Greenhouse Gas Fluxes in Tropical and Temperate Agriculture: The need for a Full-Cost accounting of Global Warming Potentials

Agriculture's contribution to radiative forcing is principally through its historical release of carbon in soil and vegetation to the atmosphere and through its contemporary release of nitrous oxide (N_2O) and methane (CHM₄). The sequestration of soil carbon in soils now depleted in soil organic matter is a well-known strategy for mitigating the buildup of CO₂ in the atmosphere. Less well-recognized are other mitigation potentials. A full-cost accounting of the effects of agriculture on greenhouse gas emissions is necessary to quantify the relative importance of all mitigation options. Such an analysis shows nitrogen fertilizer, agricultural liming, fuel use, N_2O emissions, and CH₄ fluxes to have additional significant potential for mitigation. By evaluating all sources in terms of their global warming potential it becomes possible to directly evaluate greenhouse policy options for agriculture. A comparison of temperate and tropical systems illustrates some of these options.     

Mitigating Greenhouse Gas Emissions from Rice-Wheat Cropping Systems in Asia

The rice-wheat belt comprises nearly 24–27 million ha in South and East Asia. Rice is generally grown in flooded fields whereas the ensuing wheat crop requires well-drained soil conditions. Consequently, both crops differ markedly in nature and intensity of greenhouse gas (GHG) fluxes, namely emission of (1) methane (CH₄) and (2) nitrous oxide (N_2O) as well as the sequestration of (3) carbon dioxide. Wetland rice emits large quantities of CH₄; strategies to CH₄ emissions include proper management of organic inputs, temporary (mid-season) field drainage and direct seeding. As for the wheat crop, the major GHG is N_2O that is emitted in short-term pulses after fertilization, heavy rainfall and irrigation events. However, N_2O is also emitted in larger quantities during fallow periods and during the rice crop as long as episodic irrigation or rainfall result in aerobic-anaerobic cycles. Wetland rice ensures a relatively high content of soil organic matter in the rice-wheat system as compared to permanent upland conditions. In terms of global warming potential, baseline emissions of the rice-wheat system primarily depend on the management practices during the rice crop while emissions from the wheat crop remain less sensitive to different management practices. The antagonism between CH₄ and N_2O emissions is a major impediment for devising effective mitigation strategies in rice-wheat system - measures to reduce the emission of one GHG often intensify the emission of the other GHG.     

Assessment of uncertainties in greenhouse gas emission profiles of livestock sectors in Africa,Latin America and Europe

The global animal food chain has a large contribution to the global anthropogenic greenhouse gas (GHG) emissions, but its share and sources vary highly across the world. However, the assessment of GHG emissions from livestock production is subject to various uncertainties, which have not yet been well quantified at large spatial scale. We assessed the uncertainties in the relations between animal production (milk, meat, egg) and the CO₂, CH₄, and N₂O emissions in Africa, Latin America and the European Union, using the MITERRA-Global model. The uncertainties in model inputs were derived from time series of statistical data, literature review or expert knowledge. These model inputs and parameters were further divided into nine groups based on type of data and affected greenhouse gas. The final model output uncertainty and the uncertainty contribution of each group of model inputs to the uncertainty were quantified using a Monte Carlo approach, taking into account their spatial and cross-correlation. GHG emissions and their uncertainties were determined per livestock sector, per product and per emission source category. Results show large variation in the GHG emissions and their uncertainties for different continents, livestock sectors products or source categories. The uncertainty of total GHG emissions from livestock sectors is higher in Africa and Latin America than in the European Union. The uncertainty of CH₄ emission is lower than that for N₂O and CO₂. Livestock parameters, CH₄ emission factors and N emission factors contribute most to the uncertainty in the total model output. The reliability of GHG emissions from livestock sectors is relatively high (low uncertainty) at continental level, but could be lower at country level.     

