TROPHIC LEVEL ACCUMULATION OF HEAVY METALS IN A COAL ASH BASIN DRAINAGE SYSTEM1

ABSTRACT: The uptake of ten chemical elements was measured in water, sediment, fly ash, and the major biotic components of an ash basin drainage system. The biota tested represent several trophic levels observed in the settling basin and receiving swamp of the system. Concentrations were measured by neutron activation (NAA) in the major biotic groups including aquatic bacteria, algae, macrophytes, midges, dragonflies, crayfish, tadpoles, and fish. Only three elements (Cu, Zn, Cd) were more highly concentrated in water from a nearby unpolluted stream than in the fly ash effluent. Sediment concentrations of all elements were highest in the ash drainage system with Al and Fe being consistently highest. Among the biota, Hydrodictyon sp. and Lemna perpusilla had the highest concentrations of Al and Fe while other macrophytes were the major accumulators of Mn and Ba. Invertebrates generally concentrated high amounts of Cu and Zn although Cd and Hg were accumulated most by crayfish. Selenium was selectively concentrated by bacteria, crayfish (Procambarus sp.) and mosquitofish (Gambusia afflnis). Consequences of elemental concentrations in sediment and in specific trophic level groups are discussed.     

Impact of Coal Ash from Electric Power Production on Changes in Water Quality1

ABSTRACT: Since 1972 the use of coal in the U.S. has increased much more rapidly than predicted, with much of this increased use by electric power generating plants. Residue after combustion consists primarily of inorganic materials, with the majority of chemical elements concentrated in fly ash as is sulfate. The concentration of sulfate in this ash fraction most affects the chemical and physical state of other elements when fly ash comes in contact with water by lowering the pH. In a properly constructed and operated ash settling basin, however, major water quality parameters of effluent may be improved as compared to source water. It is necessary, however, to consider the solubility or deposition in sediment of potentially toxic chemical elements from fly ash as these may affect reuse of this water, or as they may impact other parts of the aquatic environment.     

TOXIC METALS IN SURFACE WATERS FROM COAL ASH1

ABSTRACT: The concentration of 10 [titanium (Ti), manganese (Mn), copper (Cu), chromium (CR), zinc (Zn), arsenic (As), selenium (Se), cobalt (Co), cadmium (Cd), and mercury (Hg)] toxic elements were measured in the water, benthic sediment, plants, invertebrates, and vertebrates of an ash basin and its drainage system at a coal-fired power plant of the Savannah River Project, Aiken, S.C., over a period of two years. During 12 months of this period the basin was essentially filled and little settling of ash occurred. In the remaining 12 months, dredging had been completed, adequate settling occurred and most of the effluent turbidity was removed. All elements were more concentrated in sediment and biota than in water, and five (Mn, Cu, As, Zn, and Se) were biomagnified by at least one biotic component as compared to concentration in benthic sediment. Plants had high accumulations of Ti, Mn, As, and Hg; invertebrates had high accumulations of Co, Hg, Cu, Cr, Cd, and As; and vertebrates greatly biomagnified Se and Zn. The streamlined biotic community of the system accomplished major removal of Mn, Zn, As, Se, and Cd from the effluent. The magnitude of bioaccumulation of Ti, Mn, Zn, As, Se, Cd, and Hg was increased during the period of adequate settling in the basin.     

RESPONSES OF HETEROTHROPHIC BACTERIAL POPULATIONS TO pH CHANGES IN COAL ASH EFFLUENT1

ABSTRACT: Total culturable heterotrophic bacteria in a coal ash basin and drainage system were monitored over a period of two years. In the first year heavy (bottom) ash was sluiced to the basin resulting in a pH of 6.5. During the second year fly ash was precipitated and added to the sluice lowering the basin pH to 4.6. Sulfate concentrations during 1975 ranged from 16–73 ppm (mean 33) and in 1976 from 44–88 ppm (mean 72). Mean annual basin temperatures were 28.8 and 26.0 C, respectively. Approximately 1500 m in the receiving swamp below the basin, mean pH and temperature were 6.8 and 22.2 C for the first year, and 5.4 and 22.1 C for the second. Total culturable bacteria and diversity (colony types) were reduced at all sampling stations by 44 and 30 percent, respectively, whereas the percentage of the population comprised of chromagenic bacteria increased by 51 percent at the lower pH; Data indicated the pH had a greater effect than did water temperature when temperature was within the range of 15–25 C. The predominant genera within the system in the first year were Bacillus, Sarcina, Achromobacter, Flavobacterium, and Pseudomonas. In the second year, at the lower pH, predominant genera were Pseudomonas, Flavobacterium, Chromobacterium, Bacillus, and Brevibacterium.     

