酸性矿山废水的处理研究

本文简要分析了酸性矿山废水的主要污染物及危害，叙述了几种主要的处理技术：中和法、硫化沉淀浮选法、微生物法和人工湿地，并介绍了它们的机理、特点及实验研究和工业应用情况，由此对我国的酸性矿山废水的治理技术进行了前景展望。     

沉淀浮选法治理含重金属废水的研究

本文采用沉淀浮选法治理含重金属废水，找到了气浮活性好，来源广泛，价廉，几乎无毒的气浮剂ＡＳ；考察了沉淀浮选法的影响因素，确定了沉淀浮洗法治理含重金属废水的最佳工艺条件，处理实际废水的实验证明，沉淀浮洗法不仅能治理含重金属废水，还十分有效地回收了废水中的有价元素，总金属回收率达９９．２７％，且总金属富集比达１１３．５（倍），此外，还对气浮剂ＡＳ的作用机理进行了探讨，本研究结果对沉淀浮选法治理含重金属     

某金铜矿山含铜酸性废水处理研究

采用石灰调pH—铁屑置换—石灰沉淀处理工艺对废水进行试验，结果表明，采用该工艺处理含铜酸性矿山废水，不仅能使处理后的水满足排放标准，同时还能回收废水中的铜。     

凤眼莲用于废水净化

初步探讨了凤眼莲在净化废水方面的应用效果,结果表明凤眼莲除对生活污水具有较强的适应能力和净化能力外.在特殊处理后的钻井废水中,也能较正常生长、繁殖并起到一定的净化作用。本文还谈到了废水pH对凤眼莲的影响.对凤眼莲净化废水的机理也作了简述,指出用凤眼莲处理净化废水是一种经济有效的好方法。     

汽车磷化废水的处理研究及其应用

汽车磷化处理是对汽车的钢铁零件表面进行的一种化学加工工艺，其废水中含磷量高。采用石灰法处理磷化废水，在适当的pH值条件下能使PO4^3-达到良好的沉淀效果，而且石灰价格低廉，经济效益高；同时，通过研究氯化钙处理磷化废水的效果，分析和论证溶液的pH值和钙离子浓度对PO4^3-根沉淀效果的影响。     

矿山酸性废水治理技术及其发展趋势

矿山酸性废水在很多国家和地区都造成了严重的环境污染。本文分析矿山酸性废水的成因、特点及危害,并总结了中和法、硫化法和微生物法等经济、实用的酸性矿山废水处理技术现状,并进一步阐述了酸性矿山废水治理技术的发展趋势。     

金属废水溶液的中和沉淀净化理论分析

含有害金属废水溶液的中和沉淀净化过程受诸多因素的影响,其中,最重要的有溶液中金属的价态和形态,溶液的离子强度,沉淀物的组成,结构和表面效应等,本文对上述问题作了较全面的理论分析。     

焦化废水处理技术研究进展

焦化废水主要来自炼焦和煤气净化过程产生的废水，含有难降解的有机化合物。目前，焦化废水一般按常规方法先进行预处理，然后进行生物脱酚二次处理。近年来，国内外学者开展了大量的研究工作，找到了许多比较有效的焦化废水治理技术，主要有生物处理法、化学处理法、物理化学处理法和废水循环利用。     

石油开采含油废水处理技术的探讨

油田开发生产过程中产生和排放的含油废水含有多种污染物，对生态环境造成严重污染。对油田含油废水应用三段法治理工艺，混凝、沉淀、过滤综合处理油田含油废水，处理后的水质达到回注水水质要求，全部回注，研究探讨了高矿化度含油废水的治理。     

浅析PCB废水中络合态铜的处理方法

在PCB废水中,铜是主要的重金属污染物。Cu^2＋可通过加碱沉淀法完全沉淀下来,而废水中含有的络合态铜往往是造成出水总铜不能达标排放的重要因素。本文对络合态铜的各种处理方法如：化学沉淀法、氧化还原法、生物法等作了简要介绍和分析。     

SX-EW copper and the technology cycle

Technology is viewed to advance through a series of cycles, starting with the emergence of a major breakthrough, followed by a period of ferment as alternate designs and improvements rapidly appear, leading to a dominant design, and then a long plateau period of minor incremental change. In this paper, the technology cycle model is applied to the history of solvent extraction electrowinning (SX-EW) processing of copper ore, which, along with other innovations, has transformed the US copper mining industry. The general framework of the technology cycle model holds, although there are differences relating to the specific nature of SX-EW processing.One particularly interesting difference is that SX-EW initially was complementary to the original method of ore processing, known as flotation. Only in recent years has it directly challenged flotation in the processing of supergene or transitional ore. In addition, the analysis shows that the SX-EW process helped the US producers maintain their competitiveness for at least a decade before the process was widely adopted by their main competitors, the Chilean producers. This raises questions about the widely held assumption that research and development of new innovations can provide firms and countries with little or no competitive advantage because new technologies diffuse very rapidly in today’s global economy.     