Greenhouse gases emissions from a closed old landfill cultivated with biomass crops

Closed landfills need after-closure rehabilitation. The chosen option should ensure greenhouse gases release, from the landfill, is not promoted once settled. The objective of this study was to estimate and confront, during different seasons, CH₄, CO₂ and N₂O emissions under three vegetation covers in a closed landfill in Buenos Aires, Argentina. CH₄ (methane), CO₂ (carbon dioxide) and N₂O (nitrous oxide) emissions from landfill’s technosol under spontaneous vegetation (control), Pennisetum purpureum and Miscanthus giganteus (biomass crops), were quantified with non-steady-state non-flow-through chambers, in July 2014 and from February to July 2015. A linear regression analysis was performed to relate the variables “flux of a gas” and “concentration of that gas” from the 3 treatments and 6 dates, separating the 5 sampling times. A high correlation between concentrations and fluxes of CO₂ and N₂O was found, but no correlation was established for CH₄. Mean emissions (2014–2015) varied from: ?2.3 to 639.41 mgCH₄ m^?2 day^?1, 3884 to 46,365 mgCO₂ m^?2 day^?1 and 0.40 to 14.59 mgN₂O m^?2 day^?1. Vegetation covers had no significant effect on CH₄ and N₂O concentration in time, but they had on CO₂ concentration. Season of the year had a significant effect on concentration of the three gases. This is the first study on CH₄, CO₂ and N₂O emissions from a landfill closed 27 years ago covered with biomass crops.     

Mitigating GHG Emissions in the Humid Tropics: Case Studies from the Alternatives to Slash-and-Burn Program (ASB)

Tropical forest conversion contributes as much as 25% of the net annual CO₂ emissions and up to 10% of the N_2O emissions to the atmosphere. The net effect on global warming potential (GWP) also depends on the net fluxes of greenhouse gases from land-use systems following deforestation. Efforts to mitigate these effects must take into account not only the greenhouse gas fluxes of alternative land-use systems but also the social and economic consequences that influence their widespread adoption. The global alternatives to slash-and-burn program (ASB) investigated the net greenhouse gas emissions and profitability of a range of land-use alternatives in the humid tropics. The analysis showed that many tree-based systems reduced net GWP compared to annual cropping and pasture systems. Some of these systems are also profitable in terms of returns to land and labor. The widespread adoption of these systems, however, can be limited by start-up costs, credit limitations, and number of years to positive cash flow, in addition to the higher labor requirements. Projects that offset carbon emissions through carbon sinks in land use in the tropics might be a means of overcoming these limitations. A synthesis of the findings from this program can provide guidelines for the selection and promotion of land-use practices that minimize net global warming effects of slash-and-burn.     

An analysis of the environmental pressure exerted by the eucalyptus-based kraft pulp industry in Thailand

The study reported here focuses on the environmental pressure exerted by large-scale eucalyptus-based kraft pulp industry in Thailand. The objective of this study was to identify the most important sources of greenhouse gases, acidifying and eutrophying compounds and tropospheric ozone precursors, human toxicity compounds and solid waste associated with the kraft pulp industry. To this end, we performed an environmental systems analysis of the kraft pulp industry system in which we distinguished between two subsystems: the eucalyptus forestry subsystem and the kraft pulp production subsystem. The results indicate that the environmental pressure is caused by the kraft pulp production subsystem rather than by the eucalyptus forestry one. The chemical recovery unit was found to be the most important source of carbon dioxide (CO₂) and sulfur dioxide (SO₂) and responsible for more than one-half of the emissions of greenhouse gases and acidifying compounds from eucalyptus-based kraft pulp production in Thailand. Biomass combustion in the energy gene ration unit is an important source of nitrogen oxide (NO _x ) and carbon monoxide (CO) which in turn are responsible for over 50% of the emissions of tropospheric ozone precursors. About 73% of the eutrophication is caused by biological aerobic wastewater treatment emitting phosphorus (P). With respect to the eucalyptus forestry, only fertilizer use in eucalyptus plantations is a relevant source of pollution through the emission of nitrous oxide (N₂O) and phosphate (PO ₄ ³⁻ ).     

