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1.
In-stream nitrogen, phosphorus, organic carbon, and suspended sediment concentrations were measured in 18 subbasins over 2 annual cycles to assess how land use and land cover (LULC) and stream discharge regulate water quality variables. The LULC was a primary driver of in-stream constituent concentrations and nutrient speciation owing to differences in dominant sources and input pathways associated with agricultural, urban, and forested land uses. Stream discharge was shown to be a major factor that dictated not only the magnitude of constituent concentrations, but also the chemical form. In high discharge agricultural subbasins, where nitrate was the dominant nitrogen form, there was a negative correlation between discharge and nitrate concentration indicating groundwater inputs as the dominant pathway. In urban settings, however, nitrate was positively correlated with discharge, and, in forested subwatersheds, where dissolved organic nitrogen (DON) was the dominant nitrogen form, there was a positive correlation between discharge and DON, indicating washoff from the watershed as the dominant input pathway. Similarly, phosphorus concentrations were strongly regulated by LULC, discharge, and seasonality. This comparative study highlights that different mechanisms regulate different forms of nitrogen, phosphorus, and carbon, and thus field programs or water quality models used for regulatory purposes must assess these nutrient forms to accurately apply management plans for nutrient reductions.  相似文献   

2.
Exploring how water quality and land use shape the benthic macroinvertebrate community composition is of widespread interest in biodiversity conservation and environmental management. In this study, we investigated the structures of benthic macroinvertebrate assemblages and their environmental controls in terms of water quality and riparian land use in the Jinshui River, China. We carried out three campaigns including wet season (August 2009), dry season (November 2009), and normal season (April 2010) based on the hydrological regime in Jinshui basin. The result showed that macroinvertebrate assemblage variations were better explained by water quality factors than land use based on variance partitioning procedure. The land use of 2 km upstream from the sampling sites had explained more variation than that of the whole riparian zone in upstream catchment on macroinvertebrate community, and land use of 2 km upstream also had more interactions with water quality. Canonical correspondence analysis (CCA) indicated that the elements or nutrient of magnesium (Mn), selenium (Se), strontium (Sr), silicon (Si), dissolved inorganic nitrogen (DN), sulfur (S), total organic carbon (TOC), and total nitrogen (TN) in water exhibited a strong relationship with macroinvertebrate assemblages. However, the variance in water quality explained by land use was lower than that explained by water quality in rivers using redundancy analysis. Our study suggested that proximate factors (i.e., water quality) were more important to interpret the macroinvertebrate community compared to ultimate factors (i.e., land use) for macroinvertebrate assemblages in river system.  相似文献   

3.
利用生态混凝土作为护坡材料,研究暴雨条件下生态混凝土控制山坡降雨径流污染的机理,以期对生态混凝土在城市护坡和护岸中的应用提供理论依据.研究结果表明,生态混凝土改变了雨水在坡面上的水文过程,阻延径流作用十分明显,有效地降低了污染物的负荷输出.生态混凝土试验小区(T2)与裸地(CK)和改良土壤小区(T1)相比,径流量分别减少了48%和24%,TN年度污染负荷(UPLRs)分别减少了53%和45%,溶解态氮(DN)减少了26%和28%,TP减少了57%和30%,溶解态磷(DP)降低了80%和33%,COD降低了62%和40%,TSS降低了56%和43%,产流时间和流量峰均明显滞后.另外,同植被覆盖良好的小区(T3)相比,生态混凝土对各种污染指标的控制效果没有明显差异,但其抗冲刷能力较强,更能适应城市护坡和护岸的需要.  相似文献   

