Dynamic simulation of a decentralized polygeneration plant providing SNG,steam and power

The behaviour of a decentralized polygeneration plant providing synthetic natural gas (SNG), steam and electrical power is simulated in three scenarios in this study. The plant size is based on an assumed capacity of decentralized polygeneration plants processing 1070 m³ h^?1 (STP) of syngas. 396 m³ h^?1 (STP) of raw SNG, 0.4 t h^?1 of steam at 5 bar and 670 kW of electrical power can be generated by the plant at the reference scenario. Methanation reactor and steam generator are modelled in detail. Further results indicate that such a polygeneration plant can provide positive and negative operation reserves for the electricity network to the extent of 100% of the reference power output, while the amount of generated steam varies by less than 40%. At the same time, the generated SNG quality keeps constant. Lower variations in the amount of generated steam are applicable when reducing the operation reserve capacity.     

Analyzing the hydrologic effects of region-wide land and water development interventions: a case study of the Upper Blue Nile basin

In the drylands of the Upper Blue Nile basin, high climate variability and land degradation are rampant. To enhance adaptive capacity in the region, various soil and water conservation interventions have been implemented. Moreover, water resources development schemes such as the Grand Ethiopian Renaissance Dam should be implemented by 2025. We modeled the effects of these interventions on surface runoff in the basin for both current and future (2025) basin conditions, using the runoff coefficient method in a spatially explicit approach. Under current conditions, we observed high spatial variability of mean annual runoff. The northeastern Blue Nile-1 sub-basin produces the highest mean annual runoff (391 mm or 10 × 10⁹ m³), whereas the northwestern Blue Nile-2 sub-basin produces the lowest mean annual runoff (178 mm or 0.2 × 10⁹ m³). The basin generates a total annual runoff volume of 47.7 × 10⁹ m³, of which about 54 % comes from cultivated land. The strong association between land use and topography masked the direct effect of rainfall on runoff. By 2025, total annual runoff yield could decrease by up to 38 % if appropriate basin-wide soil and water conservation interventions and the Grand Ethiopian Renaissance Dam are implemented. However, the full effects of most physical structures will only last for 1 or 2 years without regular maintenance. The improved understanding of the dynamics of the Upper Blue Nile basin’s hydrology provided by the present study will help planners to design appropriate management scenarios. Developing the basin’s database remains important for a holistic understanding of the impacts of future development interventions.     

Spatio-temporal variation of macrobenthic communities in the mangrove-fringed Segara Anakan lagoon, Indonesia, affected by anthropogenic activities

The benthic macrofauna of the Segara Anakan lagoon, Java, Indonesia and its fringing mangroves were investigated between May 2004 and August 2006. This lagoon has been affected by various human activities for decades, in particular fishing, effluents from agriculture and industry, and illegal deforestation. In total, 163 taxa were identified, including 127 species occurring in the mangrove forest and 59 species in the subtidal. Mean density of macrobenthos was 2.5-fold higher in the central (881.8 ± 1,151.3 ind. m^?2) than in the eastern mangrove site (356.3 ± 218.8 ind. m^?2). Community structures differed significantly between these sites and showed a serial shift during the investigation period. Gastropods dominated the community in the central mangrove location, whereas sipunculids, polychaetes and gastropods had similar densities in the eastern site. Differences in community composition were best explained by three sediment properties: pore water salinity, δ¹³C_org, and C_org/N. It is suggested that small-scale heterogeneity of food availability and quality is a main factor determining the small-scale variability of the community composition. Compared to other Indo-West Pacific mangroves, species richness and densities are high. However, the dominance of specific taxa, especially of opportunistic species and the comparably low species richness in the subtidal of the lagoon may be attributed to the high sediment input by rivers in the central part and to the large-scale cutting of mangroves. Continuous tree logging will probably lead to a further spread of two fast growing understorey plants and thus to an increase of uniform swamp sites and a decrease of micro-habitats for benthic macrofauna. To our knowledge, this is the first detailed study on the spatio-temporal variation of benthic macrofauna in mangroves of Indonesia.     

