Differences in Dissolved Organic Carbon and Nitrogen Responses to Storm‐Event and Ground‐Water Conditions in a Forested,Glaciated Watershed in Western New York1

Abstract: Differences in the storm‐event responses of dissolved organic carbon (DOC) and nitrogen (DON) in streamflow and ground water were evaluated for a glaciated forested watershed in western New York. Eight to ten storm events with varying rainfall amounts, intensities, and antecedent moisture conditions were studied for three catchments (1.6, 3.4, and 696 ha) over a three‐year period (2003‐2005). Concentrations of DOC in streamflow exiting the catchments were significantly higher for storm events following a dry period, whereas no similar response was observed for DON. Highest DON concentrations in streamflow were typically associated with storm events following wet antecedent moisture conditions. In addition to antecedent moisture conditions, DOC concentrations were also positively correlated with precipitation amounts, while DON did not reveal a consistent pattern. Streamwater and ground‐water concentrations of DOC during storm events were also strongly correlated with riparian ground‐water depths but a similar relationship was not observed for DON. Ground‐water DON concentrations were also more variable than DOC. We hypothesized that the differences in DOC and DON responses stemmed from the differences in catchment sources of these solutes. This study suggests that while DOC and DON are intrinsically linked as components of dissolved organic matter, their dynamics and exports from watersheds may be regulated by a different set of mechanisms and factors. Identifying these differences is critical for developing more reliable and robust models for transport of dissolved organic matter.     

Evaluating stream water quality through land use analysis in two grassland catchments: impact of wetlands on stream nitrogen concentration

We evaluated the impacts of natural wetlands and various land uses on stream nitrogen concentration in two grassland-dominated catchments in eastern Hokkaido, Japan. Analyzing land use types in drainage basins, measuring denitrification potential of its soil, and water sampling in all seasons of 2003 were performed. Results showed a highly significant positive correlation between the concentration of stream NO3-N and the proportion of upland area in drainage basins in both catchments. The regression slope, which we assumed to reflect the impact on water quality, was 24% lower for the Akkeshi catchment (0.012 +/- 0.001) than for the Shibetsu catchment (0.016 +/- 0.001). In the Akkeshi catchment, there was a significant negative correlation between the proportion of wetlands in the drainage basins and stream NO3-N concentration. Stream dissolved organic nitrogen (DON) and carbon (DOC) concentrations were significantly higher in the Akkeshi catchment. Upland and urban land uses were strongly linked to increases in in-stream N concentrations in both catchments, whereas wetlands and forests tended to mitigate water quality degradation. The denitrification potential of the soils was highest in wetlands, medium in riparian forests, and lowest in grasslands; and was significant in wetlands and riparian forests in the Akkeshi catchment. The solubility of soil organic carbon (SOC) and soil moisture tended to determine the denitrification potential. These results indicate that the water environment within the catchments, which influences denitrification potential and soil organic matter content, could have caused the difference in stream water quality between the two catchments.     

FOG AND ACIDIFICATION IMPACTS ON ION BUDGETS OF BASINS IN NOVA SCOTIA,CANADA1

ABSTRACT: We examined hydrogeochemical records for a dozen watersheds in and near Kejimkujik National Park in southwestern Nova Scotia by relating stream ion concentrations and fluxes to atmospheric deposition, stream type (lake inlet versus outlet; brown versus clear water), and watershed type (catchment area, topography, soils, and dominant forest cover type). We found that fog and dry deposition make important contributions to S, N, Cl, H, Ca, Mg, K, and Na inputs into these watersheds. Seasalt chloride deposition from rain, snow, fog, and dry deposition equal total stream outputs on a region‐wide basis. Chloride outputs, however, differ among watersheds by a factor of about two, likely due to local differences in air flow and vegetational fog interception. We found that most of the incoming N is absorbed by the vegetation, as stream water NO3^‐ and NH4⁺ are very low. Our results also show that the vegetation and the soils absorb about half of the incoming SO4². In comparison with other North American watersheds with similar forest vegetation, Ca outputs are low, while Mg and K outputs are similar to other regions. Soil exchangeable Ca and soil cation exchange capacity are also very low. We found that first‐order forest streams with no upstream lakes have a distinct seasonal pattern that neither corresponds with the seasonal pattern of atmospheric deposition, nor with the seasonal pattern of downstream lake outlets.     