Trends in food production and nitrous oxide emissions from the agriculture sector in India: environmental implications

We studied trends in food production and nitrous oxide emissions from India's agricultural sector between 1961 and 2000. Data from Food and Agricultural Statistics (FAO) have been gathered covering production, consumption, fertilizer use and livestock details. IPCC 1996 revised guidelines were followed in studying the variations in N₂O-N emissions. Results suggest that total N₂O-N emissions (direct, animal waste and indirect sources) increased ~6.1 times from ~0.048 to ~0.294 Tg N₂O-N, over 40 years. Source-wise breakdown of emissions from 1961–2000 indicated that during 1961 most of the N₂O-N inputs were from crop residues (61%) and biological nitrogen fixation (25%), while during 2000 the main sources were synthetic fertilizer (~48%) and crop residues (19%). Direct emissions increased from ~0.031 to ~0.183 Tg. It is estimated that ~3.1% of global N₂O-N emissions comes from India. Trends in food production, primarily cereals (rice, wheat and coarse grains) and pulses, and fertilizer consumption from 1961–2000 suggest that food production (cereals and pulses) increased only 3.7 times, while nitrogenous fertilizer consumption increased ~43 times over this period, leading to extensive release of nitrogen to the atmosphere. From this study, we infer that the challenge for Indian agriculture lies not only in increasing production but also in achieving production stability while minimizing the impact to the environment, through various management and mitigation options.     

Modeling the effects of emission controls in the Netherlands

A photochemical air quality simulation model was applied to an area covering a large portion of The Netherlands and nearby source areas in Belgium and Germany. Simulations of an O₃ episode typical of those that occur during summer months yielded good agreement between predicted and observed O₃ levels. The level of performance for NO₂ and NO was somewhat less than that for O₃. The model was used to study the influence of mobile and stationary sources within the region, as well as the inflow of pollutants from outside the region on predicted O₃, NO₂, and NO levels within the modeling region. Pollutants transported into the region appear to have a significant influence on O₃ levels. The influence of stationary source emissions on O₃ and NO₂ levels is greater than that of mobile source emissions. The model has been a valuable tool in evaluating the possible influence of different source categories and control regulations on pollutant concentration levels.     

Soil management practices for sustainable agro-ecosystems

A doubling of the global food demand projected for the next 50 years poses a huge challenge for the sustainability of both food production and global and local environments. Today’s agricultural technologies may be increasing productivity to meet world food demand, but they may also be threatening agricultural ecosystems. For the global environment, agricultural systems provide both sources and sinks of greenhouse gases (GHGs), which include carbon dioxide (CO₂), methane (CH₄), and nitrous oxide (N₂O). This paper addresses the importance of soil organic carbon (SOC) for agro-ecosystems and GHG uptake and emission in agriculture, especially SOC changes associated with soil management. Soil management strategies have great potential to contribute to carbon sequestration, since the carbon sink capacity of the world’s agricultural and degraded soil is 50–66% of the historic carbon loss of 42–72 Pg (1 Pg=10¹⁵ g), although the actual carbon storage in cultivated soil may be smaller if climate changes lead to increasing mineralization. The importance of SOC in agricultural soil is, however, not controversial, as SOC helps to sustain soil fertility and conserve soil and water quality, and organic carbon compounds play a variety of roles in the nutrient, water, and biological cycles. No-tillage practices, cover crop management, and manure application are recommended to enhance SOC storage and to contribute to sustainable food production, which also improves soil quality. SOC sequestration could be increased at the expense of increasing the amount of non-CO₂ GHG emissions; however, soil testing, synchronized fertilization techniques, and optimum water control for flooding paddy fields, among other things, can reduce these emissions. Since increasing SOC may also be able to mitigate some local environmental problems, it will be necessary to have integrated soil management practices that are compatible with increasing SOM management and controlling soil residual nutrients. Cover crops would be a critical tool for sustainable soil management because they can scavenge soil residual nitrogen and their ecological functions can be utilized to establish an optimal nitrogen cycle. In addition to developing soil management strategies for sustainable agro-ecosystems, some political and social approaches will be needed, based on a common understanding that soil and agro-ecosystems are essential for a sustainable society.     