FACTORS INFLUENCING ACUTE TOXICfrY OF COAL ASH TO RAINBOW TROUT (SALMO GAIRDNERI) AND BLUEGILL SUNFISH (LEPOMIS MACROCHIRUS)1

ABSTRACT: The potentially toxic components in coal ash (ash particles, heavy metals) were evaluated in laboratory static, acute (96 hr) bioassays, both separately and in various combinations with extreme pH (5.0 and 8.5), using rainbow trout (Salmo gairdneri) and bluegifi sunfish (Lepomis macrochirus). Ash particle morphology and metal distribution anlaysis, using electron microscopy and surface-subsurface analysis by ion microscopy, showed that metals could be either clumped or evenly distributed on the surface of fly ash. Surface enrichment on fly ash particles from electrostatic precipitators, as measured by ion microscopy, was found for cadmium, copper, chromium, nickel, lead, mercury, titanium, arsenic, and selenium. Bottom (heavy) ash was not acutely toxic to either fish species at concentrations of up to 1500 mg/l total suspended solids (TSS) at pH 5.0, 7.5, or 8.5. Fly ash particles were not acutely toxic to blue-gill at levels up to 1360 mg/l TSS. Rainbow trout were highly sensitive to fly ash (25 to 60 percent mortality) at concentrations of 4.3 to 20.5 mg/I TSS when dissolved metal availability was high but were not sensitive at higher particulate concentrations (58 to 638 mg/I TSS) when dissolved metals were low. When metals were acid-leached from fly ash prior to testing, no rainbow trout mortality occurred at TSS concentrations of up to 2,350 mg/l TSS. When the percent of dissolved metal was high (e.g., 50–90 percent of the total), fish mortality was increased. Rainbow trout were nearly two orders of magnitude more sensitive than bluegill when subjected to a blend of cadmium, chromium, copper, nickel, lead, and zinc. The two species were similar in their acute sensitivity to acidic pH at levels at or below 4.0 and alkaline pH of 9.1. If the pH of coal ash effluent is contained within the range 6.0 to 9.0, acute toxicity to fish can be attributed to trace element availability from fly ash but not heavy ash. Control of holding pond and effluent pH and maximizing pond residence time are important strategies for minimizing effects of ash pond discharges on fish.     

垃圾焚烧飞灰处置与资源化利用研究进展

随着生活垃圾焚烧处理方式的不断推广,焚烧飞灰的产生量也不断增加。按照我国固体废物分类方法,焚烧飞灰属于危险废物,必须进一步处置才能进入填埋场或资源化利用。本文分析了飞灰物理化学特性,论述了常规处置技术（水泥固化、化学药剂稳定化、酸溶剂提取和熔融固化等）存在的问题。将原始飞灰直接应用于水泥、混凝土或路基材料,飞灰中高含量的重金属和盐类会产生新的环境问题。飞灰水洗可以高效去除其中的可溶性盐类,水洗飞灰在焙烧后重金属的浸出浓度远低于原始飞灰烧结后的相应浓度,飞灰水洗-焙烧技术具有很好的应用前景。     

EFFECTS OF NITRATE AND PHOSPHATE CONCENTRATION ON NATURAL AQUATIC BACTERIAL POPULATIONS1

ABSTRACT: Natural aquatic bacterial populations in three streams located at the Savannah River Project, Aiken, S.C. have been studied in relation to the effects of ambient temperatures, dissolved River Project, Aiken, oxygen (DO), nitrate and phosphate concentrations. ³ 3 This work was supported in part by Contract #AT (38–1–824) with the U.S. Atomic Energy Commission, and was done in part in connection with AEC Contract #AT (07–2)–1.
Samples collected at monthly intervals for a period of one year from each system, were plated in duplicate at each of two dilutions on 1/4 strength Standard Plate Count Agar (Difco). After incubation at 25±1 °C for four days, total colony forming units, percent chromagens, and number of colony types (diversity) were determined and colonies were picked for identification. Temperatures were generally equal in two of the streams throughout the year, being lowest in Upper Three Runs (U3R) and Tirns Branch (TB), and highest in the Ash Basin System (ABS). DO content did not vary appreciably between the streams. Nitrates and phosphates were lowest in U3R, next lowest in TB, higher in the last station in ABS, and highest in the ash basin per se. Total colony forming units were highest in the ash basin, whereas chromagen percentage and diversity were highest in the last station in ABS. Results of these studies indicate that high nitrates and phosphates, in the absence of high organic carbon concentrations, have little, if any detrimental effect on the stability of natural aquatic bacterial populations.     

