NO对PPS滤料影响的实验研究

PPS滤料是燃煤电厂最常用的烟气过滤材料，研究烟气中组分对PPS滤料的影响对降低除尘系统运行成本、提高设备可靠性有极其重要的实际意义。通过系统的实验方案和手段，研究了NO的浓度、作用时间和温度三个因素对PPS滤料强度的影响。结果表明，随着这三个因素数量的增大，PPS强度呈下降趋势；红外光谱和DSC/TG差热分析表明，PPS经过NO作用后，化学成分发生了轻微变化。     

PPS覆膜滤料的性能及应用

通过VDI滤料模拟测试装置、SEM等先进仪器对PPS覆膜滤料的性能进行测试分析,比较了常规PPS和PPS覆膜滤料性能,列举了其在燃煤电厂中的应用情况,阐明PPS覆膜滤料优异的过滤性能及工程应用效果。     

PPS滤料机械性能测试研究

袋式除尘行业里,所用滤料本身的性质有重要的意义,而衡量滤料性质的指标中最重要的一点就是其机械性能的稳定性。在产品大批量投产与使用之前,都要对这项指标进行测定。文章以PPS滤料为例,研究了在测定滤料机械性能时,样品选取尺寸的大小对其断裂强力和断裂伸长率两项机械性能测试数值的影响。     

几种过滤材料的静电性能测试及分析

滤料产生静电火花是袋式除尘器因静电火花产生火灾和爆炸事故的主要原因。文章从面电荷密度、摩擦电压、半衰期、表面电阻率、体积电阻率五个方面对国内主要类型的过滤材料进行了静电性能的测试。分析得出,滤料采用经向导电涤纶纤维、面层均匀导电涤纶纤维等防静电滤料可有效防止静电火花的产生。     

水刺工艺对PPS滤料产品性能的影响

水刺法相对于针刺法除尘滤料具有多方面的优势,具有更高的过滤效率和较低的排放浓度,可满足更加严格的环境空气质量标准。通过使用PPS纤维预先制成的预针刺毡作为样品,利用不同的水刺工艺进行试验,对其常规性能（厚度、透气量、断裂强度、表面效果）做对比分析,讨论了不同水刺工艺参数设置对水刺PPS滤料产品性能的影响,得出相关结论,有助于实际高压水刺滤料生产中工艺参数的选择。     

玻纤/PPS、PTFE复合水刺滤料的研发

玻纤/PPS、PTFE复合水刺滤料突破了传统针刺产品的性能局限性,利用水刺动能开纤,使纤维原纤化,同时增加滤料的抱合度,使产品具有立体三维容尘梯次结构,有效解决过滤效率和阻力之间的矛盾,替代覆膜滤料适应PM2.5的排放标准。     

聚酰亚胺滤料在水泥窑尾除尘器上的应用

分析了某水泥厂窑尾项目运行过程中抽检的聚酰亚胺滤袋的性能,结果证实该滤料在满足水泥窑尾项目4年正常运行的条件下,仍具有足够的机械强度,且过滤性能保持良好。     

青藏铁路用空气弹簧橡胶胶料耐紫外线老化试验研究

我国正在建设的青藏铁路是世界上海拔最高、线路最长的高原铁路.其气候特点对橡胶制品提出了新的技术要求,为适应在该气候条件下的运用需要,进行了针对空气弹簧胶囊用橡胶的耐紫外线老化试验研究工作,试验表明随着紫外线老化时间的增加,其硬度和300%定伸强度均提高,但拉伸强度和扯断伸长率随着紫外线老化时间的增加而降低;通过与胶料的耐臭氧试验和大气老化试验比较,基本可以认为引起空气弹簧胶囊表面龟裂的主要原因是受力状况、臭氧和大气老化的作用,而紫外线对橡胶的表面龟裂影响作用不大,因此,为提高空气弹簧胶囊的耐老化性能,主要考虑降低橡胶的受力,提高耐臭氧和耐大气老化性能.     

