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1.
Previous research in our laboratory reported a convenient laboratory-scale composting test method to study the weight loss of polymer films in aerobic thermophilic (53°C) reactors maintained at a 60% moisture content. The laboratory-scale compost reactors contained the following synthetic compost mixture (percentage on dry-weight basis): tree leaves (45.0), shredded paper (16.5), food (6.7), meat (5.8), cow manure (17.5), sawdust (1.9), aluminum and steel shavings (2.4), glass beads (1.3), urea (1.9), and a compost seed (1.0) which is designated Mix-1 in this work. To simplify the laboratory-scale compost weight loss test method and better understand how compost mixture compositions and environmental parameters affect the rate of plastic degradation, a systematic variation of the synthetic mixture composition as well as the moisture content was carried out. Cellulose acetate (CA) with a degree of substitution (DS) value of 1.7 and cellophane films were chosen as test polymer substrates for this work. The extent of CA DS-1.7 and cellophane weight loss as a function of the exposure time remained unchanged when the metal and glass components of the mixture were excluded in Mix-2. Further study showed that large variations in the mixture composition such as the replacement of tree leaves, food, meat, and sawdust with steam-exploded wood and alfalfa (forming Mix-C) could be made with little or no change in the time dependence of CA DS-1.7 film weight loss. In contrast, substituting tree leaves, food, meat, cow manure, and sawdust with steam-exploded wood in combination with either Rabbit Choice (Mix-D) or starch and urea (Mix-E) resulted in a significant time increase (from 7 to 12 days) for the complete disappearance of CA DS-1.7 films. Interestingly, in this work no direct correlation was observed between the C/N ratio (which ranged from 13.9 to 61.4) and the CA DS-1.7 film weight loss. Decreasing moisture contents of the compost Mix-2 from 60 and 50 and 40% resulted in dramatic changes in polymer degradation such that CA DS-1.7 showed an increase in the time period for a complete disappearance of polymer films from 6 to 16 and 30 days, respectively.Guest Editor: Dr. Graham Swift, Rohm & Haas.Paper presented at the Bio/Environmentally Degradable Polymer Society—Second National Meeting, August 19–21, 1993, Chicago, Illinois.  相似文献   

2.
Bioreactor landfills are designed to accelerate municipal solid waste biodegradation and stabilization; however, the uncaptured methane gas escapes to the atmosphere during their filling. This research investigates the implementation of a novel methane emission control technique that involves thin biocovers (TBC) placed as intermediate waste covers to oxidize methane without affecting the operation of bioreactor landfills. Batch incubation experiments were conducted for selecting the optimum TBC materials, capable of oxidizing methane to carbon dioxide by methanotrophic bacteria. Column experiments were performed to investigate the TBC performance under varying moisture content, compost-to-sawdust ratio, methane flow rate, and biocover thickness. Overall, the optimum TBC is comprised of a 30-cm thick bed of 0-10mass% sawdust mixed with compost, having a moisture content of 52% ww, which showed 100% CH4 oxidation efficiency over an extended period of time even at a relatively high methane inlet load of 9.4gm(-3)h(-1).  相似文献   

3.
Characterization of food waste and bulking agents for composting   总被引:1,自引:0,他引:1  
The characterization of food waste (FW) and locally available bulking agents (BA) are a prerequisite to optimizing compost recipes. This study measured the variation in FW characteristics (pH, dry matter (DM), carbon (C), wet bulk density and Total Kjeldahl Nitrogen (TKN)) produced by a restaurant and a community kitchen in downtown Montreal, Canada from May to August 2004. The project also measured the mass of FW produced by another restaurant and a group of 20-48 households, from June to August 2004. Locally available BA (hay, straw, pine wood shavings, cardboard, left over cattle feed and wheat residue pellets) were also characterized to formulate composting recipes based on the FW characteristics observed during a period representative of winter and summer conditions. Residential and restaurant FW characteristics varied significantly over the summer months, although the mass produced remained constant at 0.61 and 0.56 kg capita(-1)day(-1), respectively. In addition, the number of customers served by the restaurant increased by nearly 50% from June to August. The BA with the highest moisture adsorption capacity was found to be the wheat residue pellets, followed by chopped straw. Wheat residue pellets, chopped hay and left over cattle feed all presented a balanced C/N ratio. Wheat residue pellets and wheat straw, chopped hay and cardboard demonstrated neutral pH values. Based on the variable FW characteristics and monthly production rates, the formulation of recipes indicates that compost facilities must be flexible enough to handle seasonal variations of as much as 50% by volume.  相似文献   

