HYDROLOGIC RESPONSE TO PUMPING AND CONTAMINANT ADVECTION IN A FRACTURED ROCK ENVIRONMENT1

ABSTRACT: Ground water flow and supply at the Whiteshell Research Area (WRA) in southeastern Manitoba and the advective movement of contaminants from a hypothetical nuclear fuel waste disposal vault to the adjacent biosphere and a nearby ground water supply well are simulated using finite-element modeling and numerical particle-tracking technique. The hypothetical vault is located at a depth of 500 m, below the water table, in low-permeability plutonic rock of the Canadian Shield. The rock mass is intersected by high-permeability fracture zones (aquifers), which also act as conduits for vault contaminants to migrate to the ground surface. The ground water resource is, therefore, limited in quantity and quality and should be explored with care. A 30 m deep well, which pumps water at a rate of 120 m³/yr from a low-dipping fracture zone, LD1, reduces natural discharge from the system to augment natural recharge. At this pumping rate, a 100 m or 200 m deep well neither reduces discharge nor induces recharge into the system. Thus, at the WRA, a 30 m deep domestic water supply well best meets the water requirements of a one-person household at the rate of 120 m³/yr. The 100 m and 200 m wells best meet the requirements of a family of six and a family of six with light irrigation, respectively, without capturing contaminants’pathways from the vault to the ground surface. By virtue of the proximity of the 200 m well intake to the hypothetical vault, this well performs best as a purge well at pumping rates of 0,000 m³/yr and greater. Finite-element modeling is useful in evaluating the water supply potential of a fractured rock environment in which a nuclear waste disposal vault is proposed to be sited.     

MINE DRAINAGE AND ROCK TYPE INFLUENCES ON EASTERN OHIO STREAM WATER QUALITY1

ABSTRACT: Stream water during fair weather (base flow) is largely ground water discharge, which has been in contact with minerals of the underlying aquifer. Base flow water quality should therefore reflect aquifer mineralogy as well as upstream land use. Three upstream mining categories (unmined lands, abandoned coal mines, and reclaimed coal mines) differed in pH, specific conductance, sulfate, iron, aluminum, and alkalinity for 122 streams in eastern Ohio. Aquifer rock type influenced pH, specific conductance, sulfate, iron, and alkalinity. Reclamation returned many components of acid mine drainage to near unmined levels, although sulfate and specific conductance were not improved. Acid mine drainage problems were less severe in watersheds underlain by the calcareous Monogahela Formation. These results should ayply to other Appalachian coal regions having similar rock units. The water quality data distributions were neither consistently normal nor lognormal. Statistical tests utilizing ranks of the water quality data, instead of the data themselves, proved useful in analyzing the influences of mining category and rock type.     

浅论新疆煤矿矿井排水的处理问题

就新疆煤矿矿井水的排水问题，水质特征及处理方法展开了分析讨论，介绍了几种较成熟的煤矿矿井水处理方法和工艺技术。     

EFFECT OF SEMI‐PERCHED GROUND WATER ON MONITORING OF GROUND WATER LEVELS IN A DEVELOPED AQUIFER1

ABSTRACT: Interpretation of ground water level changes in a developed aquifer usually relies on reference to some benchmark such as “predevelopment” ground water levels, changes from fall to fall and/or spring to spring, or to determination of maximum stress during the pumping season. The assumption is that ground water levels measured in the monitoring well accurately reflect the state of the ground water resource in terms of quantity in storage and the effects of local pumping. This assumption is questionable based on the patterns shown in continuous hydrographs of water levels in monitoring wells in Nebraska, and wells installed to determine vertical gradients. These hydrographs show clear evidence for vertical ground water gradients and recharge from overlying parts of the aquifer system to deeper zones in which production wells are screened. The classical concept of semi‐perched ground water, as described by Meinzer, is demonstrated by these hydrographs. The presence of semi‐perched ground water (Meinzer definition, there is no intervening unsaturated zone) invalidates the use of measured ground water levels in regional observation programs for detailed numerical management of the resource. Failure to recognize the Meinzer effect has led to faulty management. The best use of data from the observation well network would be for detection of trends and education unless it is clearly understood what is being measured.     

