Simulation and optimization technologies for petroleum waste management and remediation process control

Leakage and spill of petroleum hydrocarbons from underground storage tanks and pipelines have posed significant threats to groundwater resources across many petroleum-contaminated sites. Remediation of these sites is essential for protecting the soil and groundwater resources and reducing risks to local communities. Although many efforts have been made, effective design and management of various remediation systems are still challenging to practitioners. In recent years, the subsurface simulation model has been combined with techniques of optimization to address important problems of contaminated site management. The combined simulation-optimization system accounts for the complex behavior of the subsurface system and identifies the best management strategy under consideration of the management objectives and constraints. During the past decades, a large number of studies were conducted to simulate contaminant flow and transport in the subsurface and seek cost-effective remediation designs. This paper gives a comprehensive review on recent developments, advancements, challenges, and barriers associated with simulation and optimization techniques in supporting process control of petroleum waste management and site remediation. A number of related methodologies and applications were examined. Perspectives of effective site management were investigated, demonstrating many demanding areas for enhanced research efforts, which include issues of data availability and reliability, concerns in uncertainty, necessity of post-modeling analysis, and usefulness of development of process control techniques.     

APPLICATION OF ENHANCED ANNEALING TO GROUND WATER REMEDIATION DESIGN1

ABSTRACT: A methodology for ground water remediation design has been developed that interfaces ground water simulation models with an enhanced annealing optimizer. The ground water flow and transport simulators provide the ability to consider site‐specific contamination and geohydrologic conditions directly in the assessment of alternative remediation system designs. The optimizer facilitates analysis of tradeoffs between technical, environmental, regulatory, and financial risks for alternative design and operation scenarios. A ground water management model using an optimization method referred to as “enhanced annealing” (simulated annealing enhanced to include “directional search” and “memory” mechanisms) has been developed and successfully applied to an actual restoration problem. The demonstration site is the contaminated unconfined aquifer referred to as N‐Springs located at Han‐ford, Washington. Results of the demonstration show the potential for improving groundwater restoration system performance while reducing overall system cost.     

污染场地风险管控环境经济政策体系：国外经验与本土实践

快速城市化和工业化给我国带来了大量的场地污染问题,污染场地修复和风险管控成为国土资源可持续利用的重要领域,创新土壤污染防治经济政策,充分发挥市场调节作用是土壤污染防治的内在要求,是破解土壤生态环境问题、推进土壤污染防治管理转型的重要支撑。本文从经济政策的体系、投融资模式与机制等方面展开,对美国、德国、荷兰等发达国家的污染场地风险管控环境经济政策进行了梳理分析,总结其可借鉴的成功经验;介绍了我国污染场地风险管控环境经济政策实施现状,最终从完善调控体系、明晰权责归属、拓宽资金来源、规范资金运营、丰富投融资模式、探索费用效益分析机制等方面提出我国污染场地风险管控环境经济政策体系的改进建议。     

A Framework for Net Environmental Benefit Analysis for Remediation or Restoration of Contaminated Sites

Net environmental benefits are gains in value of environmental services or other ecological properties attained by remediation or ecological restoration minus the value of adverse environmental effects caused by those actions. Net environmental benefit analysis (NEBA) is a methodology for comparing and ranking net environmental benefits associated with multiple management alternatives. A NEBA for chemically contaminated sites typically involves comparison of several management alternatives: (1) leaving contamination in place; (2) physically, chemically, or biologically remediating the site through traditional means; (3) improving ecological value through onsite and offsite restoration alternatives that do not directly focus on removal of chemical contamination; or (4) a combination of those alternatives. NEBA involves activities that are common to remedial alternatives analysis for state regulations and the Comprehensive Environmental Response, Compensation, and Liability Act, post-closure and corrective action permits under the Resource Conservation and Recovery Act, evaluation of generic types of response actions pertinent to the Oil Pollution Act, and land management actions that are negotiated with regulatory agencies in flexible regulatory environments (i.e., valuing environmental services or other ecological properties, assessing adverse impacts, and evaluating remediation or restoration options). This article presents a high-level framework for NEBA at contaminated sites with subframeworks for natural attenuation (the contaminated reference state), remediation, and ecological restoration alternatives. Primary information gaps related to NEBA include nonmonetary valuation methods, exposure–response models for all stressors, the temporal dynamics of ecological recovery, and optimal strategies for ecological restoration.Published online     

