湖泊生态水动力学模拟研究进展

我国湖泊河流众多,随经济发展,水体富营养化加剧。生态水动力学模拟是水质污染控制及水环境规划的有效工具。本文简述了国内外的湖泊生态水动力学模型的研究进展,重点介绍了垂向平均的二维水动力模型及WASP水质模型。提出了以后需要解决的问题及发展的方向。     

基于DEM的分布式水文模型在清江流域的应用

基于清江上游水布垭区域的数字高程模型(DEM)数据，提取出了研究区域水系、勾画了研究区域边界，并计算了研究区域地形指数分布。采用基于数字高程模型(DEM)的分布式水文模型(DDRM)来进行降雨 径流模拟。在Nash Sutcliffe效率系数、洪峰相对误差、径流深相对误差等方面对基于DEM的分布式水文模型和三水源新安江模型进行了比较分析。结果表明：在径流深模拟方面新安江模型略好于DDRM，在洪峰流量及峰现时间方面DDRM略好于新安江模型，模拟的Nash Sutcliffe效率系数两者相当，总体上基于DEM的分布式水文模型和三水源新安江模型模拟效果相当。基于DEM的分布式水文模型与三水源新安江模型相比，其优点是模型结构简单、参数较少、物理过程明确，而且能够模拟流域土壤含水量和径流量的空间分布。     

湖泊流域系统水文水动力联合模拟研究进展综述

湖泊流域水文水动力联合模拟对综合管理湖泊流域水资源具有重要的理论和实践意义。通过水文水动力联合模拟研究进展的综述,可深入了解湖泊流域联合模型发展和演变过程,把握国际研究主流趋势和前沿手段。传统湖泊流域联合模拟方法主要通过流域水文模型结合湖泊水量平衡模型来计算湖泊流域水均衡组分,但水量平衡方法仅是对湖泊过程的一般性描述,难以切实反映水位空间差异显著的湖泊系统有着显著的水动力特性。基于流域水文模型与湖泊水动力模型的联合系统克服了大尺度湖泊流域系统难以切实描述和完整模拟的难点,在湖泊流域系统水资源管理与调控中发挥了重要作用。系统概述了国内外不同尺度湖泊流域系统水文水动力联合模拟研究,归纳总结了基于外部耦合、内部耦合与全耦合技术的联合模型的优势和不足。从学科发展趋势和应用需求的角度出发,概述了湖泊流域系统联合模拟的难点和今后发展趋势     

湖泊水质模型研究进展

湖泊是最重要的淡水资源之一，对社会和经济的发展起着不可估量的作用。保护和改善湖泊水环境问题已成为当前世界关注的一个焦点。湖泊水质模型是一种利用数学语言来描述湖泊污染过程中的物理、化学、生物化学及生物生态各方面之内在规律和相互联系的手段。作为湖泊水环境污染治理、规划决策分析中的一个重要工具，它可以为湖泊的综合整治和科学管理提供科学的依据，在环境保护领域中发挥着举足轻重的作用。分别介绍了湖泊水质模型国内外研究动态、类型、常用软件（WASP、EFDC、CE QUAL W2、CE QUAL R1、CE QUAL ICM、MIKE、SMS等）和应用实例，并综观湖泊水质模型的研究历史和应用前景，系统分析了湖泊水质模型研究的发展趋势。     

基于组合模型的能源需求预测

能源是人类生存和发展的重要物质基础,也是当今国际政治、经济、军事、外交关注的焦点。能源需求预测是合理制定能源规划的基础。能源需求预测的模型很多,总的来说,可以分为单一模型预测和组合模型预测。本文在分析几种常用单一模型的优缺点和适用范围的基础上,建立BP神经网络与灰色GM的优化组合模型,对江苏省未来十五年煤炭和石油的需求量进行预测。结果表明:①随着经济的发展,未来江苏省对煤炭和石油的需求量逐渐增加,其中煤炭从2008年的19 601.39万t标准煤增加到2020年的25 615.26万t标准煤,年均增长率为1.81%;石油从2008年的2 628.64万t标准煤增加到2020年的3 532.60万t标准煤,年均增长率为1.36%;②基于BP网络与GM(1,1)的组合模型克服了单一模型的缺点,实现了优化组合模型"过去一段时间内组合预测误差最小"的原则,且预测结果误差较小,不仅适用于能源的中长期预测,还可以推广到其他领域。     