Cleaning the river Damodar (India): impact of COVID-19 lockdown on water quality and future rejuvenation strategies

Globally, it is established that the partial lockdown system assists to improve the health of the total environment due to inadequate anthropogenic actions in different economic sectors. The ample research on fitness of environment has been proved that the strict imposition of lockdown was the blessings of environment. The river Damodar has historical significance and lifeline for huge population of Jharkhand and West Bengal state of India but in the recent years the water quality has been deteriorated due to untreated industrial effluents and urban sewage. The main objective of this study is to examine the water quality of river Damodar during and prelockdown phase for domestic use and restoration of river ecosystem. A total of eleven (11) effluent discharge sites were selected in prelockdown and during lockdown phase. A new approach of water quality assessment, i.e., water pollution index (WPI) has been applied in this study. WPI is weightage free, unbiased method to analysis of water quality. The result shows that the physical, chemical and heavy elements were found beyond the standard limit in prelockdown period. The cation and anion were arranged in an order of Na²⁺ ?>?K⁺ ?>?Ca²⁺ ?>?Mg²⁺ and Cl^??>?So₄^??>?No₃^??>?F^? in both the sessions. WPI of prelockdown showed that about 100% water samples are of highly polluted. WPI of lockdown period showed that around 90.90% samples improved to ‘good quality’ and 9.10% of samples are of ‘moderately polluted.’ Hypothesis testing by ‘t’ test proved that there was a significant difference (ρ?=?0.05%) in values of each parameter between two periods. Null hypothesis was rejected and indicated the improvement of river water quality statistically. Spatial mapping using Arc GIS 10.4 interpolation (IDW) helps to understand spatial intensity of pollution load in two periods. This research study should be helpful for further management and spatial diagnosis of water resource of river Damodar.

     

Greenhouse gases emissions from a closed old landfill cultivated with biomass crops

Closed landfills need after-closure rehabilitation. The chosen option should ensure greenhouse gases release, from the landfill, is not promoted once settled. The objective of this study was to estimate and confront, during different seasons, CH₄, CO₂ and N₂O emissions under three vegetation covers in a closed landfill in Buenos Aires, Argentina. CH₄ (methane), CO₂ (carbon dioxide) and N₂O (nitrous oxide) emissions from landfill’s technosol under spontaneous vegetation (control), Pennisetum purpureum and Miscanthus giganteus (biomass crops), were quantified with non-steady-state non-flow-through chambers, in July 2014 and from February to July 2015. A linear regression analysis was performed to relate the variables “flux of a gas” and “concentration of that gas” from the 3 treatments and 6 dates, separating the 5 sampling times. A high correlation between concentrations and fluxes of CO₂ and N₂O was found, but no correlation was established for CH₄. Mean emissions (2014–2015) varied from: ?2.3 to 639.41 mgCH₄ m^?2 day^?1, 3884 to 46,365 mgCO₂ m^?2 day^?1 and 0.40 to 14.59 mgN₂O m^?2 day^?1. Vegetation covers had no significant effect on CH₄ and N₂O concentration in time, but they had on CO₂ concentration. Season of the year had a significant effect on concentration of the three gases. This is the first study on CH₄, CO₂ and N₂O emissions from a landfill closed 27 years ago covered with biomass crops.     

Impact of Massanjore Dam on hydro-geomorphological modification of Mayurakshi River,Eastern India

Massanjore reservoir (area ~67 km²) located 84 km downstream from the most distant upstream source capacitates 620,000,000 m³ of water, and regulated flow characters are highly responsible for dam downstream alteration of hydrological, sedimentological and geomorphological characteristics of Mayurakshi River. In dam after condition, monsoon water level (mean water level during monsoon months) and pre-monsoon water level (mean water level during pre-monsoon months, i.e., March–May) have attenuated about 0.56 and 0.32 m, respectively. Maximum duration of high flow period during monsoon has reduced up to 16.5 %; coefficient of variation of diurnal fluctuation of water level during monsoon has increased from 31 to 47 %. Suspended sediment load in Mayurakshi River is reduced to 34 % in dam after period as recorded at Narayanpur gauge station. Average suspended sediment load has decreased even after Tilpara barrage construction from 4.960 to 4.350 mg/L. Average suspended sediment load is 7.875 mg/L in the sites of dam upstream course, and this average is only 4.46 mg/L in different sites of dam downstream course. Volume of discharge has decreased up to 11.3 % during monsoon time in dam after condition. Such reduction in discharge volume in turn has reduced about 24.6 % bed load-carrying capacity. As a result, huge deposition within channel invigorated channel bed aggradations (average 73.6 cm up to Saspara, site 14 at Fig. 1) in dam after condition. Narrowing of active channel, coarsening of channel bed materials, lowering of lateral stability, accelerating rise of braiding index, mixed response of the channel adjustment of the tributaries to local scale positive or negative base level change due to river bed aggradations and degradation, etc. signify the morphological alteration of dam downstream course.

