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1.
Anaerobic decomposition of halogenated aromatic compounds 总被引:5,自引:0,他引:5
Häggblom MM Knight VK Kerkhof LJ 《Environmental pollution (Barking, Essex : 1987)》2000,107(2):199-207
Halogenated compounds constitute one of the largest groups of environmental pollutants, partly as a result of their widespread use as biocides, solvents and other industrial chemicals. A critical step in degradation of organohalides is the cleavage of the carbon?halogen bond. Reductive dehalogenation is generally the initial step in metabolism under methanogenic conditions, which requires a source of reducing equivalents, with the halogenated compound serving as an electron acceptor. Dehalogenation is greatly influenced by alternate electron acceptors; e.g. sulfate frequently inhibits reductive dehalogenation. On the other hand, a number of halogenated aromatic compounds can be degraded under different electron-accepting conditions and their complete oxidation to CO(2) can be coupled to processes such as denitrification, iron(III)-reduction, sulfate reduction and methanogenesis. Reductive dehalogenation was the initial step in degradation not only under methanogenic, but also under sulfate- and iron(III)-reducing conditions. Dehalogenation rates were in general slower under sulfidogenic and iron-reducing conditions, suggesting that dehalogenation was affected by the electron acceptor. The capacity for dehalogenation appears to be widely distributed in anoxic environments; however, the different substrate specificities and activities observed for the halogenated aromatic compounds suggest that distinct dehalogenating microbial populations are enriched under the different reducing conditions. Characterization of the microbial community structure using a combination of biomolecular techniques, such as cellular fatty acid profiling, and 16 S rRNA fingerprinting/sequence analysis, was used to discern the distinct populations enriched with each substrate and under each electron-accepting condition. These combined techniques will aid in identifying the organisms responsible for dehalogenation and degradation of halogenated aromatic compounds. 相似文献
2.
Biofiltration of a mixture of volatile organic emissions 总被引:9,自引:0,他引:9
Aizpuru A Malhautier L Roux JC Fanlo JL 《Journal of the Air & Waste Management Association (1995)》2001,51(12):1662-1670
Air biofiltration is now under active consideration for the removal of the volatile organic compounds (VOCs) from polluted airstreams. To optimize this emerging environmental technology and to understand compound removal mechanisms, a biofilter packed with peat was developed to treat a complex mixture of VOCs: oxygenated, aromatic, and chlorinated compounds. The removal efficiency of this process was high. The maximum elimination capacity (ECmax) obtained was approximately 120 g VOCs/m3 peat/hr. Referring to each of the mixture's components, the ECmax showed the limits in terms of biodegradability of VOCs, especially for the halogenated compounds and xylene. A stratification of biodegradation was observed in the reactor. The oxygenated compounds were metabolized before the aromatic and halogenated ones. Two assumptions are suggested. There was a competition between bacterial communities. Different communities colonized the peat-based biofilter, one specialized for the elimination of oxygenated compounds, the others more specialized for elimination of aromatic and halogenated compounds. There was also substrate competition. Bacterial communities were the same over the height of the column, but the more easily biodegradable compounds were used first for the microorganism metabolism when they were present in the gaseous effluent. 相似文献
3.
Majumdar Deepanjan Majumdar Dipanjali 《Environmental science and pollution research international》2022,29(40):60289-60301
Environmental Science and Pollution Research - Concentration of dissolved aromatic and halogenated non-methane volatile organic compounds (NMVOCs) was estimated in sewage flowing through the open... 相似文献
4.
Aitor Aizpuru Luc Malhautier Jean-Claude Roux Jean-Louis Fanlo 《Journal of the Air & Waste Management Association (1995)》2013,63(12):1662-1670
ABSTRACT Air biofiltration is now under active consideration for the removal of the volatile organic compounds (VOCs) from polluted airstreams. To optimize this emerging environmental technology and to understand compound removal mechanisms, a biofilter packed with peat was developed to treat a complex mixture of VOCs: oxygenated, aromatic, and chlorinated compounds. The removal efficiency of this process was high. The maximum elimination capacity (ECmax) obtained was ~120 g VOCs/m3 peat/hr. Referring to each of the mixture's components, the ECmax showed the limits in terms of biodegradability of VOCs, especially for the halogenated compounds and xylene. A stratification of biodegradation was observed in the reactor. The oxygenated compounds were metabolized before the aromatic and halogenated ones. Two assumptions are suggested. There was a competition between bacterial communities. Different communities colonized the peat-based biofilter, one specialized for the elimination of oxygenated compounds, the others more specialized for elimination of aromatic and halogenated compounds. There was also substrate competition. Bacterial communities were the same over the height of the column, but the more easily biodegradable compounds were used first for the microorganism metabolism when they were present in the gaseous effluent. 相似文献
5.
