成都地铁一号线站台内空气中氡浓度分布状况研究

为了解成都地铁车站环境中氡浓度水平,采用Model1027连续测氡仪,对成都地铁1号线,进行抽样监测调查。调查结果表明:成都地铁车站的氡浓度范围为12.4Bq/m3~29.0Bq/m3,平均值为16.6Bq/m3,远低于《地下建筑物氡及其子体控制标准》(GB 16356-1996)的限值;与成都市室外环境中氡浓度相当,低于成都市居室环境中氡浓度;低于全国七城市地铁站点氡浓度平均值。     

用相对危险度模型分析氡致肺癌

用持续相对危险度模型分析1930—1987年美国人受氧暴露对患肺癌的贡献,模型假定受氧照射的危险度正比于肺癌的发病率。尽管自1930年以来,氧引起的肺癌死亡人数在明显增加。美国环境保护署(EPA)仍给出了在持续的氧暴露情况下,氧致肺癌死亡人数在总的肺癌死亡人数中占得比例区间。在室内氧浓度条件下,估计这个区间为8％—25％。该文中还对主要不确定因素进行了分析计算。     

阿坝州大骨节病和扶贫开发决策中AHP方法的应用

大骨节病防治和扶贫开发试点工作涉及阿坝州的经济、社会、生态等各方面，且州内各县、乡、村情况各异，众多具体措施关系复杂。为了提高决策质量，使试点工作取得“优化举措、重点突破”的效果，应用AHP方法建立了定量模型。     

环境中的氡与肺癌

氡（222Rn），为自然界中一种放射性隋性气体。由镭（222Ra）径α衰变而产生，其物理半衰期仅为3．825夭。氧及其衰变后产生的子体能引起肺癌这一严重事实越来越引起人们的重视。1924年科学家在寻找施内贝格等矿山矿工死于“矿山病”病因的同时发现了氧这一主要致病因素。氧及其子体在空气中以离子、凝集核和粒子这三种形式存在。对机体的危害主要是氧粒子。被吸入人体内的氧及其子体20％沉积在鼻咽部，10％沉积在口腔及咽喉部，70％沉积在肺内。它对机体的危害程度与时间、吸入剂量呈正比例。氧及其子体进入人体内轻者可致呼吸道炎症，肺…     

液化气可诱发心脏病

<正> 目前液化气已成为居民生活中主要能源之一,使用它即方便又省时。但英国剑桥大学科学家测试结果表明,长期燃烧液化气造成室内气气污染,有诱发心脏病的危险,他们对168人的呼气和其住室进行了一氧化碳测定,结果表明:燃烧液化气的室内空气中,一氧化碳平均浓度为18%:而经常在燃烧液化气的室内居住者的呼气中,一氧化碳浓度可达10%～30%。在把液化气炉火由大关小时,如果室内氧气不足,液化气不能充分燃烧,导致更多的一氧     

四川省海螺沟区域臭氧本底特征分析

利用海螺沟国家大气背景站2013～2017年的地面O_3连续观测资料统计,期间海螺沟背景区域(O_3-1h)平均浓度为71μg/m~3,(O_3-8h)平均浓度为80μg/m~3,成都市(O_3-8h)平均浓度为165μg/m~3,成都市高出背景区域106%;通过分析和比较背景区域和城市臭氧浓度的变化特征,采用局部近似回归法对海螺沟臭氧背景值进行筛分分析,得出2015～2017年海螺沟区域臭氧春季本底为83±5μg/m~3,夏季本底值为72.5±5.5μg/m~3,冬季本底值为69±5μg/m~3,秋季本底值为60±3μg/m~3。     

好氧颗粒污泥降解邻苯二甲酸二甲酯的影响因素研究

本文研究了好氧颗粒污泥系统中,温度、pH、曝气强度、邻苯二酸(Phthalic Acid,PA)及氨氮(NH3-N)对邻苯二甲酸二甲酯(Dimethyl Phthahte,DMP)降解效果的影响,结果表明:好氧颗粒污泥降解DMP的最佳温度、最佳PH值范围、最佳曝气强度分别为25℃～45℃、7.0 ～9.0、1.38 cm/s.当PA浓度为100 mg/L、300 mg/L,PA对DMP降解起促进作用;当PA浓度为500 mg/L、800 mg/L,PA对DMP降解起抑制作用.进水中50 mg/L的氨氮浓度对DMP降解的影响不大.本研究中采用的19种运行工况条件中,除曝气强度为0.33 cm/s以外,其他18种运行工况条件下,当运行时间达到300 min时,DMP的浓度都小于1.0 mg/L,因此,当水力停留时间达到5h以上时,温度、pH、PA、氨氮对DMP降解速率的影响基本上可以忽略不计.     

