北京市土地利用分布与水质响应空间关系研究

以北京市16个水质监测断面和饮用水源地作为研究对象,利用2009—2010年16个水质监测自动站监测数据与2009年北京市土地利用数据,分析不同缓冲区内土地利用与过境水质之间的响应关系。研究结果表明,耕地产生的农业非点源污染对水质影响明显;在大尺度区域增加林地面积比例有利于改善水质;离水源近的农村居民用地对水质产生负面影响;工业建设用地对水质影响在较大尺度上更为显著。     

汕头市练江流域景观格局与水质的关联分析

水环境对景观格局的变化极为敏感,水域(湿地)面积、分布格局、水质、水文特征等的变化,与土地变化和人类活动有着密切的关系,明确影响水质变化的关键景观因子,对于深入了解景观格局对水质的影响机制具有重要的研究价值。该研究选择广东省汕头市练江流域为研究对象,以2019年TM卫星影像、水质监测以及工业点源污染数据为基础,利用Spearman秩相关和多元线性回归模型等统计方法综合分析在子流域、河岸带尺度水平上景观格局与水质之间的相关性。研究结果表明:流域和河岸带的城镇比例、景观多样性和破碎度均对水质有较大影响,水质指标受到多个景观指数的综合影响,景观格局指数变化对总磷的解释能力要大于其他水质指标;氨氮、化学需氧量受河岸带尺度的景观格局影响更大,总磷受流域尺度景观格局影响更大;工业点源对景观格局与水质的关联分析有较大影响,剔除重点工业点源污染后的氨氮和化学需氧量与景观格局相关性比剔除重点工业点源污染前更高。     

无锡市地下水环境质量调查与评价

为了解无锡市地下水水质状况,于2010年10—12月对无锡地区145口地下水井进行采样分析。以地理信息系统为技术手段,对不同土地利用类型和地下水类型的水污染物监测结果进行综合评价。结果表明,无锡全市地下水达标率为45.52%,整体水质情况处于"较好"级别;NH3-N、Mn和Fe为无锡市地下水的主要污染物;无锡市农业和建设用地区域地下水的污染程度整体要高于水体和林地区域;承压层的地下水污染较为严重。提出,无锡市管理部门应根据地下水污染现状,对地下水资源进行动态监测(包括水量和水质监测),并采取强有力的保护与治理措施,以实现区域水资源的持续利用。     

无锡市国控环境空气自动监测站点周边裸土分布高分辨率遥感监测

以无锡市为研究区,使用过境时间相近的哨兵2号Sentinel-2和Landsat8影像,综合使用NDSI、NDISI、MNDWI、LST等指数进行决策树分类,获得10 m高空间分辨率的土地利用分类结果和裸土分布,裸土提取精度达到94.13%。统计了无锡市与8个国控环境空气自动监测站点1、2、3 km缓冲区范围内的裸土分布情况,并与各站点监测的大气颗粒物浓度进行相关性分析。结果表明,国控环境空气自动监测站点周边裸土面积对颗粒物浓度有较大影响,其中对PM₁₀浓度的影响明显大于PM_2.5;相比于1 km和3 km,2 km缓冲区范围内的裸土面积对PM₁₀浓度的影响最大,建议环境管理部门重点关注无锡地区国控监测站点周边2 km范围内的裸土扬尘源分布情况。     

基于RS与GIS的福州新区热环境空间分布特征研究

采用2014—2021年福州新区的地表温度、归一化差值植被指数（NDVI）和土地利用类型等数据,从乡镇单元尺度分析热环境的空间分布情况,并探究植被和土地利用对热环境空间分布的影响。结果表明：2014—2021年福州新区地表温度在空间上有明显的空间自相关性,空间集聚特征显著,新区热岛比例指数（URI）呈现出下降趋势,表明在此期间热岛效应状况总体有所缓解;植被覆盖率（FVC）影响热环境的空间分布,可将福州新区的“热点”划分为FVC、NDVI均较低的乡镇和FVC较高、NDVI较低的乡镇两类;土地利用类型、土地利用程度及周边环境亦影响热环境的空间分布。     

