湿法炼锌循环经济产业链设计及指标

湿法炼锌属于高污染、高能耗行业之一。随着市场竞争日益激烈以及社会对资源节约和环境保护的重视,锌冶炼生产企业必须实现可持续发展,走出传统的"资源消费—产品—废物排放"的直线型经济增长模式。针对湿法炼锌工艺特点,运用循环经济的基本理论,利用主链、支链、延链和补链设计出针对湿法炼锌的循环经济产业链网,并以某10×104t锌冶炼企业为例,分析了该产业链网中的物流和能流,提出了湿法炼锌企业的循环经济产业链指标。     

锡渣及其类似物中钽铌的回收

多数锡矿石都含有钽铌矿物,在炼锡过程中所产生的锡渣中常食有相当数量的钽铌。但由于品位太低,若直接运用常规冶炼钽铌的方法来处理这类锡渣是很不经济的;若首先用稀硫酸处理,浸出内含物,则可以富集其中的钽铌、生产出人造钽铌精矿,然后用湿法个炼工艺回收其中的钽铌,可变废为宝,节约资源。其工艺过程如下：1锡渣的酸浸处理。将锡渣研磨成一定粒度后,用0.5％～1.0％的硫酸。在温度为50℃左右的条件下酸30min～90min,然后过滤,这样渣中的钙、硅、铝等被浸出。钽铌及钛、锆等组分大部分将留于固体残渣中,经过该工序处理后的残渣…     

生活垃圾焚烧底渣中重金属和多环芳烃的浸出实验研究

随着生活垃圾焚烧处理方式的不断推广，焚烧底渣的产生量也不断增加。按照我国的固体废物分类方法，底渣属于一般固体废物，无需进一步处置而可直接进入环境。实验结果表明，底渣中的重金属和多环芳烃可以被浸出而迁移进入环境。重金属的浸出浓度受到水相pH值和底渣粒度的影响，初期的浸出浓度最大。在底渣浸出液中，可以检测到8种环数≤4的多环芳烃，其中菲的浸出浓度最大（超过10ng／mL）。实验结果显示，底渣中的多环芳烃对环境造成的二次污染比较严重。     

有机菌肥对铅、镉、锌污染土壤和水体联合修复研究

为了研究液体有机菌肥在矿区周边农田污染土壤重金属去除效果，以重金属污染为研究对象，开展液体有机菌肥吸附混合液重金属试验和土壤重金属浸出毒性吸附实验，分析液体有机菌肥对重金属离子去除作用。结果表明：随着液体有机菌肥用量的增加，水体重金属铅、镉和锌含量浓度呈显著下降，液体有机菌肥容易吸附铅，吸附量高达到1667mg/kg,其次是镉和锌。在1%质量比添加量下，经过液体有机菌肥修复后的土壤镉、锌和铅含量下降率分别是29.62%、23.94%和11.66%,土壤重金属TCLP浸出毒性去除率效果显著。有机菌肥处理可改善土壤环境，对土壤和水体的铅、镉、锌重金属有一定修复作用。     

FR菌富集锌的研究

电镀厂排放废水中常含有大量的锌,若将其回收,不但能减轻对环境的污染,而且能使废锌资源化。本文研究了FR菌富集电镀废水中锌的条件,包括锌的浓度,菌的用量,酸度,吸附平衡时间和处理含锌电镀废水的效果。同时用~(65)Zn示踪研究了最佳条件下,FR菌对~(65)Zn和稳定性锌富集的差异。实验表明,可用~(65)Zn代替稳定性锌进行微生物富集锌的研究,而省去繁冗的分析操作。     

铬渣湿法和干法解毒技术的应用对比

通过对国内典型铬渣处理的项目进行分析,并结合某铬渣污染治理工程实例,从反应机理、解毒工艺、工艺适应性、资源回收利用、设备选型、处理规模、场址选择、污染控制及安全生产和经济性方面对铬渣湿法解毒和干法解毒技术在实际应用中的选择进行对比,为该项目提出了更适合的解毒技术。     