IMPACTS OF URBANIZATION ON NUTRIENT CONCENTRATIONS IN SMALL SOUTHEASTERN COASTAL STREAMS1

ABSTRACT: Coastal watersheds in the southeastern United States are rapidly changing due to population growth and attendant increases in residential development, industry, and tourism related commerce. This research examined spatial and temporal patterns of nutrient concentrations in streams from 10 small watersheds (< 4 km²) that drain into Murrells Inlet (impacted) and North Inlet (pristine), two high salinity estuaries along the South Carolina coast. Monthly grab samples were collected during baseflow during 1999 and analyzed for total and dissolved inorganic and organic forms of nitrogen and phosphorus. Data were grouped into forested wetland creeks (representing predevelopment reference sites), urban creeks, and urban ponds. DON and NH4 concentrations were greater in forested streams than in urban streams. NO3 and TP concentrations were greatest in urban streams. Seasonally, concentrations were highest during summer for TN, NH4, DON, and TP, while NO3 concentrations were greatest during winter. Nutrient ratios clearly highlighted the reduction in organic nitrogen due to coastal development. Multiple regression models to predict instream nutrient concentrations from land use in Murrells Inlet suggest that effects are not significant (small r²). The findings indicate that broad land use/land cover classes cannot be used to predict nutrient concentrations in streams in the very small watersheds in our study areas.     

Urea Fluctuations in Stream Baseflow across Land Cover Gradients and Seasons in a Coastal Plain River System

Urea‐N is a component of bioavailable dissolved organic nitrogen (DON) that contributes to coastal eutrophication. In this study, we assessed urea‐N in baseflow across land cover gradients and seasons in the Manokin River Basin on the Delmarva Peninsula. From March 2010 to June 2011, we conducted monthly sampling of 11 streams (4 tidal and 7 nontidal), 2 wastewater treatment plants, an agricultural drainage ditch, and groundwater underlying a cropped field. At each site, we measured urea‐N, DON, dissolved organic carbon (DOC), total dissolved nitrogen (TDN), NO₃^?‐N, and NH₄⁺‐N. In general, urea‐N comprised between 1% and 6% of TDN, with the highest urea‐N levels in drainage ditches (0.054 mg N/L) and wetland‐dominated streams (0.035–0.045 mg N/L). While urea‐N did not vary seasonally in tidal rivers, nontidal streams saw distinct urea‐N peaks in summer (0.038 mg N/L) that occurred several months after cropland fertilization in spring. Notably, the proportion of wetlands explained 78% of the variance in baseflow urea‐N levels across the Manokin watershed. In wetland‐dominated basins, we found urea‐N was positively related to water temperature and negatively related to DOC:DON ratios, indicating short‐term urea‐N dynamics at baseflow were more likely influenced by instream and wetland‐driven processes than by recent agricultural urea‐N inputs. Findings demonstrate important controls of wetlands on baseflow urea‐N concentrations in mixed land‐use basins.     

Upland disturbance affects headwater stream nutrients and suspended sediments during baseflow and stormflow

