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1.
As power production from renewable energy and natural gas grows, closures of some coal-fired power plants in Texas become increasingly likely. In this study, the potential effects of such closures on air quality and human health were analyzed by linking a regional photochemical model with a health impacts assessment tool. The impacts varied significantly across 13 of the state’s largest coal-fired power plants, sometimes by more than an order of magnitude, even after normalizing by generation. While some power plants had negligible impacts on concentrations at important monitors, average impacts up to 0.5 parts per billion (ppb) and 0.2 µg/m3 and maximum impacts up to 3.3 ppb and 0.9 µg/m3 were seen for ozone and fine particulate matter (PM2.5), respectively. Individual power plants impacted average visibility by up to 0.25 deciviews in Class I Areas. Health impacts arose mostly from PM2.5 and were an order of magnitude higher for plants that lack scrubbers for SO2. Rankings of health impacts were largely consistent across the base model results and two reduced form models. Carbon dioxide emissions were relatively uniform, ranging from 1.00 to 1.26 short tons/MWh, and can be monetized based on a social cost of carbon. Despite all of these unpaid externalities, estimated direct costs of each power plant exceeded wholesale power prices in 2016.

Implications: While their CO2 emission rates are fairly similar, sharply different NOx and SO2 emission rates and spatial factors cause coal-fired power plants to vary by an order of magnitude in their impacts on ozone, particulate matter, and associated health and visibility outcomes. On a monetized basis, the air pollution health impacts often exceed the value of the electricity generated and are of similar magnitude to climate impacts. This suggests that both air pollution and climate should be considered if externalities are used to inform decision making about power-plant dispatch and retirement.  相似文献   


2.
Although sulphur emissions (mainly as SO2) have been continuously decreasing over the last 20 years in most western industrialized countries, localized SO2 problems still exist in conjunction with strong local emission, meteorological, and topographical factors. In this study, the effect of supplementary installed flue gas desulphurization (FGD) units at high-capacity power plants on regional air pollution in the Carpathian Basin is investigated. The dispersion and accumulation of the SO2 air pollutant are studied with the regional three-dimensional on-line atmosphere-chemistry model REMOTE. The changes in the SO2 air pollution are investigated by parallel simulations in a case study, where the single modified parameter is the SO2 emission rate. The results show that FGD units significantly reduce the horizontal and the vertical dispersion of the emitted SO2, and its transboundary transport, too. Beside the SO2 removal efficiency, the dispersion and accumulation also depend on the seasonal weather conditions. During winter, the dispersion and accumulation are higher than in other seasons. Due to this phenomenon, higher SO2 removal efficiency is needed to guarantee similar air quality features like in the other seasons.  相似文献   

3.
ABSTRACT

A study was conducted to estimate the changes in wintertime visual air quality in Dallas-Fort Worth (DFW) that might occur due to proposed reductions in SO2 emissions at two steam electric generating plants in eastern Texas, each over 100 km from the city. To provide information for designing subsequent investigations, the haze was characterized broadly during the first year of the study. Meteorological data acquired then demonstrated that, during haze episodes, emissions from only one of the two plants were likely to be transported directly to DFW. Therefore, the second year of the study was centered on just one of the power plants. Air quality was then characterized within the urban area and at rural locations that would be upwind and downwind of the plant during transport to DFW. An instrumented aircraft measured plume dispersion and the air surrounding the plume on selected days. A mathematical model was used to predict the change that would occur in airborne particulate matter concentrations in DFW if SO2 emissions were reduced to reflect the proposed limitations. The contribution of particles in the atmosphere to light extinction was estimated, and simulated photographs were produced to illustrate the visibility changes. The study concluded that the proposed emission reductions would, at most, subtly change perceived wintertime visibility.  相似文献   

