Metal content in street dust as a reflection of atmospheric dust emissions from coal power plants, metal smelters, and traffic

Resuspended street dust is a source of inhalable particles in urban environments. Despite contaminated street dust being a possible health risk factor for local population, little is known about the contribution of atmospheric dust emissions and other factors to the content of toxic metals in street dust. The impact of smelting, traffic, and power plants on metal contaminates in street dust is the focus of street dust sampling at 46 locations in the Witbank area (Republic of South Africa). This area is characterized by numerous open-pit coal mines in the Karoo coal basin, which provides a cheap source of energy to numerous metallurgical smelters and ironworks and supplies coal to the coal-fired power plants located nearby. Street dust was collected on asphalt or concrete surfaces with hard plastic brushes, avoiding collecting of possible sand, soil, or plant particles. Chemical analysis was done on the <0.125 mm fraction using inductively coupled plasma mass spectrometry subsequent to total digestion. Exceptionally high concentrations of metals were detected with concentrations of Fe reaching 17.7 %, Cr 4.3 %, Mn 2 %, Ni 366 mg/kg, and V 4,410 mg/kg. Factor analysis indicates three sources for the pollution. Road traffic which contributes to the high concentrations of Cu, Pb, Sb, and Sn, with the highest impacts detected in the town of Witbank. The second source is associated with the metal smelting industry, contributing to Fe, Co, Mn, and V emissions. The highest factor scores were observed around four metallurgical smelter operations, located in the Ferrobank, Highveld, and Clewer industrial areas. Impact of vanadium smelter to street dust composition could still be detected some 20 km away from the sources. Exceptionally high concentrations of Cr were observed in four samples collected next to the Ferrobank industrial area, despite Cr not being loaded in factor 2. The last source of the pollution is most probably fly ash associated with the coal-fired power plants and fly ash dumps. Elements which are associated with this source are Al, Sr, and Li. This factor is abundant in the coal mining part of the study area.     

Bio-accessibility and health risk assessment of some selected heavy metals in indoor dust from higher institutions in Ondo State,Nigeria

Environmental Science and Pollution Research - Risks of heavy metal exposure from contaminated indoor dust constitute a major threat to human health. In this paper, heavy metals in deposited indoor...     

Occurrence of organic and inorganic biocides in the museum environment

In the museum environment organic and inorganic chemicals can be found, which originate from both outside and inside the building. Many of the contaminants may cause adverse effects on works of art and human health, but in the past, pollution research in museums has focused on the protection of artifacts, while the risk assessment for humans has been neglected. Especially, the application of biocides leads to a conflict of interest: on the one hand cultural assets have to be protected against microorganisms, insects and rodents while on the other hand it is essential to provide healthy conditions for museum staff and visitors. It has recently been shown that the release of organic indoor pollutants from building products is one of the main reasons for deterioration of artifacts. In this work, we present the results of screening measurements on biocides in different locations of German museums. The major components that could be identified were DDT, PCP, lindane, methoxychlor, naphthalene, chlorinated naphthalenes, 1,4-dichlorobenzene, PCBs and arsenic. It is demonstrated that the application of chlorinated organic compounds and arsenic for preventive conservation is one of the prime reasons for indoor pollution in museums and provides a potential for exposure. However, the concentrations in air, dust and material are widely different and a health risk for humans has to be evaluated case by case.     

Evaluation and investigation of the effects of ventilation layout,rate, and room temperature on pollution dispersion across a laboratory indoor environment

The presence of chemicals in laboratories and research centers exposes the staff working at such indoor environment to health risks. In this piece of research, a study was performed on the indoor environment of the Center for Environmental Engineering Research at Sahand University of Technology (Tabriz, Iran). For this purpose, the parameters affecting the dispersion of volatile organic compounds (VOCs), including ventilation rate, room temperature, pollution emission time, venting location, air flow regime within the indoor environment, and the number of vents, were simulated via CFD modeling. The CFD modeling was performed three-dimensionally in unsteady state. In case of turbulent flow within the indoor environment, k–ε turbulence model was used to obtain air velocity profile. Experimental data was used to validate the model. Results of the present research showed that when the venting location is on the ceiling, pollution concentration of 25 ppm can be achieved at some low temperature under a particular set of conditions. However, when the venting location was on the walls close to the pollution source, concentrations as low as 5 ppm and lower were observed within the laboratory indoor environment.