4.
BACKGROUND: Organochlorine pesticides (OCPs) have been dispersed ubiquitously in the environment. Bottom sediments act as sinks for these compounds and their concentrations often reflect the degree of anthropogenic pollution. This study was designed to evaluate the occurrence and distribution of OCPs in superficial streambed sediments and their relation to land use in two creeks that contribute to the coastal pollution of the southeastern region of Argentina. METHODS: Sampling sites were selected by a combination of land use and stream type. Las Brusquitas creek, which passes through vast agricultural areas, and La Tapera creek which originates in a natural wetland and passes through horticultural farming and urban areas. OCPs quantification was carried out by GC-ECD. RESULTS AND DISCUSSION: Results showed similar total OCP concentrations in sediments from both creeks in the range of 6-25 ng/g dry wt. However, when OCPs were expressed in ng/g total organic carbon (TOC), La Tapera creek presented 4-fold higher total levels as a consequence of a higher OCP input during the recent past in that watershed. La Tapera outfall showed 4-fold higher levels than that seen in Las Brusquitas, although both values were below the sediment quality criteria demanded to protect wildlife. Sigmaendosulfans, sigmaDDTs and sigmachlordanes were the main OCP group in all samples, with Endosulfan sulfate being the most frequent and abundant compound. The predominance of metabolites with respect to parent compounds suggests a contamination mainly by runoff from aged and weathered agricultural soils. CONCLUSIONS: Despite OCPs being banned, they still exist in creek sediments from the studied region, representing continuous contributions of land-based source contaminants to the marine environment. OUTLOOK: Future research on OCP levels in suspended sediments is recommended in order to determine the total OCP concentrations in the selected stream systems.  相似文献   

5.
Projected changes in climate in Southern Norway include increases in summer and autumn precipitation. This may affect leaching of dissolved organic matter (DOM) from soils. Effects of experimentally added extra precipitation (10 mm week) during the growing season of 3 years (2004-2006) to small headwater catchments at Storgama (59 degrees 0'N, 550-600 m a.s.l.) on leaching of total organic carbon (TOC) and total organic nitrogen (TON) were assessed. Extra precipitation did not have a significant effect on average TOC and TON concentrations in runoff. Thus, fluxes of TOC and TON increased nearly proportionally with water fluxes. This suggests that a store of adsorbed and potentially mobile TOC and TON in catchment soils buffers the concentration of DOM in runoff. The size and dynamics of the pool of TOC and TON depends on the balance between production and leaching rates. Infrequent short droughts had only small effects on TOC and TON fluxes in runoff from the reference catchments.  相似文献   

6.
The influence of land use on water quality in streams is scale-dependent and varies in time and space. In this study, land cover patterns and stocking rates were used as measures of agricultural development in two pasture and one native grassland catchment in New Zealand and were related to water quality in streams of various orders. The amount of pasture per subcatchment correlated well to total nitrogen and nitrate in one catchment and turbidity and total phosphorous in the other catchment. Stocking rates were only correlated to total phosphorous in one pasture catchment but showed stronger correlations to ammonium, total phosphorous and total nitrogen in the other pasture catchment. Winter and spring floods were significant sources of nutrients and faecal coliforms from one of the pasture catchments into a wetland complex. Nutrient and faecal coliform concentrations were better predicted by pastural land cover in fourth-order than in second-order streams. This suggests that upstream land use is more influential in larger streams, while local land use and other factors may be more important in smaller streams. These temporal and spatial scale effects indicate that water-monitoring schemes need to be scale-sensitive.  相似文献   

7.
Storm runoff from six types of underlying surface area during five rainfall events in two urban study areas of Wenzhou City, China was investigated to measure phosphorus (P) concentrations and discharge rates. The average event mean concentrations (EMCs) of total phosphorus (TP), total dissolved phosphorus (TDP), and particulate phosphorus (PP) ranged from 0.02 to 2.5 mg?·?L?1, 0.01 to 0.48 mg?·?L?1, and 0.02 to 2.43 mg?·?L?1, respectively. PP was generally the dominant component of TP in storm runoff, while the major form of P varied over time, especially in roof runoff, where TDP made up the largest portion in the latter stages of runoff events. Both TP and PP concentrations were positively correlated with pH, total suspended solids (TSS), and biochemical oxygen demand (BOD)/chemical oxygen demand (COD) concentrations (p?<?0.01), while TDP was positively correlated with BOD/COD only (p?<?0.01). In addition, the EMCs of TP and PP were negatively correlated with maximum rainfall intensity (p?<?0.05), while the EMCs of TDP positively correlated with the antecedent dry weather period (p?<?0.05). The annual TP emission fluxes from the two study areas were 367.33 and 237.85 kg, respectively. Underlying surface type determined the TP and PP loadings in storm runoff, but regional environmental conditions affected the export of TDP more significantly. Our results indicate that the removal of particles from storm runoff could be an effective measure to attenuate P loadings to receiving water bodies.  相似文献   