4.
The use of regulatory and compliance-based modeling for air quality impact assessment is invariably relied upon to predict future air quality under various management scenarios particularly where air quality monitoring data are limited. This paper examines the dispersion from a multi-stack cement manufacturing complex with associated quarries and transport activities for regulatory compliance under uncertain emission and meteorological conditions. The concentrations of CO, NOx, SO2 and PM at sensitive receptor locations were used as indicators in comparison to World Health Organization (WHO) interim guidelines. Exceedance exposure areas were delineated under bounded uncertainties in input emission factors and meteorological parameters. Planning and management initiatives were tested to control/minimize potential exposure. Compared to the case of low emissions and actual meteorological conditions, the consideration of worst emissions coupled to worst meteorological conditions enlarged the boundaries of the exceedance exposure areas considerably. The implementation of best available technologies and enforcement of emission standards improved air quality in the region significantly and lowered the exposure at many population centers to below health standards. Uncertainty in the output of atmospheric dispersion models continues to play a significant role to be considered at the point where science is translated into political decision making.  相似文献   

5.
Using a WRF-SMOKE-CMAQ modeling framework, we investigate the impacts of smoke from prescribed fires on model performance, regional and loc al air quality, health impacts, and visibility in protected natural environments using three different prescribed fire emission scenarios: 100% fire, no fire, and 30% fire. The 30% fire case reflects a 70% reduction in fire activities due to harvesting of logging residues for use as a feedstock for a potential aviation biofuel supply chain. Overall model performance improves for several performance metrics when fire emissions are included, especially for organic carbon, irrespective of the model goals and criteria used. This effect on model performance is more pronounced for the rural and remote IMPROVE sites for organic carbon and total PM2.5. A reduction in prescribed fire emissions (30% fire case) results in significant improvement in air quality in areas in western Oregon, northern Idaho, and western Montana, where most prescribed fires occur. Prescribed burning contributes to visibility impairment, and a relatively large portion of protected class I areas will benefit from a reduced emission scenario. For the haziest 20% days, prescribed burning is an important source of visibility impairment, and approximately 50% of IMPROVE sites in the model domain show a significant improvement in visibility for the reduced fire case. Using BenMAP, a health impact assessment tool, we show that several hundred additional deaths, several thousand upper and lower respiratory symptom cases, several hundred bronchitis cases, and more than 35,000 workday losses can be attributed to prescribed fires, and these health impacts decrease by 25–30% when a 30% fire emission scenario is considered.

Implications: This study assesses the potential regional and local air quality, public health, and visibility impacts from prescribed burning activities, as well as benefits that can be achieved by a potential reduction in emissions for a scenario where biomass is harvested for conversion to biofuel. As prescribed burning activities become more frequent, they can be more detrimental for air quality and health. Forest residue-based biofuel industry can be source of cleaner fuel with co-benefits of improved air quality, reduction in health impacts, and improved visibility.  相似文献   


6.
Federal new source performance standards to control air emissions of sulfur dioxide from new industrial boilers were proposed by EPA on June 19, 1986. These standards would require boiler owners to reduce SO2 emissions by 90 percent and meet an emission limit of 1.2 lb/MM Btu of heat input for coal-fired boilers and 0.8 lb/MM Btu for oil-fired boilers. In developing these standards, several regulatory options were considered, from standards that could be met by firing low sulfur fuels to standards that would necessitate flue gas treatment. The environmental, economic, and cost impacts of each option were analyzed. National impacts were estimated by a computer model that projects the population of new boilers over the 5-year period following proposal, predicts the compliance strategy that will be used to comply with the particular option (always assuming that the lowest cost method of compliance will be selected), and estimates the resulting emission reductions and costs. Impacts on specific industries and on model boilers were also analyzed. This paper focuses on these analyses and their results. The Agency's conclusions from these analyses, which led to the decision to establish percent reduction standards, are provided, and the proposed SO2 standards are summarized. The proposed standards also include an emission limit for particulate matter from oil-fired boilers (0.1 lb/MM Btu). However, this article focuses only on the SO2 standards.  相似文献   

