THE TENDENCY OF A NEW WATER DISINFECTANT TO PRODUCE TOXIC TRIHALOMETHANES1

A new organic N-chloramine disinfectant (3-chloro-4, 4-dimethyl-2-oxazolidinone, agent I) has been compared with calcium hypochlorite as to its tendency to react with organic matter in water to produce toxic trihalomethanes. Agent I reacts much less readily with organic demand than does calcium hypochlorite. This study shows that agent I should be safe to use as a disinfectant for water containing appreciable organic load in either sunlight or darkness. On the other hand, calcium hypochlorite may not be a satisfactory disinfectant from the toxicity standpoint for water which contains organic load which must be stored for extended time periods in either sunlight or darkness.     

THE STABILITY IN WATER OF A NEW CHLORAMINE DISINFECTANT1

ABSTRACT: The stability in water of a novel new chloramine agent, 3-chloro-4, 4-dimethyl-2-oxazolidinone (agent I), which is an excellent water disinfectant, has been compared to the stabilities of several other water disinfectants. The agents tested in addition to agent I included N-chlorosuccinimide, 2, 4-dichloro-5, 5-dimethylhydantoin, tichloroisocyanuric acid, calcium hypochlorite, commercial grade HTH, and household bleach. The total chlorine content of a water solution of agent I in a demand free environment remains constant over a period of at least eight weeks, while that for all of the other agents declines markedly over that time period. An explanation for these observations will be offered. Prior work in these laboratories concerning use of agent I as a disinfectant for lake water in a laboratory scale treatment plant had shown that agent I has considerable potential for use as an alternative to chlorine gas for water disinfection.     

PERFORMANCE OF A NEW POLYMERIC WATER DISINFECTANT1

ABSTRACT: A new insoluble N-halamine polymeric disinfectant material has been tested in a water filter application to determine (1) its tendencies to leach undesirable decomposition products, (2) its range of potential applicability, and (3) its regenerability. In flowing water tests, poly-1,3-dichloro-5-methyl-5-(4‘-vinylphenyl)hydantoin (Poly-I) leached only small amounts of total organic carbon, free and total chlorine, anions, and volatile organics such as trihalomethanes. Furthermore, Poly-I provided bactericidal efficacy over the pH range 4.5 to 9.5 and at temperatures as high as 37°C. Poly-I is deactivated by reducing agents such as sodium thiosulfate and by ethanol; following deactivation, it can be regenerated by exposure to flowing aqueous free chlorine. Poly-I appears suitable for use as a biocidal filter for small potable and recreational waters, for it is effective over a wide pH and temperature range and is readily regenerable. It would not be useful, however, for disinfection of large bodies of water such as in city treatment plants because of its cost and the large amount of the material that would be necessary.     

CHARACTERIZATION OF SURFACE WATER QUALITY ALONG A WATERSHED DISTURBANCE GRADIENT1

ABSTRACT. Characterizing ecological indicators such as water quality is necessary to effectively manage human-dominated systems such as the New Jersey Pinelands. Pinelands surface waters are naturally acidic and low in nutrients and other dissolved substances. Water quality for 14 Pinelands stream sites monitored by the U.S. Geological Survey was characterized in relation to land use. A gradient of increasing pH, specific conductance, and concentration of dissolved calcium, dissolved magnesium, total nitrite + nitrate-nitrogen, total ammonia-nitrogen, and total phosphorus was associated with a watershed disturbance gradient of increasing land use intensity and waste water flow. These two parallel gradients emphasized the significant effect that watershed disturbance can have on natural water chemistry in the Pinelands. The results of this study can be applied to planning and regulatory programs in the Pinelands.     