北京市环境电磁辐射自动站数据分析及网络建设

选取北京市环境电磁辐射自动监测站点2年多的数据,利用SPSS统计软件,对各站点数据进行了主要电磁辐射源、长期数据趋势、各站点时间代表性分析;并结合网格法监测数据,对自动站点空间代表性进行分析。结果表明,5个环境电磁辐射自动站周围主要电磁辐射源均为移动通信基站;其总体电磁辐射水平为0.69~0.97 V/m,低于北京市1 V/m的电磁辐射环境本底水平,且单站点连续12个月的监测数据可以描述该点位电磁辐射平均水平和变化趋势;经分析,连续5年全市网格法电磁辐射射频电场的监测数据总体具有较好的一致性,但单站点的电磁辐射水平不能代表所在行政区的电磁辐射总体水平。提出了电磁辐射自动监测网络建设建议。     

鄱阳湖生态环境监测布点现状及优化建议

通过分析环保、水利、国土、农业、林业、气象和高等院校科研单位等现有监测点位,提出鄱阳湖生态环境监测布点建议。在空间尺度上设置8个中心站,34个监测点,26个监测断面,当星子水位高于15. 99 m时加设12个监测断面;人类生产活动监测范围以环湖11县区覆盖范围为边界,生态环境监测范围小于人类生产活动监测范围;在时间尺度上以月为最大单位,每月采样时间在当月下旬且在采样当天前5天未降雨;气象、环保和水利等部门设置监测点要统一;生物多样性监测点在气象、水文和水质监测点半径5 km内设置。     

快速城市化背景下的思雅河流域水环境分析

通过对思雅河流域连续3年的水环境质量监测,结合遥感影像获得其土地利用类型变化,据此研究城市化对水环境的影响。结果表明:2012—2014年间思雅河流域自然、农业景观面积占比减少,而建设用地面积持续增加;研究期间除TDS年均值略微下降外,其余水质指标的年均值几乎均呈递增趋势,尤以TSS和COD增加最显著;TSS、COD、NH 3-N和TP的相对标准偏差均>0.1,显著高于其余参数,说明其波动程度较大。主成分分析表明水环境变化最主要的影响因子为第一主成分(TSS、COD、NH 3-N和TP)。贵安新区大学城建设活动加重了思雅河流域水体污染趋势。     

基于GIS的百花湖流域土地利用变化与水质响应

利用ArcGIS和ENVI软件并结合Spearman分析法,探究百花湖流域1997年、2007年和2017年土地利用类型变化对5种水质指标年均值的响应。结果表明:1997—2017年流域内林地和建筑用地面积递增,耕地面积递减,林地占整个流域面积的50%以上;在土地转移中林地、建筑用地和耕地之间的转移最大,林地和建筑用地的增加主要来自耕地;1997年水质最好,2007年水质最差,2017年对流域实施水污染治理工程后水质有所改善;相关分析得出建筑用地、耕地与TN、TP、NH_3-N呈显著正相关,对TN、TP、NH_3-N有"源"的作用,林地与TN、TP呈显著负相关,对TN、TP有"汇"的作用。     

北京市城市屋面径流特征研究

对北京市城区不同功能区和不同类型的屋面进行三场降雨径流监测,并分析屋面径流污染过程和水质特征。采用降雨径流污染物平均浓度(EMC)分析评价径流污染程度,结果表明径流水质与屋面材质、降雨强度等因素有关,沥青屋面污染较重,降雨强度越大,径流水质越差;三场降雨中污染物浓度随降雨历时总体上呈先升高后降低的变化趋势,初期径流水质较差,存在明显的初始冲刷现象。     