A Stochastic Modeling Approach to Address Hydrogeologic Uncertainties in Modeling Wellhead Protection Boundaries in Karst Aquifers1

Abstract: Development of any numerical ground‐water model is dependent on hydrogeologic data describing the subsurface. These data are obtained from geologic core analyses, stratigraphic analyses, aquifer performance tests, and geophysical studies. But typically in remote areas, these types of data are very sparse and site‐specific in terms of the aerial extent of the resource to be modeled. Uncertainties exist as to how well the available data from a few locations defines a heterogeneous surficial aquifer such as the Biscayne Aquifer in Miami‐Dade County, Florida. This is particularly the case when an exceptionally conductive horizontal flow zone is detected at one site due to specialized testing that was not historically conducted at the other at sites that provided data for the model. Not adequately accounting for the potential effect of the high flow zone in the aquifer within a ground‐water numerical model, even though the zone may be of very limited thickness, might underpredict the well field protection capture boundaries. Applied Stochastic ground‐water modeling in determining well field protection zones is steadily becoming important in addressing the uncertainty of the hydrogeologic subsurface parameters, specifically in karstic heterogeneous aquifers. This is particularly important in addressing the uncertainty of a 60‐day travel time capture zone in the Northwest Well Field, Miami‐Dade County, where a predominantly high flow zone controls much of the flow in the production wells. A stochastic ground‐water modeling application along with combination of pilot points and regularization technique is presented to further consolidate the uncertainty of the subsurface.     

GROUND WATER USE IN AN ENERGY DEVELOPMENT AREA: THE TONGUE RIVER BASIN,SOUTHEASTERN MONTANA1

ABSTRACT: Ground water, of relatively good quality, occurs though-out southeastern Montana's Tongue River basin and can be procured cheaply and easily. The widespread occurrence of springs and the de velopment of shallow aquifers enables settlement to occur away from perennial streams and allows for extensive grazing of the range. Ground water m the Tongue River basin occurs in five aquifers ranging from shallow alluvium to the extremely deep Madison Group. Coal beds of the Fort Union Formation contain significant quantities of good quality ground water. Extensive strip mining of these coal beds lowers the water level of nearby wells and causes springs to dry up. There are over 1,700 permits for ground water appropriation in the Tongue River Valley. Development of ground water has been especially important to ranchers in that it enabled most of the basin to be used for grazing. Ground water also provides an important source of water for domestic use. Ground water quality varies considerably in the basin depending upon locality and aquifer. Generally, ground water is characterized by high sodium, sulfate, and bicarbonate levels. Strip mining significantly alters ground water quality, primarily by leachates entering from the mine spoil.     

EDWARDS AQUIFER EVALUATION: KINNEY COUNTY,TEXAS1

ABSTRACT: The Edwards Aquifer is one of the most studied and most prolific aquifers in the United States. The aquifer is a heavily fractured and faulted carbonate aquifer with transmissivities in excess of 100 ft²/s. The City of San Antonio relies upon the Edwards Aquifer as its sole source for water. Much work has been done on quantifying recharge to the aquifer and discharge from wells and acquiring aquifer characteristics from pumping tests, specific capacity tests, and geophysical logs. Although the aquifer has been well studied in Bexar County, much less is known about the Edwards Aquifer in Kinney County. This is partly due to the lower population within the county (approximately 3,500 people) relative to the eastern counties (Uvalde, Medina, Bexar, Comal, and Hays) and the great distance of Kinney County from high profile discharge areas such as the City of San Antonio and Comal and San Marcos Springs. Three key products resulted from this study: (1) exploratory well drilling and the largest aquifer test in the county that were conducted to evaluate the well yields within a 10,000 acre study area in which a drawdown of 2.5 ft approximately 1.2 miles away was observed while pumping at approximately 4,600 gpm; (2) a recharge estimate for the Edwards Aquifer within Kinney County of approximately 71,382 ac‐ft/yr; and (3) locating the Brackettville Groundwater Divide from an evaluation of ground water flow direction and hydrograph analysis. These results help evaluate the complex hydraulics occurring within Kinney County and aid in development of ground water modeling that will be used in managing the Edwards Aquifer.     