CO2 emissions in German, Swedish and Colombian manufacturing industries

This study evaluates and compares the trends in CO₂ emissions for the manufacturing industries of three countries: two developed countries (Germany and Sweden) that have applied several measures to promote a shift towards a low-carbon economy and one developing country (Colombia) that has shown substantial improvements in the reduction of CO₂ emissions. This analysis is conducted using panel data cointegration techniques to infer causality between CO₂ emissions, production factors and energy sources. The results indicate a trend of producing more output with less pollution. The trends for these countries’ CO₂ emissions depend on investment levels, energy sources and economic factors. Furthermore, the trends in CO₂ emissions indicate that there are emission level differences between the two developed countries and the developing country. Moreover, the study confirms that it is possible to achieve economic growth and sustainable development while reducing greenhouse gas emissions, as Germany and Sweden demonstrate. In the case of Colombia, it is important to encourage a reduction in CO₂ emissions through policies that combine technical and economic instruments and incentivise the application of new technologies that promote clean and environmentally friendly processes.     

Sea to air transport of trace gases in the coastal zone: a literature review

Exchange of trace gases between the oceans and the atmosphere affects the atmospheric content and cycling of a range of chemical species which are related to climate change, ozone layer depletion, acid deposition, eutrophication, atmospheric particle formation, photo-oxidants, trace metals and persistent organic pollutants (POPs). The effects and impacts of air–sea exchange of these gases can be local, regional and global. Until now, most of the research has concentrated on the sea–air exchange of trace gases in the open ocean. The flux rates of the trace gases from the coastal waters to the air are much higher than the rates for the open ocean and the contribution of the coastal areas to the total oceanic emissions of these trace gases can be significant on a global scale. This contribution can be as high as 50% and more for nitrous oxide and COS. Concerning the contribution of the trace gas production in the coastal areas to the total global production of these gases, it can be concluded that this contribution seems to be below 2% except for nitrous oxide. However, it should be pointed out that on the local and even regional scale the emissions in the coastal areas can be very important, contributing substantially to the total emission of these gases in a studied area. Thus, there is a need to carry out studies in the future with the aim to provide more accurate understanding of the production and sea–air exchange processes for these gases around the world. Electronic Publication     

Greenhouse gas emissions from a semi-arid tropical reservoir in northeastern Brazil

We estimated carbon dioxide (CO₂) and methane (CH₄) emissions by diffusion, ebullition, and degassing in turbines from a semi-arid hydropower reservoir in northeastern Brazil. Sampling sites were allocated within the littoral and deeper waters of one embayment, the main-stream, and at turbines. Annual carbon emissions were estimated at 2.3?×?10⁵?±?7.45?×?10⁴ t C year^?1, or in CO₂-equivalents (CO₂-eq) at 1.33?×?10⁶?±?4.5?×?10⁵ t CO₂-eq year^?1. Diffusion across the water surface was the main pathway accounting for 96% of total carbon emissions. Ebullition was limited to littoral areas. A slight accumulation of CO₂, but not of CH₄, in bottom waters close to the turbines inlet led to degassing emissions about 8?×?10³ t C year^?1. Emissions in littoral areas were higher than in main-stream and contribute to 40% of the total carbon. Carbon (C) emissions per electricity generated, at 60% of installed capacity, is 0.05 t C-CO₂-eq MWh^?1. The ratio increases to 0.09 t C-CO₂ MWh^?1, equating 80% of the emissions from natural gas and 40% of diesel or coal power plants. Retention time and benthic metabolism were identified as main drivers for carbon emissions in littoral areas, while water column mixing and rapid water flow are important factors preventing CH₄ accumulation and loss by degassing. Our results indicate that Itaparica Reservoir, located in the semi-arid region of Northeastern Brazil, acts as a source of GHGs. Management measurements are needed to prevent emissions to raise in the future.     

Estimating the effect of nitrogen fertilizer on the greenhouse gas balance of soils in Wales under current and future climate