我国沙尘暴灾害及其治理对策初步研究

分析研究了沙尘暴的成因、时空分布、发展趋势及造成的灾害,结合国外经验提出了我国治理的对策建议。     

Dissipation and residue of metalaxyl and cymoxanil in pepper and soil

A simple and accurate method of determining metalaxyl and cymoxanil in pepper and soil was developed by ultra-performance liquid chromatography–photodiode array detection. The limits of detection were 0.015 mg/kg for metalaxyl and 0.003 mg/kg for cymoxanil. The limits of quantification were 0.05 mg/kg for metalaxyl in pepper and soil as well as 0.01 mg/kg for cymoxanil in pepper and soil. Recoveries of pepper and soil were investigated at three spiking levels and ranged within 77.52 to 102.05 % for metalaxyl and 87.15 to 103.21 % for cymoxanil, with relative standard deviations below 9.30 %. For field experiments, the half-lives of metalaxyl were 3.2 to 3.9 days in pepper and 4.4 to 9.5 days in soil at the three experimental locations in China. At harvest, pepper samples were found to contain metalaxyl and cymoxanil well below the maximum residue limit MRLs of the European Union (EU) following the recommended dosage and the interval of 21 days after last application.     

Determination and study on dissipation and residue of bismerthiazol and its metabolite in Chinese cabbage and soil

A simple and accurate method for the determination of bismerthiazol and its metabolite 2-amino-5-mercapto-1,3,4-thiadiazole was developed in Chinese cabbage and soil by high-performance liquid chromatography-diode array detection in this study. The limits of detection were 0.06 mg/kg for bismerthiazol and 0.03 mg/kg for 2-amino-5-mercapto-1,3,4-thiadiazole, respectively. Recoveries of cabbage and soil were investigated at three spiking levels and were in the range of 84.0–96.0 % for bismerthiazol and 71.0–74.6 % for 2-amino-5-mercapto-1,3,4-thiadiazole, with relative standard deviations below 7.0 %. For field experiments, the half-life of bismerthiazol was 2.4–2.5 days in Chinese cabbage and 2.5–4.8 days in soil at the two experimental locations in China. Dissipation residues of 2-amino-5-mercapto-1,3,4-thiadiazole were lower than 0.72 mg/kg. Terminal residues of bismerthiazol and its metabolite were less than 3.0 and 0.3 mg/kg in Chinese cabbage, respectively. No bismerthiazol or metabolite residues were detected in soil on days 5, 7, 10, and 14 after the last spraying at the two dosage levels.     

Residues and dissipation of trifloxystrobin and its metabolite in tomatoes and soil

A simple residue analytical method using the quick, easy, cheap, effective, rugged, and safe (QuEChERS) procedure for the determination of trifloxystrobin and its metabolite trifloxystrobin acid (CGA321113) in tomato and soil was developed using high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS). The limits of detection were 0.0005 mg/kg for trifloxystrobin and 0.001 mg/kg for trifloxystrobin acid, respectively. The average recoveries in tomato and soil ranged from 73–99 % for trifloxystrobin and 75–109 % for trifloxystrobin acid, with relative standard deviations below 15 %. The method was then used to study the dissipation and residues in tomato and soil. The dissipation half-lives of trifloxystrobin in tomato were 2.9 days (Beijing) and 5.4 days (Shandong), while in soil were 1.9 days (Beijing) and 3.0 days (Shandong), respectively. The final results showed that the major residue compound was trifloxystrobin in tomato whereas it was its metabolite, trifloxystrobin acid, in soil. The final residues of total trifloxystrobin (including trifloxystrobin acid) were below the EU maximum residue limit of 0.5 mg kg^?1 in tomato 3 days after the treatment.     

