湖州合溪新港污染物入湖通量估算与分析

根据2021年5月—2022年4月合溪新港河流水量、水质(TN和TP)的同步监测数据,利用通量模型核算了合溪新港污染物(TN和TP)通量。通过测算合溪新港TN、TP通量与断面降雨强度、水质的响应关系,分析了该区域的污染类型及特点,为后期水质污染调查及通量研究提供了新思路。结果表明：合溪新港流量与降雨量存在明显相关关系,在强降雨期(7—8月)水体流量最高,占监测周期总流量的57.77%;少雨期则流量最低,且会出现湖水倒灌现象(11—12月)。通过分析合溪新港TN、TP通量与流量、水质的相关关系,确定了该流域污染类型为点源污染及农业面源污染共存的混合型污染,且在高强度降雨时污染物负荷量较大。综上,可针对农业面源污染对该流域治理提出相关对策,建立农业面源污染防治体系,以有效降低TN和TP污染物的入湖通量,减少太湖TN和TP污染物负荷量。     

洪泽湖流域生态环境问题及治理对策

分析了洪泽湖水环境和污染源特征,针对存在的氮磷超标导致湖体富营养化、生态退化以及入境客水污染等主要环境问题,提出制订入湖河流TN标准、控制污染物排放总量、修复湖泊生态、治理客水和强化水质监控等措施,为有效地改善洪泽湖水环境质量,遏制湖泊富营养化趋势提供科学支撑。     

洪泽湖湖滨带表层沉积物氮、磷、有机质分布及污染评价

洪泽湖作为中国第四大淡水湖泊,是江苏北部地区重要的水源地,同时也是南水北调东线工程的重要调蓄湖泊之一,研究其湖滨带表层沉积物氮、磷、有机质的污染情况对维持洪泽湖水安全和生物多样性具有重要现实意义。基于2020年8月于洪泽湖湖滨带采集的43个表层（0~10 cm）沉积物样品,分析了总氮（TN）、总磷（TP）和有机质（OM）含量的空间分布特征及相关性,并运用综合污染指数法和有机污染指数法评价其污染程度。结果表明,洪泽湖湖滨带表层沉积物TN、TP、OM含量范围分别为232~2 152 ,123~439,0.91~18.65 mg/kg,均值分别为985,276,10.93 mg/kg;空间分布上均表现为东部大堤、成子湖和西部区域的TN、TP、OM含量高于过水通道;Pearson相关性分析显示,表层沉积物中ω(OM)与ω(TN)（r=0.705,P<0.01）、ω(TN)与ω(TP)（r=0.504,P<0.01）呈显著正相关;洪泽湖湖滨带表层沉积物综合污染指数范围为0.45~1.88,平均值为0.93,有机污染指数范围为0.001~0.221,平均值为0.067,2种评价方法均显示洪泽湖湖滨带表层沉积物中TN、TP、OM整体处于清洁—轻度污染状态。     

太湖氮磷大气干湿沉降时空特征

为了探索太湖氮磷营养盐干湿沉降特征及对太湖营养盐输入的贡献,于2011年不同季节采集太湖不同位点的大气干湿沉降样品,分析干湿沉降中氮（N）和磷（P）的形态和沉降量。研究结果表明,输入太湖的磷以干沉降为主,而氮以湿沉降为主。在太湖干沉降中总无机氮（TIN）占总氮（TN）的77.1%,溶解性磷（DIP）占总磷（TP）的77.9%。干沉降中TIN主要以NH+4-N为主。西太湖是TN与TP通过大气干湿沉降输入太湖的最高湖区。太湖全年大气TN沉降总量为20 978 t,TP沉降总量为1 268 t,因此,氮磷大气干湿沉降是太湖营养盐输入的重要来源之一。     

太湖主要入湖河流排污控制量研究

利用2006—2008年的监测数据对太湖主要入湖河流的水环境状况进行了分析,通过对研究区工业污染源、农业污染源和城镇生活污水排污的分布以及入河情况的调查,对各种污染源的入河量进行了计算,根据确定的水质目标,分别计算出主要入湖河流以及区域水系的水环境容量和排污控制量。结果表明:15条主要入湖河流超标现象显著,近3a来污染程度有所波动,N、P污染最为严重。研究区内污染物入河量较大,未接管的生活源污染物入河量所占比重最大,各类污染物均在50%～60%之间;张家港市的污染物入河量最大,各类污染物所占比重达总入河量的18%～20%。研究区内河网密布,水环境容量分布不均匀,望虞河、直湖港、武进港等7条河流水环境容量较大,张家港市区域水环境容量较大。为保证水质达标,研究区内近期共须削减CODCr66554.38t/a、NH4-N8105.71t/a、TP1324.42t/a;远期共须削减CODCr96719.08t/a、NH4-N11541.45t/a、TP1788.71t/a。     

