NITRATE CONTAMINATION IN OREGON WELL WATER: GEOLOGIC VARIABILITY AND THE PUBLIC'S PERCEPTION1

ABSTRACT: Approximately 4.5 million people in the United States who rely on well water are exposed to nitrate‐N concentrations exceeding the 10 mg/l standard. In this study in the Southern Willamette Valley in Oregon we reassessed nitrate‐N in rural wells sampled in 2000–2001, compared nitrate‐N concentrations among geological units, and surveyed residents about their perceptions of well water quality. Nitrate‐N concentrations were again sampled in 2002 and found to have increased significantly from the previous period. With rapid population growth in the area, the potential health risk in drinking well water that exceeds 10 mg/l nitrate‐N warrants continued public education. Nitrate‐N concentrations were found to be higher in the Holocene alluvium of the Willamette River and the Pleistocene sand and gravel post‐Missoula Flood deposits. Researchers conducting future studies may choose to stratify and monitor wells by geologic unit and by other parameters that estimate input of nutrients to the environment. Opinions differed between agricultural landowners and nonagricultural landowners with regard to the impact that agricultural fertilizers may have on water quality. Participants were supportive of a range of regulatory actions that might be used by homeowners or landowners to address ground water contamination. Given that the area is now designated a Groundwater Management Area, understanding local stakeholders’perceptions is critical and strategic and has the potential to help public agencies manage potential conflicts of opinion among stakeholders, build consensus, and help guide the approach to restoring ground water quality.     

VOLATILE ORGANIC COMPOUNDS IN GROUND WATER FROM RURAL PRIVATE WELLS, 1986 TO 19991

ABSTRACT: The U.S. Geological Survey (USGS) collected or compiled data on volatile organic compounds (VOCs) in samples of untreated ground water from 1,926 rural private wells during 1986 to 1999. At least one VOC was detected in 12 percent of samples from rural private wells. Individual VOCs were not commonly detected with the seven most frequently detected compounds found in only 1 to 5 percent of samples at or above a concentration of 0.2 microgram per liter (μg/l). An assessment level of 0.2 μg/l was selected so that comparisons of detection frequencies between VOCs could be made. The seven most frequently detected VOCs were: trichloromethane, methyl tert‐butyl ether, tetrachloroethene, dichlorodifluoromethane, methylbenzene, 1,1,1‐trichloroethane, and 1,2‐dibromo‐3‐chloropropane. Solvents and trihalomethanes were the most frequently detected VOC groups in private wells. The distributions of detections of gasoline oxygenates and fumigants seemed to be related to the use patterns of compounds in these groups. Mixtures were a common mode of occurrence of VOCs with one‐quarter of all samples with detections including two or more VOCs. The concentrations of most detected VOCs were relatively small and only 1.4 percent of samples had one or more VOC concentrations that exceeded a federally established drinking water standard or health criterion.     

RELATIONSHIP OF NITRATE CONCENTRATIONS TO DISTANCE OF WELL SCREEN OPENINGS BELOW CASING WATER LEVELS1

ABSTRACT: Data from 54 well in central and eastern Kansas developed in unconsolidated deposits of Quaternary age indicate that nitrate concentrations are inversely related to the depth of the well screen opening below the water level in the well casing because this relationship was found to exist in an area of Nebraska and in a large area of Kansas, the relationship is generally valid over a wide geo- graphical area. In addition, the data indicate that the incidence of nitrate concentrations exceeding 45 milligrams per liter and nitrate concentrations, in general, are significantly lower in water from wells with screens deeper than 25 feet below the water table in unconfined aquifers or where screens are placed in deep confined aquifers. No concentrations of nitrate greater than 45 milligrams per liter were in obseved wells where screens were deeper than 60 feet below the casing water level. These findings suggest that general placement of well screens as far below the water table as possible in unconfined unconsolidated aquifers in Kansas. and possibly other areas of the Midwest, may be an effective measure in preventing undesirable nitrate concentrations in ground water supplies. particularly in areas where nitrate is a problem.     