四川红原牧民新居室内热环境测试研究

以四川省阿坝州红原县典型新建定居房为研究对象,在冬夏两季典型气候条件下,对太阳辐射强度、温度、湿度等室内热环境参数进行测试,并分析了各参数的变化特点。基于测试数据,总结出红原县民居建筑的优点和不足,提出改善策略。     

间歇式活性污泥法处理1-4丁二醇废水的研究

用间歇式活性污泥法(SBR法)对高浓度1-4丁二醇废水进行了处理研究。实验测定了污泥沉降性能,测试了最佳曝气时间、最佳pH值范围以及SBR处理系统耐污染的负荷。实验结果表明:SBR法的污泥沉降比为15%～30%,完全符合活性污泥正常运行时的沉降标准。处理污水的最佳曝气时间为5h,最佳pH值范围为7～8。该处理系统耐冲击,能承受较高的污染负荷,对水质的波动有较强的承受能力。利用SBR法可以处理1-4丁二醇、聚丙烯酰胺和顺丁烯二酸酐三套装置排放的混合污水。     

中国入境旅游市场的多元回归预测

为了准确预测我国入境旅客的规模,收集了1978～2003年中国入境游客量的值,运用多元回归分析的方法,并借助SPSS软件,对我国入境游客的规模进行了预测,建立了以预测年前3年的入境游客量为自变量的多元回归方程:X(t)=251.067 0.178(t-3)-0.441X(t-2) 1.286X(t-1).与传统预测的时间序列等方法比较,该方法模拟、预测精度更高,更符合入境游客量的变化规模,同时可通过增加每年的实际值,动态更新方程,使之更能反映游客量的变化.     

Correlation of indoor radon concentration to commonly available geologic data

Over the last several years, the inhalation of decay products coming from radon-222 has become a national health concern. It is estimated that somewhere between 16,000 and 20,000 people die annually in the United States from lung cancer due to exposure to these decay products. Nationwide, 95% of all homes have not been tested for radon, and so it would seem that any methodology that could give a general idea of indoor radon concentrations (without actually testing the house itself) might be useful. While not intended to replace a radon test, which is both simple and inexpensive, our project attempts to predict indoor radon concentrations based on easily obtainable information from Soil Conservation Service county soil surveys and US Geological Survey surficial geology maps. We have chosen four parameters: soil permeability, surficial geology, soil shrink-swell potential, and distance to the nearest geologic fault. Of these four variables, surficial geology and distance to fault correlated well to winter indoor radon concentrations as measured by short-term (48-h) tests. While it is understood that there are limits to this methodology, primarily because of map scale problems, the correlations mentioned above were very strong and suggest further study would be useful.     

我国室内氡污染现状及相关控制标准

氡是仅次于吸烟的第二大致肺癌因素，对人体健康有较大危害。通过对我国室内氡研究的相关文献资料进行的汇总和分析，表明近20年来我国室内氡浓度明显增高，并有继续增高的趋势，讨论了我国室内氡浓度控制标准及相关研究进展，并在此基础上提出了我国室内氡在环境毒理学、污染控制、标准体系方面研究的建议。     

Cost-benefit analyses of radon mitigation projects

Radon is a radioactive gas that enters buildings and is known to cause lung cancer. Danish building regulation recommends simple remedial measures for radon levels between 200 and 400 Bq m⁻³, and more effective methods for levels above 400 Bq m⁻³. The Danish National Board of Health found that radon levels in 4.6% of the dwellings were above the reference level, and that the distribution of radon levels in Danish one-family houses is lognormal with a geometric mean of 57.7 Bq m⁻³ and a geometric standard deviation of 2.28. The purpose of the paper is to present a cost–benefit analysis of a possible future governmental intervention against radon in existing Danish one-family houses. In other words, it seeks to answer the question: is it socio-economically worthwhile to avert lung cancer deaths by reducing radon levels in the most exposed dwellings? The results indicate that an intervention based on the anti-radon measures recommended by the Danish building regulation would, if implemented, avert less than 30 deaths each year. By comparison, a total of 300 people die from radon exposure annually in Denmark. The total costs exceed the valuated health benefits by €62 million (6% discount rate). It is concluded that it is not socio-economically favourable to reduce radon levels in existing Danish one-family houses. These results are based on a discount rate of 6%, a value of preventing a statistical fatality of €1.4 million, and a relatively high cost of remediation in Denmark compared to other countries. Based on the sensitivity analysis, the conclusion will be different if a discount rate of 4.3% or less is used, or if the value of preventing a statistical fatality is €2.54 million or higher, or if the cost of remediation is reduced.     