地下水DNAPLs污染的研究进展

地下水有机污染特别是DNAPLs污染是当前国际上地下水污染控制的热点问题。本文综述了DNAPLs的监测技术、DNAPL在含水层的迁移及DNAPb污染场地修复技术的研究进展。     

Risk-based economic decision analysis of remediation options at a PCE-contaminated site

Remediation methods for contaminated sites cover a wide range of technical solutions with different remedial efficiencies and costs. Additionally, they may vary in their secondary impacts on the environment i.e. the potential impacts generated due to emissions and resource use caused by the remediation activities. More attention is increasingly being given to these secondary environmental impacts when evaluating remediation options. This paper presents a methodology for an integrated economic decision analysis which combines assessments of remediation costs, health risk costs and potential environmental costs. The health risks costs are associated with the residual contamination left at the site and its migration to groundwater used for drinking water. A probabilistic exposure model using first- and second-order reliability methods (FORM/SORM) is used to estimate the contaminant concentrations at a downstream groundwater well. Potential environmental impacts on the local, regional and global scales due to the site remediation activities are evaluated using life cycle assessments (LCA). The potential impacts on health and environment are converted to monetary units using a simplified cost model.A case study based upon the developed methodology is presented in which the following remediation scenarios are analyzed and compared: (a) no action, (b) excavation and off-site treatment of soil, (c) soil vapor extraction and (d) thermally enhanced soil vapor extraction by electrical heating of the soil. Ultimately, the developed methodology facilitates societal cost estimations of remediation scenarios which can be used for internal ranking of the analyzed options. Despite the inherent uncertainties of placing a value on health and environmental impacts, the presented methodology is believed to be valuable in supporting decisions on remedial interventions.     

Remediation of contaminated land and groundwater: experience in England and Wales

Remediation of contaminated land and groundwater is of common international concern. The context and approach taken to the problem are, however, country-specific. A survey of remedial activity occurring within England and Wales over the period 1996-1999 was commissioned by the Environment Agency (for England and Wales) to establish a baseline against which future trends in remedial activity could be judged. This paper: explains the context of contaminated land and groundwater remediation in England and Wales (Britain); provides an overview of the 1996-1999 survey of remedial activity, discussing its findings within its legislative and institutional context; and, discusses the survey results of significance to the management of contaminated land and groundwater internationally. The survey obtained specific data from 367 remediated sites supplemented by general data from a further 1189 contaminated (not necessarily remediated) sites. The survey aimed to be, and was indicative of remediation practice, and did not seek to identify every remediation scheme operating. Previous anecdotal evidences were generally confirmed. Civil engineering-based techniques dominated and were used at 94% of sites with in situ techniques (predominantly vapour extraction-based) on 16% and ex situ on just 5%. Although disposal to landfill was dominant and occurred at over 80% of sites, integrated use of multiple techniques was common. Remediation was predominantly of soil (rather than water), development-based, designed to protect human health and reflected national development-led and 'suitable for use' policies. Lessons of international relevance from the survey and general British experience are drawn concerning remediation technique selection, regulatory and financial support of innovative remediation techniques and demonstration sites, competent use of risk-based approaches to allow pragmatic remediation and effective use of quality guidelines, need for effective guidance to highlight water quality issues, the necessity of post remediation monitoring to prove remediation effectiveness and the keeping of remediation databases.     

THE USE OF BINARY OPTIMIZATION AND HYDROLOGIC MODELS TO FORM RIPARIAN BUFFERS1

ABSTRACT: Riparian buffers are considered important management options for protecting water quality. Land costs and buffer performance, which are functions of local environmental characteristics, are likely to be key attributes in the selection process, especially when budgets are limited. In this article we demonstrate how a framework involving hydrologic models and binary optimization can be used to find the optimal buffer subject to a budget constraint. Two hydrologic models, SWAT and REMM, were used to predict the loads from different source areas with and without riparian buffers. These loads provided inputs for a binary optimization model to select the most cost efficient parcels to form a riparian buffer. This methodology was applied in a watershed in Delaware County, New York. The models were parameterized using readily available digital databases and were later compared against observed flow and water quality data available for the site. As a result of the application of this method, the marginal utility of incremental increases in buffer widths along the stream channel and the set of parcels to form the best affordable riparian buffer were obtained.     