     

Determination of Heavy Metals in Indoor Dust From Primary School (Sri Serdang,Malaysia): Estimation of the Health Risks

Heavy metal concentrations (Pb, Cd, and Cu) in classroom indoor dust were measured. The health risk (non-carcinogenic) of these heavy metals in classroom indoor dust to children was assessed based on United States Environmental Protection Agency health risk model. Indoor classroom dust samples were collected from 21 locations including windows, fans, and floors at a primary school in Sri Serdang, Malaysia. Classroom dust samples were processed using aqua regia method and analyzed for Pb, Cd, and Cu concentrations. The highest average heavy metal concentrations were found in windows, followed by floor and fan. Pb concentrations ranged from 34.17 μg/g to 101.87 μg/g, Cd concentrations ranged from 1.73 μg/g to 7.5 μg/g, and Cu concentrations ranged from 20.27 μg/g to 82.13 μg/g. Ventilation and cleaning process were found as the possible factors that contributed to heavy metal concentration in window, floor, and fan. Moreover, the hazard index (HI) and hazard quotient (HQ) values for heavy metals Cd and Cu were less than one. By contrast, the HI and HQ values for Pb (maximum values) were more than one, indicating potential non-carcinogenic risk to children. Long-term persistence of leaded petrol, building materials, interior paint, school located near industrial areas and major roads, as well as vehicle emission are the factors attributed to the presence of heavy metals in classroom dust. Further research under a long-term monitoring plan and actual values in a health risk model is crucial before a final decision on heavy metal exposure and its relationship to young children health risks can be made. Nevertheless, the findings of this study provide crucial evidence to include indoor dust quality in school assessment because the environmental processes and impacts of surrounding school area have health risk implications on young children.     

Indoor air and respiratory health in preadolescent children

The effect of indoor exposure to nitrogen dioxide, ammonia, particulate matter and parental tobacco smoke on respiratory health was studied over a period of six months in all second graders born and living in two area of continental Croatia 8–10 yr of age. The study group was divided into two sections corresponding to area of residence (industrial/rural). Information on respiratory symptoms was collected from a self-administered questionnaire completed by the parents of the children. The mean values of concentrations of indoor air pollution that had been recorded in 24-h samples of air collected at schools were mostly below threshold limit for ambient pollution. In addition, information on parental smoking, the density of habitation and the type of fuel used for heating and/or cooking in the home was obtained by a questionnaire. In the investigated period the prevalence of respiratory illness was 22% in the children exposed to lower indoor air pollution and 25% in those exposed to higher indoor air pollution. Exposure to parental smoking was also associated with more respiratory symptoms (28 : 19%). The results indicate that the measured air pollutants only had a slight effect on the respiratory health of preadolescent children. However, the effect of exposure to parental smoking was more pronounced.     

Distribution,sources and pollution status of Pb in indoor and outdoor dusts of Kerman City,SE Iran

The aims of this study were to explore the status of pollution and the temporal/spatial distribution of indoor and outdoor dust-Pb in the city of Kerman (SE Iran), located in a dry playa and arid climatic zone. Flat panes were laid at appropriate locations, in the indoor and the outdoor spaces of selected one-story houses in different areas of the city, to collect dust samples. Forty-two samples were taken and analyzed using the ICP-MS method. The measurements have shown that the outdoor dust-Pb concentrations varied from 23.7 to 275.2?mg kg^?1, with a mean value of 71.8?mg kg^?1, and indoor dust-Pb concentrations ranged from 47.6 to 150.2?mg kg^?1, with a mean value of 89.6?mg kg^?1. Based on these measurements, Pb was enriched in the outdoor and the indoor dust samples up to 48.8 and 29.4 times, respectively. Dilution, as a result of prevalence of geogenic dust in the outdoor space, is expected to be the main cause of the temporal differences. This study has shown that the eastern part of the city is more polluted compared to the other parts, and, because of the stable air conditions, the concentration of Pb in the summer dust is higher than the other seasons.     

