Indoor air pollution due to organic gases and vapours of solvents in building materials

The emission of organic gases and vapours of solvent type from 42 commonly used building materials was measured under standard atmospheric conditions. An average of 22 compounds was found in the air around each building material, and the total concentration of gases and vapours was from 0.01 to 1410 mg/m³. The average arithmetic emission rate was 9.5 mg/m² h, and 52 different compounds were identified. A mathematical model was established for the indoor air concentrations of pollutants originating from building materials. The model was tested on three model rooms constructed from the materials investigated. The calculated total air concentrations of gases and vapours in the three rooms ranged from 1.6 to 23.6 mg/m³, and the number of compounds in the air from 23 to 32. These concentrations and number of compounds did not differ from those found in actual rooms similar in size and construction to the model rooms. The risks of health effects due to the compounds identified from the building materials were investigated, and criteria for future air quality standards are discussed. It is concluded that the possibility of negative health effects cannot be neglected, especially not for the more sensitive minority of the general population.     

Describing the annual cyclic behaviour of Be concentrations in surface air in Oceania

Surface air concentrations of ⁷Be at a number of stations in Oceania show a distinct annual cycle. We apply a sinusoidal model to describe this cycle. The results show that peak ⁷Be concentrations in surface air occur during early spring at tropical latitudes and during mid-to-late summer at middle latitudes. Comparison with available ⁹⁰Sr surface air data for the southern hemisphere indicates that stratosphere-to-troposphere exchange is an active atmospheric process controlling the ⁷Be annual cycle throughout the Oceania region. Vertical transport of air within the troposphere also seems to influence the observed annual cycle. Seasonality in rainfall is not thought to control the annual cyclic behaviour of ⁷Be in surface air.     

An improved method for Kr analysis by liquid scintillation counting and its application to atmospheric Kr determination

Atmospheric ⁸⁵Kr concentration at Fukuoka, Japan was determined by an improved ⁸⁵Kr analytical method using liquid scintillation counting (LSC). An average value of 1.54 ± 0.05 Bq m⁻³ was observed in 2008, which is about two times that measured in 1981 at Fukuoka, indicating a 29 mBq y⁻¹ rate of increase as an average for these 27 years. The analytical method developed involves collecting Kr from air using activated charcoal at liquid N₂ temperature and purifying it using He at dry ice temperature, followed by Kr separation by gas chromatography. An overall Kr recovery of 76.4 ± 8.1% was achieved when Kr was analyzed in 500-1000 l of air. The Kr isolated by gas chromatography was collected on silica gel in a quartz glass vial cooled to liquid N₂ temperature and the activity of ⁸⁵Kr was measured with a low-background LS counter. The detection limit of ⁸⁵Kr activity by the present analytical method is 0.0015 Bq at a 95% confidence level, including all propagation errors, which is equivalent with ⁸⁵Kr in 1.3 l of the present air under the analytical conditions of 72.1% counting efficiency, 0.1597 cps background count rate, and 76.4% Kr recovery.     

Temporal variation of Be concentrations in atmosphere for 8 y from 2000 at Yamagata,Japan: solar influence on the Be time series

We have been continuously observing the daily ⁷Be concentrations in surface air at Yamagata, Japan (38.25° N, 140.35° E) since 2000. The yearly profile of the ⁷Be concentration indicates the variation in galactic cosmic rays owing to solar modulation. Over 8 y, the ⁷Be concentration, cosmic neutrons, and number of sunspots varied by 37.4%, 12.2%, and 92.8%, respectively. The influence of precipitation on the ⁷Be variability was approximately 5%. Hence, the yearly ⁷Be concentration was mainly varied by the solar modulation of the ⁷Be production rates. Based on the production rates found in an EXPACS simulation, the observed variability indicates ⁷Be transport from high latitudes. The daily ⁷Be concentrations have two significant periodic components of 19 d and 36 d. The 36-d component implies a relationship between the sun's rotation and the vertical transport of air masses under quiet solar activity.     