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Fig. 1 Mayurakshi River basin indicating Massanjore Dam, Tilpara barrage and sample working sites

     

Estimating the effect of nitrogen fertilizer on the greenhouse gas balance of soils in Wales under current and future climate

The Welsh Government is committed to reduce greenhouse gas (GHG) emissions from agricultural systems and combat the effects of future climate change. In this study, the ECOSSE model was applied spatially to estimate GHG and soil organic carbon (SOC) fluxes from three major land uses (grass, arable and forest) in Wales. The aims of the simulations were: (1) to estimate the annual net GHG balance for Wales; (2) to investigate the efficiency of the reduced nitrogen (N) fertilizer goal of the sustainable land management scheme (Glastir), through which the Welsh Government offers financial support to farmers and land managers on GHG flux reduction; and (3) to investigate the effects of future climate change on the emissions of GHG and plant net primary production (NPP). Three climate scenarios were studied: baseline (1961–1990) and low and high emission climate scenarios (2015–2050). Results reveal that grassland and cropland are the major nitrous oxide (N₂O) emitters and consequently emit more GHG to the atmosphere than forests. The overall average simulated annual net GHG balance for Wales under baseline climate (1961–1990) is equivalent to 0.2 t CO₂e ha^?1 y^?1 which gives an estimate of total annual net flux for Wales of 0.34 Mt CO₂e y^?1. Reducing N fertilizer by 20 and 40 % could reduce annual net GHG fluxes by 7 and 25 %, respectively. If the current N fertilizer application rate continues, predicted climate change by the year 2050 would not significantly affect GHG emissions or NPP from soils in Wales.     

Towards green membranes: preparation of cellulose acetate ultrafiltration membranes using methyl lactate as a biosolvent

Ultrafiltration membranes were prepared using cellulose acetate (CA) as a polymer, LiCl and CaCl₂ as porogens and methyl-(S)-lactate as a solvent. CA, methyl lactate and the porogens used in this work are obtained from renewable resources; they are biodegradable, non-toxic and non-volatile organic compounds. Flat sheet ultrafiltration membranes were prepared by the phase inversion technique. A molecular weight cut-off between 15 and 35 kDa (polyethylene glycol) and pure water permeability between 13 and 177 litres h^? 1m^? 2 bar^? 1 were obtained. These parameters are in the ideal range for water treatment industry. Improvement of pollutant degree and ecotoxicity of the process was evaluated by ‘green’ metrics by the P (pollutants, persistent and bioaccumulative) and E (ecotoxicity) parameters. Both of these variables were recorded as zero using our method. This study represents a step ahead towards the production of ultrafiltration polymeric membranes by a ‘greener’ process than current methods.     

Which crop production system is more efficient in energy use: wheat or barley?

Efficient use of energy helps to achieve increased production and productivity and contributes to the economy, profitability, and competitiveness of agricultural sustainability of rural communities. Evaluation of wheat and barley production systems in view of energy balance was conducted in Khorasan Razavi Province, Iran. Data were collected by using a face-to-face questionnaire from wheat and barley fields in 2011. Results revealed that total energy input for wheat was 51,040 MJ ha^?1 and for barley 44,866; in wheat and barley systems, renewable energy was consumed by 25.43 and 23.53 %, while non-renewable energy was consumed by 74.57 and 76.47 %, respectively. Energy use efficiency, energy productivity, and net energy were 1.7 kg MJ^?1, 0.088 kg MJ^?1, and 35,987 MJ ha^?1 in wheat system and 1.83 kg MJ^?1, 0.092 kg MJ^?1, and 33,833 MJ ha^?1 in barley system, respectively. Energy intensiveness in wheat fields (61.84 MJ $^?1) was higher than in barley fields (58.71 MJ $^?1). Also, benefit-to-cost ratio in wheat system (1.59) was higher than in barley system (1.35). In general, production in barley fields was more sustainable than wheat production because, in view of ecological indices such as amount of energy use and renewable energy consumption, it was more environment-friendly production.     