湿法解毒技术对铬渣污染土壤的修复效果研究

文章以某铬盐生产场地内的铬渣污染土壤为研究对象,探讨硫酸亚铁湿法解毒技术的修复效果及其主要影响因素。     

低品位氧化锌矿的碱法浸出研究进展

随着世界对锌的需求量的增加,碱法浸出低品位氧化锌矿因其显著的优点（浸出率达90%以上、环境污染小等）而成为国内外研究的热点。本文主要介绍了低品位氧化锌矿氢氧化钠浸出体系的动力学和热力学过程,氨浸体系中氯铵、碳铵、硫氨浸出的国内外各研究单位的最近研究成果,并对碱浸过程中矿石活化、闪锌矿难溶解两类问题进行了讨论。     

含汞气田汞污染控制技术研究

痕量组分汞可能出现在大多数天然气气藏中。汞及其化合物均是剧毒物质,在含汞天然气处理过程中可能危害操作人员健康、腐蚀管线设备以及污染环境。针对某气田含汞天然气处理工艺,分析汞在天然气处理过程中分布情况,评价汞对天然气处理工艺及环境的影响,提出了含汞气田汞污染的控制技术以及防护措施,对降低含汞气田开发风险、保护人身健康及防止环境污染具有现实意义。     

黄河以北地区输水干线底泥对调水水质的影响

通过对南水北调东线一期工程的黄河以北地区输水干线底泥污染现状的调查和污染物浸出性实验,分析了输水干线底泥可能对调水水质产生的潜在风险,并根据水质目标要求进行了风险预测分析,最后提出了相应的保障措施和建议。     

Time-series analysis of global zinc demand associated with steel

This study aimed to analyze the global-scale substance flow of zinc associated with steel in order to discuss the sustainable use of zinc resources in the future. The relationship between the demand for steel and zinc was characterized in terms of zinc intensity for galvanized steel and the percentage of galvanized steel that accounts for the total steel demand. Zinc consumption for steel was divided into end uses according to the statistics on steel. Zinc demand in the future was forecasted with three scenarios for zinc intensity. Future steel demand was estimated using the stocks-drive-flows model, in which the demand is determined by the change in stock. The growth of in-use stock of galvanized steel in the future was estimated by considering economic growth on the basis of the transition of in-use stock of galvanized steel in the past. The cumulative zinc demand for galvanized steel up to the year 2050 was compared with the zinc reserves. It was found that the global average recovery rate of zinc was estimated at approximately 20% by the dynamic substance flow analysis for zinc. It is hoped that the recovery rate will increase. Even if zinc intensity is continuously reduced according to an experience curve based on technological development, a large portion of the current reserves will be consumed for galvanized steel. It was concluded that technological development in reducing zinc intensity will play a significant role in zinc resource conservation.     

A CONFIRMATION OF MOUNT'S AUTOPSY TECHNIQUE FOR ZINC-CAUSED FISH MORTALITY1

ABSTRACT. A total of 203 bluegill sunfish (Lepornis macrochirus, Rafinesque) which had been used in several acute zinc experiments carried out under varied environmental conditions were autopsied according to Mount's procedure for determining fish mortality due to zinc poisoning. Three classes of fish were used: those exposed to but not killed by zinc; those killed by zinc; and those not exposed to zinc. Two statistical tests were used to analyze these data and both tests gave results indicating significant differences (a = .05) between all three classes of fish. This indicates that the Mount autopsy technique is very probably a valid generalization. The possibilities of using Mount's technique as a predictive tool are discussed.     