Thermodynamic Controls on Quality of Water From Underground Coal Mines in Colorado1

ABSTRACT: Water samples collected from 14 underground coal mines in Colorado were analyzed for major dissolved constituents. The data indicate the water quality of 13 of the samples has developed by the interaction of calcite saturated ground water with sodium rich marine shales. Those samples that displayed evidence of being most completely reacted were composed almost entirely of sodium and bicarbonate ions and had a calcium to sodium activity ratio of 0.16, similar to that of seawater. The one sample that was not saturated with respect to calcite was saturated with respect to gypsum. The dissolved solids concentration attainable by dissolution of gypsum is much less than that attainable by the calcite marine shale equilibration, or approximately 2,500 milligrams per liter. By considering the maximum predicted concentrations of dissolved solids in relation to promulgated water quality criteria, it is possible to predict the hazards of reuse of this mine drainage. The primary problems would be damage or destruction of crops if the drainage water was used for irrigation. In addition, some samples contained concentrations of chloride and sulfate in excess of recommended standards for public water supplies.     

RESULTS OF ACIDIZING WATER WELLS IN ARIZONA1

Two wellfields have been developed to provide water for a coal fired electric generating station in Arizona. Wellfield No. 1 penetrates the unconfined Coconino Sandstone aquifer, and wellfield No. 2 penetrates the composite Kaibab Limestone-Coconino Sandstone aquifer where ground water occurs under confined conditions. A well in each wellfield was pumped and water level drawdown data were collected before and after acidizing. The drawdown data at the various pumping rates were analyzed to determine the potential benefits of acidizing production water wells in both wellfields. After acidizing, the specific capacity of the well in wellfield No. 1 was improved about 50 percent at water production rates ranging from about 200 to 500 gallons per minute (gpm) (13 to 32 liters per second (lps)). After acidizing, the specific capacity of the well completed in wellfield No. 2 was improved about 100 percent at pumping rates ranging from about 1,250 to 2,200 gpm (79 to 139 lps). An annual saving of approximately 11 percent in pumping costs can be realized in wellfield No. 2, and savings are approximately four percent in wellfield No. 1. Acidization is beneficial for wells that can produce more than 500 gpm (32 lps), and is of marginal value for those that produce less than that amount.     

Effect of flue gas desulfurization (FGD) by-product on water quality at an underground coal mine

In this paper, a field study was carried out to examine the effect of flue gas desulfurization (FGD) by-product on water quality at an underground coal mine in central-eastern Ohio. Flue gas desulfurizalion by-product was injected into the down-dip portions of the Robert-Dawson mine in an attempt to seal major seeps exiting the mine and to coat exposed pyritic surfaces. Immediately following grout injection, significant increases in acidity, iron, aluminum, sulfur, and calcium were observed at most surface and ground water locations near where grouting was carried out. Following this initial flush of elements, concentrations of most constituents have decreased to near pre-grouting levels. Data from the site and geochemical modeling suggest that an increase in water level or rerouting of drainage flow resulted in the dissolution of iron and aluminum sulfate salts and ferrihydrite. Dissolution of the FGD grout material resulted in increases in calcium and sulfate concentrations in the drainage waters. Water within the mine voids was saturated with respect to calcium sulfate and gypsum immediately following grout injection. Based on an analysis of core samples obtained from the site, acid mine drainage (AMD) was in contact with at least some portions of the grout and this resulted in grout weathering. Subsequent transport of calcium and sulfate to the underclay, perhaps by fracture flow, has resulted in the deposition of gypsum and calcium sulfate solids.     