太湖流域河流入河污染负荷通量与入湖水质响应关系分析——以殷村港为例

以2020年1—12月太湖主要入湖河流殷村港水质自动监测站的监测数据及2020年太湖水位资料为依据,构建了一维水量水质耦合数学模型,建立了入河污染负荷通量与入湖控制断面水质响应关系,以入太湖控制断面殷村港站达Ⅲ类水质水为目标,模拟计算了殷村港站主要污染物入湖水质变化过程。结果表明,殷村港站高锰酸盐指数、氨氮、总磷等水质指标浓度最大值均明显的降低,其中氨氮浓度降低幅度相对较大,主要集中于3—6月;高锰酸盐指数和总磷日均入河污染负荷通量变化相对较小,氨氮日均入河污染负荷通量降低幅度相对较大;殷村港站高锰酸盐指数、氨氮、总磷等水质指标年入河污染负荷削减量分别为24.17,41.43,3.87 t。提出,基于核算出的削减量需进一步结合污染负荷通量过程和污染源溯源分析,确定不同水质指标下入河污染负荷控制方向,为科学合理规划殷村港主要污染物的入河污染负荷总量控制提供科学依据。     

基于比值法解析老城区河段氮磷污染特征

2013年12月—2015年2月,对南淝河老城区约4 km河段水体和主要点源的氮、磷污染物进行测定,并利用碳氮比(CODCr/TN)、氮磷比(TN/TP)、氨氮百分含量(NH3-N/TN)等主要指标对所得数据进行分析研究。结果表明,南淝河老城区段水体的氮磷污染严重,氨氮百分含量接近甚至超过50%,具有一般城市生活污水的特征;氮磷比在春夏季处于藻类适宜的生长范围(9.0TN/TP22.6);整个水体处于低碳氮比水平(碳氮比小于2.5),不利于水体的净化;主要受上游望塘污水处理厂、城市生活污水和地表径流的影响。其主要支流四里河水体的氮磷污染亦相当严重,且氮、磷污染物的输入途径一致。     

基于DPeRS模型的渭河典型断面汇水区面源污染评估及污染成因分析

近年来甘肃渭河桦林断面月度水质不稳定达标的问题引起了管理部门的广泛关注,掌握桦林断面汇水范围面源污染现状,对控制流域面源污染和促进水质稳定达标具有重要意义。采用遥感分布式污染估算（DPeRS）面源污染评估模型,对2018年黄河流域甘肃桦林断面汇水区面源污染空间分布特征进行分析,开展多类型污染量产排特征解析。结果表明：农业面源污染量方面,2018年甘肃桦林断面汇水区总氮（TN）、总磷（TP）、氨氮（NH⁺₄-N）、重铬酸盐指数（COD_Cr）面源污染排放量分别为11 591,2 697,7 141和1 458 t,入河量分别为2 184,512,1347,263 t;空间分布上,氮型（TN和NH⁺₄-N）排放负荷高值区主要分布在陇西县、武山县县段和岷县县段;武山县县段TP排放负荷较为突出;COD_Cr型面源污染高负荷区主要分布在陇西县、渭源县县段和武山县县段。农业面源污染物入河排放负荷空间分布差异明显,氮磷型（TN、NH⁺₄-N和TP）入河高负荷区主要分布在武山县县段、陇西县、临洮县县段;COD_Cr型面源污染入河高负荷区呈分散分布。漳县西部地区水土流失量较高,漳县西部、陇西县和渭源县县段北部局部地区泥沙负荷量较高。枯水期污染治理仍是保障水质稳定达标的关键期,农田径流是渭河桦林断面所在汇水区氮磷型面源污染的首要污染类型,畜禽养殖是COD_Cr型面源污染的首要污染类型。     

基于非参数检验的水质变化趋势分析

综合应用Mann Kendall（M K）、季节性Kendall(S K)非参数检验方法和局部加权回归散点平滑法（LOWESS）分析东江流域长时间尺度（16 a）和短时间尺度（5 a）水质变化趋势,解析流量与点面源污染对水质指标变化的贡献。结果表明：东江干流DO呈明显下降趋势,TN呈明显上升趋势;二级支流淡水河整治成效显著,水质呈明显改善趋势。流域中上游水体耗氧有机物相对稳定且水平较低,而下游存在较大量耗氧有机物排放。S K检验有利于发现不同月份水情影响下的水质变化,检验出东江干流NH3-N呈明显下降趋势。M K（LOWESS）模型有利于解析各水质指标受上游集雨区汇水过程和点面源污染影响情况。     