Study on assessment of slope stability and mixed disposal of overburden in voids of Singrauli Coalfield

The mining industry can be considered the backbone of the Indian economy as well as facilitating the power that drives most of the other industries in the company. The overburden and waste rocks produced during coal mining are major concerns in regard to the amount of land that is required for their disposal, as well as the stability of dumps for these materials, which are of increasing height. Land reclamation issues are also a concern. In this work the adverse impacts caused by the dumping of overburden on land and acidic mine water on water bodies is discussed. Remote sensing tools were used along with the laboratory experimentation to assess the various impacts. This study also shows that silt released from waste dumps, can affected the angle of repose of the overburden dump slope. The angle of repose of the overburden materials varies with particle size composition. Thus, use of in‐pit crushers in large opencast mining operations can effectively reduce the area locked under the waste dumps. The acid neutralization potential of fly ash and overburden for the treatment of acid water was tested in the laboratory by using fly ash and waste rock materials on acidic coalfield water. The results are encouraging, and fly ash may prove to be a good acid neutralizer when used in conjunction of coal overburden material.     

粉煤灰对硫化钠烟气脱硫的影响研究

通过对烟气带入吸收系统的粉煤灰物理性质及化学组成的分析，研究了粉煤灰对硫化钠法烟气脱硫反应的可能影响，并对粉煤灰的去除工艺进行了探讨。     

我国南方某城市垃圾焚烧飞灰特性及固化/稳定化处置实验

我国南方某城市主要采用焚烧法处理生活垃圾,已建7个焚烧厂日产生飞灰量为101.62 t/d。文章分析了各个垃圾焚烧厂飞灰的化学组成和重金属浸出毒性,其主要成分为CaO、SiO2、MgO、Al2O3、Fe2O3、Na2O、SO3和Cl,所有焚烧飞灰都有至少一种重金属浸出浓度超标,属于危险废物。在飞灰处置出路亟待解决的背景下,实验探讨了飞灰稳定化工艺,结果表明10%的水泥添加量可以使飞灰中超标重金属(Cd、Pb和Zn)的浸出浓度满足危险废物鉴别浓度限值和安全填埋场入场浓度限值。同时,通过人体健康风险评价分析了飞灰豁免管理的可行性,并对近期和远期该城市焚烧厂飞灰的处理处置及管理提出建议。     

The reuse of municipal solid waste incinerator fly ash slag as a cement substitute

The results of the treatment of fly ash from a municipal solid waste incinerator (MSWI) by melting are described, and the safety and the effectiveness of using the slag produced by this melting treatment are studied. The properties of the MSWI fly ash slag were analyzed, to evaluate the feasibility of its reuse as a substitute for part of the cement required in mortar preparation. This MSWI fly ash slag was found to be comprised mainly of SiO₂ and CaO, which can be substituted for up to 20% of the cement content in mortar, without sacrificing the quality of the resultant concrete. In fact, the concrete thus produced has greater compressive strength, 10% higher than that without the substitution. The setting time of the fresh mortar becomes lengthens as increasing amounts of cement are replaced; while the spread flow value increases with the increasing percentage of cement substitution. X-ray diffraction analysis reveals that when the W/C=0.38 and the curing AGE=28 days, the crystal patterns in the mortar samples, prepared with different amounts of cement having been replaced by MSWI fly ash slag are similar. According to the results of the toxic characteristic leaching procedure analysis, MSWI fly ash slag should be classified as general non-hazardous industrial waste, that meets the effluent standard. Therefore, the reuse of MSWI fly ash slag is feasible, and will not result in pollution due to the leaching of heavy metals.     