The impact of coal utilization in Texas under the National energy plan

The paper describes the results of a study of the impact of the National Energy on the trend towards increased utilization of coal and lignite in Texas with forecasts of increased coal and lignite utilization for the electric utility and industrial sectors. Environmental impacts of this increased coal and lignite use are projected in terms of increased air pollutant emissions and air quality impacts. Economic costs of compliance with alternative source emission regulations are also projected for the electric utility industry.Lignite consumption in Texas under the National Energy Plan is projected to increase from the present 13 million metric tons in 1976 to 57 million metric tons annually by 1985. Sub-bituminous coal consumption in Texas is projected to increase from 1 million metric per year in 1976 to 49 million metric tons per year in 1985. Bituminous coal consumption in Texas is expected to increase from less than one million metric tons per year in 1976 to about 3 million metric tons per year in 1985.Major increases in sulfur oxides emissions from coal and lignite combustion in Texas can be expected by 1985 of up to 1.5 × 10⁹ kg per year without controls and 0.2 × 10⁹ kg per year with controls. Increases in acid precipitation formation will result in north-east Texas from extensive lignite usage for electric power generation as a detriment to agriculture. The photochemical air pollution problem in the Houston area will probably worsen primarily because of increased nitrogen oxides and sulfur oxides emissions because of industrial coal combustion. Capital costs of air pollution controls in Texas for coal-fired utility boilers are estimated as up to U.S. $3.9 billion by 1985, with total operating costs of up to U.S. $1.2 billion per year.     

Ventilation requirements in occupied spaces during smoking and nonsmoking occupancy

Ventilation requirements in occupied spaces have traditionally derived largely from odor control. The requirements have rested on the notion that an environment that seems subjectively acceptable to a visitor will in fact be healthful and comfortable for both visitor and occupant alike. Ventilation requirements have derived secondarily from criterion concentrations of notable contaminants (e.g., carbon dioxide). The present investigation looked again at both sensory (odor, irritation) and physical criteria of acceptability, paying particular attention to the difference between smoking and nonsmoking occupancy in a well-controlled environmental chamber. More than 200 persons (visitors) made judgments of odor intensity and acceptability under various conditions of occupancy (up to 12 nonsmoking occupants; a temperature of up to 25.5°C; up to 16 cigarettes smoked per hour). The results implied that under nonsmoking conditions and moderate humidity only about 7.5 cfm (3.8 L sec⁻¹) of fresh air per occupant sufficed to satisfy visitors, but that under smoking conditions at least 5 times as much fresh air is necessary. Our estimate of ventilation requirements for smoking were derived in part from measurements of carbon monoxide and total suspended particulate (TSP) mass concentration. Levels of TSP achieved during realistic smoking and ventilation rates exceeded levels deemed acceptable outdoors. Surfaces in the chamber played an important role in the elimination of particles, presumably via adsorption. Use of an electrostatic precipitator could keep TSP levels under control. Nevertheless, it remains to be seen whether control of TSP will eliminate the need for enormous ventilation for odor control during smoking occupancy.     

Plutonium isotopes in surface air of Prague in 1986–2006

Monitoring of ^239,240Pu in surface air of Prague started in 1986 in connection with the Chernobyl accident. Measurable activities of 10–28 μBq m⁻³ were found from 29 April 1986 to 5 May 1986. In the most of the monitoring periods of 1987–1996, activities of ^239,240Pu in air were not measurable. Positive values for ^239,240Pu and ²³⁸Pu in air could be obtained after installation of an aerosol sampler with higher flow-rate in 1997. Activity concentrations of ^239,240Pu and ²³⁸Pu in Prague air in the most of quarters of 1997–2006 were in the range 0.53–5.06 and <0.16–1.10 nBq m⁻³, respectively. Seasonal fluctuations can be found in content of ^239,240Pu in air. Activity ratios of ²³⁸Pu/^239,240Pu in air are higher than those in top soil, so it can be supposed that ²³⁸Pu is coming to air of Prague also from other sources than resuspension of fallout from atmospheric nuclear tests.     