Long-term simulation of effects of energy crop cultivation on nitrogen leaching and surface water quality in Saxony/Germany

The production of energy crops in Germany is a growing agronomic sector and is expected to occupy a substantial share of farmland in the near future. At the same time, there are concerns that energy crops might cause increased nitrogen pollution of soil water, surface water and groundwater. Therefore, the Federal State of Saxony, Germany, funded a study on potential effects of an intensified cultivation of energy crops. In frame of this study, we used the Web GIS-based model STOFFBILANZ to simulate N leaching from the rooting zone and N loads of surface water for a reference scenario and an energy crop scenario. For the reference scenario, we used data representing the crop cultivation for the year 2005 at municipality level. We found that the total loads for N leaching from the rooting zone of cropland are highest for the loess region (8,067 t year^?1), followed by mountainous region (6,797 t year^?1) and lowland (5,443 t year^?1). However, highest N fluxes in the leachate from rooting zones have been simulated for lowland (40.6 kg ha^?1 year^?1) and mountainous region (37.1 kg ha^?1 year^?1), while nitrate concentrations of leachate were highest for the lowland (101.8 mg l^?1). In terms of diffuse N input into surface water, the mountainous region is the most important source area (total N load 6,380 t year^?1, flux 34.6 kg ha^?1 year^?1). Retention by in-stream processes accounts for 15 % (3,784 t year^?1) of the total N load leaving the study area (25,136 t year^?1). In the 2020 energy crop scenario, shares of rape and silage maize (id., ensiled corn) were limited for each municipality to a maximum of 25 and 33 %, respectively. The conversion of grasslands to crop farming was not allowed. Under these conditions, we found slight to substantial reductions of nitrogen loads for leachate from the rooting zone and for surface waters. The simulated reduction depends strongly on local conditions. Only small reductions (ca. 4–8 %) were found for the lowlands and mountainous regions of Saxony, while reductions for the loess region were substantial (ca. 22 %). A major outcome of our study is that the cultivation of energy crops might reduce N loss if certain preconditions are assumed, for example, without conversion of grasslands to crop farming. However, effects might vary widely depending on local conditions.     

Direct N2O emission from agricultural soils in Poland between 1960 and 2009

Nitrogen fertilization (N) is commonly known as a main source of direct nitrous oxide (N₂O) emission from agricultural soils. An area of 38 % of the total land surface of Poland was covered by agricultural soils in 2009. In this paper, we aimed at analyzing data regarding the land exploitation for 13 selected subareas of Poland between 1960 and 2009. Seven out of the 13 subareas studied are located in the West (area A), and six subareas are located in southeast of Poland (area B). The total area covered by large farms (>20 ha) differed largely, between area A (10.6 %) and area B (0.9 %) in 2009. Both areas varied in terms of the amount of fertilizers used annually, average crop yield and crop structure. Average direct emissions of N₂O from agricultural soils were 1.66 ± 0.09 kg N₂O–N ha^?1 a^?1 for area A, 1.39 ± 0.07 kg N₂O–N ha^?1 a^?1 for area B and 1.46 ± 0.07 kg N₂O–N ha^?1 a^?1 for the whole country between 1960 and 2009.     

Factors influencing farmers’ decisions on nitrogen fertilizer application in the Liangzihu Lake basin,Central China

Overuse of nitrogen (N) fertilizers in agriculture activities has caused severe water pollution in China. The lack of data at producer level hampers decision makers in the development and implementation of efficient policies to curb excessive N-fertilizer use. In a survey of 300 farm households in the Liangzihu Lake basin, we identified factors associated with farmers’ decisions on N-fertilizer use and application rate. Household survey and multiple linear regression models indicate that the average application rate in the study region is 229 kg N ha^?1, which exceeds the recommended rate for maximum profit for cereal crops (maize, wheat, and rice) in China of 150–180 kg N ha^?1. High N-application rates are associated with low farmland productivity (coefficient = ?15.66, p = 0.02), a high share of off-farm income (coefficient = 27.14, p = 0.003), and a low education level of the household head (coefficient = ?10.83, p = 0.039). Neither physical infrastructure nor access to input markets appears to be related to N-application rates. It may be concluded that excessive use of N in agriculture of Central China is mainly a problem of insufficient awareness and high share of off-farm income.     