7.
Contribution of pollution from different types of sources in Jamshedpur, the steel city of India, has been estimated in winter 1993 using two approaches in order to delineate and prioritize air quality management strategies for the development of region in an environmental friendly manner. The first approach mainly aims at preparation of a comprehensive emission inventory and estimation of spatial distribution of pollution loads in terms of SO2 and NO2 from different types of industrial, domestic and vehicular sources in the region. The results indicate that industrial sources account for 77% and 68% of the total emissions of SO2 and NO2, respectively, in the region, whereas vehicular emissions contributed to about 28% of the total NO2 emissions. In the second approach, contribution of these sources to ambient air quality levels to which the people are exposed to, was assessed through air pollution dispersion modelling. Ambient concentration levels of SO2 and NO2 have been predicted in winter season using the ISCST3 model. The analysis indicates that emissions from industrial sources are responsible for more than 50% of the total SO2 and NO2 concentration levels. Vehicular activities contributed to about 40% of NO2 pollution and domestic fuel combustion contributed to about 38% of SO2 pollution. Predicted 24-h concentrations were compared with measured concentrations at 11 ambient air monitoring stations and good agreement was noted between the two values. In-depth zone-wise analysis of the above indicates that for effective air quality management, industrial source emissions should be given highest priority, followed by vehicular and domestic sources in Jamshedpur region.  相似文献   

8.
Due to the dynamic nature of the atmosphere, substantial amounts of gaseous and particulate pollutants are transported to the areas distant from their sources. In order to determine the regional concentration levels of atmospheric pollutants in Lithuania, concentrations of gaseous O3, SO2, NO2 and other pollutants have been measured at the Preila background station (55°20′ N and 21°00′ E, 5 m a.s.l.) since 1981. The long-term concentration data set enabled us to get temporal trends, both on a seasonal and longer time scale, to identify source areas of pollutants and to relate them to the emission data. Based on the data obtained, the different tendencies in the pollutant concentration changes were revealed. Positive trends for ozone (of 2.9% per year during 1983–2000) and a distinct negative trend for both sulphur dioxide (of 3.8% per year during 1981–2000) and nitrogen dioxide (of 3.8% per year during 1983–2000) were found. The air mass back-trajectory analysis was used to assess the source region of air pollutants transported to Lithuania. The pollutant concentration levels were compared with their emission changes in Europe and Lithuania. The general trends in SO2 as well as in NO2 concentrations observed are consistent with changes in SO2 and NO2 emissions in Europe and Lithuania.  相似文献   

9.
A risk assessment of the potential impacts of sulphur dioxide (SO2) on the agriculture of central Chile was carried out, using Critical Levels (threshold values above which chronic effects may occur) set by the United Nations Economic Commission for Europe (UNECE, 1993; Sanders et al., 1995), crop sensitivity studies, agricultural land-use data, and air quality data for several years. Ambient SO2 concentrations around three copper smelters in this region were found to pose a significant risk to crops (such as cereals, staples and legumes) on both local and regional scales. Adverse effects on yield, growth and fruit production were considered possible. Frequent high exposure periods during winter months may also give rise to acute injury in sensitive species and/or crops maintained under optimum water conditions. This study identified high-risk areas, where additional monitoring as well as field studies would be beneficial, and has important policy implications, given the secondary SO2 air quality standard currently in force in Chile.  相似文献   

10.
In the present study, a modified approach was adopted to quantify the assimilative capacity (i.e., the maximum emission an area can take without violating the permissible pollutant standards) of a major industrial cluster (Manali, India) and to assess the effectiveness of adopted air pollution control measures at the region. Seasonal analysis of assimilative capacity was carried out corresponding to critical, high, medium, and low pollution levels to know the best and worst conditions for industrial operations. Bottom-up approach was employed to quantify sulfur dioxide (SO2), nitrogen dioxide (NO2), and particulate matter (aerodynamic diameter <10 μm; PM10) emissions at a fine spatial resolution of 500 × 500 m2 in Manali industrial cluster. AERMOD (American Meteorological Society/U.S. Environmental Protection Agency Regulatory Model), an U.S. Environmental Protection Agency (EPA) regulatory model, was used for estimating assimilative capacity. Results indicated that 22.8 tonnes/day of SO2, 7.8 tonnes/day of NO2, and 7.1 tonnes/day of PM10 were emitted from the industries of Manali. The estimated assimilative capacities for SO2, NO2, and PM10 were found to be 16.05, 17.36, and 19.78 tonnes/day, respectively. It was observed that the current SO2 emissions were exceeding the estimated safe load by 6.7 tonnes/day, whereas PM10 and NO2 were within the safe limits. Seasonal analysis of assimilative capacity showed that post-monsoon had the lowest load-carrying capacity, followed by winter, summer, and monsoon seasons, and the allowable SO2 emissions during post-monsoon and winter seasons were found to be 35% and 26% lower, respectively, when compared with monsoon season.