DEVELOPMENT OF A FRACTURED MEDIUM FLOW MODEL FOR A WASTE SITE1

ABSTRACT: A three‐dimensional fractured medium flow model was developed for the Bear Creek Valley (BCV) S‐3 site of the Oak Ridge Reservation (ORR) using SWIFT III. The numerical modeling for this site focused on a conceptual model established through the analysis of heterogeneous geologic units and matrix fracture properties of the subsurface in the BCV area. The SWIFT III modeling analysis was based on the previous modeling studies that used MODFLOW and MODPATH. A rigorous calibration was obtained first by comparing simulated results with the existing data on ground water levels and then by comparing pumping test results with the simulated ground water levels. A satisfactory agreement between observed and simulated results was obtained. The calibrated model was used to determine sustained yield from a ground water interceptor trench. Different withdrawal rates were used to simulate the performance of the trench for the sustained withdrawal of ground water.     

CONJUNCTIVE SURFACE AND GROUND WATER MANAGEMENT IN THE JAKARTA REGION,INDONESIA1

ABSTRACT: This study investigates the degree of economic inefficiency of the current institutional arrangements for surface and ground water management in meeting urban water demand in the Jakarta region. A numerical model of integrated surface and ground water management is developed using GAMS (General Algebraic Modelling System) software. The model maximizes the net present value of social benefits from piped water and ground water consumption across all users over time from 1999 to 2025. Four policy scenarios are examined: the status quo, the social planner's solution, and two ground water pumping quota scenarios: an aggregate ground water pumping quota and a partial quota applied to commercial and industrial users. Three variations in each policy scenario are considered: investment in water infrastructure of the Jakarta water enterprise (PAM Jaya), water demand growth, and discount rates. The status quo, depending on the investment option, the growth of water demand, and the discount rate, results in a 7.4 to 47.8 percent loss in economic efficiency relative to the social planner's solution. The partial quota is the most feasible, applicable, and manageable scenario. The optimal investment option could increase the volume of piped water supply and reduce the cost of water production. The volume of water delivery could increase by up to 156 percent, but it implies only a 35 percent increase in the surface raw water demands above the current level. However, it does not significantly reduce cumulative ground water extraction over the time period considered.     

ESTIMATING TRANSMISSIVITY AND HYDRAULIC CONDUCTIVITY OF CHICOT AQUIFER FROM SPECIFIC CAPACITY DATA1

ABSTRACT: Specific capacity data obtained from Well Construction reports which are available from USGS offices, can provide useful estimates of tranamissivity (T), and hydraulic conductivity (K), of an aquifer. The Chicot Aquifer in Louisiana is one of the largest sources of fresh ground water in North America. Hydrologic data collected for the Chicot Aquifer indicate that specific capacity tests can be used in estimating local and regional values for T and K, if the Cooper-Jacob equation for transient flow is used with proper corrections for well loss and partial penetration. Where full scale pumping test data are scarce, specific capacity test data that are adequately distributed spatially can be used to map changes in T and K values and can be summarized statistically to indicate applicable regional values. A computer program called “TGUESS” which is available from International Ground Water Modeling Center, Holcomb Research Institute, was used in this study. The contour maps for T and K values are prepared for different well depth intervals to avoid wide variation of values.     