The cost effectiveness of radon mitigation in existing German dwellings – A decision theoretic analysis

Radon is a naturally occurring inert radioactive gas found in soils and rocks that can accumulate in dwellings, and is associated with an increased risk of lung cancer. This study aims to analyze the cost effectiveness of different intervention strategies to reduce radon concentrations in existing German dwellings. The cost effectiveness analysis (CEA) was conducted as a scenario analysis, where each scenario represents a specific regulatory regime. A decision theoretic model was developed, which reflects accepted recommendations for radon screening and mitigation and uses most up-to-date data on radon distribution and relative risks. The model was programmed to account for compliance with respect to the single steps of radon intervention, as well as data on the sensitivity/specificity of radon tests. A societal perspective was adopted to calculate costs and effects. All scenarios were calculated for different action levels. Cost effectiveness was measured in costs per averted case of lung cancer, costs per life year gained and costs per quality adjusted life year (QALY) gained. Univariate and multivariate deterministic and probabilistic sensitivity analyses (SA) were performed. Probabilistic sensitivity analyses were based on Monte Carlo simulations with 5000 model runs. The results show that legal regulations with mandatory screening and mitigation for indoor radon levels >100 Bq/m³ are most cost effective. Incremental cost effectiveness compared to the no mitigation base case is 25,181 € (95% CI: 7371 €–90,593 €) per QALY gained. Other intervention strategies focussing primarily on the personal responsibility for screening and/or mitigative actions show considerably worse cost effectiveness ratios. However, targeting radon intervention to radon-prone areas is significantly more cost effective. Most of the uncertainty that surrounds the results can be ascribed to the relative risk of radon exposure. It can be concluded that in the light of international experience a legal regulation requiring radon screening and, if necessary, mitigation is justifiable under the terms of CEA.     

Nitrate reduction in the presence of wüstite

Recent strategies to reduce elevated nitrate concentrations employ metallic Fe0 as a reductant. Secondary products of Fe0 corrosion include magnetite (Fe3O4), green rust [Fe6(OH)12SO4], and wüstite [FeO(s)]. To our knowledge, no studies have been reported on the reactivity of NO3- with FeO(s). This project was initiated to evaluate the reactivity of FeO(s) with NO3- under abiotic conditions. Stirred batch reactions were performed in an anaerobic chamber over a range of pH values (5.45, 6.45, and 7.45), initial FeO(s) concentrations (1, 5, and 10 g L(-1)), initial NO3- concentrations (1, 10, and 15 mM), and temperatures (3, 21, 31, and 41 degrees C) for kinetic and thermodynamic determinations. Suspensions were periodically removed and filtered to measure dissolved nitrogen and iron species. Solid phases were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM). Nitrate reduction by FeO was rapid and characterized by nearly stoichiometric conversion of NO3- to NH4+. Transient NO2- formation also occurred. The XRD and SEM results indicated the formation of Fe3O4 as a reaction product of the heterogeneous redox reaction. Kinetics of NO3- reduction suggested a rate equation of the type: -d[NO3-]/dt = k[FeO]0.57[H]0.22[NO3-]1.12 where k = 3.46 x 10(-3) +/- 0.38 x 10(-3) M(-1) s(-1), at 25 degrees C. Arrhenius and Eyring plots indicate that the reaction is surface chemical-controlled and proceeds by an associative mechanism involving a step where both NO3- and FeO(s) bind together in an intermediate complex.     

居室放射性

本文介绍了放射性的来源,讨论了室内γ射线和氡及其子体,计算了相关的年剂量当量     

Atmospheric fate of OH initiated oxidation of terpenes. Reaction mechanism of alpha-pinene degradation and secondary organic aerosol formation