Vegetation dynamics and climate change on the Loess Plateau,China: 1982–2011

Monitoring the dynamics of vegetation growth and its response to climate change is important to understand the mechanisms underlying ecosystem behaviors. This study investigated the relationship between vegetation growth and climate change during the growing seasons on the Loess Plateau in China by analyzing the normalized difference vegetation index (NDVI) derived from the Land Long Term Data Record dataset from 1982 to 2011. Results showed that growing-season NDVI had increased at an annual rate of 0.0028, particularly in the semi-arid and semi-humid regions. By contrast, the NDVI first increased from 1982 to 1994 (0.0013 year^?1, P < 0.05) and then decreased from 1994 to 2011 (0.0016 year^?1, P < 0.05) in the arid region. Temperature had a positive effect on NDVI in most periods within and across seasons in the semi-humid region but had no significant effect in the arid region. Precipitation had a positive effect on NDVI in the arid region in summer and in the semi-arid region in autumn. Summer precipitation was important for autumn vegetation growth in the arid region, whereas summer temperature increased autumn vegetation growth in the semi-arid and semi-humid regions. Further analyses supported the lag-time effects of climate change on vegetation growth on the Loess Plateau. Precipitation shifts had 15- to 18-month time lag effects on vegetation growth in the three climate regions. Vegetation NDVI had a 17-month lag response to temperature in the semi-arid region. Human activities should not be neglected in analyzing the relationship between vegetation growth and climate change on the Loess Plateau.     

The impact of land use on riparian soil dissolved organic matter and on streamwater quality on Chongming Island,China

Riparian wetland controls the transfer of terrestrial dissolved organic matter (DOM) to surface water bodies. However, the effects of land use on riparian soil DOM quality and its contribution to aquatic environment are largely unknown. In this study, the amount and composition of water-extracted soil organic matter (WSOM) in riparian wetlands were determined to evaluate the effect of land uses on spatial patterns of WSOM and streamwater quality on Chongming Island, China. The fluorescent properties of WSOM and fluvial DOM were analyzed using EEM spectra-combining PARAFAC model and accurate MS and MS/MS identification. Our findings showed no differences in the riparian WSOC contents between land use types (agricultural land, natural wetland, commercial land and industrial land). However, the fluorescent WSOM and its humic-like (Comp.1 and Comp.2) and microbial degradation (Comp.4) components significantly varied under different land uses (P < 0.05). Overall, the fluorescent WSOM quantities and its components (Comp.1, Comp.2 and Comp.4) were present at markedly lower concentrations for agricultural land use relative to the other three land uses. The same distribution pattern was observed for carbonyl compounds and fatty acids in the riparian WSOM molecules (P < 0.05), but the distribution patterns of the lipids were different between the four land uses (P < 0.05). Industrial land could result in the input of more organic matter into the riparian wetland. Our results showed that fluvial Comp.1 and Comp.2 were significantly correlated with WSOM Comp.2 and WSOM Comp.4 (P < 0.05). We also observed that the fluvial trophic status was significantly higher when the fluvial DOM components increased (P < 0.05). These results indicated that land uses can alter the composition of riparian WSOM, reshape fluvial DOM compositions and significantly affect fluvial water quality.     

Greenhouse gas emissions from a semi-arid tropical reservoir in northeastern Brazil

We estimated carbon dioxide (CO₂) and methane (CH₄) emissions by diffusion, ebullition, and degassing in turbines from a semi-arid hydropower reservoir in northeastern Brazil. Sampling sites were allocated within the littoral and deeper waters of one embayment, the main-stream, and at turbines. Annual carbon emissions were estimated at 2.3?×?10⁵?±?7.45?×?10⁴ t C year^?1, or in CO₂-equivalents (CO₂-eq) at 1.33?×?10⁶?±?4.5?×?10⁵ t CO₂-eq year^?1. Diffusion across the water surface was the main pathway accounting for 96% of total carbon emissions. Ebullition was limited to littoral areas. A slight accumulation of CO₂, but not of CH₄, in bottom waters close to the turbines inlet led to degassing emissions about 8?×?10³ t C year^?1. Emissions in littoral areas were higher than in main-stream and contribute to 40% of the total carbon. Carbon (C) emissions per electricity generated, at 60% of installed capacity, is 0.05 t C-CO₂-eq MWh^?1. The ratio increases to 0.09 t C-CO₂ MWh^?1, equating 80% of the emissions from natural gas and 40% of diesel or coal power plants. Retention time and benthic metabolism were identified as main drivers for carbon emissions in littoral areas, while water column mixing and rapid water flow are important factors preventing CH₄ accumulation and loss by degassing. Our results indicate that Itaparica Reservoir, located in the semi-arid region of Northeastern Brazil, acts as a source of GHGs. Management measurements are needed to prevent emissions to raise in the future.     