Integrating Environmental Restoration and Ecological Restoration: Long-Term Stewardship at the Department of Energy

With the ending of the Cold War, several federal agencies are reclaiming land through remediation and restoration and are considering potential future land uses that are compatible with current uses and local needs. Some sites are sufficiently contaminated that it is likely that the responsible federal agency will retain control over the land for the foreseeable future, providing them with a stewardship mission. This is particularly true of some of the larger Department of Energy (DOE) facilities contaminated during the production of nuclear weapons. The use of the term “restoration” is explored in this paper because the word means different things to the public, ecologists, and environmental managers responsible for contaminated sites, such as Superfund sites and the DOE facilities. While environmental restoration usually refers to remediation and removal of hazardous wastes, ecological restoration refers to the broader process of repairing damaged ecosystems and enhancing their productivity and/or biodiversity. The goals of the two types of restoration can be melded by considering environmental restoration as a special case of ecological restoration, one that involves risk reduction from hazardous wastes, and by broadening environmental restoration to include a more extensive problem-formulation phase (both temporal and spatial), which includes the goal of reestablishing a functioning ecosystem after remediation. Further, evaluating options for the desired post remediation result will inform managers and policy-makers concerning the feasibility and efficacy of environmental restoration itself.     

A Conflict-Resolution Model for the Conjunctive Use of Surface and Groundwater Resources that Considers Water-Quality Issues: A Case Study

The conjunctive use of surface and groundwater resources is one alternative for optimal use of available water resources in arid and semiarid regions. The optimization models proposed for conjunctive water allocation are often complicated, nonlinear, and computationally intensive, especially when different stakeholders are involved that have conflicting interests. In this article, a new conflict-resolution methodology developed for the conjunctive use of surface and groundwater resources using Nondominated Sorting Genetic Algorithm II (NSGA-II) and Young Conflict-Resolution Theory (YCRT) is presented. The proposed model is applied to the Tehran aquifer in the Tehran metropolitan area of Iran. Stakeholders in the study area have conflicting interests related to water supply with acceptable quality, pumping costs, groundwater quality, and groundwater table fluctuations. In the proposed methodology, MODFLOW and MT3D groundwater quantity and quality simulation models are linked with the NSGA-II optimization model to develop Pareto fronts among the objectives. The best solutions on the Pareto fronts are then selected using YCRT. The results of the proposed model show the significance of applying an integrated conflict-resolution approach to conjunctive use of surface and groundwater resources in the study area.     

A technicoeconomic approach for the selection of a site remediation strategy--part A: theory

A technicoeconomic model is developed to select an optimal strategy for the remediation of a contaminated site and to determine the value of this remediation strategy. The model is an extension of actual cost-benefit analysis, with consideration of "irreversible" remediation technology choices, technology effectiveness, and uncertainty on the site's level of contamination. The model considers the possibility of reducing uncertainty by both acquiring more and better information on the level of contamination and by offering the decision-maker the opportunity to reevaluate his decision and switch to a more appropriate technology. It is believed that this model will help decision-makers in the selection of a remediation strategy by presenting all potentially feasible strategies, and how uncertainty on the site's level of contamination affects these strategies.     

Remediation technologies for heavy metal contaminated groundwater

The contamination of groundwater by heavy metal, originating either from natural soil sources or from anthropogenic sources is a matter of utmost concern to the public health. Remediation of contaminated groundwater is of highest priority since billions of people all over the world use it for drinking purpose. In this paper, thirty five approaches for groundwater treatment have been reviewed and classified under three large categories viz chemical, biochemical/biological/biosorption and physico-chemical treatment processes. Comparison tables have been provided at the end of each process for a better understanding of each category. Selection of a suitable technology for contamination remediation at a particular site is one of the most challenging job due to extremely complex soil chemistry and aquifer characteristics and no thumb-rule can be suggested regarding this issue. In the past decade, iron based technologies, microbial remediation, biological sulphate reduction and various adsorbents played versatile and efficient remediation roles. Keeping the sustainability issues and environmental ethics in mind, the technologies encompassing natural chemistry, bioremediation and biosorption are recommended to be adopted in appropriate cases. In many places, two or more techniques can work synergistically for better results. Processes such as chelate extraction and chemical soil washings are advisable only for recovery of valuable metals in highly contaminated industrial sites depending on economical feasibility.     