8.
The long-term impacts of current forest management methods on surface water quality in Fennoscandia are largely unexplored. We studied the long-term effects of clear-cutting and site preparation on runoff and the export of total nitrogen (total N), total organic nitrogen (TON), ammonium (NH4-N), nitrate (NO3-N), total phosphorus (total P), phosphate (PO4-P), total organic carbon, and suspended solids (SS) in three paired-catchments in Eastern Finland. Clear-cutting and soil preparation were carried out on 34 % (C34), 11 % (C11), and 8 % (C8) of the area of the treated catchments and wide buffer zones were left along the streams. Clear-cutting and soil preparation increased annual runoff and total N, TON, NO3-N, PO4-P, and SS loads, except for SS, only in C34. Runoff increased by 16 % and the annual exports of total N, TON, NO3-N, and PO4-P by 18, 12, 270, and 12 %, respectively, during the 14-year period after clear-cutting. SS export increased by 291 % in C34, 134 % in C11, and 16 % in C8 during the 14, 6, and 11-year periods after clear-cutting. In the C11 catchment, NO3-N export decreased by 12 %. The results indicate that while current forest management practices can increase the export of N, P and SS from boreal catchments for many years (>10 years), the increases are only significant when the area of clear cutting exceeds 30 % of catchment area.  相似文献   

9.
Projected climate change might increase the deposition of nitrogen by about 10% to seminatural ecosystems in southern Norway. At Storgama, increased precipitation in the growing season increased the fluxes of total organic carbon (TOC) and total organic nitrogen (TON) in proportion to the water flux. In winter, soil temperatures near 0 degrees C, common under a snowpack, induced higher runoff of inorganic nitrogen (N) and lower runoff of TOC. By contrast, soil temperatures below freezing, caused by little snow accumulation (expected in a warmer world), reduced runoff of inorganic N, TON, and TOC. Long-term monitoring data showed that reduced snowpack can cause either decreased or increased N leaching, depending on interactions with N deposition, soil temperature regime, and winter discharge. Seasonal variation in TOC was mainly climatically controlled, whereas deposition of sulfate and nitrate (NO3) explained the long-term TOC increase. Upscaling to the river basin scale showed that the annual flux of NO3 will remain unchanged in response to climate change projections.  相似文献   

10.
We studied the effects of catchment characteristics (soil type and land use) on the concentration and quality of dissolved organic matter (DOM) in river water and on the bacterial degradation of terrestrial DOM. The share of organic soil was the strongest predictor of high concentrations of dissolved organic carbon, nitrogen, and phosphorus (DOC, DON, and DOP, respectively), and was linked to DOM quality. Soil type was more important than land use in determining the concentration and quality of riverine DOM. On average, 5–9 % of the DOC and 45 % of the DON were degraded by the bacterial communities within 2–3 months. Simultaneously, the proportion of humic-like compounds in the DOM pool increased. Bioavailable DON accounted for approximately one-third of the total bioavailable dissolved nitrogen, and thus, terrestrial DON can markedly contribute to the coastal plankton dynamics and support the heterotrophic food web.  相似文献   

11.
Urban stormwater runoff quality, widely investigated around the world, has been monitored less in Beijing, China, which impedes the municipal government to use best management practices to protect surface water. In this study, rainwater and stormwater runoff samples from roofs, roads, and a lawn on the campus of the Research Center for Eco-Environmental Sciences (RCEES) (Beijing, China) and from a ring road, with heavy traffic, have been sampled and analyzed for 31 storm events from June 2004 to August 2005. Total suspended solids (TSS), chemical oxygen demand (COD), 5-day biochemical oxygen demand (BOD5), total nitrogen, and total phosphorus concentrations in rainwater and runoff ranged over 2 or more orders of magnitude, meaning that the highest concentration of a certain pollutant did not always occur in a certain kind of runoff. Runoff contained significantly higher concentrations of pollutants than rainwater. On the campus of RCEES, TSS and total phosphorus in runoff samples from the lawn and roads were significantly higher than those from roofs, while the COD, BOD5, and total nitrogen concentrations were not significantly different in runoff among surfaces. Compared with runoff from the roads on campus, runoff from the ring road contained more COD and total nitrogen, but less TSS, BOD5, and total phosphorus. All pollutants measured in runoff from roofs on campus and from the ring road showed a peak concentration in starting runoff, which then decreased sharply. The peak concentrations of COD, BOD5, total nitrogen, and total phosphorus in the roof runoff increased with the increase in time of the antecedent dry period. Thus, urban stormwater pollution control, especially for first-flush control, is of great importance for the full use of rainwater and prevention of water pollution.  相似文献   

