Optimal design of additional sampling pattern for drinking-water quality control

A crucial step in complementary studies of the water quality determination is to design the additional sampling pattern or, in other words, to determine the number and location of the additional samples. Since location and number of samples highly affect decisions’ uncertainties, and because sampling process is quite costly and time-consuming, optimization of the sampling pattern will enhance the efficiency and productivity. Solution of such an optimization problem requires defining an objective function and constraints. There exist many previous studies regarding locating additional samples in other environmental problems wherein the objective function is defined as the minimization of the kriging variance (based on the problem nature), but the point is that kriging variance is not sensitive to local variability. Since manner and extent of small-scale variations are both important and necessary in water quality studies, it is required to resolve this shortcoming of the traditional objective function. Solution is to make use of the combined variance consisting of kriging and local variances. In this study, the applicability and efficiency of the minimization of combined variance as the objective function of the additional sampling was adopted and proved for a salt marsh (east of Iran) on the basis of a simulated annealing-based algorithm. It was shown, practically, that the locational distribution of additional sampling points is quite logical and more compatible with experts’ proposed methods using this objective function (compared to the traditional one).     

Determining sediment quality for regulatory proposes using fish chronic bioassays

Sediment quality assessments for regulatory purposes (i.e. dredged material disposal) are characterized by linking chemical and acute ecotoxicological data. The design of chronic bioassays that incorporate more sensible endpoints than acute tests is discussed to address sediment quality for environmental quality assessment and regulatory proposes. The chronic tests use juveniles of commercial species of fish Sparus aurata and Solea senegalensis, to assess sediment toxicity in samples collected along different littoral areas in the North and the South of Spain. The organisms were exposed during 60 days and sublethal endpoints were selected including biomarkers of exposure to metals (metallothioneins - MTs) and to organic contaminants (ethoxyresorufin-O-deethylase activity - EROD activity) and biomarkers of effect (histopathology in different tissues, gill and liver). A Multivariate Analysis Approach was conducted in order to associate these biological responses with sediment metal concentration from the ports and with chemical residues in biological tissues exposed to sediments under laboratory conditions.     

Optimisation of sampling for the temporal monitoring of technetium-99 in the Arctic marine environment

Monitoring of the marine environment for radioactivity, for both radiological protection and oceanographic purposes, remains an expensive and labour intensive activity due to the large sample volumes needed and the complex and lengthy analytical procedures required to measure low levels of contamination. Because of this, some consideration must be given to the design of sampling plans to ensure effective and efficient sampling that can be defended on the basis of scientific rationale. This article tests the hypothesis that geostatistical techniques may prove of use in the optimisation and design of sampling regimes for the monitoring of temporal fluctuations in the levels of technetium at a location in the Norwegian Arctic marine environment. The level of temporal correlation exhibited by two relevant time series was investigated and the information used to observe the effect of sampling frequency on the production of monthly estimates of activity of technetium in both seawater and seaweed. The results indicate that reduced sampling frequency allows production of estimates that acceptably replicate the actual data and that use of geostatistical procedures may offer advantages in the planning of monitoring systems for marine radioactivity. The use of an oceanographic model was also investigated as a means of assessing the temporal correlation prior to actual sampling, an approach that may offer significant advantages by reducing the need to have lengthy time series prior to designing sampling regimes.     

A linear and nonlinear approach for interpretation of groundwater quality based on water quality index

In this study using linear and nonlinear approach, aggregate indices for various water quality parameters were analyzed. Using a linear and nonlinear interpolating surface, various water quality variables at grid points were investigated that is essential for mapping. The values help in constituting a key approach for determining the water quality index (WQI), which converts pollutant concentration data into subindex values and then combines them into a single score. One of the biggest advantages of WQI is its summary and intuitive communication capability which will be extremely helpful for demarcating safe aquifer zones of groundwater and in the selection of suitable method for remedial. The present study also describes pollution potential in ground water of Madhya Pradesh, India. The aggregate indices suggest intermediate to high pollution susceptibility in some region of Madhya Pradesh that may increase further if not managed. The overall interpretation of the study will be helpful in formulating suitable approach for water quality interpretation and sustainable planning of groundwater resources.     