SPECIAL CASES OF WATER SUPPLY INTERFERENCE CAUSED BY URBAN DEVELOPMENT NEAR TORONTO,ONTARIO, CANADA1

Since 1961, control over water-supply interference problems in the Province of Ontario has been provided under The Ontario Water Resources Commission Act. A section of The Act requires persons taking more than 10,000 imperial gallons per day of water for purposes other than domestic, stock or fire-fighting to have a permit and to take the water in accordance with specified terms and conditions. Construction of some new wells, sewers, and roads to meet the needs of urban development has caused interference with both ground- and surface-water supplies. In cases of serious interference, the Commission has required that steps be taken to restore water supplies or prevent continued interference. Two cases are described where municipalities in the Toronto area restored supplies to overcome serious interference with several private wells and streamflow during testing and operation of a 500-imperial gpm municipal well adjacent to a normally effluent stream, and varying degrees of interference with private wells caused by dewatering at rates up to 2000-imperial gpm for the installation of a trunk sewer.     

Understanding stewardship behaviour: factors facilitating and constraining private water well stewardship

Regulatory frameworks to ensure municipal drinking water safety exist in most North American jurisdictions. However, similar protection is rarely provided to people reliant on water provided from private wells. In Canada, approximately 4 million people depend on privately owned, domestic wells for their drinking water. Numerous studies have shown that people who rely on private wells for their water supplies are at risk from nitrate and bacterial contamination. Given the fact that regulations relating to private wells tend to be weak or poorly enforced, actions taken by well owners to protect their own drinking water safety are extremely important. Drawing on one of the largest and most comprehensive surveys of private well owners ever conducted in Canada or elsewhere, this paper explores factors that influence well owner stewardship behaviour. Key behaviours examined included annual testing of well water and inspection of wells, measures to protect water quality, and proper decommissioning of unused wells. A geographically-stratified survey, sent to 4950 well owners in Ontario, Canada, resulted in an effective response rate of 34% (n = 1567). Logistic regression analyses revealed that motivations for well stewardship behaviours included reassurance, the perception of problems, and knowledge of the environment. Knowing how to perform stewardship behaviours was an important antecedent to action. Barriers to stewardship included complacency, inconvenience, ignorance, cost, and privacy concerns. To promote stewardship, local initiatives, better educational materials, and enforcement through real estate laws are all required. Ultimately, drinking water safety for people reliant on private wells is shown to be a responsibility shared by governments and private well owners.     

ARSENIC IN THE SHALLOW GROUND WATERS OF CONTERMINOUS UNITED STATES: ASSESSMENT,HEALTH RISKS,AND COSTS FOR MCL COMPLIANCE1

A methodology consisting of ordinal logistic regression (OLR) is used to predict the probability of occurrence of arsenic concentrations in different threshold limits in shallow ground waters of the conterminous United States (CONUS) subject to a set of influencing variables. The analysis considered a number of maximum contaminant level (MCL) options as threshold values to estimate the probabilities of occurrence of arsenic in ranges defined by a given MCL of 3, 5, 10, 20, and 50 μg/l and a detection limit of 1 μg/l. The fit between the observed and predicted probability of occurrence was around 83 percent for all MCL options. The estimated probabilities were used to estimate the median background concentration of arsenic in the CONUS. The shallow ground water of the western United States is more vulnerable than the eastern United States. Arizona, Utah, Nevada, and California in particular are hotspots for arsenic contamination. The risk assessment showed that counties in southern California, Arizona, Florida, and Washington and a few others scattered throughout the CONUS face a high risk from arsenic exposure through untreated ground water consumption. A simple cost effectiveness analysis was performed to understand the household costs for MCL compliance in using arsenic contaminated ground water. The results showed that the current MCL of 10 μg/l is a good compromise based on existing treatment technologies.     