微波消解火焰原子吸收光谱法测定茶叶中的锌

采用微波消解样品,用火焰原子吸收法直接测定茶叶中的锌含量。回收率85.98%~118.62%,相对标准偏差为1.7%。方法准确、操作简便,可实现同一样品的快速测定,且最大限度地减少了对测定的干扰。微波消解作为一种样品制备方法,在茶叶样品预处理方面,避免了传统湿法消解的限制,具有传统碱式干法消解与酸浸提法无法比拟的优点。     

ACCUMULATION OF SELECTED TRACE METALS IN SOILS OF URBAN RUNOFF SWALE DRAINS1

ABSTRACT: Field investigations were conducted at three sites in the Washington, D.C., area to detect the accumulation patterns of the trace metals, cadmium, copper, lead and zinc in the soils of roadside grassed swale drains that had been receiving urban stormwater runoff. Two sites were residential areas and one site was an intensively used highway. The research results seem to indicate that the use of swale drains to control urban stormwater runoff had few harmful effects to fine textured soils with respect to the study metals. With the exception of zinc, typical roadside patterns of decreasing metal concentrations with increasing distance from roads were observed for the upper 5 cm of study soils. Zinc accumulated in residential grassed swales due to leachate from galvanized curverts. Sampling to a depth of 60 cm revealed no evidence of subsurface trace metal enrichment in the study swales. Although the percentage of soil zinc in leachable form was as high as 20 percent of total zinc concentrations, the other study metals had small leachable components. Leachable lead was always less than 1 percent of the total lead.     

EFFECTS OF SUSPENDED SOLIDS ON THE ACUTE TOXICITY OF ZINC TO DAPHNIA MAGNA AND PIMEPHALES PROMELAS1

ABSTRACT: Current procedures for setting site-specific water quality criteria consider abiotic and biotic factors. Suspended solids were shown to be important in reducing zinc toxicity to water column organisms. At zinc concentrations of ～ 1 mg/L in solutions with < 100 mg/L of all suspended solids tested, zinc toxicity to D. magna was reduced. Sorption of zinc to suspended solids and/or changes in water chemistry due to the addition of suspended solids appear to have been the factors causing reductions in zinc toxicity to D. magna. Only suspended solids levels of 483–734 mg/L of a type that increased total alkalinity, total hardness, and total dissolved carbon clearly reduced the toxicity of ～ 20 mg/L zinc to P. promelas. The toxic form of zinc to these organisms appears to reside in the aqueous phase. Characteristics of suspended solids did not influence the partition coefficient of zinc in sorption experiments of 96 h. The slopes of dose-response curves proved to be useful for assessing the potential of an organism to respond to changes in aqueous phase zinc concentrations, and may be a useful biological parameter when considering site-specific water quality criteria for chemicals.     

Iron and Zinc status in soils, water and staple food cultivars in Itakpe, Kogi State of Nigeria

The levels of iron (Fe) and zinc (Zn) were quantitatively determined in soil and water samples as well as in staple food cultivars in Itakpe, Nigeria's major iron mining town. The survey was conducted to establish a baseline pollution index for Fe and Zn in the Itakpe environment and to evaluate the role of foods as an exogenous source of these metals among the inhabitants. Exceedingly high levels of both metals characterized the staple food cultivars in the town.     

Dynamic material flow analysis of zinc resources in China

Zinc is one of the most widely applied nonferrous metals in China. Study on the applications and recurrent situation of zinc resources is of great strategic importance for the sustainable development of China's economy. In this paper, a dynamic material flow analysis (MFA) method has been adopted to analyze quantificationally zinc resources in China, as well as to analyze and predict the quantity of zinc product scrap and their recycling situation. The weighted average method was applied to calculate average lifetimes of six major zinc products in China. The average lifetimes of battery, zinc oxide, zinc die-casting alloys, zinc material products, galvanized zinc and brass are 0.17, 5.3, 11.1, 12, 21 and 30 years, respectively. Assuming the lifetime of zinc product group obeys the Weibull distribution and the consumption of zinc products varies linearly with time, the future consumption and scrap generation of zinc products will increase continuously. It is expected that they would increase from 49% to 76% during 2004–2020, respectively. Assuming the recycling rate remains unchanged with time, the zinc old scrap index, both the theoretical and actual values, would continue increasing in China. The values are expected to reach 0.402 and 0.076 by 2020, respectively. Therefore, the regeneration resource of depreciated zinc is actually insufficient in China. According to the scenario analysis, the actual value of old scrap indexes is positively correlated with the recycling rate of zinc products. Because galvanized products are the largest consumption area of zinc products in China, the influence of their recycling rate on old scrap index is obviously larger than other zinc products. Through the analysis, this paper suggests that the increase of the recycling rate of zinc products could not only improve to a certain degree China's relative shortage of zinc resources, but greatly relive the supply pressure of zinc in the world.     