Novel approach to monitoring of the soil biological quality

In this study, a new approach to interpretation of results of the simple microbial biomass and respiration measurements in the soil microbiology is proposed. The principle is based on eight basal and derived microbial parameters, which are standardized and then plotted into sunray plots. The output is visual presentation of one plot for each soil, which makes possible the relative comparison and evaluation of soils in the monitored set. Problems of soil microbiology, such as the lack of benchmarking and reference values, can be avoided by using the proposed method. We found that eight parameters provide enough information for evaluation of the status of the soil microorganisms and, thus, for evaluation of the soil biological quality. The usage of rare parameters (potential respiration PR, ratio of potential and basal respiration PR/BR, biomass-specific potential respiration PR/C(bio), available organic carbon C(ext), and biomass-specific available organic carbon C(ext)/C(bio)) can be recommended, besides classical and well-known parameters (microbial biomass C(bio), basal respiration BR, metabolic coefficient qCO(2)). The combination of basal parameters and derived coefficients can also extend our knowledge about the condition of the soil microorganisms. In monitoring the case studies presented, we observed that soils evaluated to possess good biological quality displayed generally higher values of organic carbon, total nitrogen, clay, and cation exchange capacity. The soils of good biological quality can display higher levels of contaminants. This is probably related with the higher content of organic carbon and clay in these soils.     

Impacts of climate change on surface water quality in relation to drinking water production

Besides climate change impacts on water availability and hydrological risks, the consequences on water quality is just beginning to be studied. This review aims at proposing a synthesis of the most recent existing interdisciplinary literature on the topic. After a short presentation about the role of the main factors (warming and consequences of extreme events) explaining climate change effects on water quality, the focus will be on two main points. First, the impacts on water quality of resources (rivers and lakes) modifying parameters values (physico-chemical parameters, micropollutants and biological parameters) are considered. Then, the expected impacts on drinking water production and quality of supplied water are discussed. The main conclusion which can be drawn is that a degradation trend of drinking water quality in the context of climate change leads to an increase of at risk situations related to potential health impact.     

Development of coastal recreational water quality standards in the Mediterranean

Concern about adverse health effects arising out of human exposure to polluted seawater through bathing and other forms of aquatic recreation has led to the development of various quality criteria and standards worldwide. Attempts at quantifying health hazards from polluted recreational waters have been made in several Mediterranean countries through the conduction of epidemiological studies aimed at establishing direct correlation between the microbiological quality of the water and health effects on exposed population groups. This article provides an overview on the development of the criteria and standards for coastal recreational waters in the Mediterranean by examining the evolution of the WHO guidelines, the WHO/UNEP interim criteria for bathing waters and the EU Directives. It also provides a brief account of the various quality criteria and standards for coastal recreational waters in current use in all the Mediterranean countries.     

Drinking water quality: An in vitro approach for the assessment of cytotoxic and genotoxic load in water sampled along distribution system

An in vitro approach was performed to assess the quality of drinking water collected at two treatment/distribution networks located near the source (Plant #1) and the mouth of River Po (Plant #2). The water was sampled at different points of each distribution network, before (raw water) and after the chlorine dioxide disinfection, and in two points of the pipeline system to evaluate the influence of the distribution system on the amount and quality of the disinfection by-product. Cytotoxicity and genotoxicity of water extracts were evaluated in human peripheral lymphocytes and Hep-G2 cells by the use of the micronucleus (MN) test and Comet assay. Raw water samples of both plants induced cytotoxic effects, but not the increases of MN frequency in Hep-G2 cells and in human lymphocytes. Increases of DNA damage in human leukocytes was detected by Comet assay for raw water of Plant #2 at concentration ≥ 0.25 Leq/mL. The disinfection process generally has reduced the toxicity of water samples, even if potential direct DNA-damaging compounds have been detectable in drinking water samples. The proposal approach, if currently used together with chemical analysis, can contribute to improve the monitoring drinking water.     

Air quality management in the WHO European Region--results of a quality assurance and control programme on air quality monitoring (1994-2004)

Since the last decade the WHO Collaborating Centre for Air Quality Management and Air Pollution Control, Berlin, Germany, operates a quality assurance and control (QA/QC) programme on air quality monitoring in the WHO European Region. As main activity Intercomparison workshops have been established for air monitoring network laboratories on a regular basis to harmonise air quality measurements, analysis and calibration techniques. 36 air hygiene laboratories of public health and environmental institutions of 24 countries participated in twelve Intercomparisons between 1994 and 2004. The majority was carried out for NO, NO(2), SO(2) and O(3). The results were predominantly satisfactory for automatic methods. The results of manual methods were mainly in a good, and for several concentration levels partly very good accordance with the data obtained by the monitors.     