85Kr atmospheric concentration in Bratislava from 1980 to 1983

A cryogenic-chromatographic method for determination of ⁸⁵Kr in the atmosphere is presented. Sampling of the air on the activated-charcoal, chromatographic separation of Krypton from the other air components and radioactivity measurement are described in details. The activity of ⁸⁵Kr is measured by small proportional counters with sensitive volumes of 5 and 10 cm³. Results of the measurements of ⁸⁵Kr air concentration in Bratislava from 1980 to 1983 are presented and compared with other ⁸⁵Kr data measured in Europe.     

The effect of air mass origin on the ambient concentrations of Be and Pb in Islamabad, Pakistan

Concentration of radionuclides ²¹⁰Pb and ⁷Be, having half lives of 22.3 years and 53.29 days, respectively, in the surface air samples of Islamabad (33.38° N, 73.10° E and Altitude ∼536 m asl.) are measured. The non-destructive technique of gamma-spectrometry, with a high purity germanium HPGe detector, was employed for the analysis of all samples. The annual average concentrations of ²¹⁰Pb and ⁷Be in the surface air samples were determined as 0.284 ± 0.15 and 3.171 ± 1.14 mBq m⁻³, respectively. Our results have shown a seasonal variation of the concentration of ⁷Be in air samples with high values for the spring season. High concentrations for ²¹⁰Pb are obtained when air masses originate from plain areas of Pothohar region, located in the South-West, West and North West of Islamabad. Our values of concentrations show a nice agreement with the relevant reported results.     

Short-term effects of air pollution on respiratory morbidity at Rio de Janeiro — Part II: Health assessment

The effects of air pollution on health have been studied worldwide. Given that air pollution triggers oxidative stress and inflammation, it is plausible that high levels of air pollutants cause higher number of hospitalisations. This study aimed to assess the impact of air pollution on the emergency hospitalisation for respiratory disease in Rio de Janeiro, Brazil. The study was divided in two parts: Part I specifically addressing the air pollution assessment and Part II addressing the health assessment. Accordingly, this Part II aimed to estimate the association between the concentrations of PM₁₀, SO₂ and CO observed in Rio de Janeiro and the number of emergency hospitalisations at a central hospital due to respiratory diseases. The pollutant concentrations were measured at two different sites in Rio de Janeiro, but the excess relative risks were calculated based on the concentrations observed at one of the sites, where limits were generally exceeded more frequently, between September 2000 and December 2005. A time series analysis was performed using the number of hospitalisations, divided in three categories (children until 1 year old, children aged between 1 and 5 years old and elderly with 65 years old or more) as independent variable, the concentrations of pollutants as dependent variables and temperature, relative humidity, long term trend, and seasonality as confounders. Data were analysed using generalised additive models with smoothing for some of the dependent variables. Results showed an excess risk of hospitalisation for respiratory disease higher than 2% per 10 μg m^− 3 increase in PM₁₀ concentrations for children under 5 years old, of 2% per 10 μg m^− 3 increase in SO₂ for elderly above 65 years old and around 0.1% per 10 μg m^− 3 increase in CO for children under 1 year and elderly. Other studies have found associations that are in agreement with the results achieved in this study.The study suggests that the ambient levels of air pollutants experienced in Rio de Janeiro between 2000 and 2005 were linked to the number of hospitalisations for respiratory diseases among children and elderly.     

A statistical model to evaluate the effectiveness of PM2.5 emissions control during the Beijing 2008 Olympic Games

A statistical model was developed using satellite remote sensing data and meteorological parameters to evaluate the effectiveness of air pollution control measures during the 2008 Beijing Olympic Games. Custom satellite retrievals under hazy conditions were included in the modeling dataset to represent the air pollution levels more accurately. This model explained 70% of the PM_2.5 variability during the modeling period from June to October 2008. Using this tool, we estimate that the aggressive emission reduction measures alone effectively lowered PM_2.5 levels by 20–24 μg/m³ or 27–33% on average during the Games period, which is substantially greater than those reported previously. Since parameters required to develop this model are readily available in most cities of the world, it can be quickly applied after other major events to evaluate air pollution control policy.     