The Welsh Government is committed to reduce greenhouse gas (GHG) emissions from agricultural systems and combat the effects of future climate change. In this study, the ECOSSE model was applied spatially to estimate GHG and soil organic carbon (SOC) fluxes from three major land uses (grass, arable and forest) in Wales. The aims of the simulations were: (1) to estimate the annual net GHG balance for Wales; (2) to investigate the efficiency of the reduced nitrogen (N) fertilizer goal of the sustainable land management scheme (Glastir), through which the Welsh Government offers financial support to farmers and land managers on GHG flux reduction; and (3) to investigate the effects of future climate change on the emissions of GHG and plant net primary production (NPP). Three climate scenarios were studied: baseline (1961–1990) and low and high emission climate scenarios (2015–2050). Results reveal that grassland and cropland are the major nitrous oxide (N₂O) emitters and consequently emit more GHG to the atmosphere than forests. The overall average simulated annual net GHG balance for Wales under baseline climate (1961–1990) is equivalent to 0.2 t CO₂e ha^?1 y^?1 which gives an estimate of total annual net flux for Wales of 0.34 Mt CO₂e y^?1. Reducing N fertilizer by 20 and 40 % could reduce annual net GHG fluxes by 7 and 25 %, respectively. If the current N fertilizer application rate continues, predicted climate change by the year 2050 would not significantly affect GHG emissions or NPP from soils in Wales.     

Characteristics of oxidant precursor emissions from anthropogenic sources in the United States

Hydrocarbons (HC) and nitrogen oxides (NO_x) have been identified as the most important precursor pollutants for oxidant formation in the atmosphere. These pollutants are emitted both from natural and anthropogenic sources; however, these two types of sources are generally geographically separated. Anthropogenic emissions are dominant in and around urban centers, where the majority of severe oxidant problems occur. Based on data gathered by the MAP3S/RAINE emissions inventory project, anthropogenic emissions of HC in the conterminous United States were 24.8 million metric tons in 1979. HC emissions were predominantly from area sources, the transportation sector being the largest contributor with 39.8% of the total. State-by-state breakdowns are also included. Based on analyses by other emissions inventory projects, the nonreactive fraction of the emissions from the transportation sector is less than 20% by weight. The highest proportion of HC emissions occur at low altitudes (0–50 m range) in high population density areas. Anthropogenic emissions of NO_x were 23.7 million metric tons in 1979; 50.8% were from point sources. The transportation sector and the electric utilities sector account for 37.1% and 30.9% of the NO_x emissions, respectively. The NO₂ fraction of the emissions from the transportation and electric utilities sectors is less than 10% by weight, based on NO/NO₂ speciation data from two other emissions inventories. Highest rates of NO_x emissions occur in high population density areas and are released at low altitude (0–50 m); three areas of high electric generating capacity were found to have high release altitudes.     

Radon, helium and CO2 measurements in soils overlying a former exploited oilfield, Pechelbronn district, Bas-Rhin, France

The Pechelbronn oilfield (Rhine Graben, France), where mining activity ended in the 1960s, has been used for waste disposal for twenty years. Since the wastes are varied, work is underway to identify the discharged materials and their derivatives, as well as to locate and quantify potential discharge sites. Two major goals were assigned to the present work. The first was to identify or refine the location of hidden structures that could facilitate gas emanation up to the surface, by studying soil gas concentrations (mainly ²²²Rn, CO₂, CH₄ and helium) and carbon isotope ratios in the CO₂ phase. The second was devoted to examining, from a health and safety viewpoint, if the use of the oilfield as a waste disposal site might have led to enhanced or modified gas emanation throughout the area.It appeared that CO₂ and ²²²Rn evolution in the whole area were similar, except near some of the faults and fractures that are known through surface mapping and underground observations. These ²²²Rn and CO₂ anomalies made it possible to highlight more emissive zones that are either related to main faults or to secondary fractures acting as migration pathways. In that sense, the CO₂ phase can be used to evaluate ²²²Rn activities distant from tectonic structures but can lead to erroneous evaluations near to gas migration pathways. Dumping of wastes, as well as oil residues, did not appear to have a strong influence on soil gaseous species and emanation. Similarly, enhanced gas migration due to underground galleries and exploitation wells has not been established. Carbon isotope ratios suggested a balance of biological phenomena, despite the high CO₂ contents reached. Other monitored gaseous species (N₂, Ar, H₂ and alkanes), when detected, always showed amounts close to those found subsurface and/or in atmospheric gases.     