4.
Moisture affects the physical and biological properties of compost and other solid-state fermentation matrices. Aerobic microbial systems experience different respiration rates (oxygen uptake and CO2 evolution) as a function of moisture content and material type. In this study the microbial respiration rates of 12 mortality composting envelope materials were measured by a pressure sensor method at six different moisture levels. A wide range of respiration (1.6-94.2mg O2/g VS-day) rates were observed for different materials, with alfalfa hay, silage, oat straw, and turkey litter having the highest values. These four envelope materials may be particularly suitable for improving internal temperature and pathogen destruction rates for disease-related mortality composting. Optimum moisture content was determined based on measurements across a range that spans the maximum respiration rate. The optimum moisture content of each material was observed near water holding capacity, which ranged from near 60% to over 80% on a wet basis for all materials except a highly stabilized soil compost blend (optimum around 25% w.b.). The implications of the results for moisture management and process control strategies during mortality composting are discussed.  相似文献   

5.
Over a period of 21 months, we composted food refuse from a student restaurant in Hokkaido University using a commercially available composting machine. The machine had two reactors, each with a working volume of 250 l. The refuse was mixed with sawdust in a ratio of 5 l sawdust to 10 kg refuse, and this mixture was fed into the machine daily. We studied the characteristics of the refuse, the composting mixture, and the finished compost in an effort to optimize the operating parameters. We also evaluated the effectiveness of the composting process by determining the decomposition rates of the composting materials. The optimum moisture content of the composting mixture was between 30% wet basis (wb) and 40% wb in this machine. The composting machine worked well when the first reactor was filled with composting mixture and 0.5 kg lime was added once per week. The mass of the materials supplied was reduced by 84% over the study period. The decomposition rate of the volatile matter in all composting materials was 66%. The mass of the food refuse supplied was 14.8 kg/day on average, and the moisture content of the refuse was 77% wb on average. Received: October 4, 1999 / Accepted: April 4, 2000  相似文献   

6.
Information pertaining to biodegradability of renewable polymeric material is critical for the design and development of single-use biodegradable consumer products. The rate and extent of biodegradation of corn fiber, corn zein, cornstarch, distillers grain, and corn gluten meal were evaluated in compost environments under variable temperature, pH, and moisture conditions. Generally, composts with higher temperature (40°C), neutral pH (7.0), and 50%–60% moisture appeared to be ideal for corn coproduct biodegradation, particularly for corn gluten meal and corn zein. Low moisture conditions slowed biodegradation considerably, but degradation rates improved when moisture content increased up to 60%. Thereafter, increased moisture particularly slowed the degradation of corn gluten meal and corn zein, whereas cornstarch degradation remained unaffected. At low pH (4.0) and high pH (11.0) the rate of degradation of most coproducts was slowed somewhat. Cornstarch degradation was slower at pH 7.0, but degradation improved with increased temperatures. Increase in compost temperature from 25 to 40°C (in 5°C increments) also improved biodegradation of corn fiber and distillers grain. Addition of 1% urea to compost as a nitrogen source decreased the extent of biodegradation nearly 40% for corn gluten meal and corn zein, and 20% for cornstarch samples. Treatment of compost with 0.02% azide inhibited biodegradation of all coproducts, suggesting that the presence of metabolically active microbial cells is required for effective degradation of biobased materials in a compost environment.  相似文献   