GEOCHEMICAL CHARACTERIZATION OF SHALLOW GROUND WATER IN THE EUTAW AQUIFER,MONTGOMERY, ALABAMA1

ABSTRACT: Ground water samples were collected from 30 wells located in, or directly down gradient from, recharge areas of the Eutaw aquifer in Montgomery, Alabama. The major ion content of the water evolves from calcium‐sodium‐chloride‐dominated type in the recharge area to calcium‐bicarbonate‐dominated type in the confined portion of the aquifer. Ground water in the recharge area was under saturated with respect to aluminosilicate and carbonate minerals. Ground water in the confined portion of the aquifer was at equilibrium levels for calcite and potassium feldspar. Dissolved oxygen and nitrite‐plus‐nitrate concentrations decreased as ground water age increased; pH, iron, and sulfate concentrations increased as ground water age increased. Aluminum, copper, and zinc concentrations decreased as ground water age and pH increased. These relations indicate that nitrate, aluminum, copper, and zinc are removed from solution as water moves from recharge areas to the confined areas of the Eutaw aquifer. The natural evolution of ground water quality, which typically increases the pH and decreases the dissolved oxygen content, may be an important limiting factor to the migration of nitrogen based compounds and metals.     

EFFECT OF SEMI‐PERCHED GROUND WATER ON MONITORING OF GROUND WATER LEVELS IN A DEVELOPED AQUIFER1

ABSTRACT: Interpretation of ground water level changes in a developed aquifer usually relies on reference to some benchmark such as “predevelopment” ground water levels, changes from fall to fall and/or spring to spring, or to determination of maximum stress during the pumping season. The assumption is that ground water levels measured in the monitoring well accurately reflect the state of the ground water resource in terms of quantity in storage and the effects of local pumping. This assumption is questionable based on the patterns shown in continuous hydrographs of water levels in monitoring wells in Nebraska, and wells installed to determine vertical gradients. These hydrographs show clear evidence for vertical ground water gradients and recharge from overlying parts of the aquifer system to deeper zones in which production wells are screened. The classical concept of semi‐perched ground water, as described by Meinzer, is demonstrated by these hydrographs. The presence of semi‐perched ground water (Meinzer definition, there is no intervening unsaturated zone) invalidates the use of measured ground water levels in regional observation programs for detailed numerical management of the resource. Failure to recognize the Meinzer effect has led to faulty management. The best use of data from the observation well network would be for detection of trends and education unless it is clearly understood what is being measured.     

A NOVEL CHLORAMINE COMPOUND FOR WATER DISINFECTION1

A new chloramine agent, 3-chloio-4, 4-dimethyl-2-oxazolidinone, has been tested in a laboratory scale water treatment plant as to its efficacy in water disinfection. The agent seems to be equally effective as compared to chlorine gas in this application. The results of preliminary toxicity studies on the agent are very encouraging. The agent has a long shelf life both in water solution and in the solid state. Being a solid, the agent is clearly less hazardous to handle than chlorine gas. The agent appears to inhibit oxidative corrosion of metals as well. The agent is less likely to produce toxic halocarbons (e.g., chloroform) in water than is chlorine gas. Possibly most important from the standpoint of water disinfection, the agent is a “slow release” one for its positive chlorine, which provides prolonged bactericidal activity.     

POTENTIAL BENEFITS AND COSTS OF INGROUND STORAGE OF IMPORTED WATER1

ABSTRACT: In the near future, groundwater storage of imported water may become increasingly important as sites for surface storage are less available. This article explores the potential economic costs and benefits of groundwater storage. The costs include capital outlays, maintenance costs, land costs, legal costs, energy costs, and opportunity costs. The benefits include land cost savings, prevention of subsidence, aquifer protection, and higher economic use of surface lands that might be covered by a reservoir.     

USING GROUND WATER BASINS AS STORAGE FACILITIES IN SOUTHERN CALIFORNIA1

ABSTRACT: Southern California, now in its fifth consecutive year of drought, has always relied heavily on imported water from the Owens Valley, the State Water Project, and the Colorado River. For various reasons, these sources are now decreasing and water suppliers are being forced to look for new sources. One possible alternative is to store water obtained during peak supply periods for use during dry periods in ground water storage basins. The Santa Ana River Basin in Orange County has already been developed, and is being used to provide water to 25 cities in Orange County. The San Juan Basin, also in Orange County, is being studied as a possible future storage basin. This paper examines some of the positive and negative aspects of developing and using ground water storage basins in Southern California.     