Ingestion and egestion of microplastic by aquatic insects in Egypt wastewater

Microplastics (MPs) are frequently regarded as environmental and biota contaminants. Yet, research on the accumulation of MPs in living entities, particularly aquatic insects that serve as food resources in the aquatic food chain, is limited. This study to investigate the accumulation of MPs in aquatic insects from water and sediment in an Egyptian wastewater basin. Four typical freshwater insect groups were used. The highest MP load per gram wet weight was reported by collector-gatherers (Chironomus sp. and Hydrophilus sp.), followed by collector-filterers (Culex sp.) with the second highest MP load. However, Predators (Aeshna sp.) had the lowest values. Also, the present results showed a reduction in the number of MPs in all insect taxa tested after a 24 h depuration time, with differences in the observed egestion ability. The mean number of MPs per individual significantly reduced after 24 h in both Chironomus sp. and Culex sp. larvae, where 53% and 40% of MPs particles were ejected from them, respectively. However, the ability of MP egestion decreases in Aeshna sp. nymph (25%), and the lowest proportion of ejection was observed in Hydrophilus sp. adults (9%). Polyethylene terephthalate fibers were the most abundant type of MP in both sediment and water, followed by fragments (polyethylene and polypropylene). Yet, only polyester fibers were detected in the various insect species. The average length of fibers in the various insects was somewhat shorter than in the surrounding environment. The current study reveals that MP ingestion by aquatic insects is not always related to levels of pollution in the environment, since other factors such as feeding strategies may play a role in MP ingestion. Based on these observations, further studies should be carried out on studies on toxicological impacts of MPs on freshwater/aquatic biota.     

Influences of Spatial Scale and Soil Permeability on Relationships Between Land Cover and Baseflow Stream Nutrient Concentrations

The Little Miami River (LMR) basin, dominated by agriculture, contains two geologically-distinct regions; a glaciated northern till plain with soils three times more permeable than a southern, pre-Wisconsinan drift plain. The influences of two landscape measures, percent row crop cover (%RCC, computed at three spatial scales), and soil permeability (PERM), on baseflow nutrient concentrations were modeled using linear regressions. Quarterly water samples collected for four years were analyzed for nitrate-N (NN), Kjeldahl-N (KN), total-N (TN), and total-P (TP). In till plain streams (n = 17), NN concentrations were 8.5-times greater than drift plain streams (n = 18), but KN and TP were 20–40% lower at comparable %RCC. These differences resulted in TN/TP molar ratios >80 in till plain streams, but <6 in drift plain streams. For till plain steams regression models based on %RCC accounted for 79% of the variance in NN concentrations but only 27% in drift plain streams. However, regressions on %RCC accounted for 68–75% of the KN and TP concentration variance in the drift plain streams but essentially none in the till plain. Catchment PERM influenced the regional NN/KN ratios which were 10-fold higher in the drift plain streams. For both till and drift streams the catchment scale %RCC gave the best predictions of NN, a water soluble anion, but the smaller spatial scales produced better models for insoluble nutrient species (e.g., KN and TP). Published literature on Ohio streams indicates that these inter-regional differences in nutrient ratios have potential implications for aquatic biota in the receiving streams.     

分子键合TM技术在垃圾焚烧飞灰治理中的应用

结合国内垃圾焚烧飞灰的治理现状,对分子键合TM技术治理垃圾焚烧飞灰的原理、工艺进行了介绍分析,并通过实验研究对分子键合TM技术在垃圾焚烧飞灰治理中的应用进行了探讨。     

大庆石油管理局粉煤灰综合利用现状及前景

简要介绍了目前国内外粉煤灰利用的情况,分析了大庆石油管理局粉煤灰利用范围,主要包括筑路、生产水泥、加工切块、陶粒和步踏砖等,粉煤灰的综合利用率在70%以上。通过调查粉煤灰综合利用情况,对制作水泥和制作步踏砖存在的问题提出了解决办法。针对大庆油田的实际情况,在借鉴国内外其他方法和技术的基础上,提出了综合利用粉煤灰的其他建议,例如用于固井作业的水泥浆体系,生产铝盐,用于填埋固体废物等。     

THE LIMNOLOGY OF LAKE WABUKAYNE,A STORM-WATER IMPOUNDMENT1

ABSTRACT The limnology of a 1.9-ha storm-water detention pond is described. The eutrophic nature of this impoundment is attributed to the nutrients in runoff from the surrounding residential area. During the summer, photosynthetic activity of the phytoplankton caused surface waters to become super-saturated with oxygen, while decomposing organic material greatly reduced dissolved oxygen concentrations in the deeper water. Sediment derived from construction activity within the drainage basin caused the impoundment to be turbid. The use of road deicing salts within the drainage basin produced high chloride concentrations and a temporary meromixis during the winter and early spring. The benthic fauna consisted primarily of oligochaetes, chironomids, and chaoborids. High densities of oligochaetes were present in the settling basin. Chaoborid larvae were abundant in the deep basin where low oxygen concentrations reduced the numbers of other benthic macroinvertebrates.     