东部农业区春季干旱变化特征分析及成因初探

利用50多年青海省东部农业区的12站气象资料及青藏高原季风指数研究表明:春季干旱指数SPI变化倾向率为-0.33/10a,呈略减少趋势,减少的趋势不显著;春季东部农业区区域性轻旱、中旱、重旱、特旱分别出现12、5、4、0次,共出现21次,未出现特旱。出现干旱(包括轻旱、中旱和重旱)的几率为38.9%;春季出现过4次明显的区域性大旱,平均每13.5年发生1次,21世纪初以来我省东部农业区出现大旱的几率明显减少;近50年,春季高原季风指数以2.68gmp/a速率增加,增加趋势显著;东部农业区的干旱指数SPI与同期、前期高原季风指数的相关分析表明,高原夏季风越强,东部农业区的降水就越多,干旱指数越小,不易出现旱情;春季干旱指数SPI与同期5月北大西洋—欧洲区极涡强度指数、冬季赤道中东太平洋200hPa纬向风指数成反比,5月北大西洋—欧洲区极涡强度指数、冬季赤道中东太平洋200hPa纬向风指数越强,春季干旱指数SPI越小,春季降水量则偏少,容易发生干旱;与5月多变量ENSO指数、5月北太平洋遥相关指数、春季印度洋暖池面积成正比,这些指数较强,则春季高原指数越大,春季降水量较多,不容易发生干旱。     

汽车用材料——PA66及其玻璃纤维复合材料在不同介质中的老化行为研究

在三种介质（二次水，汽油，乙二醇，50℃温度）条件下对PA66及PA66／GF进行95天左右的人工模拟材料在汽车使用环境下的加速试验，对不同老化时间的PA66及PA66／GF试样进行了宏观力学测试及吸湿性测试，并进一步利用示差扫描量热法（DSC），红外光谱及扫描电镜等手段分析老化前后试样的微观结构及组织差异。结合老化前后试样的力学性能变化，揭示了PA66及复合材料的老化规律和机理。实验表明，PA66及PA66／GF在三种介质中拉伸强度呈现下降趋势。其主要机理是介质溶液对试样渗入的结果影响，降低了分子间的相互作用力（范德华力）从而使材料机械性能下降；同时未发现化学作用对材料的力学性能有明显的变化。     

我国煤炭生产重心与消费重心演变轨迹研究

利用重心模型,分别测算了1997—2009年我国煤炭生产重心与消费重心的动态变化轨迹,从方向和距离两方面对其进行了对比分析,探讨了煤炭生产重心与消费重心相互偏离的影响。研究表明,我国煤炭生产重心从剧烈不规则运动到剧烈向西南移动,最后平稳向西北转移,煤炭消费重心平缓地呈现出＂西进南移＂的趋势。两者在经度上收敛,纬度上背离,直线距离从1997年的182km增加到2009年的283km;两者间的背离改变了区域煤炭运输格局,加剧了煤炭运输的难度。     

新型纤维滤料的研究及应用

随着我国油田相继进入开发后期,传统的滤料及设备过滤精度已不能满足注水的要求。因此,研究并开发了具有一定抗油污能力的新型过滤材料,设计了新型的超精细过滤器系列产品。对滤料进行的室内实验结果表明,在开始过滤的近10h内,过滤后的水中含油量基本上满足注水的水质要求。在开始过滤的近20h内,滤层的水头损失随时间的变化较为平缓;随着过滤时间的延长,水头损失变化加剧。从现场实验可以看出,所设计的过滤器有良好的过滤性能和抗冲击能力。新型过滤材料的研究成功解决了油田含油污水精细过滤的问题,新型过滤器也是含油污水超精细过滤的理想产品。     

溶剂型聚氨酯涂料废物热解特性及动力学研究

采用TG研究溶剂型聚氨酯涂料废物在不同升温速率、N2气氛影响下的热解特性规律。升温速率取5,10,20,30℃/min;气氛取N2气氛(50 m L/min);实验温度范围为20~800℃。研究表明,随着升温速率的增大,涂料废物热解反应各阶段起始温度、终止温度、最大失重速率温度均向高温方向移动。在500℃时,涂料废物的热分解已基本完成。运用Kissinger法和Flynn-Wall-Ozawa法进行热解动力学分析,得到溶剂型聚氨酯涂料废物热解阶段的表观活化能为196.053 3 kJ/mol。     