Exploration and discovery of Australia's copper,nickel, lead and zinc resources 1976–2005

Examination of copper, nickel, lead and zinc (base metals) exploration expenditure and discovery in Australia over the period 1976–2005 reveals some significant trends. Australia's base metal resource inventory grew substantially as a consequence of successful exploration over the period, both through addition of resources at known deposits and new discoveries, notably a small number of very large deposits that underpin the resource base. In 2005, Australia had the world's largest economic demonstrated resources (EDR) of nickel, lead and zinc, and the second largest EDR of copper. Growth in nickel resources has been especially strong owing to discovery of large laterite resources in the late 1990s. Resource life, in average terms based on current EDR and production, is approximately 30 years for lead and zinc, 40 years for nickel sulphide (120 years for all nickel EDR) and 50 years for copper. Despite this success, major increases in production over the period (copper, nickel and zinc output increasing 3–4 fold, lead output doubling) and a fall in discovery rates during much of the 1990s means that resource life for lead and zinc is lower and nickel sulphide comparable now to that in 1976; only the resource life of copper has grown substantially over the period. Current published ore reserves are sufficient for at least 15 years operations at current production levels, but only a small number of the largest deposits currently being mined are likely to still be in production in 20 years. However, several mines have substantial inferred resources that may allow production beyond current mine reserves and there is a substantial number of undeveloped deposits that may provide the foundation for extended or new mining operations. The discovery record is strongly cyclical with resource growth for all the base metals punctuated by the discovery of giant (world-class) deposits each decade: these underpin current and future production. Recent higher metal prices and renewed interest in base metals, especially nickel, has reversed a 10 year decline in base metal exploration attended by reduced rates of discovery and resulted in record expenditure, new nickel, copper and zinc discoveries, and increased resources at a number of existing deposits, notably the Olympic Dam copper–uranium–gold deposit. With the exception of the Prominent Hill copper–gold and West Musgrave nickel–copper deposits, most of the recent discoveries, especially zinc (-lead) deposits, are of small tonnage (some of high grade). Nevertheless, these new discoveries have helped stimulate further exploration and also highlight the potential for further discoveries in little-explored provinces, especially those under regolith and shallow sedimentary cover.     

某区域内矿区土壤重金属污染与生态风险评价

探究区域内矿区土壤重金属变化并对其进行污染评价,旨在为该区域环境保护及污染治理提供一定的理论依据,以期实现矿山地质环境保护与矿产资源开发并行的矿业绿色发展。以铅、锌、镉、砷含量为评价指标,结合《土壤环境质量标准》(GB 15618—2018),采用重金属单因子污染指数法与内梅罗综合污染指数法进行重金属污染评价,并对该区域矿区潜在生态风险作出评定。结果表明,A矿区土壤各重金属含量的变异系数为149.05%~211.42%,B矿区土壤各重金属含量变异系数为60.88%~118.58%;A矿区土壤重金属均出现超标现象,其中铅、锌和镉含量超标较为严重,超标率在72%以上,而砷含量超标现象则相对较轻,超标率为36.36%;B矿区土壤铅和锌含量均未出现超标,超标率为0,而砷和镉含量则出现不同程度的超标,其中砷含量超标率为92.31%,镉含量超标率为65.38%;两个矿区土壤各重金属含量均超背景值的现象,超背景值比例为42.31%~100.00%。A矿区土壤以铅、锌和镉污染为主,而B矿区土壤中砷和镉的污染较为严重。两个矿区土壤重金属综合污染指数均属重度污染,A矿区生态风险综合指数为很强生态风险危害,而B矿区为中等生态风险危害。