total and fecal coliforms and moderate contamination by nitrate and manganese. It was found that the level of conductivity, total solids, color, chloride, chemical oxygen demand, sodium, copper, and lead in the groundwater of wells located adjacent to the disposal site were higher than in other areas. In addition, higher concentrations of sodium, chloride, calcium, and magnesium in the wells located downstream of the groundwater flow were recorded. Estimation of a leachate plume using chloride as an indicator showed that the wells located in the eastern part of the disposal site, a dominant direction of groundwater flow, were contaminated by leachate generated from the waste disposal site.     

Arsenic in groundwater: A threat to sustainable agriculture in South and South-east Asia

The problem of arsenic pollution of groundwater used for domestic water supplies is now well recognised in Bangladesh, India and some other countries of South and South-east Asia. However, it has recently become apparent that arsenic-polluted water used for irrigation is adding sufficient arsenic to soils and rice to pose serious threats to sustainable agricultural production in those countries and to the health and livelihoods of affected people. This paper reviews the nature of those threats, taking into account the natural sources of arsenic pollution, areas affected, factors influencing arsenic uptake by soils and plants, toxicity levels and the dietary risk to people consuming arsenic-contaminated rice.     

What is the best biomarker to assess arsenic exposure via drinking water?

Arsenic (As) is a ubiquitous element. The current WHO guideline for As in drinking water is 10 μg/L. Furthermore, about 130 million people have only access to drinking water containing more than 10 gAs/L. Although numerous studies have shown the related adverse effects of As, sensitive appropriate biomarkers are still required for studies of environmental epidemiology. A review of the literature has shown that various biomarkers are used for such research. Their limits and advantages are highlighted in this paper: (i) the detection of As or its derivatives in the blood is an indication of the dose ingested but it is not evidence of chronic intoxication. (ii) The detection of As in urine is an indispensible procedure because it is a good marker for internal dose. It has been demonstrated to correlate well for a number of chronic effects related to As levels in drinking water. However confounding factors must be taken into account to avoid misinterpretation and this may require As speciation. (iii) As in the hair and nails reflects the level of long term exposure but it is difficult to relate the level with the dose ingested. (iv) Some studies showed a correlation between urinary As and urinary and blood porphyrins. However, it is difficult to use only porphyrins as a biomarker in a population survey carried out without doing further studies. (v) Genotoxic effects are based on the characterization of these potential effects. Most studies have detected increases in DNA damage, sister chromatid exchange, micronuclei or chromosomal aberrations in populations exposed to As in drinking water. Micronuclei assay is the technique of choice to follow these populations, because it is sensitive and easy to use.To conclude, whatever epidemiological studies are, the urinary and toenail biomarkers are useful to provide indications of internal dose. Moreover, micronuclei assay can be complementary use as biomarker of early effects.     

Chemical evaluation of potable water in Eastern Qinghai Province, China: human health aspects

Electric conductivity, pH, COD(Mn), nutrient concentration, chloride and sulfate concentrations, total dissolved sodium, potassium, calcium, magnesium, manganese, iron, cadmium, copper, arsenic, nickel, zinc, chromium and lead were evaluated to clarify concerns about the quality and safety of water used for drinking purposes in Qinghai Province, China. For this purpose, 12 water samples were collected from different villages, Qinghai (Koko Nor) Lake and medicinal springs close to the Town of Pingang during a study visit to China in 2003. The results showed that National Chinese and WHO drinking water standards were exceeded for nutrient concentration (3.2 mg l(-1) of TOT-N and 0.2 mg l(-1) of TOT-P) from Qinghai Lake. The presence of elevated electric conductivity (550 mS m(-1)) in mineral water resort samples should be a matter of a public concern. Also, samples from medicinal springs showed high concentrations of Fe (up to 1.9 mg l(-1)), As (up to 0.1 mg l(-1)) and Ni (0.05 mg l(-1)), which may be detrimental for human health if the water is consumed on a daily basis. The concentrations of Cu, Cd, Cr and Pb did not exceed the National Chinese and WHO drinking water standards, and therefore, water from the sampling area does not pose any significant threat to the consumers' health regarding these metals.