HQSAR and CoMFA approaches in predicting reactivity of halogenated compounds with hydroxyl radicals 总被引:1,自引:0,他引:1
Two quantitative structure–activity relationship (QSAR) methods: hologram QSAR (HQSAR) and comparative molecular field analysis (CoMFa) were evaluated for predicting half-lives of the hydroxyl radicals reaction with substituted aromatic compounds. The HQSAR approach, which is topological in nature, results in a mathematical model which was more stable and has a greater predictive ability than the model derived on the 3-D CoMFA approach. Interpretations of the colour coded results of both methods are in good agreement with the proposed mechanism of the hydroxyl radical oxidation of halogenated aromatic compounds in the atmosphere. 相似文献
6.
Volatile organic compounds (VOCs) have been determined to be human risk factors in urban environments, as well as primary contributors to the formation of photochemical oxidants. Ambient air quality measurements of 54 VOCs including hydrocarbons, halogenated hydrocarbons and carbonyls were conducted in or near 13 urban locations in the United States during September 1996 to August 1997. Air samples were collected and analyzed in accordance with US Environmental Protection Agency-approved methods. The target compounds most commonly found were benzene, toluene, xylene and ethylbenzene. These aromatic compounds were highly correlated and proportionally related in a manner suggesting that the primary contributors were mobile sources in all the urban locations studied. Concentrations of total hydrocarbons ranged between 1.39 and 11.93 parts per billion, by volume (ppbv). Ambient air levels of halogenated hydrocarbons appeared to exhibit unique spatial variations, and no single factor seemed to explain trends for this group of compounds. The highest halogenated hydrocarbon concentrations ranged from 0.24 ppbv for methylene chloride to 1.22 ppbv for chloromethane. At participating urban locations for the year of data considered, levels of carbonyls were higher than the level of the other organic compound groups, suggesting that emissions from motor vehicles and photochemical reactions strongly influence ambient air concentrations of carbonyls. Of the most prevalent carbonyls, formaldehyde and acetaldehyde were the dominant compounds, ranging from 1.5-7.4 ppbv for formaldehyde, to 0.8-2.7 ppbv for acetaldehyde. 相似文献
7.
A method based on gas chromatography electron capture detection (GC-ECD) for the analysis of chlorinated paraffins (CPs) in biological samples has been investigated. The method includes photolytic destruction of halogenated aromatic compounds, such as PCBs, to eliminate some of the interferences in the analysis of CPs in environmental samples. Gel permeation chromatography was used to isolate CPs from the interfering components of Toxaphene and chlordane after the photolysis. GC-ECD gave a detection limit of 20 ng CPs/g fresh muscle tissue. The recovery of CPs from a spiked moose liver sample was estimated to 94%. 相似文献
8.
Ashraf Ramadan 《Journal of the Air & Waste Management Association (1995)》2017,67(11):1170-1179
Twenty-four-hour integrated ambient air samples were collected in canisters at 10 locations within Kuwait’s major power station: Doha West Power Station to assess the spatial distribution of volatile organic compounds (VOCs) within the perimeter of the station. A total of 30 samples, i.e., three samples per location, were collected during February and March. The samples were analyzed using a gas chromatography with flame ionization detection (GC-FID) system and following the U.S. EPA Method TO-14A with modification. The results reflected the emission activities on the site and the meteorological conditions during sampling. Generally speaking, there was a negative correlation between the ambient temperature and the VOC concentrations, which indicates the sources were local. The halogenated compounds formed the highest proportion (i.e. 50–75 %) of the total VOC concentrations at the ten locations. 1,2,4-Trichlorobenzene and Vinyl Chloride concentrations were the highest amongst the other halogenated compounds. The aromatic compounds formed the least proportion (i.e. 1–4%) of the total VOC levels at all locations with Toluene having the highest concentrations amongst the aromatic compounds at seven locations. Propene, which is a major constituent of the fuel used, was the highest amongst the aliphatic compounds. The findings of this study and other relevant work suggests the measured VOC levels were the highest over the year, nevertheless, further work is required to assess the precisely temporal variation of VOC due to change in meteorological conditions and the emission rates.
Implications: Assessment of VOC concentrations around a power plant in Kuwait during the peak season showed halogenated compounds to be the dominant group. The calculated indoor concentrations were lower than those reported in a residential area about 12 km away. 相似文献
9.