7.
Effectiveness of three bulking agents for food waste composting   总被引:3,自引:0,他引:3  
Rather than landfilling, composting the organic fraction of municipal solid wastes recycles the waste as a safe and nutrient enriched soil amendment, reduces emissions of greenhouse gases and generates less leachate. The objective of this project was to investigate the composting effectiveness of three bulking agents, namely chopped wheat (Triticum) straw, chopped mature hay consisting of 80% timothy (milium) and 20% clover (triphullum) and pine (pinus) wood shavings. These bulking agents were each mixed in duplicates at three different ratios with food waste (FW) and composted for 10 days using prototype in-vessel composters to observe their temperature and pH trends. Then, each mixture was matured in vertical barrels for 56 days to measure their mass loss and final nutrient content and to visually evaluate their level of decomposition. Chopped wheat straw (CWS) and chopped hay (CH) were the only two formulas that reached thermophilic temperatures during the 10 days of active composting when mixed with FW at a wet mass ratio of 8.9 and 8.6:1 (FW:CWS and FW:CH), respectively. After 56 days of maturation, these two formulas were well decomposed with no or very few recognizable substrate particles, and offered a final TN exceeding the original. Wood shavings (WS) produced the least decomposed compost at maturation, with wood particles still visible in the final product, and with a TN lower than the initial. Nevertheless, all bulking agents produced compost with an organic matter, TN, TP and TK content suitable for use as soil amendment.  相似文献   

8.
The objective of this study was to evaluate a variety of maturity indices and heavy metal concentrations in the composting process. A full-scale study was performed on animal manures (dairy:beef:swine = 50%:30%:20%, w/w) mixed with sawdust using a self-screwed turner over a time period of 63 days. Several chemical compost characteristics and germination indices were monitored on samples collected weekly at a prototype composting facility. NH(4)-N concentrations decreased during the composting time, on the contrary NO(3)-N concentrations increased sharply after 30 days. As composting proceeded, the humic acids content increased from 1.45% to 2.70% of the organic carbon content, whereas the fulvic acids content decreased gradually. Temperature in the compost pile and concentration of NH(3) averaged 32.4 degrees C and 12.9 ppm at the initial composting phase and 69.5 degrees C and 47.3 ppm at the active bio-oxidation composting phase, respectively. Seed germination and germination index (GI) increased during the composting process, and the compost samples at the end of composting phase had GI values greater than 120. Among the composting processes, there were significant differences (p<0.05) in concentration of Zn, Cu and Pb in the compost. In conclusion, the suggested maturity parameter values and metal concentrations of composted animal manures can provide better understanding of maturation process of animal manure compost.  相似文献   

9.
Combustion studies of high moisture content waste in a fluidised bed   总被引:1,自引:0,他引:1  
The combustion of three high moisture content waste materials in a fluidised bed combustor has been investigated and a comparison with co-firing of these materials with coal in the same combustor has been made. Waste materials burnt were olive oil waste, municipal solid waste and potato, which is representative of vegetable waste. Mixtures of up to 20% mass concentration water in the waste were fed to the combustor. Above that value the moisture content was too high to sustain combustion without addition of coal. Measurements of CO, NOx, SO2 temperatures were made and the carbon combustion efficiency evaluated. Co-firing with coal resulted in markedly higher combustion efficiencies with an increase of approximately 10-80% when burning the simulated MSW. However, this was much lower than the value of 93% when coal was burnt on its own. It was also much lower than the value obtained, average 90%, when co-firing potato and olive oil waste with coal and there was little difference in the combustion efficiency between the two types of waste and with increasing moisture content. It was concluded that the high ash content of the simulated MSW 26%, compared with 5% in the other two waste materials resulted in slower burning and consequently the char particles were elutriated from the bed without being fully burnt. In term of gaseous emissions during co-combustion, CO emission is relatively insensitive to change in waste fraction. While emission of SO2 can be reduced as the waste fraction increases as a result of fuel-S dilution. But in terms of percent fuel-S converted, it is actually increased by increasing waste fraction. Emissions of NO and N2O increase slightly with MSW fraction.  相似文献   

10.
In this study, a Poly(vinyl alcohol)(PVA)/compost composite bead is prepared and is indicated suitable as a filter material for biofiltration. The optimal preparation process is with the compost size of 16–35 mesh, the ratio of water to compost of 40 g/15 g compost, and the immersion time in the phosphate solution of 60 min. The composite bead prepared by this process is a porous spherical particle with a diameter between 2.4 and 6.0 mm and a density of 0.96 g/cm3. It contains 9.43 mg P/g dry solid and 12.1 mg N/g dry solid. The equilibrium moisture content of the composite bead bed from adsorption and holding experiments is 50.5 and 54.6% on a wet basis respectively, which is about 1.74 times higher than that of swine manure compost bed. It corresponds to the optimal filter material required and is sufficient to sustain biological activity as the composite bead adsorbs equilibrium moisture. The bulk compressive strength of the composite bead bed is about 1.15 times larger than that of swine manure compost bed to ensure even distribution of air flow and reduce the head loss as the air flow stream passed through. The pH value of the filter bed could maintain in the 6.9–7.2 range during the operation period due to the composite bead has the phosphate buffer capacity. The percentage of ethyl acetate removal could remain at over 99% for 40 days operation while the composite beads adsorbed inorganic nitrate nutrients. The pressure drop of two kind composite beads and pig manure compost filter beds are 0 and 2 mm H2O, respectively, after operating for 40 days.  相似文献   