Because catchment characteristics determine sediment and nutrient inputs to streams, upland disturbance can affect stream chemistry. Catchments at the Fort Benning Military Installation (near Columbus, Georgia) experience a range of upland disturbance intensities due to spatial variability in the intensity of military training. We used this disturbance gradient to investigate the effects of upland soil and vegetation disturbance on stream chemistry. During baseflow, mean total suspended sediment (TSS) concentration and mean inorganic suspended sediment (ISS) concentration increased with catchment disturbance intensity (TSS: R2= 0.7, p = 0.005, range = 4.0-10.1 mg L(-1); ISS: R2= 0.71, p = 0.004, range = 2.04-7.3 mg L(-1)); dissolved organic carbon (DOC) concentration (R2= 0.79, p = 0.001, range = 1.5-4.1 mg L(-1)) and soluble reactive phosphorus (SRP) concentration (R2= 0.75, p = 0.008, range = 1.9-6.2 microg L(-1)) decreased with increasing disturbance intensity; and ammonia (NH4+), nitrate (NO3-), and dissolved inorganic nitrogen (DIN) concentrations were unrelated to disturbance intensity. The increase in TSS and ISS during storms was positively correlated with disturbance (R2= 0.78 and 0.78, p = 0.01 and 0.01, respectively); mean maximum change in SRP during storms increased with disturbance (r = 0.7, p = 0.04); and mean maximum change in NO3- during storms was marginally correlated with disturbance (r = 0.58, p = 0.06). Soil characteristics were significant predictors of baseflow DOC, SRP, and Ca2+, but were not correlated with suspended sediment fractions, any nitrogen species, or pH. Despite the largely intact riparian zones of these headwater streams, upland soil and vegetation disturbances had clear effects on stream chemistry during baseflow and stormflow conditions.     

Influence of Catchment-Scale Military Land Use on Stream Physical and Organic Matter Variables in Small Southeastern Plains Catchments (USA)

We conducted a 3-year study designed to examine the relationship between disturbance from military land use and stream physical and organic matter variables within 12 small (<5.5 km2) Southeastern Plains catchments at the Fort Benning Military Installation, Georgia, USA. Primary land-use categories were based on percentages of bare ground and road cover and nonforested land (grasslands, sparse vegetation, shrublands, fields) in catchments and natural catchments features, including soils (% sandy soils) and catchment size (area). We quantified stream flashiness (determined by slope of recession limbs of storm hydrographs), streambed instability (measured by relative changes in bed height over time), organic matter storage [coarse wood debris (CWD) relative abundance, benthic particulate organic matter (BPOM)] and stream-water dissolved organic carbon concentration (DOC). Stream flashiness was positively correlated with average storm magnitude and percent of the catchment with sandy soil, whereas streambed instability was related to percent of the catchment containing nonforested (disturbed) land. The proportions of in-stream CWD and sediment BPOM, and stream-water DOC were negatively related to the percent of bare ground and road cover in catchments. Collectively, our results suggest that the amount of catchment disturbance causing denuded vegetation and exposed, mobile soil is (1) a key terrestrial influence on stream geomorphology and hydrology and (2) a greater determinant of in-stream organic matter conditions than is natural geomorphic or topographic variation (catchment size, soil type) in these systems.     

Factors controlling sediment and phosphorus export from two Belgian agricultural catchments

Sediment and total phosphorus (TP) export vary through space and time. This study was conducted to determine the factors controlling sediment and TP export in two agricultural catchments situated in the Belgian Loess Belt. At the outlet of these catchments runoff discharge was continuously measured and suspended sediment samples were taken during rainfall events. Within the catchments vegetation type and cover, soil surface parameters, erosion features, sediment pathways, and rainfall characteristics were monitored. Total P content and sediment characteristics such as clay, organic carbon, and suspended sediment concentration were correlated. Total sediment and TP export differ significantly between the monitored catchments. Much of the difference is due to the occurrence of an extreme event in one catchment and the morphology and spatial organization of land use in the catchments. In one catchment, the direct connection between erosive areas and the catchment outlet by means of a road system contributed to a high sediment delivery ratio (SDR) at the outlet. In the other catchment, the presence of a wide valley in the center of the catchment caused sediment deposition. Vegetation also had an effect on sediment production and deposition. Thus, many factors control sediment and TP export from small agricultural catchments; some of these factors are related to the physical catchment characteristics such as morphology and landscape structure and are (semi)permanent, while others, such as vegetation cover and land use, are time dependent.     