A COMPARISON OF MODELS PREDICTING GROUND WATER LEVELS ON HILLSIDE SLOPES1

ABSTRACT: A comparative study of ground water level predictions on hillside slopes using two models is presented. The models are a simplified mass balance model that has components for evapotran-spiration, recharge, and drainage; and a two-dimensional finite difference model that employs kriging to estimate soil parameters and accounts for non-uniform thickness of the soil layer. These models are representative of a wide range of modeling capabilities and are used to illustrate the sensitivity of ground water level predictions to the sophistication of the modeling techniques. The drainage and recharge components of the two models are evaluated and the importance of unsaturated flow in recharge computations is underscored. Piezometric observations in a small drainage depression on the slope of Kennel Creek Valley in Tongass National Forest, Alaska, were used to evaluate the two models. The results show that, although the predictions differ from the field observations, the simple physically-based mass balance model predicts the ground water levels as well as the two-dimensional model. It is suggested that caution should be exercised in using complex models to validate simpler models.     

Longevity of acid discharges from underground mines located above the regional water table

The duration of acid mine drainage flowing out of underground mines is important in the design of watershed restoration and abandoned mine land reclamation projects. Past studies have reported that acid water flows from underground mines for hundreds of years with little change, while others state that poor drainage quality may last only 20 to 40 years. More than 150 above-drainage (those not flooded after abandonment) underground mine discharges from Pittsburgh and Upper Freeport coal seams were located and sampled during 1968 in northern West Virginia, and we revisited 44 of those sites in 1999-2000 and measured water flow, pH, acidity, Fe, sulfate, and conductivity. We found no significant difference in flows between 1968 and 1999-2000. Therefore, we felt the water quality data could be compared and the data represented real changes in pollutant concentrations. There were significant water quality differences between year and coal seam, but no effect of disturbance. While pH was not significantly improved, average total acidity declined 79% between 1968 and 1999-2000 in Pittsburgh mines (from 66.8 to 14 mmol H+ L(-1)) and 56% in Upper Freeport mines (from 23.8 to 10.4 mmol H+ L(-1)). Iron decreased an average of about 80% across all sites (from an average of 400 to 72 mg L(-1)), while sulfate decreased between 50 and 75%. Pittsburgh seam discharge water was much worse in 1968 than Upper Freeport seam water. Twenty of our 44 sites had water quality information in 1980, which served as a midpoint to assess the slope of the decline in acidity and metal concentrations. Five of 20 sites (25%) showed an apparent exponential rate of decline in acidity and iron, while 10 of 20 sites (50%) showed a more linear decline. Drainage from five Upper Freeport sites increased in acidity and iron. While it is clear that surface mines and below-drainage underground mines improve in discharge quality relatively rapidly (20-40 years), above-drainage underground mines are not as easily predicted. In total, the drainage from 34 out of 44 (77%) above-drainage underground mines showed significant improvement in acidity over time, some exponentially and some linearly. Ten discharges showed no improvement and three of these got much worse.     

RECIRCULATING WELLS: GROUND WATER REMEDIATION AND PROTECTION OF SURFACE WATER RESOURCES1

ABSTRACT: Several chlorinated solvent plumes threaten the sole‐source aquifer underlying the Massachusetts Military Reservation at the western end of Cape Cod. Sensitive surface water features including ponds, cranberry bogs, and coastal wetlands are hydraulically connected to the aquifer. For one of the plumes (CS‐10 the original remedy of 120 extraction and reinjection wells has the potential for significant disruption of surface water hydrology, through the localized drawdown and mounding of the water table. Recirculating wells with in‐well air stripping offer a cost‐effective alternative to conventional pump‐and‐treat technology that does not adversely affect the configuration of the water table. Pilot testing of a two well system, pumping 300 gpm, showed a capture radius of > 200 feet per well, in‐well trichloroethylene (TCE) removal efficiencies of 92 to 98 percent per recirculation cycle, an average of three recirculation cycles within the capture zone, and no measurable effect on water table elevations at any point within the recirculation/treatment zone. During 120 days of operation, the mean concentration of TCE in the treatment zone was reduced by 83 percent, from 1,111 μg/l to 184 μg/l. Full‐scale design projections indicate that 60 wells at an average spacing of 160 feet, having an aggregate recirculation 11 MGD, can contain the CS‐b plume without ground water extraction or adverse hydraulic effects on surface water resources. The estimated capital costs for such a system are about $7 million, and annual operations‐and‐maintenance costs should be about $1.4 million, 40 percent of those associated with a pump and treat system over a 20‐year period.     