浑太河流域水质达标控制方法研究

结合浑太河流域水资源网络节点图,根据污染物来源、种类及其产生机理,针对计算单元水资源供需平衡预测数据、降雨径流值,分点源、非点源进行规划水平年污染物入河量的预测。根据浑太河流域地形特征、入河污染物降解特性,以水功能区水体纳污能力为计算单元污染物排放总量控制条件,给出基于规划水平年入河污染物变动特性的水质达标控制方法。运用该方法进行浑太河流域水质达标控制:2030年,流域总需水7.4亿立方米,缺水深度在1%以下,COD、NH3-N、TP、TN的入河量分别为28.5×104、2.8×104、3.1×104、4.6×104t,对应的入河控制量分别为9.3×104、0.6×104、0.8×104、0.9×104t,经控制后水功能区目标水质达标率100%。证实了该水质达标控制方法有效、可行。     

我国沙尘暴灾害及其治理对策初步研究

分析研究了沙尘暴的成因、时空分布、发展趋势及造成的灾害,结合国外经验提出了我国治理的对策建议。     

Dissipation and residue of metalaxyl and cymoxanil in pepper and soil

A simple and accurate method of determining metalaxyl and cymoxanil in pepper and soil was developed by ultra-performance liquid chromatography–photodiode array detection. The limits of detection were 0.015 mg/kg for metalaxyl and 0.003 mg/kg for cymoxanil. The limits of quantification were 0.05 mg/kg for metalaxyl in pepper and soil as well as 0.01 mg/kg for cymoxanil in pepper and soil. Recoveries of pepper and soil were investigated at three spiking levels and ranged within 77.52 to 102.05 % for metalaxyl and 87.15 to 103.21 % for cymoxanil, with relative standard deviations below 9.30 %. For field experiments, the half-lives of metalaxyl were 3.2 to 3.9 days in pepper and 4.4 to 9.5 days in soil at the three experimental locations in China. At harvest, pepper samples were found to contain metalaxyl and cymoxanil well below the maximum residue limit MRLs of the European Union (EU) following the recommended dosage and the interval of 21 days after last application.     

Determination and study on dissipation and residue of bismerthiazol and its metabolite in Chinese cabbage and soil

A simple and accurate method for the determination of bismerthiazol and its metabolite 2-amino-5-mercapto-1,3,4-thiadiazole was developed in Chinese cabbage and soil by high-performance liquid chromatography-diode array detection in this study. The limits of detection were 0.06 mg/kg for bismerthiazol and 0.03 mg/kg for 2-amino-5-mercapto-1,3,4-thiadiazole, respectively. Recoveries of cabbage and soil were investigated at three spiking levels and were in the range of 84.0–96.0 % for bismerthiazol and 71.0–74.6 % for 2-amino-5-mercapto-1,3,4-thiadiazole, with relative standard deviations below 7.0 %. For field experiments, the half-life of bismerthiazol was 2.4–2.5 days in Chinese cabbage and 2.5–4.8 days in soil at the two experimental locations in China. Dissipation residues of 2-amino-5-mercapto-1,3,4-thiadiazole were lower than 0.72 mg/kg. Terminal residues of bismerthiazol and its metabolite were less than 3.0 and 0.3 mg/kg in Chinese cabbage, respectively. No bismerthiazol or metabolite residues were detected in soil on days 5, 7, 10, and 14 after the last spraying at the two dosage levels.     

新疆室内环境污染监测和治理工作现状与建议

针对目前室内环境监测工作出现的种种问题,就如何规范的开展室内环境监测工作,更好地为社会提供真实、准确、有效的监测数据,本文提出相关的探讨。     

Residues and dissipation of trifloxystrobin and its metabolite in tomatoes and soil