Study of inexpensive oxygen carriers for chemical looping combustion

Norwegian industrial tailings and by-products, as well as naturally occurring minerals and ores have been surveyed with the purpose of identifying candidate oxygen carrier materials for use in a chemical looping combustion process. Nine materials, based on manganese and/or iron oxide, were selected for an initial screening test; six were deemed promising and were hence investigated further. Thermogravimetric experiments were performed to investigate the oxygen capacity, the reaction kinetics and reversibility of the oxygen absorption reaction. A manganese ore with a reversible capacity of 4.9 wt% oxygen at 1000 °C was selected as the most promising for chemical looping combustion applications. This material was modified by addition of calcia to explore the possibility of enhancing the kinetic, catalytic and mechanical properties. The addition of excess calcium relative to manganese resulted in formation of calcium manganite and related phases. The oxygen capacity of the modified material was 4.5 wt% at 1000 °C, but it has potential advantages in terms of kinetics and chemical and mechanical stability relative to the pure ore.     

Polyvinyl chloride used as a chlorinating and a reducing agent

Polyvinyl chloride (PVC) or vinyl is a recyclable material. It can be used as a chlorinating and a reducing agent. Two tests of chlorination and reduction of two different samples of jarosite and hematite were realized using PVC, results are presented in this paper. The chlorination test shows that the HCl gas produced from PVC and heated at ≈250°C can be used as a chlorine source to recover as chlorinated compounds the valuable metals such as Zn, Pb contained in jarosite. The XRD reveals the presence of lead and zinc chlorides in the condensates obtained. The second test of reduction was conducted using a mixture of PVC and hematite treated in a nitrogen atmosphere between 200 and 1000°C. The results show that at low temperature, PVC produces HCl and with kinetic consideration, no reactions can be observed with hematite. However, at high temperature, the weight of the hematite sample decreases by ≈15%, due to the reduction of hematite to iron metal.     

聚苯硫醚（PPS）纤维发展现状与展望

介绍了国内聚苯硫醚纤维生产的发展历程及现状;通过对国内外产品性能对比,指出超细、异形、复合型、改性等产品的开发应用,是高性能聚苯硫醚纤维的发展方向;介绍了几种具有代表性的聚苯硫醚纤维产品。     

Soil fate of agricultural fumigants in raised-bed, plasticulture systems in the southeastern United States

Soil concentrations and degradation rates of methyl isothio-cyanate (MITC), chloropicrin (CP), 1,3-dichloropropene (1,3-D), and dimethyl disulfide (DMDS) were determined under fumigant application scenarios representative of commercial raised bed, plastic mulched vegetable production systems. Five days after application, 1,3-D, MITC, and CP were detected at concentrations up to 3.52, 0.72, and 2.45 μg cm, respectively, in the soil atmosphere when applications were made in uniformly compacted soils with a water content >200% of field capacity and covered by a virtually impermeable or metalized film. By contrast, DMDS, MITC, and CP concentrations in the soil atmosphere were 0.81, 0.02, and 0.05 μg cm, respectively, 5 d after application in soil containing undecomposed plant residue, numerous large (>3 mm) clods, and water content below field capacity and covered by low-density polyethylene. Ranked in order of impact on the persistence of fumigants in soil were soil water content (moisture), soil tilth (the physical condition of soil as related to its fitness as a planting bed), the type of plastic film used to cover fumigated beds, and soil texture. Fumigants were readily detected 13 d after application when applied in uniformly compacted soils with water contents >200% of capacity and covered by a virtually impermeable or metalized film. By contrast, 1,3-D and MITC had dissipated 5 d after application in soils with numerous large (>3 mm) clods and water contents below field capacity that were covered by low-density polyethylene. Soil degradation of CP, DMDS, and MITC were primarily attributed to biological mechanisms, whereas degradation of 1,3-D was attributed principally to abiotic factors. This study demonstrates improved soil retention of agricultural fumigants in application scenarios representative of good agricultural practices.