中国各省区工业用水效率影响因素的空间分异

工业用水效率是影响工业用水的直接因素,剖析其影响因素并找出空间分布规律是提高中国工业用水效率的关键。通过选取Super-SBM模型,引入非期望产出指标来测算中国31省2007～2016年的工业用水效率,并从多方面综合分析工业用水效率影响因素的空间动态演变状况,以求研究结果为制定有差异的区域集约型水资源管理政策提供依据。结果发现:(1)我国多数省份的工业用水处于无效率状态,同时高效率中心由东向西转移;(2)不同影响因素对工业用水效率的影响关系不同。水资源总量、地区生产总值、工业用水占比、RD投入占比的增多对工业用水效率有负向影响,工业用水效率会降低;而地区常住人口、城镇化率和人均教育支出的增多对工业用水效率有正向影响,促进工业用水效率提升。(3)不同影响因素对中国工业用水效率的影响程度存在空间差异。城镇化率、RD投入占比和人均教育支出对工业用水效率带来的影响作用在空间上相对集中,影响高值区主要落在中部和西部地区,低值区主要在东部沿海;而水资源总量、地区生产总值、工业用水占比和地区常住人口的影响在空间上呈现一种演变的状态,随时间发展影响高值区和低值区都发生了中心转移。     

长三角地区人口密度模型及增长模式:1982～2010

基于熵值法对上海、南京和杭州影响力进行综合评价,运用Arc GIS点距离工具测算各空间单元到沪宁杭的距离,然后借鉴重力模型,将长三角地区划分为以上海、南京和杭州为中心的3个城市经济区,并进行区域人口密度模型拟合。相比线性、指数和乘幂模型,对数模型能更好地拟合经济区内各县、县级市或市辖区人口密度与其到各自经济区中心距离的关系。而相比上述基础模型,基于基础模型的二次模型拟合的判定系数更高,拟合效果更好。其中,对数二次模型拟合的判定系数最高,且明显优于基础模型。基于对数二次模型的人口密度变动的空间差异,沪、宁、杭经济区增长模式可以总结为"强向心集聚"和"近域扩散",但不同区域不同时段增长模式存在差异。     

附加环境因素:传统比较优势理论的扩展

在李嘉圈模型中，若将环境成本用追加的劳动投入来衡量。可以发现，环境成本的引入将修正传统的比较优势格局。在H-O模型中耐加环境因素，亦即假定环境作为一种生产要搴而起作用。则所形成的比较优势将建立在包含环境要素真实价格的基础之上。本文最后指出，环境要素的真实价格与现实价格的脱离，使“显示的比较优势”有可能与真实的比较优势发生偏离。从而损害效率与公平。     

WASP富营养化水质模型在GIS中的完全集成研究

模型与GIS的结合是水质模拟研究的发展趋势，但完全集成方式面临许多技术难点。通过分析WASP富营养化模型的原理，剖析其程序源代码的核心，并对其核心算法进行重新编程开发。把GIS擅长的工作完全交给GIS、把模型擅长的工作完全交给模型，模型从底层对GIS属性数据库进行直接读写，GIS对模型的起始和中间过程直接控制，实现了WASP富营养化水质模型在GIS中的完全集成。完全集成后，为WASP增加LH OAT全局参数敏感性分析功能。LH OAT全局参数敏感性分析方法集成了LH抽样与随机OAT方法的优点，在随机OAT的基础上融入LH抽样法，保证参数敏感性分析的强壮性及有效性。但LH OAT方法必须依靠复杂的计算机程序来实现，因为没有通用程序而限制了其推广应用。为此我们设计了LH OAT方法的通用程序，提高了水质模拟的性能和应用范围。这为模型与GIS的完全集成研究提供了成功案例和问题解决的新思路     

基于SCS-CN与MUSLE模型的三峡库区小流域侵蚀产沙模拟

传统土壤侵蚀模型模拟次降雨产沙时难以确定泥沙输移系数,分布式的侵蚀产沙模型对数据量需求量大。选择三峡库区宋家沟小流域为研究对象,基于2013年的降雨、植被盖度、地形、土壤等数据,利用SCS-CN和MUSLE模型耦合模拟流域的场降雨的产沙量。结果表明:该模型的模拟值的精确度在可接受范围内,整个流域2013年的泥沙流失量是3 923t,全年中5场较大的降雨贡献了泥沙流失量的80%以上;不同土地利用类型的泥沙输出量差异很大,耕地(面积44.63%)贡献了81.54%的泥沙,有林地(面积47.61%)贡献了17.63%的泥沙;坡度在0~8度的区域贡献的产沙量仅为1.75%,大于25度的区域占流域面积的比例是39.21%,产沙量占55.77%;泥沙模拟值相比实测值偏大,其原因可能是流域中分布的池塘改变了径流过程,发挥拦截泥沙功能。     