Implications: The authors present a modified approach for quantitative estimation of assimilative capacity of a critically polluted Indian industrial cluster. The authors developed a geo-coded fine-resolution PM10, NO2, and SO2 emission inventory for Manali industrial area and further quantitatively estimated its season-wise assimilative capacities corresponding to various pollution levels. This quantitative representation of assimilative capacity (in terms of emissions), when compared with routine qualitative representation, provides better data for quantifying carrying capacity of an area. This information helps policy makers and regulatory authorities to develop an effective mitigation plan for air pollution abatement.  相似文献   


11.
Previous analyses of continuously measured compounds in Fort McKay, an indigenous community in the Athabasca Oil Sands, have detected increasing concentrations of nitrogen dioxide (NO2) and total hydrocarbons (THC), but not of sulfur dioxide (SO2), ozone (O3), total reduced sulfur compounds (TRS), or particulate matter (aerodynamic diameter <2.5 μm; PM2.5). Yet the community frequently experiences odors, dust, and reduced air quality. The authors used Fort McKay’s continuously monitored air quality data (1998–2014) as a case study to assess techniques for air quality analysis that make no assumptions regarding type of change. Linear trend analysis detected increasing concentrations of higher percentiles of NO2, nitric oxide (NO), and nitrogen oxides (NOx), and THC. However, comparisons of all compounds between an early industrial expansion period (1998–2001) and current day (2011–2014) show that concentrations of NO2, SO2, THC, TRS, and PM2.5 have significantly increased, whereas concentrations of O3 are significantly lower. An assessment of the frequency and duration of periods when concentrations of each compound were above a variety of thresholds indicated that the frequency of air quality events is increasing for NO2 and THC. Assessment of change over time with odds ratios of the 25th, 50th, 75th, and 90th percentile concentrations for each compound compared with an estimate of natural background variability showed that concentrations of TRS, SO2, and THC are dynamic, higher than background, and changes are nonlinear and nonmonotonic. An assessment of concentrations as a function of wind direction showed a clear and generally increasing influence of industry on air quality. This work shows that evaluating air quality without assumptions of linearity reveals dynamic changes in air quality in Fort McKay, and that it is increasingly being affected by oil sands operations.

Implications: Understanding the nature and types of air quality changes occurring in a community or region is essential for the development of appropriate air quality management policies. Time-series trending of air quality data is a common tool for assessing air quality changes and is often used to assess the effectiveness of current emission management programs. The use of this tool, in the context of oil sands development, has significant limitations, and alternate air quality change analysis approaches need to be applied to ensure that the impact of this development on air quality is fully understood so that appropriate emission management actions can be taken.  相似文献   