Experimental analysis of thermal performance of evacuated tube and flat-plate solar air collectors at different air flow rates

The thermal performances of an evacuated tube collector (ETC) and flat-plate solar air collector (FPC) are experimentally investigated at different air flow rates. To investigate the performance of the ETC and FPC, experimental set-ups were fabricated. Air was used as a working fluid and tested at the same climatic conditions. The ETC had 15 evacuated tubes with a surface area of 1.66 m². The experimental set-up consisted of a header with a hollow pipe (square pipe) in the centre through which the air flowed. The flat-plate collector had a surface area of 1.35 m². The FPC had a black painted absorber sheet which divides the collector into two sections. The air flowed through the upper and the lower sections parallel to the collector to minimize the overall heat loss. The temperature of the outlet air depends on several factors along with the airflow rate and the intensity of the solar radiation. It was found that during the day at high flow rates, the efficiency of the ETC varies from 0.12 to 0.5, and for the flat plate it was from 0.29 to 0.68. The maximum temperature of the air was 56.7°C for the ETC and 25.7°C for the FPC.     

Indoor air quality and minimum ventilation rate

In a 30-m³ test chamber the air pollutants caused by man were measured. Variables were the number of persons and the rate of air change. During 2-h test sessions the temperature, relative humidity, carbon dioxide, and intensity of odors were measured. The relationship between the perceived odor intensities and the concentrations of carbon dioxide-independent of the number of persons and the air change rate—was observed. At air change rates of 12–15 m³/person/h, the carbon dioxide concentration was not higher than 0.15% and the odor intensity was evaluated only as a “slight annoyance.” Higher ventilation rates are necessary if smoking and increased physical activities are done in the rooms.     

Guidelines for Nordic building regulations regarding indoor air quality

A subcommittee of the Nordic Committee for Building Codes has released guidelines for building regulations regarding indoor air quality, especially concerning ventilation. The main features of the guidelines, such as acceptable outdoor air quality for ventilation and minimum outdoor air flows for dwellings and offices, are presented and discussed. Mechanical ventilation is, in principle, required in all buildings including dwellings, due to the requirement of a minimum outdoor air change of 0.5 h⁻¹ and the normal highly airtight nature of new buildings. The guidelines are a basis for designing energy-efficient buildings while maintaining an indoor air quality which provides acceptable comfort and does not impair health.     

The influence of ventilation on indoor/outdoor air contaminants in an office building

The air quality in a newly built preschool was investigated in a longitudinal study. Typical air contaminants emanating from building materials were determined, their variation over time (0–18 months) was measured, and the influence of the ventilation system (81%–91% recirculation of return air) on contaminant concentrations was studied. Volatile organic compounds were sampled by adsorption on porous polymer, analysed by a GC/FID system, and identified by MS. A spatial build-up in concentration (ppb or μg/m³ levels) is evident for all the organic compounds, as well as for CO₂, from the outdoor air, through the ventilation system, and through the rooms to the exhaust air. The longitudinal comparison over time shows that all the organic compounds decline in concentration mainly within the first 6 months of occupancy: 1-butanol 4–14 times, toluene and pentanal + hexanal 2–4 times, while formaldehyde remained at a constant low level of 90 ppb (110 μg/m³). It is difficult to believe that the problems of poor air quality in 100 preschools in Stockholm are caused by the organic compounds alone unless interactions occur. A preschool building needs to be gassed off during the first 6 months after its construction with no recirculation of return air allowed (outdoor air rate approx 4–5 ach). During at least 1–2 additional years, it is desired that the recirculation rate of return air is restricted, perhaps to 50%.     