Farm-level assessment of CO2 and N2O emissions in Lower Saxony and comparison of implementation potentials for mitigation measures in Germany and England

Greenhouse gases (GHG) emissions from agricultural farming practice contribute significantly to European GHG inventories. For example, CO₂ is emitted when grassland is converted to cropland or when peatlands are drained and cultivated. N₂O emissions result from fertilization. Enabling farmers to reduce their GHG emissions requires sufficient information about its pressure–impact relations as well as incentives, such as regulations and funding, that support climate-friendly agricultural management. This paper discusses potentials to improve the supply of information on: farm-specific climate services or impacts, present policy incentives in Germany and England that support climate-friendly farm management and related adaptation requirements. Tools which have been developed for a farm environmental management software (to be added after review because of potential identification) are presented. These tools assess CO₂ emissions from grassland conversion to cropland and peatland cultivation, as well as N₂O emissions from nitrogen fertilization. As input data, the CO₂ tool requires a classification of soil types according to soil organic carbon storage. The input data based on soil profile samples was compared with reference data from the literature. The N₂O tool relies on farm data concerning fertilization. These tools were tested on three farms in order to determine their viability with respect to the availability of required data and the differentiation of results, which determines how well site-specific conservation measures can be identified. Assessing CO₂ retention function of grassland conservation to cropland on the test farms leads to spatially differentiated results (~100 to ~900 potentially mitigated t CO₂ ha^?1). Assessed N₂O emissions varied from 0.41 to 1.1 t CO₂eq. ha^?1 a^?1. The proposed methods support policies that promote a more differentiated funding of climate conservation measures. Conservation measures and areas can be selected so that they will have the greatest mitigation effects. However, even though present policy instruments in Germany and England, such as Cross Compliance and agri-environmental measures, have the potential to reduce agricultural GHG, they do not appear to guide measures effectively or site-specifically. In order to close this gap, agri-environmental measures with the potential to support climate protection should be spatially optimized. Additionally, the wetland restoration measures which are most effective in reducing GHG emissions should be included in funding schemes.     

Comparison of indoor and outdoor air quality at two staff quarters in Hong Kong

The indoor and outdoor air quality of two staff quarters of Hong Kong Polytechnic University at Tsim Sha Tsui East (TSTE) and Shatin (ST) were investigated. The air sampling was carried out in winter for about two months starting from January to February of 1996. Fifteen flats from each staff quarter were randomly selected for indoor/outdoor air pollutant measurements. The pollutants measured were NO_x, NO, NO₂, SO₂, CO, and O₃. The variations of pollutant concentrations between indoor and outdoor air were investigated on weekday mornings, weekday evenings, weekend mornings, and weekend evenings. All indoor/outdoor pollutant concentrations measured did not exceed the ASHRAE/NAAQS standard. The carbon monoxide concentrations indoors were systemically higher than those outdoors at the TSTE and the ST quarters, both on weekdays and Sunday, which indicates there are CO sources indoors. Except for CO, the indoor levels of other pollutants (NO_x, NO, NO₂, SO₂, and O₃) are lower than those outdoors. There was a significant correlation (P < 0.05) between indoor and outdoor concentrations for SO₂ and O₃ at both the TSTE and the ST quarters. Except for O₃, the mean concentrations of all the pollutants in the TSTE quarters, both indoor and outdoor, were higher than that of the ST quarters in all sampling periods. All indoor and outdoor O₃ levels were lower at the TSTE quarters than those at the ST quarters. The O₃ ratios of TSTE/ST were 0.72 outdoor and 0.79 indoor. This can be explained by the NO titration reaction through NO conversion to NO₂.     

Using air quality modeling to study source–receptor relationships between nitrogen oxides emissions and ozone exposures over the United States