Experimental investigation of energy properties for Stigonematales sp. microalgae as potential biofuel feedstock

Microalgae has been considered potential biofuel source from the last decade owing to its versatile perspectives such as excellent capability of CO₂ capture and sequestration, water treatment, prolific growth rate and enormous energy content. Thus, energy research on microalgae is being harnessed to mitigate CO₂ and meet future energy demands. This study investigated the bioenergy potential of native blue-green microalgae consortium as initial energy research on microalgae in Brunei Darussalam. The local species of microalgae were assembled from rainwater drains, the species were identified as Stigonematales sp. and physical properties were characterised. Sundried biomass with moisture content ranging from 6.5% to 7.37% was measured to be used to determine the net and gross calorific value and they were 7.98 MJ/kg-8.57 MJ/kg and 8.70 MJ/kg-9.45 MJ/kg, respectively. Besides that, the hydrogen content, ash content, volatile matter, and bulk density were also experimented and they were 2.56%-3.15%, 43.6%-36.71%, 57–38%-63.29% and 661.2 kg/m³-673.07 kg/m³, respectively. Apart from experimental values, other physical bioenergy parameters were simulated and they were biomass characteristic index 61,822.29 kg/m³-62,341.3 kg/m³, energy density 5.27 GJ/m³-5.76G J/m³ and fuel value index 86.19–88.54. With these experimental results, microalgae manifested itself a potential source of biofuel feedstock for heat and electricity generation, a key tool to bring down the escalated atmospheric greenhouse gases and an alternation for fossil fuel.     

Viability of solar photovoltaics as an electricity generation source for Jordan

Viability of solar photovoltaics as an electricity generation source for Jordan was assessed utilising a proposed 5 MW grid‐connected solar photovoltaic power plant. Long‐term (1994–2003) monthly average daily global solar radiation and sunshine duration data for 24 locations – distributed all over the country – were studied and analysed to assess the distribution of radiation and sunshine duration over Jordan, and formed an input to the RetScreen Software for evaluation and analysis of the proposed plant's electricity production and economic feasibility. It was found that depending on the geographical location, the global solar radiation on horizontal surface varied between 1.51 and 2.46 MWh/m²/year with an overall mean value of 2.01 MWh/m²/year for Jordan. The sunshine duration was found to vary, according to the location, between 8.47 and 9.68 hours/day, with a mean value of 9.07 hours/day and about 3311 sunshine hours annually for Jordan. The annual electricity production of the proposed plant varied depending on the location between 6.886 and 11.919 GWh/year, with a mean value of 9.46 GWh/year. The specific yield varied between 340.9 and 196.9 kWh/m², while the mean value was 270.59 kWh/m². Analysis of the annual electricity production of the plant, the specific yield, besides the economic indicators, i.e. internal rate of return, simple payback period, years to positive cash flow, net present value, annual life cycle saving, benefit/cost ratio, and cost of energy – for all sites – showed that Tafila and Karak are the most suitable sites for the solar photovoltaic power plant's development and Wadi Yabis is the worst. The results also showed that an average of 7414.9 tons of greenhouse gases can be avoided annually utilising the proposed plant for electricity generation at any part of Jordan.     