Phosphorus and nitrogen sorption to soils in the presence of poultry litter-derived dissolved organic matter

Two environmental aspects associated with land application of poultry litter that have not been comprehensively evaluated are (i) the competition of dissolved organic matter (DOM) and P for soil sorption sites, and (ii) the sorption of dissolved organic nitrogen (DON) relative to inorganic nitrogen species (e.g., NO(3)(-) and NH(4)(+)) and dissolved organic carbon (DOC). The competition between DOM and P for sorption sites has often been assumed to increase the amount of P available for plant growth; however, elevating DOM concentrations may also increase P available for transport to water resources. Batch sorption experiments were conducted to (i) evaluate soil properties governing P sorption to benchmark soils of Southwestern Missouri, (ii) elucidate the impact of poultry litter-derived DOM on P sorption, and (iii) investigate DON retention relative to inorganic N species and DOC. Soils were reacted for 24 h with inorganic P (0-60 mg L(-1)) in the presence and absence of DOM (145 mg C L(-1)) using a background electrolyte solution comparable to DOM extracts (I = 10.8 mmol L(-1); pH 7.7). Soil P sorption was positively correlated with metal oxide (r(2) = 0.70) and clay content (r(2) = 0.79) and negatively correlated with Bray-1 extractable P (r(2) = 0.79). Poultry litter-derived DOM had no significant negative impact on P sorption. Dissolved organic nitrogen was preferentially removed from solution relative to (NO(3)(-)-N + NO(2)(-)-N), NH(4)(+)-N, and DOC. This research indicates that poultry litter-derived DOM is not likely to enhance inorganic P transport which contradicts the assumption that DOM released from organic wastes increases plant-available P when organic amendments and fertilizer P are co-applied. Additionally, this work demonstrates the need to further evaluate the fate and transport of DON in agroecosystem soils receiving poultry litter applications.     

EFFECT OF CATCHMENT SIZE ON PHOSPHORUS EXPORT1

ABSTRACT: We tested the common assumption, made when expressing phosphorus export on an areal basis, that this export is a linear function of catchment area and found it wanting. The data show that in agricultural catchments, TP (total phosphorus) export varies as the 0.77 power of drainage basin area, resulting in a reduction in phosphorus delivery per unit area with increasing catchment size. Following further division of catchments according to agricultural practice, we found that this spatial scale effect is restricted to row crops and pastures. We present simple statistical models to allow a comparison of TP export from catchments of different size. Such models are not needed for nonrow crops, mixed agricultural and forested catchments, where TP export is a linear function of catchment size.     

NITROGEN AND PHOSPHORUS CONCENTRATIONS IN FOREST STREAMS OF THE UNITED STATES1

ABSTRACT: Seventy to eighty percent of the water flowing in rivers in the United States originates as precipitation in forests. This project developed a synoptic picture of the patterns in water chemistry for over 300 streams in small, forested watersheds across the United States. Nitrate (NO₃^?) concentrations averaged 0.31 mg N/L, with some streams averaging ten times this level. Nitrate concentrations tended to be higher in the northeastern United States in watersheds dominated by hardwood forests (especially hardwoods other than oaks) and in recently harvested watersheds. Concentrations of dissolved organic N (mean 0.32 mg N/L) were similar to those of NO₃～, whereas ammonium (NH₄⁺) concentrations were much lower (mean 0.05 mg N/L). Nitrate dominated the N loads of streams draining hardwood forests, whereas dissolved organic N dominated the streams in coniferous forests. Concentrations of inorganic phosphate were typically much lower (mean 12 mg P/L) than dissolved organic phosphate (mean 84 mg P/L). The frequencies of chemical concentrations in streams in small, forested watersheds showed more streams with higher NO₃^? concentrations than the streams used in national monitoring programs of larger, mostly forested watersheds. At a local scale, no trend in nitrate concentration with stream order or basin size was consistent across studies.     