The Environmental sustainability of mining in Australia: key mega-trends and looming constraints

At first ‘sustainable mining’ could be perceived as a paradox—minerals are widely held to be finite resources with rising consumption causing pressure on known resources. The true sustainability of mineral resources, however, is a much more complex picture and involves exploration, technology, economics, social and environmental issues, and advancing scientific knowledge—predicting future sustainability is therefore not a simple task. This paper presents the results from a landmark study on historical trends in Australian mining, including ore milled, ore grades, open cut versus underground mining, overburden/waste rock and economic resources. When complete data sets are compiled for specific metals, particular issues stand out with respect to sustainability—technological breakthroughs (e.g. flotation, carbon-in-pulp), new discoveries (e.g. uranium or U), price changes (e.g. Au, boom/bust cycles), social issues (e.g. strikes), etc. All of these issues are of prime importance in moving towards a semi-quantitative sustainability model of mineral resources and the mining industry. For the future, critical issues will continue to be declining ore grades (also ore quality and impurities), increased waste rock and associated liabilities, known economic resources, potential breakthrough technologies, and broader environmental constraints (e.g. carbon costs, water). For this latter area, many companies now report annually on sustainability performance—facilitating analysis of environmental sustainability with respect to production performance. By linking these two commonly disparate aspects—mining production and environmental/sustainability data—it becomes possible to better understand environmental sustainability and predict future constraints such as water requirements, greenhouse emissions, energy and reagent inputs, and the like. This paper will therefore present a range of fundamental data and issues which help towards quantifying the resource and environmental sustainability of mining—with critical implications for the mining industry and society as a whole.     

Visualizing bromide and iodide water tracer in soil profiles by spray methods

In this study we developed and tested a spray method to visualize bromide water tracer in soil profiles. The method is based on the transformation reaction of a white precipitate into a colored one (Prussian blue) in the presence of Br-. After application of water containing bromide (0.2-0.4% wt.), a soil profile is dug out from the irrigated area and sprayed with a Br- indication suspension containing ferric ion and silver ferrocyanide precipitate. About two hours later, the pattern of irrigation water movement in the soil profile appears due to the formation of Prussian blue complex. We describe the method and demonstrate its use in a field experiment to visualize water flow paths. Since this method might be subject to possible interference from Cl-, a newly designed method with iodide ion as a water tracer and its indication solution containing soluble starch and ferric ion is also presented and recommended for use in soils with high chloride background.     

化学药剂对吸入式气浮净化机除油浮选动力学的影响

本研究在实验室装置上着重考察了化学药剂对吸入式气浮净化机除油浮选动力学的影响。研究结果表明化学药剂对浮选速率常数有明显影响,不同化学药剂及用量其影响效果不同。     

LIGNIN SEPARATION BY CONTINUOUS ION FLOTATION: INVESTIGATION OF PHYSICAL OPERATIONAL PARAMETERS1

ABSTRACT: Ion flotation is the term used to describe a process in which there is an initally homogeneous solution which becomes heterogeneous after the addition of an oppositely charged surfactant due to the reaction between the surfactant and specific ion(s); thus, insoluble complexes are formed. These insoluble complexes will then attached to the bubbles passing through the solution and thus leave in the foam phase. The performance of the continuous ion flotation process for the removal of haft lignin from water was investigated intensively using liquid flow rates, gas flow rates, feed locations and solution height as operational variables. The interrelationships among these physical parameters were studied and discussed. A dimensionless operational chart was established for process control. Results demonstrate that ion flotation is an effective process for removing lignin from water, provided that a quaternary ammonium salt, such as cetyldimethylbenzyl-ammonium chloride or the like, is used as a collector. At optimum operational conditions, higher than 0.95 fractional removal of lignin can be achieved.     