粉煤灰在重金属废水处理中的应用

粉煤灰是一种可再资源化的工业固体废弃物。利用粉煤灰对重金属废水进行处理可谓是一种以废治废、变废为宝、实现废物综合利用的有效途径。综述了粉煤灰吸附法在重金属废水处理中的国内外研究现状,展望了该方法的应用前景。     

以造粒粉煤灰为过滤介质去除景观水中磷的研究

研究了造粒粉煤灰的最大磷吸附量、磷吸附速率等吸附特征，以及颗粒粒径、磷浓度、水力负荷对景观水除磷效果的影响。还进行了为期21天的连续过滤试验，发现滤床在高水力负荷条件下能持续地去除景观水中的磷。     

TRACE ELEMENTS IN NORTHERN GREAT PLAINS STRIP MINE AND LIVESTOCK IMPOUNDMENT WATER1

ABSTRACT: The water from 32 strip mine water impoundments and nine livestock watering ponds in North Dakota, South Dakota, and Wyoming were analyzed for trace elements. Because of the high concentrations of trace elements in coal and bentonite clay, the possibility exists for these elements to dissolve or be suspended in the water. Strip mine ponds were not significantly higher in trace element concentrations compared to livestock ponds. All but one of the 41 ponds sampled contained elemental concentrations that would be detrimental for livestock use or aquatic life use. Cadmium and lead were the elements most frequently in excess of water quality crieria. Lead was found in the study ponds about 35 times the median concentration of North American rivers. Manganese concentrations were found to exceed iron in many ponds, which is unusual in natural waters. The potential for detrimental concentrations of trace elements in pond water must be evaluated when designing land use management plans for ponds intended to be used by livestock or aquatic life.     

POLLUTANT REMOVAL FROM COAL-ASH BASIN EFFLUENT1

ABSTRACT: The drainage system for an ash basin serving a coal-fired power plant at the Savannah River Project, Aiken, South Carolina, has been studied for 15 months to determine abiotic and biotic characteristics and mechanisms of pollutant removal. Measurements made included temperature, dissolved oxygen, pH, turbidity, alkalinity, conductance, flow rate, sulfate, nitrate, and phosphate. In addition, neutron activation analysis was employed to determine concentrations of 40 chemical elements in water, benthos, bacterial, plant, invertebrate, and vertebrate samples collected at six sampling stations. Five-day toxicity tests were performed using organisms from within and from outside the system. Conductance, pH, alkalinity and sulfate concentration varied little throughout the system. Temperature, dissolved oxygen, turbidity, nitrate, phosphate, and flow rate decreased at stations farther removed from the ash basin. Concentrations of most chemical elements measured were greatest in benthos (75 percent of total) and least in water (less than one percent of total), indicating that a major removal mechanism was sedimentation of suspended particulate matter. Eight elements (Br, Ca, C1, Cd, Na, Sb, Se, and Zn) were more highly concentrated in one or more biotic forms than in benthos. Among heavy metals only Cr was concentrated to a greater extent by plants than by animals. Midges were the greatest concentrators of Fe, Cu, Cr, Hg, Co, Sb, and As among all organisms. Plants concentrated only 15 percent of the total heavy metal concentration found in the benthos. Light, metals were more highly concentrated in animals than in plants, although all plants were found to possess 19 percent of the concentration present in the benthos and water. As and Sb were in low concentration within the system; however, on a percentage basis, these potentially toxic elements were relatively highly concentrated by a number of organisms. Active metals (Ca, Na, and K) and halogens (CI, Br, and I) were highly concentrated by most organisms. Active metals were more concentrated in crayfish and mosquito fish, Gambusia affinis, than in benthos, whereas most organisms had higher concentrations of halogens than were found in benthic sediments. Primary producers within the system were least efficient in concentration of all elements except Mn. Consumers (invertebrates and vertebrates) were found to possess highest concentrations of all other elements. Organisms found within the drainage system were observed to be able to survive a five-day toxicity test at any point within the system, whereas organisms not existing within the system were observed to vary in their resistance to the drainage system environment. The findings of this study demonstrate the necessity for the operation of entire food chains in pollutant removal and indicate potential means for increasing cycling efficiency by selective addition of resistant consumers to such a system.