Integrated hydrologic–economic decision support system for groundwater use confronting climate change uncertainties in the Tunuyán River basin,Argentina

This study presents an integrated hydrologic–economic model as decision support system for groundwater use and incorporates uncertainties of climate change. The model was developed with the Vensim software (Ventana Systems) for system dynamic simulations. The software permitted the integration of economic variables along with hydrologic variables, in a unified format with the aim of evaluating the economic impacts of climate change on arid environments. To test the model, we applied it in one of the upper Tunuyán River sub-basin, located in the Mendoza Province (Argentina), where irrigation comes from groundwater. The model defines the best mix of crops and the total land use required to maximize the total river sub-basin monetary income, considering as a limit the amount of water that does not exceed the natural annual aquifer recharge. To estimate the impacts of climatic changes, four scenarios were compared: the business as usual (with the number of existing wells) in a dry year with a temperature increase of 4 °C; the business as usual in a wet year with an increase in temperature of 1.1 °C; an efficient use of wells in a dry year and a temperature increase of 4 °C and an efficient use of wells in a wet year with a temperature increase of 1.1 °C. Outputs calculated by the model were: land use per crop, total sub-basin net benefit, total sub-basin water extraction, water extraction limit depending on river discharge and total number of wells required to irrigate the entire area. Preliminary results showed that the number of existing wells exceeded the optimized number of wells required to sustainably irrigate the entire river sub-basin. Results indicated that in an average river discharge year, if wells were efficiently used, further rural development would be possible, until the limit of 350 million m³ of water extraction per year was reached (650 million m³ for a wet year and 180 million m³ for a dry year). The unified format and the low cost of the software license make the model a useful tool for Water Resources Management Institutions, particularly in developing countries.     

Characterization of Norwegian natural organic matter: Size,diffusion coefficients,and electrophoretic mobilities

Eighteen Norwegian NOM samples were analyzed by AFM, TEM, FCS, and CE. The TEM and AFM gave complementary, but not identical, information regarding the conformation of the NOM. A large majority of the material in all samples appeared as points with a size of approximately 2 nm or less. FCS gave values for diffusion coefficients which were in the range 2.1–3.0 × 10⁻¹⁰ m² s⁻¹. This corresponds to molecular diameters of between 1.6 and 2.0 nm, in reasonable agreement with both TEM and AFM. Electropherograms, using absorbance at 200 nm, were all dissimilar except for the Gjerstad and Hellerudmyra sample pairs, for which no major differences were observed. CE was also carried out using both fluorescence (excitation at 325, 457, and 488 nm) and UV-absorbance (200, 210, 254, and 288 nm) detection on three of the NOM samples. The different modes of detection and wavelengths gave qualitatively similar electropherograms. Calculated EPMs of the major sample components were in the range -2.0 to -5.0 10⁻⁸ m² s⁻¹ V⁻¹.     

Assessment of physicochemical characteristics of Ganga Canal water quality in Uttarakhand

Assessment of physicochemical parameters of Ganga Canal water was carried out during 2012–2013 at Haridwar (Uttarakhand) with two different sites, i.e., Bhimgoda Barrage (site 1—control site) and Bahadrabad (site 2—contaminated site), where canal water flows with loads of pollution from highly commercial and industrial areas. During investigation, maximum turbidity (287.72 ± 56.28 JTU), total solids (1167.60 ± 303.90 mg l^?1), free CO₂ (1.88 ± 0.22 mg l^?1), total hardness (60.14 ± 1.13 mg l^?1), pH (7.1 ± 0.13), nitrate (0.048 ± 0.010), nitrite (0.019 ± 0.001), biochemical oxygen demand (2.866 ± 1.098), chemical oxygen demand (6.8 ± 2.61) and phosphate (0.087 ± 0.015), while minimum velocity (1.71 ± 0.19 ms^?1), transparency (0.12 ± 0.08 m) and dissolved oxygen (7.95 ± 0.44 mg l^?1) were recorded in monsoon season at site 2 in comparison with site 1. The mean values of these parameters were compared with WHO and ISI standards and found significant differences (p < 0.05) in the mean values of turbidity, total solids, pH, dissolved oxygen, free CO₂ and total hardness with sampling sites. The turbidity of both the sites 1 and 2 was recorded above the permissible limit. Turbidity of site 2 is much higher than of site 1, so it is counted as more polluted. The values of the studied parameters were more during monsoon season and summer season at site 2 as compared to site 1. The results indicated that most of the physicochemical parameters from Ganga Canal system were within or at periphery in comparison with permissible limit of ISI and WHO for drinking water and therefore may be suitable for domestic purposes, but it requires perceptible consideration due to intense changes in climate and increase in pollution.