室内电磁辐射污染与防护

基于电磁辐射污染对环境和人体健康的影响 ,探讨了目前室内电磁辐射污染的现状和室内潜在的电磁辐射污染源 ,并就室内电磁辐射污染的防护措施提出了几点建议     

Preparation and performance of a biological dust suppressant based on the synergistic effect of enzyme-induced carbonate precipitation and surfactant

Environmental Science and Pollution Research - To control the dust pollution caused by open-pit coal mining and reduce or avoid the secondary hazards of existing dust suppressants to the...     

我国室内空气污染现状、成因与对策

室内空气污染严重影响公众健康 ,已经受到广泛关注。本文分析了我国室内空气污染的现状和成因 ,并从法规建设、监督管理、科学研究和宣传教育等方面介绍了我国控制室内空气污染的对策措施     

A review of polychlorinated biphenyls (PCBs) pollution in indoor air environment

Polychlorinated biphenyls (PCBs) were widely used in industrial production due to the unique physical and chemical properties. As a kind of persistent organic pollutants, the PCBs would lead to environment pollution and cause serious problems for human health. Thus, they have been banned since the 1980s due to the environment pollution in the past years. Indoor air is the most direct and important environment medium to human beings; thus, the PCBs pollution research in indoor air is important for the protection of human health. This paper introduces the industrial application and potential harm of PCBs, summarizes the sampling, extracting, and analytical methods of environment monitoring, and compares the indoor air levels of urban areas with those of industrial areas in different countries according to various reports. This paper can provide a basic summary for PCBs pollution control in the indoor air environment.

Implications: The review of PCBs pollution in indoor air in China is still limited. In this paper, we introduce the industrial application and potential harm of PCBs, summarize the sampling, extracting, and analytical methods of environment monitoring, and compare the indoor air levels of urban areas with industrial areas in different countries according to various reports.     

Windsor, Ontario exposure assessment study: design and methods validation of personal, indoor, and outdoor air pollution monitoring

The Windsor, Ontario Exposure Assessment Study evaluated the contribution of ambient air pollutants to personal and indoor exposures of adults and asthmatic children living in Windsor, Ontario, Canada. In addition, the role of personal, indoor, and outdoor air pollution exposures upon asthmatic children's respiratory health was assessed. Several active and passive sampling methods were applied, or adapted, for personal, indoor, and outdoor residential monitoring of nitrogen dioxide, volatile organic compounds, particulate matter (PM; PM-2.5 pm [PM2.5] and < or =10 microm [PM10] in aerodynamic diameter), elemental carbon, ultrafine particles, ozone, air exchange rates, allergens in settled dust, and particulate-associated metals. Participants completed five consecutive days of monitoring during the winter and summer of 2005 and 2006. During 2006, in addition to undertaking the air pollution measurements, asthmatic children completed respiratory health measurements (including peak flow meter tests and exhaled breath condensate) and tracked respiratory symptoms in a diary. Extensive quality assurance and quality control steps were implemented, including the collocation of instruments at the National Air Pollution Surveillance site operated by Environment Canada and at the Michigan Department of Environmental Quality site in Allen Park, Detroit, MI. During field sampling, duplicate and blank samples were also completed and these data are reported. In total, 50 adults and 51 asthmatic children were recruited to participate, resulting in 922 participant days of data. When comparing the methods used in the study with standard reference methods, field blanks were low and bias was acceptable, with most methods being within 20% of reference methods. Duplicates were typically within less than 10% of each other, indicating that study results can be used with confidence. This paper covers study design, recruitment, methodology, time activity diary, surveys, and quality assurance and control results for the different methods used.     