Model halogenated aromatic and aliphatic hydrocarbons and halogenated phenols were dehalogenated in seconds by solvated electrons generated from sodium in both anhydrous liquid ammonia and ammonia/water solutions. The minimum sodium required to completely dehalogenate these model compounds was determined by increasing the Na/substrate ratio until halogen loss was complete. Minimum sodium consumptions were determined in both anhydrous liquid ammonia and with a (5, 20, 50-fold molar excess of water per mole of halide). While more Na was consumed in the presence of water, these dehalogenations were still efficient when a 50-fold water excess was present. Dehalogenation is faster than competiting reactions with water. CCl4 and CH3CCl3 in the presence of a stoichiometric deficiency of sodium produced only CH4 and CH3CH3 and recovered CCl4 or CH3CCl3, respectively. No partially dechlorinated products were detected, indicating dechlorination was diffusion controlled. Na consumption per chlorine removed (as NaCl) was lower than that of Li, K or Ca and this advantage increased in the presence of water. Na consumption was lower using Na chunks instead of a thin Na mirror. Chloroaromatic compounds gave the parent aromatic hydrocarbon and aminated products in anhydrous ammonia but aminated products did not form when water was present. 相似文献
10.
Enhanced dehalogenation of halogenated methanes by bimetallic Cu/Al 总被引:10,自引:0,他引:10
A low-cost and high effective copper/aluminum (Cu/Al) bimetal has been developed for treatments of halogenated methanes, including dichloromethane, in near neutral and high pH aqueous systems. Bimetallic Cu/Al was prepared by a simple two-step synthetic method where Cu was deposited onto the Al surface. The presence of Cu on Al significantly enhanced rates of degradation of halogenated methanes and reduced toxic halogenated intermediates. The stability of Cu/Al was preliminarily studied by a multi-spiking batch experiment where complete degradation of carbon tetrachloride was achieved for seven times although the Cu/Al aging was found. Roles of Cu may involve protecting Al against an undesirable oxidation with water, enhancing reaction rates through the galvanic corrosion, and increasing the selectivity to a benign compound (i.e., methane). Kinetic analyses indicated that the activity of bimetallic Cu/Al was comparable to that of iron-based bimetals (e.g., palladized iron) and zero-valent metals. Bimetallic Cu/Al could be a promising reactive reagent for remediation of halogenated solvents-contaminated groundwater associated with high pH problems. 相似文献
11.
Several identified and potential natural brominated bioaccumulative compounds were studied in this work. 4,6-dibromo-2-(2('),4(')-dibromo)phenoxyanisole (BC-2) previously detected in Australian marine mammals and isolated from sponges, was synthesized. Two byproducts (a tetrabromo isomer and a tribromo congener) were investigated as well. The byproducts of the synthesis were not identified in the environmental samples investigated. Previously described natural brominated compounds (BC-1, BC-2, BC-3, BC-10, BC-11, MHC-1) and anthropogenic brominated diphenyl ethers (BDE-47, BDE-99, BDE-100, BDE-154) were detected in a sample of human milk. The sample was from a woman from the Faeroe Islands who frequently consumed fish as well as whale blubber and meat. The most abundant compound originated from the natural tetrabromo phenoxyanisole BC-3 which may have a 3:1 distribution of bromine on the two phenyl units. This sample also accumulated a dibromochloroanisole, as well as a previously unknown mixed halogenated compound (MHC-X) and an unknown, most likely aromatic brominated compound. Co-elutions on a DB-5 column were found for BDE-99 and BC-11 as well as BDE-154 and the unknown brominated compound. This suggests that quantification of these two compounds has to be carried out carefully.Two samples of lower trophic level, namely Baltic cod liver and Mexican mussel tissue, were investigated as well. The cod liver samples contained BDE congeners but also abundant signals for the natural 2,3,3('),4,4('),5,5(')-heptachloro-1(')-methyl-1,2(')-bipyrrole Q1 and tribromoanisole (TBA). The mussel sample contained Q1, TBA, another halogenated anisole, BC-1, BC-2, and BC-3, as well as additional, potential natural brominated compounds in the elution range of tribromophenoxyanisoles. 相似文献
12.