12.
Water quality degradation is often a severe consequence of rapid economic expansion in developing countries. Methods to assess spatial-temporal patterns and trends in water quality are essential for guiding adaptive management efforts aimed at water quality remediation. Temporal and spatial patterns of surface water quality were investigated for 54 monitoring sites in the Wen-Rui Tang River watershed of eastern China to identify such patterns in water quality occurring across a rural-suburban-urban interface. Twenty physical and chemical water quality parameters were analyzed in surface waters collected once every 4–8 weeks from 2000 to 2010. Temporal and spatial variations among water quality parameters were assessed between seasons (wet/dry) and among major land use zones (urban/suburban/rural). Factor analysis was used to identify parameters that were important in assessing seasonal and spatial variations in water quality. Results revealed that parameters related to organic pollutants (dissolved oxygen (DO), chemical oxygen demand (manganese) (CODMn), and 5-day biochemical oxygen demand (BOD5)), nutrients (ammonia nitrogen (NH4 +-N), total nitrogen (TN), total phosphorus (TP)), and salt concentration (electrical conductivity (EC)) were the most important parameters contributing to water quality variation. Collectively, they explained 70.9 % of the total variance. A trend study using the seasonal Kendall test revealed reductions in CODMn, BOD5, NH4 +-N, petrol, V-phen, and EC concentrations over the 11-year study period. Cluster analysis was employed to evaluate variation among 14 sampling sites representative of dominant land use categories and indicated three, three, and four clusters based on organic, nutrient, and salt water quality characteristics, respectively. Factors that are typically responsible for water quality degradation (including population, topography, and land use) showed no strong correlation with water quality trends implying considerable point source inputs in the watershed. The results of this study help inform ongoing water quality remediation efforts by documenting trends in water quality across various land use zones.  相似文献   

13.
九寨沟公路和栈道降雨径流污染负荷过程的研究   总被引:1,自引:0,他引:1  
对九寨沟国家公园中的公路和游客栈道进行了人工降雨试验的设计、操作和测试数据分析.模拟试验选择6处公路和栈道试验区,采用人工降雨方法模拟雨量出现概率60%、历时30 min的降雨.试验按3 min间隔对各试验场降雨径流带出的总磷负荷进行现场监测.研究结果提供了在具有代表性的降雨条件对总磷营养物输出的定量估计.尤其对公路和栈道降雨径流特征获得了认识:污染物初始冲刷浓度期延续约3 min;在降雨强度不变的情况下,污染物负荷率接近常量.大部分污染物负荷可由出现频率较大的小降雨事件输出.表明研究结果提供了一种思路,即可采用平均负荷方式取代过去的平均浓度方式去构建公路和栈道的负荷模型.  相似文献   

14.
Nitrogen (N) losses from agricultural fields have been extensively studied. In contrast, surface runoff and N losses have rarely been considered for bamboo forests that are widespread in regions such as southern China. The thriving of bamboo industries has led to increasing fertilizer use in bamboo forests. In this study, we evaluated surface runoff and N losses in runoff following different fertilization treatments under field conditions in a bamboo (Phyllostachys pubescens) forest in the catchment of Lake Taihu in Jiangsu, China. Under three different fertilization regimes, i.e., control, site-specific nutrient management (SSNM), and farmer's fertilization practice (FFP), the water runoff rate amounted to 356, 361, and 342 m3?ha?1 and accounted for 1.91, 1.98, and 1.85 % of the water input, respectively, from June 2009 to May 2010. The total N losses via surface runoff ranged from 1.2 to 1.8 kg?ha?1. Compared with FFP, the SSNM treatment reduced total nitrogen (TN) and dissolved nitrogen (DN) losses by 31 and 34 %, respectively. The results also showed that variations in N losses depended mainly on runoff fluxes, not N concentrations. Runoff samples collected from all treatments throughout the year showed TN concentrations greater than 0.35 mg?L?1, with the mean TN concentration in the runoff from the FFP treatment reaching 8.97 mg?L?1. The loss of NO3 ?–N was greater than the loss of NH4 +–N. The total loss of dissolved organic nitrogen (DON) reached 23–41 % of the corresponding DN. Therefore, DON is likely the main N species in runoff from bamboo forests and should be emphasized in the assessment and management of N losses in bamboo forest.  相似文献   