GROUND WATER MONITORING FOR TEMIK (ALDICARB) IN FLORIDA1

ABSTRACT: Over 700 community drinking water supplies were sampled for the pesticide Temik (aldicarb and its oxidative metabolites aldicarb sulfoxide and aldicarb sulfone) in Florida. All community supply wells sampled for Temik were located in counties where Temik was reported to have been used and approximately one-half of the wells were located in counties where ground water was determined to be highly susceptible to contamination by Temik. Susceptibility was determined using ranking criteria that incorporated ground water recharge characteristics, water use, and Temik use patterns. Temik was not detected in any of the community supply wells sampled during the study. However, Temik was detected in shallow, private wells, as was the pesticide ethylene dibromide in counties with ground water characterized as highly susceptible to contamination.     

Quantifying the influence of environmental and water conservation attitudes on household end use water consumption

Within the research field of urban water demand management, understanding the link between environmental and water conservation attitudes and observed end use water consumption has been limited. Through a mixed method research design incorporating field-based smart metering technology and questionnaire surveys, this paper reveals the relationship between environmental and water conservation attitudes and a domestic water end use break down for 132 detached households located in Gold Coast city, Australia. Using confirmatory factor analysis, attitudinal factors were developed and refined; households were then categorised based on these factors through cluster analysis technique. Results indicated that residents with very positive environmental and water conservation attitudes consumed significantly less water in total and across the behaviourally influenced end uses of shower, clothes washer, irrigation and tap, than those with moderately positive attitudinal concern. The paper concluded with implications for urban water demand management planning, policy and practice.     

IRRIGATION METHODS AND TRANSPORT OF IMAZAMETHABENZ‐METHYL TO GROUND WATER: GREENFIELDS BENCH,MONTANA1

ABSTRACT: A series of gravel terraces support a shallow aquifer that is the sole source of drinking water for three public water supplies and more than 400 private wells on the Greenfields Bench in west‐central Montana. Farming practices on the Greenfields Bench include irrigation of malting barley and the yearly application of herbicides for the control of weeds. The most commonly used herbicide (imazamethabenz‐methyl, U.S. trade name Assert®) has been found in the ground water on the Greenfields Bench. An experiment was conducted in 2000 and 2001 to characterize the transport of Assert and its acid metabolite to ground water under three irrigation methods: flood, wheel line sprinkler, and center pivot sprinkler. Results show that Assert concentrations in ground water are controlled by hydraulic loading rates of each irrigation method, Assert persistence in soil, hydraulic characteristics of the aquifer, and adsorption/desorption of Assert onto clay particles and organic matter.     

MUNICIPAL RESPONSES TO VOLATILE ORGANIC COMPOUNDS IN WISCONSIN GROUND WATER1

ABSTRACT: Contamination of ground water supplies with volatile organic compounds is a new and significant problem. Municipalities and their community water systems are often the first to discover ground water contamination because of the monitoring programs they are required to carry out. When contamination exceeds standards, some action is required. The responses of Wisconsin municipalities to volatile organic compounds that exceed standards in their ground water sources is described. Actions to protect human health are prompt, but the survey results indicate plumes of contaminated ground water are usually not treated. They may continue to migrate and contaminate other private and public wells.     

IDENTIFYING DISCHARGE ZONES OF ARSENIC IN THE GOOSE RIVER BASIN,MAINE1

ABSTRACT: Water balance modeling and the analysis of stable water isotopes in ground water were conducted to aid the location of ground water discharge areas within the Goose River basin, in mid‐coastal Maine. Previous investigations of drinking water from wells in the fractured crystalline bedrock encountered persistent elevated total arsenic. Such contamination may be related to discharging ground water from fractured zones in the basin. Modeled discharge rates greater than +10 cm/yr and ¹⁸O values lighter than‐9.5 per mil VSMOW may indicate recent recharge is mixing with deeper ground water and is focused along some fractured zones in arsenic bearing crystalline rocks.     