新疆室内环境污染监测和治理工作现状与建议

针对目前室内环境监测工作出现的种种问题,就如何规范的开展室内环境监测工作,更好地为社会提供真实、准确、有效的监测数据,本文提出相关的探讨。     

Lake destratification and speciation of iron and manganese

A long-term study of the effect of artificial aeration (destratification) of a water storage dam upon the speciation of iron and manganese in the dam waters has been undertaken. Separation of dam samples into soluble and insoluble forms by selective membrane filtration was undertaken before using the techniques of EPR spectroscopy, ion chromatography and gel filtration to assess the speciation of soluble species, and selective extraction and surface analysis (ESCA, SIMS and SEM) techniques to determine the speciation of particulate iron and manganese species. The percentages of soluble iron and manganese before (1983–85) and after (1986–88) artificial aeration are compared for the periods Jan–Dec, Jan–Mar, and Jun–Aug at three depths 6 m, 15 m and 0.5 m above the dam base, to assess the importance of seasonal changes in the various depths of the dam. Although aeration had an initial marked reduction in levels of soluble iron and manganese at all depths of the dam, the concentrations of these mtals showed a steady increase over succeeding years. Analysis of the figures over summer and winter periods shows that the reduction of soluble iron was maintained in summer, but not during winter. Upon aeration, the initial reduction of soluble manganese concentration was maintained in succeeding years in the epilimnic regions of the dam, but not in the hypolimnion. Statistical analysis of data has been undertaken to correlate the changes in relationship between the various forms of iron and manganese with the advent of aeration.     

Disembodied and Disembedded? The Social and Economic Implications of Atmospheric Change and Biodiversity

The social and economic implications of atmospheric change on biodiversity need to be seen in a global context of major shifts in the conceptualization and management of our relationship with nature. Traditionally, we have conceptualized the atmosphere and the other creatures of the biosphere as separate from the human, but their quasi-autonomy is now becoming subject to more and more human management. This raises not only economic issues, but social, political, and ethical concerns that will have substantial influence on public policy. Among these are the commodification of genetic material; the privatization of traditional knowledge; and the management of information. In this broader context, the paper examines an array of current and proposed strategies of response to changes in biodiversity as a result of climatic and other stresses.     

Atmospheric Change and Biodiversity: Co-Networks and Networking

Canada responded to the Global Biodiversity Convention by completing the Canadian Biodiversity Strategy in 1995. At the same time, Environment Canada also completed a national Science Assessment on Biodiversity. During this period, the Smithsonian Institution, in partnership with Parks and Environment Canada, initiated the implementation of a global biodiversity monitoring program in Canada. Under the auspices of the United Nations Man and the Biosphere Program, the SI/MAB monitoring protocols and plots have spread across Canada at an unprecedented rate. National champions in the science and educational sectors, working within an inter-disciplinary ecological framework, have guided the development, education, quality control and sharing of atmosphere-biodiversity observations electronically.Atmospheric-Biodiversity Networks and Networking have traditionally operated within separate mandates with little degree of integration. Air-Bio Networks were designed within an integrated framework to better understand the atmospheric stress on biodiversity and the adaptation actions, nationally and regionally. Detailed examples of the cumulative effects of climate change, stratospheric ozone depletion, acid deposition, ground-level ozone, suspended particulate matter and hazardous air pollutants on biodiversity will be discussed using a Southern Ontario case study. In addition, recommendations will be presented for future paired SI/MAB plots, linked networks and networking for adaptation within the context of climate, chemical and ecological gradients.     

太原市冬、夏季醛酮化合物污染特征及来源分析

针对太原市空气臭氧污染较为严重的问题,开展臭氧主要前体物醛酮化合物质量浓度及其变化规律研究.利用2,4-二硝基苯肼固相吸附/高效液相色谱方法,通过对太原市2019年冬季和夏季大气的醛酮化合物进行分析,发现太原市冬季总醛酮化合物的平均质量浓度为13μg/m3,低于夏季的27μg/m3.其中甲醛、乙醛和丙酮质量浓度最高,且...