DRAINAGE QUALITY AT DEEP COAL MINE SITES1

ABSTRACT: Samples were collected from the drainages of inactive deep coal mine sites located in eight states. Drainage quality was found to be highly variable, with a majority of sites exceeding federal effluent quality guidelines. Concentrations of trace metals including cadmium, mercury, zinc, and nickel were low. The presence of overburden calcareous material was shown to affect drainage quality. A consistent pattern of pH-acidity response was found to exist for the mine sites monitored. An empirical formula was developed to characterize this response.     

Drainage and utilization of Chinese coal mine methane with a coal–methane co-exploitation model: Analysis and projections

Coal mine methane (CMM) released during coal mining attributes to unsafe working conditions and environmental impact. China, the largest coal producer in the world, is facing problems associated with CMM such as fatal gas accidents and intense greenhouse gas emission along the path to deep mining. Complicated geological conditions featured with low permeability, high gas pressure and gas content of Chinese coal seams have been hindering the coal extraction. To solve these problems, a model of coal–methane co-exploitation is proposed. This model realizes the extraction of two resources with safety ensured and has been successfully applied in Huainan coalfield, China. The current situation of drainage and utilization of CMM in China are diagnosed. Connections between the coal production, methane emissions, drainage and utilization are analyzed. Estimations of future coal production, methane emissions, drainage and utilization are made in a co-exploitation based scenario. The emitted, drained and utilized CMM are projected to reach 26.6, 13.3 and 9.3 billion m³, respectively by adapting the assumption of 3800 million metric tons of coal production by 2020.     

ESTABLISHING PRIORITIES IN MINE DRAINAGE REDUCTION A COST-EFFECTIVENESS APPROACH1

ABSTRACT Twenty-seven watersheds in the Susquehanna River Basin are severely degraded by acid mine drainage pollution. Approximately 620 miles of significant tributaries as well as 230 miles of principal rivers are either sterile or intermittently degraded by acid slugs. As a result of the acid discharges, many uses of the streams, such as water supply and recreation, are precluded. In the past, acid mine drainage abatement programs did not look beyond the immediate problem area. No considerations were given to the blending effect of natural alkalinity in other streams. Since the abatement of acid mine drainage pollution is extremely costly, a method of minimizing these costs was needed. The systematic, cost-effectiveness approach, discussed in this paper presents such a method. This system allows the water resources planners to control the allocation of funds for maximizing the abatement of acid mine drainage.     

Efficient and Practical Approaches to Ground‐Water Right Transfers Under the Prior Appropriation Doctrine and the Snake River Example1

Abstract: Water right transfers are one of the basic means of implementing changes in water use in the highly appropriated water resource systems of the western United States. Many of these systems are governed by the Prior Appropriation Doctrine, which was not originally intended for application to ground‐water pumping and the conjunctive management of ground water and surface water, and thus creates an administrative challenge. That challenge results from the fact that ground‐water pumping can affect all interconnected surface‐water bodies and the effects may be immeasurably small relative to surface water discharge and greatly attenuated in time. Although we may have the ability to calculate the effects of ground‐water pumping and transfers of pumping location on surface‐water bodies, mitigating for all the impacts of each individual transfer is sufficiently inefficient that it impedes the transfer process, frustrates water users, and consequently inhibits economic development. A more holistic approach to ground‐water right transfers, such as a ground‐water accounting or banking scheme, may adequately control transfer third‐party effects while reducing mitigation requirements on individual transfers. Acceptance of an accounting scheme can accelerate the transfer process, and possibly reduce the administrative burden.