12.
It is estimated that there is sufficient in-state “technically” recoverable biomass to support nearly 4000 MW of bioelectricity generation capacity. This study assesses the emissions of greenhouse gases and air pollutants and resulting air quality impacts of new and existing bioenergy capacity throughout the state of California, focusing on feedstocks and advanced technologies utilizing biomass resources predominant in each region. The options for bioresources include the production of bioelectricity and renewable natural gas (NG). Emissions of criteria pollutants and greenhouse gases are quantified for a set of scenarios that span the emission factors for power generation and the use of renewable natural gas for vehicle fueling. Emissions are input to the Community Multiscale Air Quality (CMAQ) model to predict regional and statewide temporal air quality impacts from the biopower scenarios. With current technology and at the emission levels of current installations, maximum bioelectricity production could increase nitrogen oxide (NOx) emissions by 10% in 2020, which would cause increases in ozone and particulate matter concentrations in large areas of California. Technology upgrades would achieve the lowest criteria pollutant emissions. Conversion of biomass to compressed NG (CNG) for vehicles would achieve comparable emission reductions of criteria pollutants and minimize emissions of greenhouse gases (GHG). Air quality modeling of biomass scenarios suggest that applying technological changes and emission controls would minimize the air quality impacts of bioelectricity generation. And a shift from bioelectricity production to CNG production for vehicles would reduce air quality impacts further. From a co-benefits standpoint, CNG production for vehicles appears to provide the best benefits in terms of GHG emissions and air quality.

Implications:?This investigation provides a consistent analysis of air quality impacts and greenhouse gas emissions for scenarios examining increased biomass use. Further work involving economic assessment, seasonal or annual emissions and air quality modeling, and potential exposure analysis would help inform policy makers and industry with respect to further development and direction of biomass policy and bioenergy technology alternatives needed to meet energy and environmental goals in California.  相似文献   

13.
The Indo-Gangetic plain (IGP) has received extensive attention of the global scientific community due to higher levels of trace gases and aerosols over this region. Satellite retrievals and model simulations show that, in particular, the eastern part IGP is highly polluted. Despite this attention, in situ measurements of trace gases are very limited over this region. This paper presents measurements of SO2, CO, CH4, and C2–C5 NMHCs during March 2012–February 2013 over Kolkata, a megacity in the eastern IGP, with a focus on processes impacting their levels. The mean SO2 and C2H6 concentrations during winter and post-monsoon periods were eight and three times higher compared to pre-monsoon and monsoon. Early morning enhancements in SO2 and several NMHCs during winter connote boundary layer effects. Daytime elevations in SO2 during pre-monsoon and monsoon suggest impacts of photo-oxidation. Inter-species correlations and trajectory analysis evince transport of SO2 from regional combustion sources (e.g., coal burning in power plants, industries) along the east of the Indo-Gangetic plain impacting SO2 levels at the site. However, C2H2 to CO ratio over Kolkata, which are comparable to other urban regions in India, show impacts of local biofuel combustions. Further, high levels of C3H8 and C4H10 evince the dominance of LPG/petrochemicals over the study location. The suite of trace gases measured during this study helps to decipher between impacts of local emissions and influence of transport on their levels.  相似文献   

14.
ABSTRACT

One of the major challenges facing the world today is defining paths to sustainable futures. Part of the challenge is developing a national energy strategy that promotes an adequate energy supply for the United States, while enhancing environmental quality and maintaining U.S. competitiveness in the world economy. To assist in this challenge, we have developed a screening technique to analyze the effectiveness of different proposed emissions reduction strategies. The technique, referred to as the visibility assessment screening technique (VAST), is designed to examine possible impacts on visibility of emission changes of sulfur oxides, nitrogen oxides, volatile organic compounds (i.e., SO2, NOx, and VOC) and fine and coarse particulate matter (PM). The influence of relative humidity, natural aerosols, and the chemical interconnections among sulfur and nitrogen components of aerosols in determining the effectiveness of Clean Air Act Amendment and other projected energy-related emissions changes on eastern and western visibility are explored.