CONTRIBUTION OF PRECIPITATION TO QUALITY OF URBAN STORM RUNOFF1

Precipitation and runoff samples were collected for 13 storms in a nonindustrial urban area in Central Pennsylvania between July 1980 and June 1981. Runoff was collected from tree surfaces, a residential roof and street, a shopping mall parking lot, a downtown business district alley, and a heavily traveled street. Analysis of the water samples showed 10 to 25 percent of the nitrogen, 25 percent of the sulfate, and less than 5 percent of the phosphorus, potassium, and calcium in water below a tree was deposited by the precipitation. The residential roof caused insignificant changes in water chemistry. The results for the four paved areas showed that all the nitrogen, and from 16 to 40 percent of the sulfate and 13, 4, and 2 percent of the phosphorus, potassium, and calcium, respectively, in runoff was deposited by the precipitation. Precipitation can also be an important source of sulfate and phosphorus in runoff. All of the surfaces raised the pH of the runoff, with the largest increases, from a pH of 4 to about 7, occurring in runoff from the paved areas. Precipitation and runoff chemistry was not related to antecedent conditions such as the length of the preceding dry period.     

A LAND-USE POLICY BASED ON WATER SUPPLY1

ABSTRACT: Santa Fe Country, New Mexico, has adopted a land-use policy in which zoning densities provide a balance between the water use on a parcel of land and the water supply available bencath that land. In two of four mapped hydrologic zones, ground water in storage will be allowed to be mined to exhaustion in 100 years (40 years in urban areas). Elsewhere, the policy is for a steady state with use balanced by recharge. Equations to determine storage or recharge can be solved using site specific data or regional estimates of hydrologic conditions. Substantial reductions in the lot size requirements are allowed if water conservation convenants are adopted. Public acceptance indicates that the policy successfully integrates technical and political concerns. It is simple to administer, yet reflects widely expressed public goals and values.     

EVALUATION OF THE SUSTAINABILITY OF WATER WITHDRAWALS IN THE UNITED STATES, 1995 TO 20251

To evaluate the long term sustainability of water withdrawals in the United States, a county level analysis of the availability of renewable water resources was conducted, and the magnitudes of human withdrawals from surface water and ground water sources and the stored water requirements during the warmest months of the year were evaluated. Estimates of growth in population and electricity generation were then used to estimate the change in withdrawals assuming that the rates of water use either remain at their current levels (the business as usual scenario) or that they exhibit improvements in efficiency at the same rate as observed over 1975 to 1995 (the improved efficiency scenario). The estimates show several areas, notably the Southwest and major metropolitan areas throughout the United States, as being likely to have significant new storage requirements with the business‐as‐usual scenario, under the condition of average water availability. These new requirements could be substantially eliminated under the improved efficiency scenario, thus indicating the importance of water use efficiency in meeting future requirements. The national assessment identified regions of potential water sustainability concern; these regions can be the subject of more targeted data collection and analyses in the future.     

次氯酸钠药剂在不同水厂的应用

次氯酸钠药剂在水务行业应用广泛,常被用作消毒剂,对于保障水质具有重要的作用。介绍了近6年来次氯酸钠消毒剂在水务行业的应用情况,以期为不同性质水厂的运行提供参考。     

A NEW CHALLENGE FOR WESTERN WATER SUPPLIES1

ABSTRACT: In many of the limited water resource areas of the western United States most water supplies have been put to beneficial uses. Energy, a fast expanding high-priority water use, is making challenging demands for these limited supplies. Can water supplies be stretched, supplemented, or redirected so that present uses can be maintained and energy water needs satisfied? The Bureau of Reclamation is investigating innovative methods of water management, reregulation, and use to meet these demands. Related programs under study include potentials for: development of additional hydroelectric power, installation of low-head turbines in western water courses, utilization of pumped storage and underground storage, use of geo-thermal heat, extension of water supplies through more efficient irrigation systems and practices, and weather modification.     