15.
Large-scale forestry operations, like clear-cutting, may impair surface water quality if not done with environmental considerations in mind. Catchment and country level estimates of nutrient loads from forestry are generally based on specific export values, i.e., changes in annual exports due to the implemented forestry operations expressed in kg ha−1. We introduce here a specific concentration approach as a method to estimate the impact of clear-cutting on nutrient concentrations and export in headwater streams. This new method is potentially a more dynamic and flexible tool to estimate nutrient loads caused by forestry, because variation in annual runoff can be taken into account in load assessments. We combined water quality data from eight boreal headwater catchment pairs located in Finland and Sweden, where the effect of clear-cutting on stream water quality has been studied experimentally. Statistically significant specific concentration values could be produced for total nitrogen, nitrate, ammonium, and phosphate. The significant increases in the concentrations of these nutrients occurred between 2 and 6 years after clear-cutting. Significant specific concentration values could not be produced for total phosphorus and total organic carbon with the whole dataset, although in some single studies significant increases in their concentrations after clear-cutting were observed. The presented method enables taking into account variation in runoff, temporal dynamics of effects, and the proportional size of the treated area in load calculations. The number of existing studies considering large site-specific variation in responses to clear-cutting is small, and therefore further empirical studies are needed to improve predictive capabilities of the specific concentration values.  相似文献   

16.
Provincial-level data for population, livestock, land use, economic growth, development of sewage systems, and wastewater treatment rates were used to construct a river nitrogen (N) export model in this paper. Despite uncertainties, our results indicated that river N export to coastal waters increased from 531 to 1,244 kg N km?2 year?1 in the Changjiang River basin, 107 to 223 kg N km?2 year?1 in the Huanghe River basin, and 412 to 1,219 kg N km?2 year?1 in the Zhujiang River basin from 1980 to 2010 as a result of rapid population and economic growth. Significant temporal changes in water N sources showed that as the percentage of runoff from croplands increased, contributions of natural system runoff and rural human and livestock excreta decreased in the three basins from 1980 to 2010. Moreover, the nonpoint source N decreased from 72 to 58 % in the Changjiang River basin, 80 to 67 % in the Huanghe River basin, and 69 to 51 % in the Zhujiang River basin, while the contributions of point sources increased greatly during the same period. Estimated results indicated that the N concentrations in the Changjiang, Huanghe, and Zhujiang rivers during 1980–2004 were higher than those in the St. Lawrence River in Canada and lower than those in the Thames, Donau, Rhine, Seine, and Han rivers during the same period. River N export will reduce by 58, 54, and 57 % for the Changjiang River, Huanghe River, and Zhujiang River in the control scenario in 2050 compared with the basic scenario.  相似文献   

17.
在野外模拟降雨条件下,开展了晋江西溪流域茶园和裸地的径流产沙及氮磷养分流失过程对比实验,研究结果表明,在相同降雨强度下,3种下垫面径流和产沙量顺序均为:裸地>2年茶园>4年茶园,径流量与产沙量之间呈显著正相关.对地表径流水相而言,2年茶园、4年茶园和裸地的TN流失量分别为:461.29、129.38和107.86 mg/m2;NO3-N流失量分别为:286.42、98.58和103.00 mg/m2,均占TN流失量的60%以上;NH4-N流失量分别为:48.67、16.19和4.42 mg/m2;Tp流失量分别为:34.71、16.47和23.88 mg/m2.对径流泥沙相而言,2年茶园、4年茶园和裸地的TN流失量分别为:379.28、44.81和747.16 mg/m2,占流失总量的比重在25.72%~87.93%之间;TP流失量分别为:27.94、4.17和58.85 mg/m2,占流失总量的比重在53.42% ~68.36%之间.茶园的N、P主要随径流流失,而裸地以泥沙迁移为主.这说明茶叶种植具有一定的水土保持效应,且种植年限较长的茶园可显著减少随径流泥沙进入水体中的N、P元素.  相似文献   