Human exposure to ambient ozone (O₃) has been linked to a variety of adverse health effects. The ozone level at a location is contributed by local production, regional transport, and background ozone. This study combines detailed emission inventory, air quality modeling, and census data to investigate the source–receptor relationships between nitrogen oxides (NO_x) emissions and population exposure to ambient O₃ in 48 states over the continental United States. By removing NO_x emissions from each state one at a time, we calculate the change in O₃ exposures by examining the difference between the base and the sensitivity simulations. Based on the 49 simulations, we construct state-level and census region-level source–receptor matrices describing the relationships among these states/regions. We find that, for 43 receptor states, cumulative NO_x emissions from upwind states contribute more to O₃ exposures than the state's own emissions. In-state emissions are responsible for less than 15% of O₃ exposures in 90% of U.S. states. A state's NO_x emissions can influence 2 to 40 downwind states by at least a 0.1 ppbv change in population-averaged O₃ exposure. The results suggest that the U.S. generally needs a regional strategy to effectively reduce O₃ exposures. But the current regional emission control program in the U.S. is a cap-and-trade program that assumes the marginal damage of every ton of NO_x is equal. In this study, the average O₃ exposures caused by one ton of NO_x emissions ranges from ? 2.0 to 2.3 ppm-people-hours depending on the state. The actual damage caused by one ton of NO_x emissions varies considerably over space.     

The chemistry of smog formation: A review of current knowledge

This paper describes smog chemistry and the methods used to develop our knowledge of its complex chemistry. These methods employ computer modeling, fundamental chemistry, smog chamber experiments, sophisticated analytical instrumentation, and process analysis techniques. The photochemistry leading to smog formation involves a kinetically controlled and coupled competitive process. The essential pathway for formation of nitrogen oxides starts with emissions composed primarily of NO, which are converted to NO₂, mostly via reactions with peroxy radicals; NO₂ is converted to photochemically inert nitric acid primarily by reaction with OH. Organics in smog chemistry are eventually oxidized to CO₂ and water; before this, they typically react with OH to form peroxy radicals. The peroxy (RO₂·) radicals couple the organic and nitrogen chemistry by converting NO to NO₂; the RO₂· radicals are converted to RO radicals, which typically lead to oxygenated intermediate organics that continue through OH·---RO₂·---RO· cycles. These OH·---RO₂·---RO· cycles produce CO, CO₂, and radical products. The radical products, which usually derive from photolysis of oxygenated intermediate organic products, are central to the overall process of smog formation. This is because the balance of these radicals affects the rapidity and severity of smog development. The radical balance is, in turn, controlled by the sources and sinks that depend on the HC/NO_x ratio, the types of organics, and the light flux. With only a rudimentary understanding of smog chemistry as a process, many of the effects observed from precursor controls can be explained and the basic shape of Empirical Kinetics Modeling Approach (EKMA) isopleth curves can be accounted for. The next step beyond this basic level of understanding involves a host of subprocesses composed of a complex series of chemical reactions. Current research in smog chemistry centers on the assessment and elucidation of these complex subprocesses. Atmospheric models currently in use rely on condensed chemical mechanisms. All such modern mechanisms treat the same basic processes, but differ both in their method of condensation and in their manner of addressing the complex subprocesses of smog chemistry.     

Annual and diurnal variations of gaseous and particulate pollutants in 31 provincial capital cities based on in situ air quality monitoring data from China National Environmental Monitoring Center

Long-term air quality data with high temporal and spatial resolutions are needed to understand some important processes affecting the air quality and corresponding environmental and health effects. The annual and diurnal variations of each criteria pollutant including PM_2.5 and PM₁₀ (particulate matter with aerodynamic diameter less than 2.5 μm and 10 μm, respectively), CO (carbon monoxide), NO₂ (nitrogen dioxide), SO₂ (sulfur dioxide) and O₃ (ozone) in 31 provincial capital cities between April 2014 and March 2015 were investigated by cluster analysis to evaluate current air pollution situations in China, and the cities were classified as severely, moderately, and slightly polluted cities according to the variations. The concentrations of air pollutants in winter months were significantly higher than those in other months with the exception of O₃, and the cities with the highest CO and SO₂ concentrations were located in northern China. The annual variation of PM_2.5 concentrations in northern cities was bimodal with comparable peaks in October 2014 and January 2015, while that in southern China was unobvious with slightly high PM_2.5 concentrations in winter months. The concentrations of particulate matter and trace gases from primary emissions (SO₂ and CO) and NO₂ were low in the afternoon (~ 16:00), while diurnal variation of O₃ concentrations was opposite to that of other pollutants with the highest values in the afternoon. The most polluted cities were mainly located in North China Plain, while slightly polluted cities mostly focus on southern China and the cities with high altitude such as Lasa. This study provides a basis for the formulation of future urban air pollution control measures in China.