A Proactive Approach Can Make Site Remediation Less Expensive

Without any incentive to clean up a contaminated site, remediation is often delayed until the site owner is compelled to act by regulatory agencies. In such a context, the selected technology is typically the one that will reach the remediation goals as quickly as possible. Unfortunately, this criterion is often met by overly expensive technologies, resulting in high and sometimes unaffordable total remediation costs, leading to a remediation with a negative net benefit. This study examines the effects of time constraint and benefit value on the optimal remediation strategy for a diesel-contaminated site. This strategy is developed using the technico-economic model METEORS, which takes into account the technology’s effectiveness, the uncertainty of the level of contamination, and the possibility of reducing this uncertainty through either an additional characterization (before selecting and applying a technology) or the monitoring of the remediation technology (during its use). Results of simulations with both economic and temporal constraints support a proactive approach to site remediation.     

IDENTIFICATION OF AN OPTIMAL GROUNDWATER MANAGEMENT STRATEGY IN A CONTAMINATED AQUIFER1

A groundwater hydraulic management model is used to identify the optimal strategy for allocating limited fresh-water supplies and containing wastes in a hypothetical aquifer affected by brine contamination from surface disposal ponds. The present cost of pumping from a network of potential supply and interception wells is minimized over a five-year planning period, subject to a set of hydraulic, institutional, and legal constraints. Hydraulic constraints are formulated using linear systems theory to describe drawdown and velocity variables as linear functions of supply and interception well discharge decision variables. Successful validation of the optimal management strategy suggests that the model formulation can feasibly be applied to define management options for locally contaminated aquifer systems which are used to fulfill fresh-water demands.     

A Technicoeconomic Approach for the Selection of a Site Remediation Strategy—Part A: Theory

A technicoeconomic model is developed to select an optimal strategy for the remediation of a contaminated site and to determine the value of this remediation strategy. The model is an extension of actual cost–benefit analysis, with consideration of “irreversible” remediation technology choices, technology effectiveness, and uncertainty on the site's level of contamination. The model considers the possibility of reducing uncertainty by both acquiring more and better information on the level of contamination and by offering the decision-maker the opportunity to reevaluate his decision and switch to a more appropriate technology. It is believed that this model will help decision-makers in the selection of a remediation strategy by presenting all potentially feasible strategies, and how uncertainty on the site's level of contamination affects these strategies.     

GROUND WATER SOLUTE TRANSPORT,OPTIMAL REMEDIATION PLANNING,AND DECISION MAKING UNDER UNCERTAINTY1

ABSTRACT: A groundwater quality modeling advisory system has been developed for the U.S. Air Force for use in investigating remediation alternatives for the cleanup of subsurface contamination. The system is capable of accounting for uncertainty, not only in the prediction of solute transport but also in the optimization of the remediation scheme through chance constraints. The system guides users in the selection of appropriate transport models through an algorithm independently tested with machine learning codes. An application to Hill Air Force Base, Utah, is presented for which different pump-and-treat strategies are considered: the results are evaluated in terms of the cumulative distribution of the contaminant concentration for each case and the tradeoff relationship between the cost of remediation and the probability that the remediation strategy exceeds an established maximum allowable contaminant concentration.     

Shifting Priorities at the Department of Energy's Bomb Factories: Protecting Human and Ecological Health

More than 50 years of research, development, manufacture, and testing of nuclear weapons at Department of Energy (DOE) sites has left a legacy of on-site contamination that often spreads to surrounding areas. Despite substantial cleanup budgets in the last decade, the DOE's top-to-bottom review team concluded that relatively little actual cleanup has been accomplished, although milestones have been met and work packages completed. Rather than solely use regulatory constraints to direct cleanup, many people have suggested that human and ecological health should guide long-term stewardship goals of DOE-managed sites. The main questions are how ecological and human health considerations should be applied in deciding the extent of cleanup that contaminated sites should receive and how near-term and longer run considerations of costs and benefits should be balanced as cleanup decisions are made. One effort to protect ecological integrity is the designation of the largest sites as National Environmental Research Parks (NERPs). Recently, the Competitive Enterprise Institute (CEI) suggested isolating and conserving DOE sites as a policy priority because of their rich ecological diversity. A more effective long-term stewardship approach for former nuclear weapons complex sites may emerge if the guiding principles are to (1) reduce risks to human and ecological health, (2) protect cultural traditions, and (3) lower short- and long-term cleanup and remediation costs. A “net benefits” perspective that takes both near- and longer-term costs and consequences into account can help illuminate the trade-offs between expensive cleanup in the near term and the need to assure long-term protection of human health, cultural values, and high levels of biodiversity and ecological integrity that currently exist at many DOE sites.     