18.
Road runoff is a major source of environmental pollution, significantly threatening nearby aquatic habitats. Chemical analyses indicate high pollutant concentrations in the road’s “first flush”, but bioassays are more advantageous for addressing the cumulative effects of the numerous pollutants within the runoff. We used Bufo viridis embryos and larvae to assess the toxicity of road runoff from two major highways in Israel. We show, for the first time, that exposure to midseason runoff not only has an adverse effect on growth and development rates of B. viridis larvae but can also lead to increased rates of morphological deformations. Seasonal first flushes, despite having higher metal concentrations, did not adversely affect the toad larvae, apparently due to a counter effect of organic matter that potentially served as a supplementary energy resource. Road runoff can be a major cause for a qualitative decrease in the quality of aquatic habitats threatening amphibians in Israel.  相似文献   

19.
The assessment of spatial and temporal variation of water quality influenced by land use is necessary to manage the environment sustainably in basin scales. Understanding the correlations between land use and different formats of nonpoint source nutrients pollutants is a priority in order to assess pollutants loading and predicting the impact on surface water quality. Forest, upland, paddy field, and pasture are the dominant land use in the study area, and their land use pattern status has direct connection with nonpoint source (NPS) pollutant loading. In this study, two land use scenarios (1995 and 2010) were used to evaluate the impact of land use changes on NPS pollutants loading in basins upstream of Three Gorges Reservoir (TGR), using a calibrated and validated version of the soil and water assessment tool (SWAT) model. The Pengxi River is one of the largest tributaries of the Yangtze River upstream of the TGR, and the study area included the basins of the Dong and Puli Rivers, two major tributaries of the Pengxi River. The results indicated that the calibrated SWAT model could successfully reproduce the loading of NPS pollutants in the basins of the Dong and Puli Rivers. During the 16-year study period, the land use changed markedly with obvious increase of water body and construction. Average distance was used to measure relative distribution patterns of land use types to basin outlets. Forest was mainly distributed in upstream areas whereas other land use types, in particular, water bodies and construction areas were mainly distributed in downstream areas. The precipitation showed a non-significant influence on NPS pollutants loading; to the contrary, interaction between precipitation and land use were significant sources of variation. The different types of land use change were sensitive to NPS pollutants as well as land use pattern. The influence of background value of soil nutrient on NPS pollutants loading was evaluated in upland and paddy field. It was found that total nitrogen (TN) and total phosphorous (TP) in upland were more sensitive to NPS pollutants loading than in paddy fields. The results of this study have implications for management of the TGR to reduce the loading of NPS pollutants into downstream water bodies.  相似文献   

20.
Bioremediation is the use of living organisms, primarily microorganisms, to degrade environmental contaminants into less toxic forms. Nine biobeds (ground cavity filled with a mixture of composted organic matter, topsoil, and a surface grass) were established at Kentucky State University research farm (Franklin County, KY) to study the impact of this practice on reducing surface runoff water contamination by residues of dimethazone and trifluralin herbicides arising from an agricultural field. Biobed (biofilter) systems were installed at the bottom of the slope of specially designed runoff plots to examine herbicides retention and degradation before entering streams and rivers. In addition to biobed systems, three soil management practices: municipal sewage sludge (SS), SS mixed with yard waste compost (SS + YW), and no-mulch rototilled bare soil (NM used for comparison purposes) were used to monitor the impact of soil amendments on herbicide residues in soil following natural rainfall events. Organic amendments increased soil organic matter content and herbicide residues retained in soil following rainfall events. Biobeds installed in NM soil reduced dimethazone and trifluralin by 84 and 82%, respectively in runoff water that would have been transported down the land slope of agricultural fields and contaminated natural water resources. Biobeds installed in SS and SS+YW treatments reduced dimethazone by 65 and 46% and trifluralin by 52 and 79%, respectively. These findings indicated that biobeds are effective for treating dimethazone and trifluralin residues in runoff water.  相似文献   

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