Possible effect of solar tides on radon signals

Large temporal variations of radon (²²²Rn) are often encountered in air in the geologic environment, at time scales from diurnal to annual. Interpretations as to the nature of these variations, unique to ²²²Rn, often invoke either above surface atmospheric variations, or the influence of subtle active geodynamic processes. So far the eventual geophysical drivers of the variation of ²²²Rn as well as its specific qualities enabling this temporal variation are not known. New insight on the temporal variation of ²²²Rn is gained by experimental simulation in confined air. Two short laboratory experiments, and one external experiment lasting over 3 years, were performed inside closed canisters and using natural and commercial ²²²Rn sources. Internal and external gamma and alpha detectors recorded variations of the radiation, up to around 20% of the equilibrium level. Radon signals of different time scale occurred with: a) periodic annual and semi-annual signals; b) non-periodic multi-day signals; c) periodic daily signals. Similar, related, inversely-related and dissimilar temporal patterns were manifested in the measured time series of the different sensors. Diurnal periodicity was dominated by the solar tide components S1, S2 and S3, exhibiting unlike relative amplitudes and different phases at the different sensors. A compound association occurs among the amplitudes and phases of the diurnal and seasonal periodicities of the daily ²²²Rn signal, linking the periodic phenomena to the rotation of earth around its axis and around the sun. ²²²Rn variation patterns in the frequency-time domain cannot be driven by the corresponding atmospheric variation patterns. These results, obtained under static and isolated conditions, are in disagreement with the expected radioactive equilibrium and its spatially uniform expression within and around the experimental volume. The external influence which drives the daily signals evolving from ²²²Rn inside the canister is non-atmospheric and seemed to be from a remote source and traversed a 5-cm thick lead shield. The similarities with observations on ²²²Rn signals from upper crustal levels imply that such an external influence, possibly as a component of solar irradiance, drives the ²²²Rn signals to a depth of at least 100 m. New combined prospects for the research are indicated in terms of the radioactive behavior of ²²²Rn in air and in terms of an above surface geophysical driver for this behavior.     

Mutagenicity of atmospheric air and snow cover in the city of Syktyvkar estimated by the somatic mutation test inTradescantia (Clone 02) stamen hairs

Genotoxicity of atmospheric air was studied in Syktyvkar for three years (1995–1997) using the test of somatic mutations inTradescantia (clone 02) stamen hairs. The data obtained indicate local air pollution in the city. The tested samples of snowmelt, where Ni⁺ and Zn²⁺ ions were the main pollutants, had a high teratogenic effect on stamen hairs. The somatic mutation rate similar to that in the control group was obtained in the experiment with only one sample, in which the total content of metal ions was the lowest.     

The comparison of generic model predictions with chernobyl fallout data on the transfer of radioiodine over the air-pasture-cow-milk pathway

Data have been collected on concentrations of ¹³¹I in air, vegetation and milk from numerous locations receiving Chernobyl fallout. Time-integrated concentrations derived from these data are used to compare predictions from generic models used for routine environmental radiological assessments. In general, the models markedly overestimated the transfer of ¹³¹I over the air-grass-cow-milk pathway. The reasons for this overestimate appear to be related to a combination of different factors, among which overestimation of the dry deposition velocity assumed for elemental ¹³¹I, overestimation of the interception and retention of wet-deposited ¹³¹I by pasture vegetation and overestimation of the cow's diet-to-milk transfer coefficient appear to be most important. The low transfer of Chernobyl ¹³¹I from air to milk indicates that the direct inhalation of contaminated air by humans may be more important in determining the ¹³¹I exposure to large populations than the consumption of contaminated cow's milk. Radiological assessments conducted prior to the Chernobyl accident have typically assumed that ¹³¹I exposure would be dominated by the consumption of milk. The consumption of milk, however, is still of dominant importance for the exposure of critical population subgroups composed of infants and small children.     

Po-210 and Pb-210 as atmospheric tracers and global atmospheric Pb-210 fallout: a review