Monitoring nitrogen loading and retention in an urban stormwater detention pond

Stormwater detention ponds have become ubiquitous in urbanized areas and have been suggested as potential hotspots of N transformation within urban watersheds. As a result, there is a great deal of interest in their use as structural best management practices to reduce the excessive N export from these watersheds. We conducted continuous monitoring of the influent and effluent N loads of a stormwater detention pond located on the Princeton University campus in Princeton, New Jersey. Our monitoring was conducted during four 21-d periods representing the four seasons of the northeastern United States. Water quality samples were collected and analyzed for nitrate (NO3-) during all four monitoring periods. During two of these periods, loads of ammonium (NH4+), dissolved organic N, and particulate N (PN) were measured. Our results show that NO3- dominated the influent N load, particularly in dry weather inflows to the detention pond. However, PN, which is often neglected in stormwater quality monitoring, made up as much as 30% of the total load and an even greater fraction during storm events. The results of our monitoring suggest that seasonal variation may play an important role in N retention within the detention pond. Although retention of NO3-, the most dominant fraction of N in the influent stormwater, was observed during the summer sampling period, no significant NO3- retention was observed during the spring or the two cold-weather sampling periods.     

Leachate chemistry of field-weathered spent mushroom substrate

Passive leaching by rainfall and snowmelt is a popular method to treat piles of spent mushroom substrate (SMS) before its reuse. During this field weathering process, leachate percolates into the underlying soils. A field study was conducted to examine the chemistry of SMS leachate and effects of infiltration. Two SMS piles were deposited (90 and 150 cm in height) over a Typic Hapludult and weathered for 24 mo. Leachate was collected biweekly using passive capillary samplers. The SMS leachate contained high concentrations of dissolved organic carbon (DOC; 0.8-11.0 g L(-1)), dissolved organic nitrogen (DON; 0.1-2 g L(-1)), and inorganic salts. The pH, electrical conductivity, and acid neutralizing capacity were 6.6 to 9.0, 21 to 66 ds m(-1), and 10 to 75 mmolc L(-1), respectively. Inorganic chemistry of the leachate was dominated by K+, Cl-, and SO24-. Leachate DOC was predominantly low molecular weight (<1000 Da) organic acids. During 2 yr of weathering, the 90-cm SMS pile released (per cubic meter of SMS) 3.0 kg of DOC, 1.6 kg of dissolved N, and 26.6 kg of inorganic salts. The 150-cm pile released (per cubic meter of SMS) 2.8 kg of DOC, 0.7 kg of dissolved N, and 13.6 kg of inorganic salts. The 150 cm pile retained more water and exhibited lower net nitrification compared with the 90-cm pile. The top 90 cm of soil retained 20 to 89% of the leachate solutes. Weathering of SMS in piles of 90 cm depth or greater may adversely affect ground water quality.     

Spatial Variability of Nitrate Concentrations Under Diverse Conditions in Tributaries to a Lake Watershed1

Abstract: Nitrate‐nitrogen (NO₃‐N) concentrations in stream water often respond uniquely to changes in inter‐annual conditions (e.g., biological N uptake and precipitation) in individual catchments. In this paper, we assess (1) how the spatial distribution of NO₃‐N concentrations varies across a dense network of nonnested catchments and (2) how relationships between multiple landscape factors [within whole catchments and hydrologically sensitive areas (HSAs) of the catchments] and stream NO₃‐N are expressed under a variety of annual conditions. Stream NO₃‐N data were collected during two synoptic sampling events across >55 tributaries and two synoptic sampling periods with >11 tributaries during summer low flow periods. Sample tributaries drain mixed land cover watersheds ranging in size from 0.150 to 312 km² and outlet directly to Cayuga Lake, New York. Changes in NO₃‐N concentration ratios between each sampling event suggest a high degree of spatial heterogeneity in catchment response across the Cayuga Lake Watershed, ranging from 0.230 to 61.4. Variations in NO₃‐N concentrations within each of the large synoptic sampling events were also high, ranging from 0.040 to 8.7 mg NO₃‐N/l (March) and 0.090 to 15.5 mg NO₃‐N/l (October). Although Pearson correlation coefficients suggest that this variability is related to multiple landscape factors during all four sampling events, partial correlations suggest percentage of row crops in the catchments as the only similar factor in March and October and catchment area as the only factor during summer low flows. Further, the strength of the relationships is typically lower in the HSAs of catchment. Advancing current understanding of such variations and relationships to landscape factors across multiple catchments – and under a variety of biogeochemical and hydrological conditions – is important, as (1) nitrate continues to be employed as an indicator of regional aquatic ecosystem health and services and (2) a unified framework approach for understanding individual catchment processes is a rapidly evolving focus for catchment‐based science and management.     