优化分配方式 提高资金环境绩效

十一五期间中央环境保护专项资金下达近91亿元,为我国环境污染防治和监管基础能力建设提供了强有力的资金保障。随着财政资金使用改革的不断深入,财政部和环保部对中央环境保护专项资金的管理已从过去以评审为中心转变为以绩效为中心,无论在资金投向、分配方式、过程管理、绩效评估等方面都紧密围绕环境绩效这一中心开展。本文在对十一五期间中央环境保护专项资金资金分配总体情况总结归纳的基础上,分析了资金分配方式制约绩效发挥的主要问题,以改革创新资金分配方式、提高环境绩效为目的,对中央统筹法、项目申报法、因素分配法等三种分配方式提出了若干改革优化的建议。     

Harmful and Needless Emission of Refrigerant and Countermeasures

Abstract

Refrigerants used in refrigerators are an important source of ozone depleting substances released into the atmosphere, and can have a significantly negative effect on the hole in the ozone layer. But most emission of refrigerants is man-made, unreasonable and needless. Since in most emission cases the refrigerants are contained in the refrigerators, we can retrieve them by some technique that changes the ‘manual emission’ into manual retrieving. To promote the retrieval action and diminish the pollution, society can use economic, administrative and technical countermeasures, which can create a ‘good-cycle’ both ‘harnessing pollution and earning income simultaneously’, reinforce the motive of retrieving, and retrieve most proportion of refrigerants used by all refrigerators. This ‘good-cycle’ method can be easily promoted, and also a valuable way to promote other forms of environmental protection. The three countermeasures have almost no social cost, even no cost at all.     

Harmful and Needless Emission of Refrigerant and Countermeasures

Refrigerants used in refrigerators are an important source of ozone depleting substances released into the atmosphere, and can have a significantly negative effect on the hole in the ozone layer. But most-emission of refrigerants is man-made, unreasonable and needless. Since in most emission cases the refrigerants are contained in the refrigerators, we can retrieve them by some technique that changes the ＇manual emission＇ into manual retrieving. To promote the retrieval action and diminish the pollution, society can use economic, administrative and technical countermeasures, which can create a ＇good-cycle＇ both ＇harnessing pollution and earning income simultaneously＇, reinforce the motive of retrieving, and retrieve most proportion of refrigerants used by＇all refrigerators. This ＇good-cycle＇ method can be easily promoted, and also a valuable way to promote other forms of environmental protection. The three countermeasures have almost no social cost, even no cost at all.     

Comparisons of elements and inorganic compounds inside and outside of residences

The results of more than 1 yr of air monitoring inside and outside of five homes in each of two communities are presented for SO₂, NO₂, mass respirable particles, SO₄, Al, Br, Cl, Mn, Na, and V. Outdoor measurements across the home site in each city are consistent with proximity to outdoor sources. Looking across indoor residential sites in each city, the home appears to alter outdoor concentrations in several ways. Indoor level of SO₂, SO₄, Mn, and V are lower than those measured outdoors. These constituents are thought generally to result from outdoor sources. The other constituents studied are at times found in excess within homes. In some cases the source or sources of excess concentration of a particular constituent could be identified; often, however, the source of excess indoor concentration could not be identified.     

Mutagenic and carcinogenic potency of extracts of diesel and related environmental emissions: Summary and discussion of the results

The proposed conversion from gasoline powered automobiles to diesel powered vehicels has prompted the Environmental Protection Agency to evaluate the potential health effects associated with exposure to diesel emissions. At present, there is no direct epidemiological link between this exposure and human health. Therefore, a research program was constructed to compare the health effects associated with diesel emissions with those from other emission sources for which epidemiological information was available. The emission sources chosen were cigarette smoke, roofing tar, and coke oven. An additional comparative emission source which was a gasoline catalyst engine. Respirable particles from a variety of combustion sources have the potential of being carcinogenic and mutagenic. The objective of these studies was to determine the relative biological activity of the organic material adsorbed on these particles in both in vitro mutagenesis and in vitro and in vivo bioassays. The organic extracts from the following series of emission sources were quantitatively bioassayed in a matrix of tests for their carcinogenic and mutagenic activity: (1) a light-duty Oldsmobile diesel 350 engine; (2) a heavy-duty Caterpillar diesel engine; (3) a light-duty Nissan engine; (4) a Volkswagen Rabbit diesel engine; (5) cigarette smoke; (6) roofing tar; (7) coke oven; and (8) a gasoline catalyst Mustang. The test matrix consisted of the following bioassay: reverse mutation in Salmonella typhimurium; mitotic recombination in Saccharomyces cerevisiae; DNA damage in Syrian hamster embryo cells (SHE); sister chromatid exchange in CHO cells; gene mutation in L5178Y mouse lymphoma cells, Balb/c 3T3 mouse embryo fibroblasts and CHO cells; viral enhancement of SHE cells; oncogenic transformation in Balb/c 3T3 cells; and skin tumor initiation in SENCAR and C57 black mice. The results of this test matrix are discussed.     