Over the past ∼5 decades, the distribution of ²²²Rn and its progenies (mainly ²¹⁰Pb, ²¹⁰Bi and ²¹⁰Po) have provided a wealth of information as tracers to quantify several atmospheric processes that include: i) source tracking and transport time scales of air masses; ii) the stability and vertical movement of air masses iii) removal rate constants and residence times of aerosols; iv) chemical behavior of analog species; and v) washout ratios and deposition velocities of aerosols. Most of these applications require that the sources and sink terms of these nuclides are well characterized.Utility of ²¹⁰Pb, ²¹⁰Bi and ²¹⁰Po as atmospheric tracers requires that data on the ²²²Rn emanation rates is well documented. Due to low concentrations of ²²⁶Ra in surface waters, the ²²²Rn emanation rates from the continent is about two orders of magnitude higher than that of the ocean. This has led to distinctly higher ²¹⁰Pb concentrations in continental air masses compared to oceanic air masses. The highly varying concentrations of ²¹⁰Pb in air as well the depositional fluxes have yielded insight on the sources and transit times of aerosols. In an ideal enclosed air mass (closed system with respect to these nuclides), the residence times of aerosols obtained from the activity ratios of ²¹⁰Pb/²²²Rn, ²¹⁰Bi/²¹⁰Pb, and ²¹⁰Po/²¹⁰Pb are expected to agree with each other, but a large number of studies have indicated discordance between the residence times obtained from these three pairs. Recent results from the distribution of these nuclides in size-fractionated aerosols appear to yield consistent residence time in smaller-size aerosols, possibly suggesting that larger size aerosols are derived from resuspended dust. The residence times calculated from the ²¹⁰Pb/²²²Rn, ²¹⁰Bi/²¹⁰Pb, and ²¹⁰Po/²¹⁰Pb activity ratios published from 1970’s are compared to those data obtained in size-fractionated aerosols in this decade and possible reasons for the discordance is discussed with some key recommendations for future studies.The existing global atmospheric inventory data of ²¹⁰Pb is re-evaluated and a ‘global curve’ for the depositional fluxes of ²¹⁰Pb is established. A current global budget for atmospheric ²¹⁰Po and ²¹⁰Pb is also established. The relative importance of dry fallout of ²¹⁰Po and ²¹⁰Pb at different latitudes is evaluated. The global values for the deposition velocities of aerosols using ²¹⁰Po and ²¹⁰Pb are synthesized.     

Can car air filters be useful as a sampling medium for air pollution monitoring purposes?

Urban air quality and real human exposure to chemical environmental stressors is an issue of high scientific and political interest. In an effort to find innovative and inexpensive means for air quality monitoring, the ability of car engine air filters (CAFs) to act as efficient samplers collecting street level air, to which people are exposed to, was tested. In particular, in the case of taxis, air filters are replaced after regular distances, the itineraries are almost exclusively urban, cruising mode is similar and, thus, knowledge of the air flow can provide with an integrated city air sample. The present pilot study focused on polycyclic aromatic hydrocarbons (PAHs), the most important category of organic pollutants associated with traffic emissions. Concentrations of ΣPAHs in CAFs ranged between 650 and 2900 μg CAF^− 1, with benzo[b]fluoranthene, benzo[k]fluoranthene and indeno[123-cd]pyrene being the most abundant PAHs. Benzo[a]pyrene (BaP) ranged between 110 and 250 μg CAF^− 1, accounting regularly for 5–15% of the total carcinogenic PAHs. The CAF PAH loads were used to derive road-level atmospheric PAH concentrations from a standard formula relating to the CAF air flow. Important parameters/assumptions for these estimates are the cruising speed and the exposure duration of each CAF. Based on information obtained from the garage experts, an average ‘sampled air volume’ of 48,750 m³ per CAF was estimated, with uncertainty in this calculation estimated to be about a factor of 4 between the two extreme scenarios. Based on this air volume, ΣPAHs ranged between 13 and 56 ng m^− 3 and BaP between 2.1 and 5.0 ng m^− 3, suggesting that in-traffic BaP concentrations can be many times higher than the limit values set by the UK (0.25 ng m^− 3) and the European Union (1.0 ng m^− 3), or from active sampling stations normally cited on building roof tops or far from city centres.Notwithstanding the limitations of this approach, the very low cost, the continuous availability of very high amounts of “sample”, and the “retroactivity” render it very useful and complementary to existing passive sampling techniques. This approach yields estimated air concentrations that reflect the pollutant concentrations to which taxi drivers, pedestrians, cyclists and road-related professionals are exposed.