A simple residue analytical method using the quick, easy, cheap, effective, rugged, and safe (QuEChERS) procedure for the determination of trifloxystrobin and its metabolite trifloxystrobin acid (CGA321113) in tomato and soil was developed using high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS). The limits of detection were 0.0005 mg/kg for trifloxystrobin and 0.001 mg/kg for trifloxystrobin acid, respectively. The average recoveries in tomato and soil ranged from 73–99 % for trifloxystrobin and 75–109 % for trifloxystrobin acid, with relative standard deviations below 15 %. The method was then used to study the dissipation and residues in tomato and soil. The dissipation half-lives of trifloxystrobin in tomato were 2.9 days (Beijing) and 5.4 days (Shandong), while in soil were 1.9 days (Beijing) and 3.0 days (Shandong), respectively. The final results showed that the major residue compound was trifloxystrobin in tomato whereas it was its metabolite, trifloxystrobin acid, in soil. The final residues of total trifloxystrobin (including trifloxystrobin acid) were below the EU maximum residue limit of 0.5 mg kg^?1 in tomato 3 days after the treatment.     

Lake destratification and speciation of iron and manganese

A long-term study of the effect of artificial aeration (destratification) of a water storage dam upon the speciation of iron and manganese in the dam waters has been undertaken. Separation of dam samples into soluble and insoluble forms by selective membrane filtration was undertaken before using the techniques of EPR spectroscopy, ion chromatography and gel filtration to assess the speciation of soluble species, and selective extraction and surface analysis (ESCA, SIMS and SEM) techniques to determine the speciation of particulate iron and manganese species. The percentages of soluble iron and manganese before (1983–85) and after (1986–88) artificial aeration are compared for the periods Jan–Dec, Jan–Mar, and Jun–Aug at three depths 6 m, 15 m and 0.5 m above the dam base, to assess the importance of seasonal changes in the various depths of the dam. Although aeration had an initial marked reduction in levels of soluble iron and manganese at all depths of the dam, the concentrations of these mtals showed a steady increase over succeeding years. Analysis of the figures over summer and winter periods shows that the reduction of soluble iron was maintained in summer, but not during winter. Upon aeration, the initial reduction of soluble manganese concentration was maintained in succeeding years in the epilimnic regions of the dam, but not in the hypolimnion. Statistical analysis of data has been undertaken to correlate the changes in relationship between the various forms of iron and manganese with the advent of aeration.     

太原市冬、夏季醛酮化合物污染特征及来源分析

针对太原市空气臭氧污染较为严重的问题,开展臭氧主要前体物醛酮化合物质量浓度及其变化规律研究.利用2,4-二硝基苯肼固相吸附/高效液相色谱方法,通过对太原市2019年冬季和夏季大气的醛酮化合物进行分析,发现太原市冬季总醛酮化合物的平均质量浓度为13μg/m3,低于夏季的27μg/m3.其中甲醛、乙醛和丙酮质量浓度最高,且...     

Disembodied and Disembedded? The Social and Economic Implications of Atmospheric Change and Biodiversity

The social and economic implications of atmospheric change on biodiversity need to be seen in a global context of major shifts in the conceptualization and management of our relationship with nature. Traditionally, we have conceptualized the atmosphere and the other creatures of the biosphere as separate from the human, but their quasi-autonomy is now becoming subject to more and more human management. This raises not only economic issues, but social, political, and ethical concerns that will have substantial influence on public policy. Among these are the commodification of genetic material; the privatization of traditional knowledge; and the management of information. In this broader context, the paper examines an array of current and proposed strategies of response to changes in biodiversity as a result of climatic and other stresses.     

Atmospheric Change and Biodiversity: Co-Networks and Networking

Canada responded to the Global Biodiversity Convention by completing the Canadian Biodiversity Strategy in 1995. At the same time, Environment Canada also completed a national Science Assessment on Biodiversity. During this period, the Smithsonian Institution, in partnership with Parks and Environment Canada, initiated the implementation of a global biodiversity monitoring program in Canada. Under the auspices of the United Nations Man and the Biosphere Program, the SI/MAB monitoring protocols and plots have spread across Canada at an unprecedented rate. National champions in the science and educational sectors, working within an inter-disciplinary ecological framework, have guided the development, education, quality control and sharing of atmosphere-biodiversity observations electronically.Atmospheric-Biodiversity Networks and Networking have traditionally operated within separate mandates with little degree of integration. Air-Bio Networks were designed within an integrated framework to better understand the atmospheric stress on biodiversity and the adaptation actions, nationally and regionally. Detailed examples of the cumulative effects of climate change, stratospheric ozone depletion, acid deposition, ground-level ozone, suspended particulate matter and hazardous air pollutants on biodiversity will be discussed using a Southern Ontario case study. In addition, recommendations will be presented for future paired SI/MAB plots, linked networks and networking for adaptation within the context of climate, chemical and ecological gradients.