11.
In this paper, a mechanical filtering system to treat pig slurry is proposed. The filter was made from the aerobic decomposition product of the organic fraction of municipal wastes and wheat straw was used as the support.Using a pilot plant to treat 2100 liters of swine slurry, an adequate reduction in BOD5; COD, and other parameters was obtained. The organic matter content of the material trapped in the filter was similar to that of compost and farmyard manure, but the nitrogen and phosphorous levels and the C/N ratio were more similar to farmyard manure. After passing through a filtering system, the treated liquid can be used for fertirrigation and as a feed for algae ponds. After a period of stabilization, the solid material can be mixed to produce manure. Although wheat straw was used as the support in this experiment, other agricultural wastes such as rice straw, corn stalks, millet stems, banana, cotton, and coconut trash can be used. Rather than municipal solid waste compost, other kinds of compost obtained from agricultural wastes such as leaves, bark, husks, etc., can be used as the filter.  相似文献   

12.
A laboratory-scale bioreactor was used to investigate the influence of dairy manure addition (as an inoculum and a carbon source) on the biological and thermal kinetics of the composting process of tomato plant residues-wood shavings mixture. Urea was added (as a nitrogen source) to correct the initial C:N ratio to 30:1 and the initial moisture content was also adjusted to 60%. The result of this study indicated that manure addition to the tomato residues-wood shavings mixture is a good source of macro and micronutrients required for supporting the composting microorganisms. Manure addition increased the rate of temperature increase and the duration of maximum temperature and reduced the lag and the peak time, all of which resulted in a significant reduction in the retention time. However, thermophilic temperature (> or = 40 degrees Celsius) was only achieved with 30%, 40% and 50% manure addition for 3, 7 and 9h. Total carbon reductions were in the range of 9.4-10.8% and TKN reductions were in the range of 3.4-6.0%. Neither the nitrogen nor the moisture content were limiting factors as the C:N ratio remained in the range of 26:1 to 28:1 and the moisture content remained within the optimum range of 58-61%. The maximum temperature of each mixture correlated with the reduction of total carbon, but carbon availability was a limiting factor in these experiments. In order to attain and sustain a thermophilic phase during the composting process, the addition of a readily available carbon source to the tomato should be investigated and carbon type (carbohydrates, proteins and fats) should be taken into account.  相似文献   