Concentrations of chlorinated and brominated contaminants and their metabolites in serum of harbour seals and harbour porpoises

Harbour seals (Phoca vitulina) and harbour porpoises (Phocoena phocoena) are top predators in the North Sea and consequently accumulate a variety of pollutants in their tissues. Concentrations of polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs) and their hydroxylated metabolites (HO-PCBs and HO-PBDEs) were measured in serum of wild harbour seals (n = 47) and captive harbour porpoises (n = 21). Both species exhibit long life spans and do not have extreme situations, such as complete fasting during periods of lactation, in their annual cycles. For PCBs, concentrations in adult males were slightly higher than in juveniles and lowest in juvenile females. For PBDEs, juveniles have higher levels than adult males and females, probably as a consequence of lactational transfer. However, differences between these age–gender groups were not statistical significant, indicating that individual variation was limited within each species, even without knowing the feeding status of the animals. Body condition, particularly emaciation, has a major influence on the levels of chlorinated and brominated contaminants in serum. Profiles of PCBs were CB 153 > CB 138 > CB 187 > CB 180 and CB 153 > CB 138 > CB 149 > CB 187 > CB 180 for harbour seals and porpoises respectively. For PBDEs, BDE 47 was the predominant congener followed by BDE 100 and 99 in both species. In harbour seals, concentrations of sum PCBs (median: 39,200 pg/ml) were more than 200 times higher than levels of sum PBDEs (median: 130 pg/ml) and almost 10 times higher than concentrations of sum HO-PCBs (4350 pg/ml). In harbour porpoises, concentrations of sum PCBs (median: 24,300 pg/ml) were about 20 times higher than concentrations of PBDEs (median: 1300 pg/ml). HO-PCBs were detected in only 4 harbour porpoises and this at very low concentrations. Naturally-produced MeO-PBDEs were only found in harbour porpoises at concentrations ranging from 120 to 810 pg/ml. HO-PBDEs were not found in any species. In general, harbour seals accumulate less compounds and have mostly lower concentrations than harbour porpoises possibly as a result of a better developed metabolism.     

Relevance of BFRs and thermal conditions on the formation pathways of brominated and brominated-chlorinated dibenzodioxins and dibenzofurans

The widespread use of brominated flame-retarded products in the last two decades has resulted in an increasing presence of bromine in thermal processes such as waste combustion and accidental fires. Brominated and brominated-chlorinated dibenzodioxins and dibenzofurans (PBDDs/PBDFs, PXDDs/PXDFs) are micropollutants of concern arising from such processes. The present review aims to evaluate the relevance of these compound classes in actual thermal processes. Four categories of thermal processes are discussed in this respect according to their potential for PBDD/PBDF and PXDD/PXDF generation: thermal stress, pyrolysis/gasification, insufficient combustion conditions and controlled combustion conditions. Under thermal stress situations, as they may occur in production or recycling processes, PBDDs/PBDFs precursors like polybrominated diphenylethers (PBDE) can have a relevant potential for PBDD/PBDF formation via a simple elimination. Under insufficient combustion conditions as they are present in, e.g. accidental fires and uncontrolled burning as well as gasification/pyrolysis processes, considerable amounts of PBDDs/PBDFs can be formed from BFRs, preferably via the precursor pathway. In contrast, under controlled combustion conditions, BFRs and PBDDs/PBDFs can be destroyed with high efficiency. The relevance of de novo synthesis of PXDDs/PXDFs is discussed for this condition.Providing a basis for the understanding of PXDD/PXDF formation in actual thermal processes, the present paper also summarises the formation pathways of brominated and brominated-chlorinated PXDDs/PXDFs from brominated flame retardants (BFRs) investigated during laboratory thermolysis experiments. Relevant mechanistic steps for PBDD/PBDF formation from brominated precursors are discussed including elimination reactions, condensation steps and debromination/hydrogenation reactions.In addition, chlorination/bromination and halogen exchange reactions are briefly discussed with respect for their relevance on the final distribution of PBDDs/PBDFs, mixed chlorinated PXDDs/PXDFs and PCDDs/PCDFs resulting from thermal processes.     