LONG-TERM GROUNDWATER MANAGEMENT BY A MODFLOW BASED DYNAMIC OPTIMIZATION TOOL1

ABSTRACT: This paper describes a computer-aided tool for selecting optimal management policies involving groundwater hydraulics over a large number of management periods. The tool, referred to as DOMODF, uses a dynamic optimization algorithm linked to an existing popular groundwater flow simulation code MODFLOW. It combines the expert knowledge of management policies with the effectiveness of optimization oriented search technique. Due to the dynamic nature of the search technique implemented in DOMODF, it is effective in dealing with long-term decision making problems. DOMODF can be used as a guidance tool for finding desirable policies to achieve various groundwater management objectives, leading to considerable savings in management costs over those predicted by currently available policies that are fed into the tool as input. The preliminary test results show the promising potential of DOMODF as an effective long-term groundwater management tool.     

Eco-efficiency in contaminated land management in Finland – Barriers and development needs

In Finland the number of potentially contaminated sites totals ca. 20?000. The annual costs of remediation are 60–70 million euros. Excavation combined with disposal or off-site treatment is the most common soil remediation method. To define which factors make contaminated land management (CLM) eco-efficient and to study whether eco-efficiency has been considered in CLM decisions we carried out a literature survey, two stakeholder seminars, thematic interviews and a questionnaire study on economic instruments. Generally speaking, eco-efficiency means gaining environmental benefits with fewer resources. To assess its realization in CLM, it is necessary to have a more specific definition. In our study, we arrived at a list of several qualifications for eco-efficiency. It was also shown that eco-efficiency has hardly been a real issue in the selection of remediation techniques or generally, in the decision-making concerning contaminated sites. The existing policy instruments seem to be insufficient to promote eco-efficiency in CLM. Several concrete barriers to eco-efficiency also came up, urgency and lack of money being the most important. The scarcity of the use of in situ remediation methods and the difficulties involved in recycling slightly contaminated or treated soil were considered to be major problems. Insufficient site studies, inadequate or unsuitable methods for risk assessment and cost evaluation, and deficient and mistimed risk communication can also hinder the realization of eco-efficiency. Hence, there is a need to promote the use of more eco-efficient remediation techniques and to develop CLM policy instruments, guidelines, and participatory processes and methods to assess the eco-efficiency of CLM options.     

The “Short Cut” Approach for the Reality of Enhanced Groundwater Contamination

Based on the reality of (a) soil heterogeneity in the vadose zone, (b) enhanced desorption from soil and solubility in water of water insoluble contaminants in the presence of surfactants, and (c) wetting/drying cycles of groundwater recharge (a major cause of fractures formation), a coherent “short-cut” conceptual approach is advanced to account for enhanced groundwater contamination. This is an attempt to close the gap between theory, lab simulations and conventional modelling-based predictions, and observed higher concentrations and more rapid arrival times of contaminants reaching groundwater. Recent data concerning chloride ion and non-ionic surfactants concentrations in aquifers and groundwater wells, combined with previous results concerning the concentrations of tritium, chlorides, metals, organic hydrocarbons and surfactants in the unsaturated and saturated zones of Israel's aquifers, are accounted for in terms of the “short-cut” approach. The contradiction between predictions of groundwater contamination made with conventional, deterministic, homogeneous models and the actual observed behavior of contaminants in soils and aquifers is thus explaind. The “short cut” approach should not be perceived as a better type of model to guide modelling. Rather, it is a proposal for a conceptual change from the realistically invalid, but commonly accepted, conventional “buffer-protective soil/long-term groundwater contamination” to the “short cut” conceptual model to explain the enhanced groundwater contamination actually observed. Although the validity of the proposed approach is strongly supported by the data here presented for the case of Israel (serving as an illustrative case study), selected results and conclusions drawn from studies conducted worldwide suggest its general applicability and usefulness. A major conclusion evolved from the “short-cut” conceptual model is that contemporary groundwater management policies, based on the current perception of groundwater contamination processes and their modelling, may result in an irreversible detrimental effect on the environmental situation in the long run. In any case, prevention, rather than correction/remediation, is strongly recommended as the strategy of choice for rational long-term management of groundwater resources.