13.
Landfill aeration by means of low pressure air injection is a promising tool to reduce long term emissions from organic waste fractions through accelerated biological stabilization. Top covers that enhance methane oxidation could provide a simple and economic way to mitigate residual greenhouse gas emissions from in situ aerated landfills, and may replace off-gas extraction and treatment, particularly at smaller and older sites. In this respect the installation of a landfill cover system adjusted to the forced-aerated landfill body is of great significance. Investigations into large scale lysimeters (2 × 2 × 3 m) under field conditions have been carried out using different top covers including compost materials and natural soils as a surrogate to gas extraction during active low pressure aeration. In the present study, the emission behaviour as well as the water balance performance of the lysimeters has been investigated, both prior to and during the first months of in situ aeration. Results reveal that mature sewage sludge compost (SSC) placed in one lysimeter exhibits in principle optimal ambient conditions for methanotrophic bacteria to enhance methane oxidation. Under laboratory conditions the mature compost mitigated CH4 loadings up to 300 l CH4/m2 d. In addition, the compost material provided high air permeability even at 100% water holding capacity (WHC). In contrast, the more cohesive, mineral soil cover was expected to cause a notably uniform distribution of the injected air within the waste layer. Laboratory results also revealed sufficient air permeability of the soil materials (TS-F and SS-Z) placed in lysimeter C. However, at higher compaction density SS-Z became impermeable at 100% WHC.Methane emissions from the reference lysimeter with the smaller substrate cover (12–52 g CH4/m2 d) were significantly higher than fluxes from the other lysimeters (0–19 g CH4/m2 d) during in situ aeration. Regarding water balance, lysimeters covered with compost and compost-sand mixture, showed the lowest leachate rate (18–26% of the precipitation) due to the high water holding capacity and more favourable plant growth conditions compared to the lysimeters with mineral, more cohesive, soil covers (27–45% of the precipitation).On the basis of these results, the authors suggest a layered top cover system using both compost material as well as mineral soil in order to support active low-pressure aeration. Conventional soil materials with lower permeability may be used on top of the landfill body for a more uniform aeration of the waste due to an increased resistance to vertical gas flow. A compost cover may be built on top of the soil cover underlain by a gas distribution layer to improve methane oxidation rates and minimise water infiltration. By planting vegetation with a high transpiration rate, the leachate amount emanating from the landfill could be further minimised. The suggested design may be particularly suitable in combination with intermittent in situ aeration, in the later stage of an aeration measure, or at very small sites and shallow deposits. The top cover system could further regulate water infiltration into the landfill and mitigate residual CH4 emissions, even beyond the time of active aeration.  相似文献   

14.
Carrageenan-based films demonstrate good performance, the raw materials for their production are abundant in nature and can be sustainably sourced from seaweeds. Similar to other naturally-derived biopolymers, however, carrageenans are relatively expensive to purify and form into useful materials. In order to potentially lower the production costs compared to pure carrageenan, semi-refined carrageenan (SRC) plasticized with 0–50% (w/w) glycerol was investigated using a solution casting method. The film color and opacity increased along with the moisture content, whereas the water vapor permeability decreased with increasing levels of glycerol. The tensile properties of the SRC films improved significantly, particularly at glycerol additions greater than 30% (w/w). Moreover, the addition of glycerol improved the thermal stability and altered the surface morphology of the films. In general, the properties of the SRC films were comparable with refined carrageenan films suggesting that SRC has potential to be furthered developed into more cost effective primary food packaging materials.  相似文献   

15.
Waste gas containing monomethylamine (MMA) was treated in a biofilter packed with compost along with wood chips and enriched with Pseudomonas mendocina. The biofilter could remove MMA to the extent of more than 99% at a loading of 42.36 gm(-3)h(-1) with an empty bed retention time of 12s. At optimal operating conditions, the moisture content in the biofilter was maintained at around 45%. The biodegradative products of MMA were ammonia, nitrite, and nitrate.  相似文献   

16.
Development of a cheap system for reuse of glycerol by-product discharged from the biodiesel fuel (BDF) production process is needed in parallel with development of a low-cost BDF production system. In this article, optimization of compost fermentation of glycerol by-product was studied. The type and amount of additive nitrogen source was studied, and good utilization of glycerol was observed when 0.5 g of urea was added to a mixture of 625 g dry sawdust, 25 g of microbial seed, and 50 g of glycerol by-product. To achieve efficient compost fermentation, repeated batch fermentation was applied and five batch cultures were repeated. Although the pH level and nitrogen and water contents were maintained at suitable levels for microbial growth, the glycerol consumption rate gradually decreased with accumulation of oily compounds in the compost. Finally, a material cost evaluation of the compost fermentation proposed in this study was performed. The total material cost decreased to ¥0.57 /l of BDF when employing an existing compost system for the fermentation process, although sawdust used for mushroom cultivation was used in this study at the very high cost of ¥123 /kg dry sawdust. However, the cost of disposal of the glycerol byproduct as an industrial waste was ¥5.2 /l of BDF produced; therefore, there might be an economical advantage to compost fermentation of glycerol by-product from BDF production.  相似文献   