THE EFFECTS OF DEICING SALTS ON WATER CHEMISTRY IN PINHOOK BOG,INDIANA1

ABSTRACT: A five-year study was conducted to identify the effects of road salt intrusion on the water chemistry of Pinhook Bog following operation of an uncovered salt storage pile adjacent to the bog for ten years. A distinct pattern of elevated salt concentrations was observed in the interstitial waters of the surface peat that corresponded to observed alterations in the bog vegetation. Yearly mean salt concentrations as high as 468 mg/l sodium and 1215 mg/l chloride were recorded in the plant root zone of the peat mat. The salt concentrations decreased significantly each year from 1979 to 1981 throughout the impacted area. Some increases of a lesser magnitude occurred in 1982 and 1983. Analysis of salt movements suggested that vertical transport by water movement was responsible for concentration changes. The major declines in salt levels occurred in the spring following snowmelt and heavy precipitation events. Evapotranspiration during periods of drought resulted in the gradual increases in surface peat salt concentrations. Diverted highway runoff was shown to be the major continuing source of sodium chloride contamination and was the likely source of the elevated calcium, magnesium, potassium, bicarbonate, and pH levels also observed in the impacted area.     

BACTERIAL LEVELS IN CISTERN WATER SYSTEMS OF NORTHERN KENTUCKY1

ABSTRACT: In rural Northern Kentucky, rainwater is commonly collected from rooftops and stored in cement block cisterns as the sole source of drinking water. Although every cistern system is unique in some aspect of design, use, or maintenance, a bacterial survey of 30 rural Northern Kentucky cistern systems suggests that coliforms and heterotrophic bacteria are common to all types of cistern storage systems. An average of 600 coliforms/ml and 3.6 ± 10⁵ heterotrophic bacteria/ml were detected in water samples from the bottoms of the cistern storage tanks. Bacterial levels in water delivered to household cold tap faucets were similar to the levels found in the storage tanks. When detected, fecal coliforms were recovered throughout the entire system including the household cold tap faucet. Current U.S. regulations for drinking water quality are discussed, with a suggestion that fecal coliform levels may be a more appropriate guideline for interpreting the water quality of individually maintained, nonchlorinated, nonpiped water supplies, such as cistern storage systems.     

CHEMISTRY OF COALBED METHANE DISCHARGE WATER INTERACTING WITH SEMI‐ARID EPHEMERAL STREAM CHANNELS1

ABSTRACT: The objective of this study was to examine the chemistry of Coalbed Methane (CBM) discharge water reacting with semi‐arid ephemeral stream channels in the Powder River Basin, Wyoming. The study area consisted of two ephemeral streams: Burger Draw and Sue Draw. These streams are tributaries to the perennial Powder River. Samples were collected bimonthly from three CBM discharge points and seven channel locations in Burger Draw and Sue Draw. Samples were also collected bimonthly from the Powder River above and below the confluence of Burger Draw. Before sample collection, the pH and electrical conductivity (EC) were measured in the field. Samples were transported to the laboratory and analyzed for alkalinity, major cations, and anions. From the measurement of sodium (Na), calcium (Ca), and magnesium (Mg), practical sodium adsorption ratio (SARp) and true sodium adsorption ratio (SARt) were calculated. Results suggest pH and EC of CBM discharge water was 7.1 and 4.3 dS/m, respectively. The CBM discharge water consisted of higher concentrations of sodium and alkalinity compared to other components. The pH of CBM discharge water increased significantly (p = 0.000) in the downstream channel of Burger Draw from 7.1 to 8.84 before it joined with the Powder River. Dissolved calcium concentration of CBM discharge water decreased significantly (p = 0.000) in the downstream channel water. Subsequently, SARp increased approximately from 24 to 29. The SARt also increased significantly (p = 0.001) in the downstream channel water. For instance, SARt of CBM discharge water increased from 32.93 to 45.5 downstream channels after the confluence of Sue Draw with the Burger Draw. The only significant difference in water chemistry above and below the confluence of Burger Draw with the Powder River was pH, which increased from 8.36 to 8.52. The significant increase in SAR values of CBM discharge water in Burger Draw and Sue Draw tributaries suggest a careful monitoring of salinity and sodicity is needed if CBM discharge water is used for irrigation in semi‐arid environments. Results discussed in this study will be useful to downstream water users who depend on water for irrigation.     