This paper studies the reaction products of alpha-pinene, beta-pinene, sabinene, 3-carene and limonene with OH radicals and of alpha-pinene with ozone using FT-IR spectroscopy for measuring gas phase products and HPLC-MS-MS to measure products in the aerosol phase. These techniques were used to investigate the secondary organic aerosol (SOA) formation from the terpenes. The gas phase reaction products were all quantified using reference compounds. At low terpene concentrations (0.9-2.1 ppm), the molar yields of gas phase reaction products were: HCHO 16-92%, HCOOH 10-54% (OH source: H2O2, 6-25 ppm); HCHO 127-148%, HCOOH 4-6% (OH source: CH3ONO, 5-8 ppm). At high terpene concentrations (4.1-13.2 ppm) the results were: HCHO 9-27%, HCOOH 15-23%, CH3(CO)CH3 0-14%, CH3COOH 0-5%, nopinone 24% (only from beta-pinene oxidation), limona ketone 61% (only from limonene oxidation), pinonaldehyde was identified during alpha-pinene degradation (OH source H2O2, 23-30 ppm); HCHO 76-183%, HCOOH 12-15%, CH3(CO)CH3 0-12%, nopinone 17% (from beta-pinene oxidation), limona ketone 48% (from limonene oxidation), pinonaldehyde was identified during alpha-pinene degradation (OH source CH3ONO, 14-16 ppm). Pinic acid, pinonic acid, limonic acid, limoninic acid, 3-caric acid, 3-caronic acid and sabinic acid were identified in the aerosol phase. On the basis of these results, we propose a formation mechanism for pinonic and pinic acid in the aerosol phase explaining how degradation products could influence SOA formation and growth in the troposphere.     

Lorenz Curve and Gini Coefficient: Novel tools for analysing seasonal variation of environmental radon gas

Using a methodology derived from Economics, the Lorenz Curve and Gini Coefficient are introduced as tools for investigating and quantifying seasonal variability in environmental radon gas concentration. While the Lorenz Curve presents a graphical view of the cumulative exposure during the course of the time-frame of interest, typically one year, the Gini Coefficient distils this data still further, to provide a single-parameter measure of temporal clustering. Using the assumption that domestic indoor radon concentrations show annual cyclic behaviour, generally higher in the winter months than in summer, published data on seasonal variability of domestic radon concentration levels, in various areas of the UK, Europe, Asia and North America, are analysed. The results demonstrate significantly different annual variation profiles between domestic radon concentrations in different countries and between regions within a country, highlighting the need for caution in ascribing seasonal correction factors to extended geographical areas. The underlying geography, geology and meteorology of a region have defining influences on the seasonal variability of domestic radon concentration, and some examples of potential associations between the Gini Coefficient and regional geological and geographical characteristics are proposed. Similar differences in annual variation profiles are found for soil-gas radon measured as a function of depth at a common site, and among the activity levels of certain radon progeny species, specifically ²¹⁴Bi deposited preferentially in human body-fat by decay of inhaled radon gas. Conclusions on the association between these observed measures of variation and potential underlying defining parameters are presented.     

环境中氡的水平及其对人体危害

氡是致人体天然辐射剂量贡献最大的核素,也是肺癌发病的重要因子,是净化空气要优先考虑的问题。为此,本文报告了环境氡的水平以及它对人体产生的危害,这些知识对净化环境,保护健康有重要意义     

Quantitative,chemical, and mineralogical characterization of flue gas desulfurization by-products

The objective of this study was to demonstrate that simple fractionation and selective dissolution techniques can be used to provide detailed chemical and mineralogical analyses of flue gas desulfurization by-products. The material studied was a mine grout prepared as a 1:1 mixture (wt./wt.) of fly ash (FA) and filter cake (FC) with hydrated lime (50 g kg(-1)) added to improve handling. The hydrated lime was composed mostly of calcite (CaCO3), portlandite [Ca(OH)2], lime (CaO), and brucite [Mg(OH)2] (515, 321, 55, and 35 g kg(-1), respectively) and had low (<6 g kg(-1)) concentrations of most trace elements. The FC contained hannebachite (CaSO3 x 0.5H2O) (786 g kg(-1)) with smaller quantities (<10 g kg(-1)) of calcite, quartz (SiO2), brucite, and gypsum (CaSO4 x 2H2O). Except for B and Cu, trace element concentrations were comparable to those in the hydrated lime. The FA contained both magnetic (222 g kg(-1)) and nonmagnetic (778 g kg(-1)) fractions. The former was composed mostly of hematite (Fe2O3), magnetite (Fe3O4), and glass (272, 293, and 287 g kg(-1), respectively), whereas the latter was enriched in glass, quartz, and mullite (Al6Si2O13) (515, 243, and 140 g kg(-1), respectively). Etching with 1% HF showed that 60 to 100% of trace elements were concentrated in the glass, although some metals (Co, Cr, and Mn) were clearly enriched in the magnetic phase. The aged grout contained 147 g kg(-1) ettringite [Ca6Al2(SO4)3(OH)12 x 26H2O] in addition to 314 g kg(-1) hannebachite and 537 g kg(-1) insoluble phases (mullite, quartz, hematite, magnetite, and glass).