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超临界水氧化法处理有机污染物 总被引:13,自引:1,他引:13
介绍了超临界水氧化法处理有机污染物的基本原理,工艺流程和应用实例及使用范围,对比分析了超临界水氧化法与焚烧法处理有机污染物的技术特点,经济实用性,指明了超临界水氧化法作为一种有效的有机污染物处理方法,在化工环保等领域将具有广阔的应用前景。 相似文献
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《化工环保》2001,21(6):372
美国得克萨斯洲Harlingen市建成第一套超临界水污泥处理装置,现正进行试运行,待第二套装置建成后,污泥总处理能力约为35000加仑/d(污泥固体质量分数为7%~8%),可处理掉2座城市污水处理场和1座工业废水处理场产生的全部污泥. 这是超临界水氧化法首次工业化用于处理污水场污泥.在1100、3400磅/英寸2及有氧存在的条件下,有机物被氧化成二氧化碳和水,重金属被氧化成不能被滤出的状态. 该装置的投资为300万美元,污泥(干泥)处理费约为180美元/t,而土地施用法和土地填埋法对污泥的处置费用为275美元/t .该装置处理1 t干泥产生的废热及CO2产品可销售120美元,从而使处理费用降至60美元/ t. (以上由陈殿英供稿) 相似文献
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Waste printed circuit boards (PCBs) contain a large number of metals such as Cu, Sn, Pb, Cd, Cr, Zn, and Mn. In this work, an efficient and environmentally friendly process for metals recovery from waste PCBs by supercritical water (SCW) pre-treatment combined with acid leaching was developed. In the proposed process, waste PCBs were pre-treated by SCW, then the separated solid phase product with concentrated metals was subjected to an acid leaching process for metals recovery. The effect of SCW pre-treatment on the recovery of different metals from waste PCBs was investigated. Two methods of SCW pre-treatment were studied: supercritical water oxidation (SCWO) and supercritical water depolymerization (SCWD). Experimental results indicated that SCWO and SCWD pre-treatment had significant effect on the recovery of different metals. SCWO pre-treatment was highly efficient for enhancing the recovery of Cu and Pb, and the recovery efficiency increased significantly with increasing pre-treatment temperature. The recovery efficiency of Cu and Pb for SCWO pre-treatment at 420 °C was 99.8% and 80%, respectively, whereas most of the Sn and Cr were immobilized in the residue. The recovery of all studied metals was enhanced by SCWD pre-treatment and increased along with pre-treatment temperature. Up to 90% of Sn, Zn, Cr, Cd, and Mn could be recovered for SCWD pre-treatment at 440 °C. 相似文献
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Destruction of PAHS from soil by using pressurized hot water extraction coupled with supercritical water oxidation 总被引:4,自引:0,他引:4
Chemical processes utilizing water both as extraction solvent and reaction medium are promising "Green Chemistry" alternatives to conventional techniques. Equipment for on-line coupled hot water extraction and supercritical water oxidation was constructed to extract polyaromatic hydrocarbons and toluene from sea sand followed by oxidation using hydrogen peroxide. The effectiveness of the technique is based on the physico-chemical properties of heated and pressurized water. Extraction efficiency increased with temperature and time; the best results were obtained at 300 degrees C with 40 min extraction time. In the oxidation stage, conversion of the PAHs increased with reaction time and oxidant concentration and the best conversion (97.0-99.9%, depending on the compound) was obtained at 425 degrees C with 43 s reaction time. Benzaldehyde and benzoic acid were the most abundant reaction intermediates in the oxidation process. In addition, phenol, p-cresol, and benzyl alcohol were found as intermediates. The intermediates originated mainly from toluene, which was present in much greater concentration than PAHs in the reaction medium. 相似文献
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徐州电厂超超临界1000MW机组投产后及时采用了给水加氧处理技术,介绍了1号机组给水加氧转换过程、水汽指标的变化情况。加氧处理技术实施后水汽系统含铁量显著降低,精处理混床运行周期延长,加药量减少,效果显著,提高了机组运行的经济性和安全性。 相似文献