The effectiveness of these strategies on particulate matter impacts and potentially on ozone is also noted.  相似文献   

15.
The impact of ship emissions on air quality in Alaska National Parks and Wilderness Areas was investigated using the Weather Research and Forecasting model inline coupled with chemistry (WRF/Chem). The visibility and deposition of atmospheric contaminants was analyzed for the length of the 2006 tourist season. WRF/Chem reproduced the meteorological situation well. It seems to have captured the temporal behavior of aerosol concentrations when compared with the few data available. Air quality follows certain predetermined patterns associated with local meteorological conditions and ship emissions. Ship emissions have maximum impacts in Prince William Sound where topography and decaying lows trap pollutants. Along sea-lanes and adjacent coastal areas, NOx, SO2, O3, PAN, HNO3, and PM2.5 increase up to 650 pptv, 325 pptv, 900 pptv, 18 pptv, 10 pptv, and 100 ng m?3. Some of these increases are significant (95% confidence). Enhanced particulate matter concentrations from ship emissions reduce visibility up to 30% in Prince William Sound and 5–25% along sea-lanes.  相似文献   

16.
Abstract

This paper analyzes the air quality impacts of coal-fired power plants in the northern passageway of the West-East Power Transmission Project in China. A three-layer Lagrangian model called ATMOS, was used to simulate the spatial distribution of incremental sulfur dioxide (SO2) and coarse particulate matter (PM10) concentrations under different emission control scenarios. In the year 2005, the emissions from planned power plants mainly affected the air quality of Shanxi, Shaanxi, the common boundary of Inner Mongolia and Shanxi, and the area around the boundary between Inner Mongolia and Ningxia. In these areas, the annually averaged incremental SO2 and PM10 concentrations exceed 2 and 2.5 µg/m3, respectively. The maximum increases of the annually averaged SO2 and PM10 concentrations are 8.3 and 7.2 µg/m3, respectively, which occur around Hancheng city, near the boundary of the Shaanxi and Shanxi provinces. After integrated control measures are considered, the maximum increases of annually averaged SO2 and PM10 concentrations fall to 4.9 and 4 µg/m3, respectively. In the year 2010, the areas affected by planned power plants are mainly North Shaanxi, North Ningxia, and Northwest Shanxi. The maximum increases of the annually averaged SO2 and PM10 concentrations are, respectively, 6.3 and 5.6 µg/m3, occurring in Northwest Shanxi, which decline to 4.4 and 4.1 µg/m3 after the control measures are implemented. The results showed that the proposed power plants mainly affect the air quality of the region where the power plants are built, with little impact on East China where the electricity will be used. The influences of planned power plants on air quality will be decreased greatly by implementing integrated control measures.  相似文献   

17.
We present measurements of several trace gases made at a subtropical coastal site in Hong Kong in October and November 1997. The gases include O3, CO, SO2, and NOx. The surface measurement data are compared with those from an aircraft study [Kok et al. J. Geophys. Res. 102 (D15) (1997) 19043–19057], and a subset of the latter is used to show the vertical distribution of the trace gases in the boundary layer. During the study period, averaged concentrations at the surface site for O3, CO, NOx, and SO2 were 50, 298, 2.75, and 1.65 ppbv, respectively. Their atmospheric abundance and diurnal pattern are similar to those found in the “polluted” rural areas in North America. The measured trace gases are fairly well mixed in the coastal boundary layer in the warm South China region. Large variability is indicated from the data. Examination of 10-day, isentropic back trajectories shows that the measured trace gases are influenced by maritime air masses, outflow of pollution-laden continental air, and the mixing of the two. The trajectories capture the contrasting chemical features of the large-scale air masses impacting on the study area. CO, NOx and SO2 all show higher concentrations in the strong outflow of continental air, as expected, than those in the marine category. Compared with previously reported values for the western Pacific, the much higher levels found in the marine trajectories in our study suggest the impacts of regional and/or sub-regional emissions on the measured trace gases at the study site. The presence of abundant O3 and other chemically active trace gases in the autumn season, coupled with high solar radiation and warm weather, suggests that the South China Sea is a photochemically active region important for studying the chemical transformation of pollutants emitted from the Asian continent.  相似文献   

18.
Title IV of the Clean Air Act Amendments of 1990 establishes a unique “market-based“ approach to reduce national electric utility sulfur dioxide (SO2) emissions during the next century by about 10 million tons/year below the corresponding level in 1980. This program is designed to provide utility operators with the flexibility to achieve the applicable SO2 emissions limitations (total tons) using the most cost-effective approach. However, in reality, it is unlikely that many utility operators would have such operational flexibility, especially in the case of plants located in the Western United States. This is due to the fact that these sources may also be subject to other more stringent provisions of the Act, such as to protect public health and visibility, which override the Title IV provisions.