17.
Compost air permeability controls air flow through compost during composting or when using compost as biofilter material. Air permeability is therefore an important characteristic of compost. The relationships between air permeability (k(a)) in compost and compost dry bulk density (rho b), gravimetric water content (omega), and volumetric air content (epsilon) was investigated for two types of composts. The composts used were produced from a digested sewage sludge-straw mixture and from garden waste and measurements were conducted on sieved and repacked 100 cm3 compost samples. Results showed a linear relation between log(k(a)) and rho b at constant values of omega for both composts, indicating an exponential relationship between k(a) and rho b. The slopes of these relationships generally became more negative with increasing rho b. The results further showed a linear relationship between log(k(a)) and log(epsilon) for both composts as also often observed for soils. It was observed that the log(k(a)) and log(epsilon) relationships for the garden waste compost all intercepted at the same location despite having very different slopes. This means that it is possible to predict the entire k(a)-epsilon relationship using only one measurement of corresponding (k(a), epsilon) for garden waste. It was not possible to determine whether this was also the case for the sewage sludge compost due to difficulties in sample preparation at low and high water content.  相似文献   

18.
In the first part of this work, the effect of municipal organic waste (MOW) composts on plant growth was evaluated in a greenhouse trial. The treatments included soil amended with 14 different composts (prepared by shredding, adding wood shavings, cocomposting with biosolids or vermicomposting), an inorganically fertilized soil, and a control soil. All of the treatments significantly increased plant growth compared to the control, and yields of three of the amended treatments were as high as that of the inorganic fertilizer treatment. When comparing differently prepared composts to the conventional compost, it was found that cocomposting MOW with biosolids was the method which most positively influenced yields (26-41% yield increases). In the second part of this work, we evaluated the effects of the different preparation methods on compost quality, using a multivariate approach. Three main quality aspects were considered collectively in a principal component analysis: organic matter and nutrient concentrations, degradability and capacity to mineralize these nutrients, and plant growth. The model was restricted to the first and second components (PC1 and PC1) which accounted for 94% of data variance. On the resulting factorial plane, four groups were distinguished. Each of the groups was compared to the reference compost to determine quality increases or decreases. Based on this analysis, it was found that cocomposting MOW with biosolids produced the highest quality products (higher total nutrient and OM concentration, nutrient mineralization potential, and plant growth). Addition of wood shavings increased OM concentration, but reduced quality in terms of the other aspects studied. Shredding was only effective to increase product quality when it was not combined with other methods, whereas vermicomposting only increased quality when MOW was not mixed with biosolids.  相似文献   

19.
Poultry litter from broilers and turkeys are a mixture of manure, feathers, feed and wood shavings, thus pyrolysis oils produced from this material are influenced by the individual components. In order to determine the influence of wood shavings that are used as bedding material, we investigated the pyrolysis of pine wood shavings and poultry manure. Because manure from layer chickens are usually not contaminated with wood shavings, we made mixtures of layer manure and pine wood shavings in the following manure to wood ratios, 100:0, 75:25, 50:50, 25:75, and 0:100 w/w and pyrolyzed them in a fluidized bed reactor at 450 °C. The total liquid yield ranged from 43.3 to 62.7 wt.%. The layer manure oil had a HHV of 29.7 MJ/kg and pH of 5.89 compared to pine wood oil which had HHV of 25.6 MJ/kg and pH of 3.04. The addition of wood shavings to manure clearly influenced the physical properties of the oil, resulting in a decrease in pH and HHV and an increase in density. The oils had relatively high nitrogen content ranging from 1.36 to 5.88 wt.%. The ash (<0.07 wt.%) and sulfur (<0.28 wt.%) contents were very low. FTIR, 13C NMR and 1H NMR spectrometric analysis of the oils showed that manure oil was rich in hydrocarbons and nitrogenous compounds such as primary, secondary amides, aromatic amines and N-heterocyclic. The properties of the oils were strongly influenced by the amount of wood in the mixture.  相似文献   

20.
Although composting has been successfully used at pilot scale to manage waste algae removed from eutrophied water environments and the compost product applied as a fertiliser, clear guidelines are not available for full scale algae composting. The review reports on the application of composting to stabilize waste algae, which to date has mainly been macro-algae, and identifies the peculiarities of algae as a composting feedstock, these being: relatively low carbon to nitrogen (C/N) ratio, which can result in nitrogen loss as NH3 and even N2O; high moisture content and low porosity, which together make aeration challenging; potentially high salinity, which can have adverse consequence for composting; and potentially have high metals and toxin content, which can affect application of the product as a fertiliser. To overcome the challenges that these peculiarities impose co-compost materials can be employed.  相似文献   

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