CONSERVATIONAL WATER PRICING FOR INCREASED WATER SUPPLY BENEFITS1

ABSTRACT: A study was undertaken to see if benefits from water supply could be increased by utilizing price-usage information in reservoir design studies. Three pricing policies were examined. The first policy assumed no price-use relationship, and quantity demanded was based on existing community usage with a low water rate. The price of water was set to recover system costs. A price-use relationship was assumed in the second policy and the water rate was constant. The price of water was determined from the associated system which provided maximum expected net benefits. The third policy assumed the price-use relationship and the price charged for water during each billing period was a non-linear function of storage which increased as the amount of water in storage at the beginning of the period decreased. It was found that the use of the conservation pricing policies substantially reduced storage requirements while providing demonstrable net benefits to the community and a large average supply. The conservation pricing policies substantially lowered the average price paid for water. The effect of uncertainty in consumer response to changes in price was studied by using a probabilistic price-use relationship. This uncertainty did not significantly reduce the effectiveness of the conservation policy. It was concluded that demand management by the use of a proper pricing policy could significantly increase net water supply benefits to a community.     

REGION,LANDSCAPE, AND SCALE EFFECTS ON LAKE SUPERIOR TRIBUTARY WATER QUALITY1

ABSTRACT: In 1998 and 1999, third‐order watersheds in high mature forest (HMF) and low mature forest (LMF) classes were selected along gradients of watershed storage within each of two hydrogeomorphic regions in the Lake Superior Basin to evaluate threshold effects of storage on hydrologic regimes and watershed exports. Differences were detected between regions (North and South Shore) for particulates, nutrients, and pH, with all but silica values higher for South Shore streams (p < 0.05). Mature forest effects were detected for turbidity, nutrients, color, and alkalinity, with higher values in the LMF watersheds, that is, watersheds with less that 50 percent mature forest cover. Dissolved N, ammonium, N:P, organic carbon, and color increased, while suspended solids, turbidity, and dissolved P decreased as a function of storage. Few two‐way interactions were detected between region and mature forest or watershed storage, thus threshold based classification schemes could be used to extrapolate effects across regions. Both regional differences in water quality and those associated with watershed attributes were more common for third‐order streams in the western Lake Superior drainage basin as compared with second‐order streams examined in an earlier study. Use of ecoregions alone as a basis for setting regional water quality criteria would have led to misinterpretation of reference condition and assessment of impacts in the Northern Lakes and Forest Ecoregion.     

APPLICATION OF A SINGLE RESERVOIR OPERATION POLICY TO A RAIN WATER CISTERN SYSTEM1

The operation policy for a single reservoir is applied to a rain water cistern system because the functions of a cistern are similar to a simple single reservoir. Since the cistern is a closed system, water loss is negligible. In this study, a dynamic programming analysis has been made to study the effects of the probable weekly rainfall and the water storage in the cistern towards the water consumption policy. The result of this study indicates that the water consumption rate should be adjusted into a lower rate when the water storage in the cistern is low and/or when the expected probable weekly rainfall is low if the owner of the cistern does not want to risk the chance of an empty cistern. The demand for a reliable method for forecasting weekly rainfall is evident in this study.