Windsor, Ontario exposure assessment study: design and methods validation of personal, indoor, and outdoor air pollution monitoring

The Windsor, Ontario Exposure Assessment Study evaluated the contribution of ambient air pollutants to personal and indoor exposures of adults and asthmatic children living in Windsor, Ontario, Canada. In addition, the role of personal, indoor, and outdoor air pollution exposures upon asthmatic children's respiratory health was assessed. Several active and passive sampling methods were applied, or adapted, for personal, indoor, and outdoor residential monitoring of nitrogen dioxide, volatile organic compounds, particulate matter (PM; PM < or = 2.5 microm [PM2.5] and < or = 10 microm [PM10] in aerodynamic diameter), elemental carbon, ultrafine particles, ozone, air exchange rates, allergens in settled dust, and particulate-associated metals. Participants completed five consecutive days of monitoring during the winter and summer of 2005 and 2006. During 2006, in addition to undertaking the air pollution measurements, asthmatic children completed respiratory health measurements (including peak flow meter tests and exhaled breath condensate) and tracked respiratory symptoms in a diary. Extensive quality assurance and quality control steps were implemented, including the collocation of instruments at the National Air Pollution Surveillance site operated by Environment Canada and at the Michigan Department of Environmental Quality site in Allen Park, Detroit, MI. During field sampling, duplicate and blank samples were also completed and these data are reported. In total, 50 adults and 51 asthmatic children were recruited to participate, resulting in 922 participant days of data. When comparing the methods used in the study with standard reference methods, field blanks were low and bias was acceptable, with most methods being within 20% of reference methods. Duplicates were typically within less than 10% of each other, indicating that study results can be used with confidence. This paper covers study design, recruitment, methodology, time activity diary, surveys, and quality assurance and control results for the different methods used.     

Analysis of atmospheric aerosol (PM2.5) in Recife city,Brazil

Several studies indicate that mortality and morbidity can be well correlated to atmospheric aerosol concentrations with aerodynamic diameter less than 2.5 µm (PM_2.5). In this work the PM_2.5 at Recife city was analyzed as part of a main research project (INAIRA) to evaluate the air pollution impact on human health in six Brazilian metropolitan areas. The average concentration, for 309 samples (24-hr), from June 2007 to July 2008, was 7.3 µg/m³, with an average of 1.1 µg/m³ of black carbon. The elemental concentrations of samples were obtained by x-ray fluorescence. The concentrations were then used for characterizing the aerosol, and also were employed for receptor modelling to identify the major local sources of PM_2.5. Positive matrix factorization analysis indicated six main factors, with four being associated to soil dust, vehicles and sea spray, metallurgical activities, and biomass burning, while for a chlorine factor, and others related to S, Ca, Br, and Na, we could make no specific source association. Principal component analysis also indicated six dominant factors, with some specific characteristics. Four factors were associated to soil dust, vehicles, biomass burning, and sea spray, while for the two others, a chlorine- and copper-related factor and a nickel-related factor, it was not possible to do a specific source association. The association of the factors to the likely sources was possible thanks to meteorological analysis and sources information. Each model, although giving similar results, showed factors’ peculiarities, especially for source apportionment. The observed PM_2.5 concentration levels were acceptable, notwithstanding the high urbanization of the metropolitan area, probably due to favorable conditions for air pollution dispersion. More than a valuable historical register, these results should be very important for the next analysis, which will correlate health data, PM_2.5 levels, and sources contributions in the context of the six studied Brazilian metropolises.

Implications: The analysis of fine particulate matter (PM_2.5) in Recife city, Brazil, gave a significant picture of the local concentration and composition of this pollutant, which exhibits robust associations to adverse human health effects. Data from 1 year of sampling evaluated the seasonal variability and its connections with weather patterns. Source apportionment in this metropolitan area was obtained based in a combination of receptor models: principal component analysis (PCA)/chemical mass balance (CMB) and positive matrix factorization (PMF). These results give guidelines for local air pollution control actions, providing significant information for a health study in the context of establishing a new national air pollution protocol based on Brazilian cities data.     