高矿化度油田采出水危害性分析

长庆油田学一联合站油田采出水经三级处理后,出水水质达到低渗透、特低渗透油田回注指标,但不久水质变浑浊,并伴有大量的红棕色沉淀物生成。取样分析,红棕色沉淀物为氢氧化铁,水中pH值为6.0～6.5,铁含量在50～100mg/L。文章针对含铁量过高为主的高矿化度油田采出水可能带来的危害进行分析,并提出解决方法。     

Leaching characteristics of copper flotation waste before and after vitrification

Copper flotation waste from copper production using a pyrometallurgical process contains toxic metals such as Cu, Zn, Co and Pb. Because of the presence of trace amounts of these highly toxic metals, copper flotation waste contributes to environmental pollution. In this study, the leaching characteristics of copper flotation waste from the Black Sea Copper Works in Samsun, Turkey have been investigated before and after vitrification. Samples obtained from the factory were subjected to toxicity tests such as the extraction procedure toxicity test (EP Tox), the toxicity characteristic leaching procedure (TCLP) and the "method A" extraction procedure of the American Society of Testing and Materials. The leaching tests showed that the content of some elements in the waste before vitrification exceed the regulatory limits and cannot be disposed of in the present form. Therefore, a stabilization or inertization treatment is necessary prior to disposal. Vitrification was found to stabilize heavy metals in the copper flotation waste successfully and leaching of these metals was largely reduced. Therefore, vitrification can be an acceptable method for disposal of copper flotation waste.     

Acid-base accounting to predict post-mining drainage quality on surface mines

Acid-base accounting (ABA) is an analytical procedure that provides values to help assess the acid-producing and acid-neutralizing potential of overburden rocks prior to coal mining and other large-scale excavations. This procedure was developed by West Virginia University scientists during the 1960s. After the passage of laws requiring an assessment of surface mining on water quality, ABA became a preferred method to predict post-mining water quality, and permitting decisions for surface mines are largely based on the values determined by ABA. To predict the post-mining water quality, the amount of acid-producing rock is compared with the amount of acid-neutralizing rock, and a prediction of the water quality at the site (whether acid or alkaline) is obtained. We gathered geologic and geographic data for 56 mined sites in West Virginia, which allowed us to estimate total overburden amounts, and values were determined for maximum potential acidity (MPA), neutralization potential (NP), net neutralization potential (NNP), and NP to MPA ratios for each site based on ABA. These values were correlated to post-mining water quality from springs or seeps on the mined property. Overburden mass was determined by three methods, with the method used by Pennsylvania researchers showing the most accurate results for overburden mass. A poor relationship existed between MPA and post-mining water quality, NP was intermediate, and NNP and the NP to MPA ratio showed the best prediction accuracy. In this study, NNP and the NP to MPA ratio gave identical water quality prediction results. Therefore, with NP to MPA ratios, values were separated into categories: <1 should produce acid drainage, between 1 and 2 can produce either acid or alkaline water conditions, and >2 should produce alkaline water. On our 56 surface mined sites, NP to MPA ratios varied from 0.1 to 31, and six sites (11%) did not fit the expected pattern using this category approach. Two sites with ratios <1 did not produce acid drainage as predicted (the drainage was neutral), and four sites with a ratio >2 produced acid drainage when they should not have. These latter four sites were either mined very slowly, had nonrepresentative ABA data, received water from an adjacent underground mine, or had a surface mining practice that degraded the water. In general, an NP to MPA ratio of <1 produced mostly acid drainage sites, between 1 and 2 produced mostly alkaline drainage sites, while NP to MPA ratios >2 produced alkaline drainage with a few exceptions. Using these values, ABA is a good tool to assess overburden quality before surface mining and to predict post-mining drainage quality after mining. The interpretation from ABA values was correct in 50 out of 52 cases (96%), excluding the four anomalous sites, which had acid water for reasons other than overburden quality.     

孤岛油区外排采油污水生化处理技术的研究

针对孤岛污水矿化度高,Cl-含量高,油含量和COD含量严重超标的现象,采取微生物接触氧化工艺进行外排采油污水治理的工艺研究。在处理过程中首先对菌种进行了严格的筛选和培养,然后在室内进行了模拟试验,最后在现场进行了中试。目前已根据中试结果,对孤岛污水原有的污水池进行了改造,设置了隔油池、气浮池、接触氧化池和沉淀池四个部分,经过一年的运行,成功地实现了污水的达标排放。