Assessment of physicochemical characteristics of Ganga Canal water quality in Uttarakhand

Assessment of physicochemical parameters of Ganga Canal water was carried out during 2012–2013 at Haridwar (Uttarakhand) with two different sites, i.e., Bhimgoda Barrage (site 1—control site) and Bahadrabad (site 2—contaminated site), where canal water flows with loads of pollution from highly commercial and industrial areas. During investigation, maximum turbidity (287.72 ± 56.28 JTU), total solids (1167.60 ± 303.90 mg l^?1), free CO₂ (1.88 ± 0.22 mg l^?1), total hardness (60.14 ± 1.13 mg l^?1), pH (7.1 ± 0.13), nitrate (0.048 ± 0.010), nitrite (0.019 ± 0.001), biochemical oxygen demand (2.866 ± 1.098), chemical oxygen demand (6.8 ± 2.61) and phosphate (0.087 ± 0.015), while minimum velocity (1.71 ± 0.19 ms^?1), transparency (0.12 ± 0.08 m) and dissolved oxygen (7.95 ± 0.44 mg l^?1) were recorded in monsoon season at site 2 in comparison with site 1. The mean values of these parameters were compared with WHO and ISI standards and found significant differences (p < 0.05) in the mean values of turbidity, total solids, pH, dissolved oxygen, free CO₂ and total hardness with sampling sites. The turbidity of both the sites 1 and 2 was recorded above the permissible limit. Turbidity of site 2 is much higher than of site 1, so it is counted as more polluted. The values of the studied parameters were more during monsoon season and summer season at site 2 as compared to site 1. The results indicated that most of the physicochemical parameters from Ganga Canal system were within or at periphery in comparison with permissible limit of ISI and WHO for drinking water and therefore may be suitable for domestic purposes, but it requires perceptible consideration due to intense changes in climate and increase in pollution.     

Setting up the criteria and credit-awarding scheme for building interior material selection to achieve better indoor air quality

Methods, standards, and regulations that are aimed to reduce indoor air pollution from building materials are critically reviewed. These are classified as content control and emission control. Methods and standards can be found in both of these two classes. In the regulation domain, only content control is enforced in some countries and some regions, and asbestos is the only building material that is banned for building use. The controlled pollutants include heavy metals, radon, formaldehyde, and volatile organic compounds (VOCs). Emission rate control based upon environment chamber testing is very much in the nature of voluntary product labeling and ranking, and this mainly targets formaldehyde and VOC emissions. It is suggested that radon emission from building materials should be subject to similar emission rate control. A comprehensive set criteria and credit-awarding scheme that encourages the use of low-emission building material is synthesized, and how this scheme can be practiced in building design is proposed and discussed.     

Assessment of air quality in Turin by personal monitoring of nonsmokers for respirable suspended particles and environmental tobacco smoke

Exposure to respirable suspended particles (RSP), environmental tobacco smoke (ETS) particles, nicotine, and 3-ethenylpyridine (3-EP) was assessed in Turin for 188 subjects during February and March 1995. Personal monitors were worn over a 24-h period, each subject providing a saliva sample for cotinine analysis both prior to and following the monitoring period. Comprehensive lifestyle questionnaires were also completed before and after the 24-h monitoring period. The study comprised housewives in one group, primarily for assessing exposures in the home, and office workers in a second group to assess exposures in the workplace. A single personal monitor was worn by each participating housewife, while employed subjects wore one monitor at work and a separate monitor at home and elsewhere. Based on median 24-h time-weighted average exposures, the most highly exposed subjects to RSP, ETS particles, nicotine, and 3-EP were office workers living with smokers and employed in locations where smoking was allowed. Annualised exposures for nonsmokers living and working in smoking environments indicate that the home contribution to RSP is between 3 and 4 times that obtained from the workplace. Similarly nicotine and ETS particle contributions from the home are, respectively, 4 and 7 times more than those obtained from the workplace. Subjects living and working with smokers had the highest median saliva cotinine levels of 1.7 ng mL⁻¹. Using a cut off level of 25 ng mL⁻¹, up to 6.5% of subjects were found to have misreported themselves as nonsmokers.     