Dust events as a risk factor for daily hospitalization for respiratory and cardiovascular diseases in Minqin,China

Dust events are common air pollution events in parts of the world with arid, semi-arid, or desert areas. There is little research on the association between respiratory and cardiovascular health and dust events in places which are close to the deserts. The aim of this study is to evaluate the health effects of dust events in a location where traffic and industry are underdeveloped and dust events are most frequent in China. The setting allows the opportunity to reduce confounding by anthropogenically derived particulate matter and to confirm the health effects of dust events. The present study was done using daily counts of hospitalizations in Minqin (1994–2003) for respiratory and cardiovascular diseases (International Classification of Diseases, Tenth revision) for males and females. Using a semi-parametric generalized additive model and controlling for long-term temporal trends, day of the week, meteorological factors, and seasonal influence, counts of hospitalization were analyzed for dust events in a Poisson regression.Relative risks (RRs) were used to estimate the risk of dust events for respiratory and cardiovascular hospitalizations. In the year-round model, dust events with a lag of 3 days were significantly associated with total respiratory hospitalization for males and females, with RRs of 1.14 (95% confidence interval (CI) 1.01–1.29) and 1.18 (95% CI 1.00–1.41); dust events with a lag of 4 days were significantly associated with upper respiratory tract infection (URTI) in males (RR 1.28, 95% CI 1.04–1.59), and dust events with a lag of 6 days were significantly associated with pneumonia in males, with an RR of 1.17 (95% CI 1.00–1.38). A significant association between dust events with a lag of 3 days and hypertension in males was also found (RR 1.30, 95% CI 1.03,1.64). In the seasonal analysis model, the associations between the dust events and respiratory and cardiovascular hospitalizations were stronger in spring and in winter, respectively.The results show the health effects of dust events on respiratory and cardiovascular hospitalizations, and the characteristic seasonal distribution of the health effects. In addition, the health effects of dust events are consistent with recent animal and human data showing the respiratory and cardiovascular effects of particulate matter.     

Occupational exposure to synthetic musks in barbershops,compared with the common exposure in the dormitories and households

Synthetic musks (SMs) have been widely used as fragrance ingredients in personal care and sanitary commodities. Due to their high volatility and particle-binding affinity, the indoor dust is a major reservoir of SMs, and dust ingestion could be an important exposure way to special populations, such as hairdressers. In spite of the known toxicity of SMs, there is no information regarding the occurrence of SMs in barbershop dusts and the exposure of hairdressers through indoor dust ingestion. In the present study, the levels of two nitro musks and five polycyclic musks were measured from indoor dust samples collected from barbershops, and some other indoor dust samples were also collected from dormitories, bathhouses and households for comparison. The concentrations of ∑SMs in barbershop dusts were 10–100 times higher than those from the other three indoor microenvironments. Polycyclic musks accounted for 89.4% of ∑SMs on average in all samples, of which two compounds, HHCB and AHTN jointly dominated 97.9% of polycyclic musks. The levels of HHCB and AHTN varied from 12.2 to 8.39 × 10⁵ and from 13.2 to 3.49 × 10⁵ ng g⁻¹, respectively. The daily intakes (DIs) of ∑SMs through house dust ingestion were estimated using the model of high dust ingestion and worst-case exposure (P95), and the corresponding exposure rates were 2791, 135 and 727 ng d⁻¹ for the hairdressers, general population and toddlers. SMs were also detected in blood samples collected from the hairdressers and normal adults (n = 50 and 10, respectively). There was no significant difference between these two groups. Despite the absence of higher SM concentrations in hairdresser’s blood, we should not overlook the potential occupational health risks due to their high SMs ingestion rate.     