经济波动与最优城镇化水平和速度研究

城镇化对经济波动具有重要影响,过快和过慢均不利于经济的平稳发展。我国经济新常态客观上要求实施新型城镇化战略,关键是积极稳妥推进城镇化,科学控制城镇化水平和速度。以宏观经济稳定为目标,确定最优城镇化规则,诊断当前城镇化水平和速度,可为落实新型城镇化,稳定宏观经济提供决策参考。本文建立了附加城镇化变量的后顾型宏观经济模型,利用最优控制理论求解基于宏观经济波动最小化的最优城镇化水平和速度决定规则,实证结果表明:我国人口城镇化速度主要对宏观总需求产生影响,而土地城镇化速度既影响总需求也影响总供给;最优城镇化速度规则对总产出缺口负反馈,对通胀缺口正反馈。在此基础上,进一步模拟了1990-2013年间最优人口城镇化、土地城镇化水平以及相应的总产出和通胀波动情况,模拟结果显示:最优城镇化水平和速度规则具有逆经济周期的特征,为保持经济平稳发展,经济过度繁荣时城镇化应减速,经济衰退时应加速城镇化,我国历史上城镇化速度和水平存在较大的优化空间;最优城镇化水平和速度规则会小幅度降低城镇化进程和总产出的平滑性,但会大幅度抑制通胀波动,总体来看使总福利损失下降约三分之一;当前我国人口城镇化水平超前速度过快,土地城镇化水平偏低速度过慢。建议"十三五"期间,政府应该根据宏观经济波动情况适当控制人口城镇化速度,加快推进土地城镇化,提高土地城镇化水平和质量,同时应制定相应的财政政策和货币政策以促进最优城镇化规则发挥其降低宏观经济波动功能。     

Fate and transport of pathogens in lakes and reservoirs

Outbreaks of water-borne disease via public water supplies continue to be reported in developed countries even though there is increased awareness of, and treatment for, pathogen contamination. Pathogen episodes in lakes and reservoirs are often associated with rain events, and the riverine inflow is considered to be major source of pathogens. Consequently, the behaviour of these inflows is of particular importance in determining pathogen transport and distribution. Inflows are controlled by their density relative to that of the lake, such that warm inflows will flow over the surface of the lake as a buoyant surface flow and cold, dense inflows will sink beneath the lake water where they will flow along the bathymetry towards the deepest point. The fate of pathogens is determined by loss processes including settling and inactivation by temperature, UV and grazing. The general trend is for the insertion timescale to be shortest, followed by sedimentation losses and temperature inactivity. The fate of Cryptosporidium due to UV light inactivation can occur at opposite ends of the scale, depending on the location of the oocysts in the water column and the extinction coefficient for UV light. For this reason, the extinction coefficient for UV light appears to be a vitally important parameter for determining the risk of Cryptosporidium contamination. For risk assessment of pathogens in supply reservoirs, it is important to understand the role of hydrodynamics in determining the timescale of transport to the off-take relative to the timescale of inactivation. The characteristics of the riverine intrusion must also be considered when designing a sampling program for pathogens. A risk management framework is presented that accounts for pathogen fate and transport for reservoirs.     

中国地表权、地下权概念、应用模式及相关问题分析

文章通过对地表权、地下权相关法律概念的梳理,指出地表权、地下权概念界定的复杂性,借鉴《商业词典》对地表权和地下权的定义,探讨了在中国矿产资源一元所有制及土地二元所有制并存的情形下,地表权与地下权的应用模式、相关产权界定及存在的问题。文章分三种情形对二者的应用模式进行了探讨,指出:地表权与地下权相分离的模式是符合中国国情的一种合理选择,但是在具体实践中却存在农村集体作为土地拥有者的地位没有得到应有的尊重、矿业权主体行政审批问题严重、矿产资源的国家所有权权益没有得到应有的体现、矿产资源开发中的环境产权界定不清晰等问题;在探讨中指出两个启迪性的思路:一是使农村集体参与矿产资源开发收益分成模式;二是在现有的征地制度下,理顺价格机制,建立有效的土地流转市场,在土地使用权转让中,给予土地所有者以价格补偿。文章进一步对矿产资源开发中的土地所有权界定、税费问题、土地价格补偿及环境产权分配给予相应的分析并给出建议。