Earthworm additions affect leachate production and nitrogen losses in typical midwestern agroecosystems

Earthworms affect soil structure and the movement of agrochemicals. Yet, there have been few field-scale studies that quantify the effect of earthworms on dissolved nitrogen fluxes in agroecosystems. We investigated the influence of semi-annual earthworm additions on leachate production and quality in different row crop agroecosystems. Chisel-till corn (Zea mays L.)-soybean [Glycine max (L.) Merr.] rotation (CT) and ridge-till corn-soybean-wheat (Triticum aestivum L.) rotation (RT) plots were arranged in a complete randomized block design (n = 3) with earthworm treatments (addition and ambient) as subplots where zero-tension lysimeters were placed 45 cm below ground. We assessed earthworm populations semi-annually and collected leachate biweekly over a three-year period and determined leachate volume and concentrations of total inorganic nitrogen (TIN) and dissolved organic nitrogen (DON). Abundance of deep-burrowing earthworms was increased in addition treatments over ambient and for both agroecosystems. Leachate loss was similar among agroecosystems, but earthworm additions increased leachate production in the range of 4.5 to 45.2% above ambient in CT cropping. Although leachate TIN and DON concentrations were generally similar between agroecosystems or earthworm treatments, transport of TIN was significantly increased in addition treatments over ambient in CT cropping due to increased leachate volume. Losses of total nitrogen in leachate loadings were up to approximately 10% of agroecosystem N inputs. The coincidence of (i) soluble N production and availability and (ii) preferential leaching pathways formed by deep-burrowing earthworms thereby increased N losses from the CT agroecosystem at the 45-cm depth. Processing of N compounds and transport in soil water from RT cropping were more affected by management phase and largely independent of earthworm activity.     

Scientist and Policy-Maker Response Types and Times in Suburban Watersheds

Differences between scientist and policy-maker response types and times, or the “how” and “when” of action, constrain effective water resource management in suburbanizing watersheds. Policy-makers are often rushed to find a single policy that can be applied across an entire, homogeneous, geopolitical region, whereas scientists undertake multiyear research projects to appreciate the complex interactions occurring within heterogeneous catchments. As a result, watershed management is often practiced with science and policy out of synch. Meanwhile, development pressures in suburban watersheds create changes in the social and physical fabric and pose a moving target for science and policy. Recent and anticipated advances in the scientific understanding of urbanized catchment hydrology and pollutant transport suggest that management should become increasingly sensitive to spatial heterogeneities in watershed features, such as soil types, terrain slopes, and seasonal watertable profiles. Toward this end, policy-makers should encourage funding scientific research that characterizes the impacts of these watershed heterogeneities within a geopolitical zoning and development framework.     

Sorption and fractionation of dissolved organic matter and associated phosphorus in agricultural soil

Mobility of dissolved organic matter (DOM) strongly affects the export of nitrogen (N) and phosphorus (P) from soils to surface waters. To study the sorption and mobility of dissolved organic C and P (DOC, DOP) in soil, the pH-dependent sorption of DOM to samples from Ap, EB, and Bt horizons from a Danish agricultural Humic Hapludult was investigated and a kinetic model applicable in field-scale models tested. Sorption experiments of 1 to 72 h duration were conducted at two pH levels (pH 5.0 and 7.0) and six initial DOC concentrations (0-4.7 mmol L(-1)). Most sorption/desorption occurred during the first few hours. Dissolved organic carbon and DOP sorption decreased strongly with increased pH and desorption dominated at pH 7, especially for DOC. Due to fractionation during DOM sorption/desorption at DOC concentrations up to 2 mmol L(-1), the solution fraction of DOM was enriched in P indicating preferred leaching of DOP. The kinetics of sorption was expressed as a function of how far the solution DOC or DOP concentrations deviate from "equilibrium." The model was able to simulate the kinetics of DOC and DOP sorption/desorption at all concentrations investigated and at both pH levels making it useful for incorporation in field-scale models for quantifying DOC and DOP dynamics.     