Comparisons of the dust/smoke particulate that settled inside the surrounding buildings and outside on the streets of southern New York City after the collapse of the World Trade Center, September 11, 2001

The collapse of the World Trade Center (WTC) on September 11, 2001, generated large amounts of dust and smoke that settled in the surrounding indoor and outdoor environments in southern Manhattan. Sixteen dust samples were collected from undisturbed locations inside two uncleaned buildings that were adjacent to Ground Zero. These samples were analyzed for morphology, metals, and organic compounds, and the results were compared with the previously reported outdoor WTC dust/smoke results. We also analyzed seven additional dust samples provided by residents in the local neighborhoods. The morphologic analyses showed that the indoor WTC dust/smoke samples were similar to the outdoor WTC dust/smoke samples in composition and characteristics but with more than 50% mass in the <53-microm size fraction. This was in contrast to the outdoor samples that contained >50% of mass above >53 microm. Elemental analyses also showed the similarities, but at lower concentrations. Organic compounds present in the outdoor samples were also detected in the indoor samples. Conversely, the resident-provided convenience dust samples were different from either the WTC indoor or outdoor samples in composition and pH, indicating that they were not WTC-affected locations. In summary, the indoor dust/smoke was similar in concentration to the outdoor dust/smoke but had a greater percentage of mass <53 microm in diameter.     

Study on temporal and spatial evolution law for dust pollution in double roadway ventilation system of short wall continuous mining face

Environmental Science and Pollution Research - To explore the laws of variations in the evolution of dust pollution within a double tunnel ventilation system at a short wall continuous mining face,...     

Distribution of polybrominated diphenyl ethers and dust particle size fractions adherent to skin in indoor dust,Pretoria, South Africa

In order to determine human exposure to the indoor toxicant, selection of dust fraction and understanding dust particle size distribution in settled indoor dust are very important. This study examined the influence of dust particle size on the concentration of polybrominated diphenyl ethers (PBDEs) congeners, assessed the distribution of dust particle size and characterized the main indoor emission sources of PBDEs. Accordingly, the concentrations of PBDE congeners determined in different indoor dust fractions were found to be relatively higher in the order of dust particle size: 45–106 μm?>?(<45 μm)?>?106–150 μm. The finding shows arbitrary selection of dust fractions for exposure determination may result in wrong conclusions. Statistically significant moderate correlation between the concentration of Σ₉PBDEs and organic matter content calculated with respect to the total dust mass was also observed (r?=?0.55, p?=?0.001). On average, of total dust particle size <250 μm, 93.4 % (m/m%) of dust fractions was associated with less than 150 μm. Furthermore, of skin adherent dust fractions considered (<150 μm), 86 % (v/v%) is in the range of particle size 9.25–104.7 μm. Electronic materials treated with PBDEs were found the main emission sources of PBDE congeners in indoor environment. Based on concentrations of PBDEs determined and mass of indoor dust observed, 150 μm metallic sieve is adequate for human exposure risk assessment. However, research in this area is very limited and more research is required to generalize the fact.     

Comparisons of the Dust/Smoke Particulate that Settled Inside the Surrounding Buildings and Outside on the Streets of Southern New York City after the Collapse of the World Trade Center,September 11, 2001

Abstract

The collapse of the World Trade Center (WTC) on September 11, 2001, generated large amounts of dust and smoke that settled in the surrounding indoor and outdoor environments in southern Manhattan. Sixteen dust samples were collected from undisturbed locations inside two uncleaned buildings that were adjacent to Ground Zero. These samples were analyzed for morphology, metals, and organic compounds, and the results were compared with the previously reported outdoor WTC dust/smoke results. We also analyzed seven additional dust samples provided by residents in the local neighborhoods. The morphologic analyses showed that the indoor WTC dust/smoke samples were similar to the outdoor WTC dust/smoke samples in composition and characteristics but with more than 50% mass in the <53 μm size fraction. This was in contrast to the outdoor samples that contained >50% of mass above >53 μm. Elemental analyses also showed the similarities, but at lower concentrations. Organic compounds present in the outdoor samples were also detected in the indoor samples. Conversely, the resident-provided convenience dust samples were different from either the WTC indoor or outdoor samples in composition and pH, indicating that they were not WTC-affected locations. In summary, the indoor dust/smoke was similar in concentration to the outdoor dust/smoke but had a greater percentage of mass <53 μm in diameter.