BOD-DO modeling and water quality analysis of a waste water outfall off Kochi, west coast of India

Water quality scenarios around an offshore outfall off Kochi were simulated using MIKE21 water quality model, assuming a high Biochemical Oxygen Demand (BOD=50 mg l(-1)) effluent discharge. The discharge is introduced into the model through an outfall located at a distance of 6.8 km from the shore at a depth of 10 m. Three scenarios were simulated with different discharge rates such as 2, 5 and 10 m3 s(-1), with BOD load of 8640, 21,600 and 43,200 kg day(-1) respectively. Model simulations were carried out to estimate the assimilation capacity of the waters off Kochi for the three discharge rates. The results show that for 10 m3 s(-1) effluent discharge, the initial BOD of 50 mg l(-1) reduced to 3.33 mg l(-1) at the outfall after 48 h. High BOD values were confined to an elliptical area of approximately 8 km2 around the outfall. Based on this, the assimilative capacity of the waters off Kochi in terms of BOD can be estimated as 38,000 kg day(-1). It is suggested that offshore waters could be used as a feasible alternative to the Kochi backwaters for the disposal of treated effluent.     

Shifting drivers and static baselines in environmental governance: challenges for improving and proving water quality outcomes

Understanding the conditions that enable or constrain success in environmental governance is crucial for developing effective interventions and adapting approaches. Efforts to achieve and assess success in environmental quality improvement are often impeded by changes in conditions that drive outcomes but lie outside the scope of intervention and monitoring. We document how long-term changes in land use, agriculture, and climate act as non-stationary, shifting drivers of change that combine to render water quality management interventions less effective and increasingly difficult to assess. Focusing on the Yahara River watershed of south-central Wisconsin, USA, we ask how baselines influence program modeling, monitoring, and evaluation, as well as adaptation in governance approach. Through historical trend, GIS, and policy and qualitative data analyses, we find that changes in long-term land use and precipitation pattern dynamics exert tremendous pressure on water quality outcomes but are not captured in snapshot baseline assessments used in management planning or evaluation. Specifically, agricultural sector change related to the intensification of milk and manure production is increasingly challenging to address through best management practices, and flashier precipitation associated with climate change makes it difficult to achieve goals and establish a causal connection between management interventions and outcomes. Analysis of shifting drivers demonstrates challenges facing environmental governance in the context of climatic and social–ecological change. We suggest that goal setting, program design, and evaluation incorporate new modes of analysis that address slowly changing and external determinants of success.     

Radiological assessment of surface water quality around proposed uranium mining site in India

The gross alpha and gross beta activities were estimated for radiological assessment of surface water quality around the proposed uranium mining site Kylleng Pyndengsohiong Mawthabah (Domiasiat), West Khasi Hills District, Meghalaya situated in a high rainfall area (12,000 mm) in India. 189 Surface water samples were collected over different seasons of the year from nine different locations covering around 100 km². Gross beta activities were found to vary from 144 to 361 mBq/L which is much below the prescribed WHO limit of 1000 mBq/L for drinking water. Gross alpha activities varied from 61 to 127 mBq/L. These values are much below the reported gross alpha values by other countries. In about 7% of the samples the alpha activities remain exceeded the WHO guideline limit of 100 mBq/L. Surface water samples collected during the summer season of the year show higher activity whereas low activity was found from samples collected during monsoon season. Results show that all water sources are acceptable as drinking water for human consumption from the radiological point of view, the higher gross alpha concentrations in a few locations remains so only for short duration during the summer season.     

Effect of Nile River water quality on algal distribution at Cairo,Egypt

Changes of phytoplankton density and their relation to physicochemical characteristics along the Nile River have been noted in the Cairo district between 1976 and 1982. Three major phytoplankton groups were found to dominate the river Nile: green algae, blue-green algae, and diatoms. Diatoms represent the most dominant group and comprised from 42% to 96% of the phytoplankton community during the investigated period. Blue-green algae comprised from 0.7% to 48% of total cell number. Green algae represent the low percentage group, which ranges from 0.2% to 41% of Nile water algae. High species diversity (H′) was detected in green algae (1.22) followed by diatoms (0.84); the lowest diversity was in blue-green algae (0.45). The density of total phytoplankton count fluctuated between 10⁶ and 10⁷ organism/L. The concentration of chlorophyll-a ranged from 5 to 37 mg/m³. Primary production rates in the Nile River ranged from 8.5 to 52 mg O₂/m³h. Statistical analysis revealed significant positive correlations between chlorophyll-a content, and concentrations of phosphoruss and nitrate. Phytoplankton diversity, primary production, ammonia, and nitrite content revealed that there is no indication of pollution in the Nile.     

Quantity and quality modelling of groundwater to manage water resources in Isfahan-Borkhar Aquifer

Environment, Development and Sustainability - Groundwater resources are increasingly exposed to significant overexploitation in many parts of the world, markedly in Iran, one of the most arid...