Linking Nitrogen Export to Landscape Heterogeneity: The Role of Infrastructure and Storm Flows in a Mediterranean Urban System

Urban ecosystems are often sources of nonpoint source (NPS) nitrogen (N) pollution to aquatic ecosystems. However, N export from urban watersheds is highly variable. Examples of densely urbanized watersheds are not well studied, and these may have comparatively low export rates. Commonly used metrics of landscape heterogeneity may obscure our ability to discern relationships among landscape characteristics that can explain these lower export rates. We expected that differences not often captured by these metrics in the relative cover of vegetation, structures, and impervious surfaces would better explain observed variation in N export. We examined these relationships during storms in residential watersheds. Contrary to expectations, land cover did not directly predict variation in N or water export. Instead, N export was strongly linked to drainage infrastructure density. Our research highlights the role of fine‐scaled landscape attributes, mainly infrastructure, in explaining patterns of N export from densely urbanized watersheds. Changes to hydrologic flow paths by infrastructure explained more variation in N export than land cover. Our findings support further development of landscape ecological models of urban N export that focus on hydrologic modification by infrastructure rather than traditional landscape measures such as land use, as indicators for evaluating patterns of NPS nitrogen pollution in densely urbanized watersheds.     

Modeled Sources,Transport, and Accumulation of Dissolved Solids in Water Resources of the Southwestern United States1

Anning, David W., 2011. Modeled Sources, Transport, and Accumulation of Dissolved Solids in Water Resources of the Southwestern United States. Journal of the American Water Resources Association (JAWRA) 47(5):1087‐1109. DOI: 10.1111/j.1752‐1688.2011.00579.x Abstract: Information on important source areas for dissolved solids in streams of the southwestern United States, the relative share of deliveries of dissolved solids to streams from natural and human sources, and the potential for salt accumulation in soil or groundwater was developed using a SPAtially Referenced Regressions On Watershed attributes model. Predicted area‐normalized reach‐catchment delivery rates of dissolved solids to streams ranged from <10 (kg/year)/km² for catchments with little or no natural or human‐related solute sources in them to 563,000 (kg/year)/km² for catchments that were almost entirely cultivated land. For the region as a whole, geologic units contributed 44% of the dissolved‐solids deliveries to streams and the remaining 56% of the deliveries came from the release of solutes through irrigation of cultivated and pasture lands, which comprise only 2.5% of the land area. Dissolved‐solids accumulation is manifested as precipitated salts in the soil or underlying sediments, and (or) dissolved salts in soil‐pore or sediment‐pore water, or groundwater, and therefore represents a potential for aquifer contamination. Accumulation rates were <10,000 (kg/year)/km² for many hydrologic accounting units (large river basins), but were more than 40,000 (kg/year)/km² for the Middle Gila, Lower Gila‐Agua Fria, Lower Gila, Lower Bear, Great Salt Lake accounting units, and 247,000 (kg/year)/km² for the Salton Sea accounting unit.     

Decreased carbon and nutrient input to boreal lakes from particulate organic matter following riparian clear-cutting

The plankton communities of oligotrophic Canadian Shield lakes are strongly regulated by the allochthonous supply of total phosphorus (TP) and dissolved organic carbon (DOC), a proportion of both of which originate from particulate organic matter. Although decreased inputs of allochthonous leaf litter have been documented for small streams whose riparian forests have been removed, no such data exist for boreal lakes. Through estimates of airborne litter input from forested and clear-cut shorelines and laboratory measurements of concentrations released from leaf leachate, we determined that riparian deforestation resulted in reductions of DOC from 17.8 to 0.4 g/m shoreline/yr and of TP from 2.9 to 0.3 g/m shoreline/yr. Previous predictive models indicate that such reductions may be substantial enough to decrease basic metabolic processes of lake plankton communities by as much as 9% in primary production and 17% in respiration.