This paper examines the Phase II allowance allocations for the utility units located in the 11 western states and assesses the potential impacts of the current federal/state air quality regulatory programs on the allowance market in the West. This analysis shows that, even after accounting for the projected population growth and the accompanying growth in electric power demand during the next decade, the West should have a surplus of allowances, especially if new regulations are initiated to further reduce SO2 emissions, mainly for the purpose of improving visibility in Western Class I areas.  相似文献   

19.
In 1995, Taiwan's Environmental Protection Administration (EPA/TW) instituted a policy of levying emission taxes on polluters in order to combat the rampant national issue of pollution. Since that time, pollution control strategies, tightening exhaust emission standards for industry, improvements in fuel quality, and new stricter vehicle emission standards, etc., have been implemented. This study evaluates the effectiveness of these measures and examines the improvement of Taiwan's air quality. In this paper, we conduct a detailed analysis of change in the concentrations of pollutants (SO2, NOx and particulate matter [PM]) between two three-year periods (from 1996 to1998 and from 2000 to 2002). The pollution levels were generally lower in the latter period. Concentrations at 14 EPA/TW stations in central Taiwan were simulated and source apportionment analyses in three of Central Taiwan's largest cities were conducted using a trajectory transfer-coefficient air quality model. Correlation coefficients (r) between simulations and observations for the monthly means of the concentrations of SO2, NOx, PM2.5 and PM10 during the study periods at the 14 stations are 0.56, 0.63, 0.70 and 0.31, respectively. The sulfur control policy greatly reduced SO2 concentration island-wide, a stringent emission standard put into place for gasoline vehicles reduced NOx concentration along highways, and an emissions tax placed on construction sites, as well as a regular program for road-dust sweeping, reduced primary particulate matter. Among all of the pollution abatement policies implemented, the most effective method for reducing PM2.5 concentrations in the three largest cities involved the reduction of fine ammonium sulfate aerosols from point sources (56–63% of net PM2.5 reduction). The next largest reduction was attributed to a diminishment in primary PM2.5 emanating from point sources (27–56% of net PM2.5 reduction). Secondary particulate matter, especially sulfate, was reduced from distances up to 150 km leeward of major pollution point sources such as Taichung Power Plant.  相似文献   

20.
Abstract

Visibility data collected from Kaohsiung City, Taiwan, for the past two decades indicated that the air pollutants have significantly degraded visibility in recent years. During our study period, the seasonal mean visibilities in spring, summer, fall, and winter were only 5.4, 9.1, 8.2, and 3.4 km, respectively. To ascertain how urban aerosols influence the visibility, we conducted concurrent visibility monitoring and aerosol sampling in 1999 to identify the principal causes of visibility impairments in the region. In this study, ambient aerosols were sampled and analyzed for 11 constituents, including water-soluble ions and carbon materials, to investigate the chemical composition of Kaohsiung aerosols. Stepwise regression method was used to correlate the impact of aerosol species on visibility impairments. Both seasonal and diurnal variation patterns were found from the monitoring of visibility. Our results showed that light scattering was attributed primarily to aerosols with sizes that range from 0.26 to 0.90 μm, corresponding with the wavelength region of visible light, which accounted for ~72% of the light scattering coefficient. Sulfate was a dominant component that affected both the light scattering coefficient and the visibility in the region. On average, (NH4)2SO4, NH4NO3, total carbon, and fine particulate matter (PM2.5)-remainder contributed 53%, 17%, 16%, and 14% to total light scattering, respectively. An empirical regression model of visibility based on sulfate, elemental carbon, and humidity was developed, and the comparison indicated that visibility in an urban area could be properly simulated by the equation derived herein.  相似文献   

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