Susanne J. McDonald Mahlon C. Kennicutt II Jose Sericano Terry L. Wade Hong Liu Stephen H. Safe 《Chemosphere》1994,28(12):2237-2248
Variable levels of halogenated aromatic hydrocarbons were measured in clams (Laternula elliptica) collected from McMurdo Sound, Antarctica. Clams collected in and near Winter Quarters Bay contained high levels of organochlorine compounds, particularly polychlorinated biphenyls (PCBs). A strong gradient has been documented in Winter Quarters Bay that been linked to human activities at McMurdo Station. The activity of clam extracts as inducers of P4501A1-dependent ethoxyresorufin O-deethylase (EROD) activity was determined using in vitro bioassays utilizing rat hepatoma H4IIE cells. The extracts which exhibited the highest induction activities were those derived from clams collected in contaminated areas. Additionally, there was an excellent linear correlation between induced EROD activity versus total PCB levels (r2=0.96). The complimentary nature of both the analytical and bioanalytical data confirms the utility of the latter assay and provides a method for estimating the 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) toxic equivalents in extracts from marine biota. 相似文献
13.
Roland Treu Jerzy Falandysz 《Journal of environmental science and health. Part. B》2017,52(3):148-155
ABSTRACTThe literature on hydrocarbon remediation with basidiomycetes was reviewed. Two ecological groups are considered for bioremediation, the saprotrophic basidiomycetes (white-rot and brown-rot fungi) and the ectomycorrhizal basidiomycetes. A remarkable capacity of basidiomycetes for in vitro degradation of simple and recalcitrant hydrocarbons, such as PAH, persistent organic pollutants (POPs), halogenated HC, aromatic HC and phenols, explosives and dyes was reported for many species. However, there is a need for more studies on the practical feasibility of field applications with basidiomycetes. 相似文献
14.
The Ah receptor was identified and characterized in cytosol from a large number of diverse animal species. Molecular properties of the Ah receptor were similar in all species which had detectable receptor. However, subtle differences in receptor properties exist among animal species and these differences indicate that the Ah receptor protein is not identical in all species. It is not yet known whether differences in receptor properties among animal species play a significant role in determining differential susceptibility of the species to toxicity from halogenated aromatic compounds. 相似文献
15.
16.
Solyanikova IP Golovleva LA 《Journal of environmental science and health. Part. B》2004,39(3):333-351
Chlorophenols belong to the group of toxic and persistent to microbial attack xenobiotics. Nevertheless, due to the adaptation microorganisms acquire the ability to use chlorophenols as the sole source of carbon and energy. The present review describes the diversity of aerobic pathways for the utilization of halogenated phenols by bacteria with the emphasis on the main reactions and intermediates formed, enzymes responsible for these reactions and their genetic basis. Taking into account (i) the fact that enzymes degrading chlorophenols are similar to the ones involved in the conversion of other (chloro)aromatic compounds and (ii) that present numerous publications describing the properties of separated enzymes or encoding their genes are published, this review was planned as the attempt to present both, the most general and specific aspects in chlorophenols degradation with the emphasis on the literature of the last ten years. 相似文献
17.
To provide additional evidence that several halogenated organic compounds (HOCs) found in environmental samples are natural and not industrially produced, we analyzed an archived whale oil sample collected in 1921 from the last voyage of the whaling ship Charles W. Morgan. This sample, which pre-dates large-scale industrial manufacture of HOCs, contained two methoxylated polybrominated diphenyl ethers (MeO-PBDEs), five halogenated methyl bipyrroles (MBPs), one halogenated dimethyl bipyrrole (DMBP), and tentatively one dimethoxylated polybrominated biphenyl (diMeO-PBB). This result indicates, at least in part, a natural source of the latter compounds. 相似文献
18.
19.
Analysis of halogenated polycyclic aromatic hydrocarbons in urban air, snow and automobile exhaust 总被引:1,自引:0,他引:1
Urban air, snow and automobile exhaust samples were extensively cleaned up by open column liquid chromatography. The appropriate fractions were analysed for halogenated polycyclic aromatic hydrocarbons (XPAH) by gas chromatography/negative chemical ionization mass spectrometry (GC/NCIMS). XPAH were found in all three sample types. A urban air sample was found to contain chlorinated pyrenes, fluoranthenes and benzopyrene and brominated pyrenes and fluoranthenes. Furthermore, the concentration of 1-chloropyrene in that air sample was estimated to be 10 pg/m3. XPAH were also found in snow samples taken in the vicinity of a motor-way. Ethylene dibromide and ethylene dichloride, are probably the source of the halogen atoms in the XPAH detected in car exhaust. 相似文献
20.
Reductive dechlorination and debromination of halogenated biphenyls (PCBs) and diphenyl ethers (PBDEs) occurs efficiently at moderately elevated temperatures (350-600 °C) with zero valent iron (iron powder) in a nitrogen atmosphere. The proton donors tested were waste transformer oil, iso-octane, and n-decane. Observation of production of biphenyl and diphenyl ether and their condensation products indicates that the reaction is not simple pyrolysis, but a reduction. No halogenated organic products are observed. 相似文献