LEAD AND CADMIUM ASSOCIATED WITH SALTWATER INTRUSION IN A NEW JERSEY AQUIFER SYSTEM1

ABSTRACT: The U.S. Geological Survey collected ground-water samples from the upper and middle aquifers of the Potomac-Raritan-Magothy aquifer system in a 400-square-mile area of New Jersey from 1984 through 1986. Concentrations of lead were greater than the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 50 micrograms per liter in water from 16 of 239 wells. The cencentrations of cadmium were greater than the MCL of 10 micrograms per liter in water from 10 to 241 wells. One-half of the wells that exceeded the lead MCL were in known areas of saltwater intrusion, as were all 10 wells that exceeded the cadmium MCL. The association of elevated concentrations of these metals with elevated concentrations of chloride indicates a mochanism related to saltwater intrusion.     

IMPACT OF DROUGHT ON QUALITY IN A NEW JERSEY WATER SUPPLY SYSTEM1

ABSTRACT. New Jersey, together with other states in the northeast, was stricken with drought during 1961-66. The effect of this drought was most severe in the northern part of the State. The water quality of the Passaic River, which drains the urban, industrialized northeast, perhaps deteriorated the most among the major drainage systems. This river system is used as a raw-water source by 10 water suppliers. The impact of the drought upon the water supply of the Passaic Valley Water Commission, the most downstream of the basin's suppliers, which supplies an average of about 90 million gallons a day to more than 650,000 persons, is evaluated herein. The drought's impact on the raw-water quality is appraised by the comparison of before-and-after qualities of dissolved solids, dissolved oxygen, biochemical-oxygen demand, turbidity, and hardness. For example, at the worst point during the drought, monthly average dissolved-solids content in the raw water were about 210 percent, hardness, about 167 percent, and biochemical-oxygen demand about 270 percent higher than antecedent values. In general, the study concludes that the drought produced a deterioration in both raw and finished water quality, and is estimated to have increased chemical-treatment costs during the drought by about $650,000.     

A Baseline Study on Water Resources of the Tourist Island, Pulau Perhentian, Peninsular Malaysia, from an Ecological Perspective

Ambient water quality and bacterial populations in the water resources of Pulau Perhentian, a Marine Park of Malaysia, were studied during a peak tourist arrival, off-monsoon period. The overall water and bacteriological quality of swimming/boating sites in the island is at an acceptable condition, although the conductivity (0.88–60 mS m^–1) due to high dissolved solid concentrations is slightly high, when compared with the recommended standard and published guidelines for the protection/maintenance of recreation water and its aesthetic enjoyment (Universiti Malaya, Department of Environment, Malaysia, 1986). However, the bacteriological quality of the drinking/bathing water wells is poor, with faecal coliform counts (2 up to 1,600 MPN per 100 ml sample water) exceeding the permissible levels defined for raw water supplies (with or without treatment). This suggests that the groundwater, seepage and run-off into the wells is contaminated. Contrary to the belief of the water users being interviewed in a social survey, the untreated drinking/bathing water is not bacteria-free. The excessive counts are attributable to deoxygenated conditions (12–42 percent corresponding to 0.9–3.3 mg l^–1) prevailing in the wells, high total suspended solids (up to 202 mg l^–1) which promote bacterial growth, lack of adequate sewerage systems to receive effluents from lavatories of dwellings, chalets and resorts, as well as the lack of centralised water treatment plants and storage tanks to cope with water scarcity and waterway contamination.     

HERBICIDES AND DEGRADATES IN SHALLOW AQUIFERS OF ILLINOIS: SPATIAL AND TEMPORAL TRENDS1

ABSTRACT: During the fall of 2000, the occurrence was examined of 16 herbicides and 13 herbicide degradates in samples from 55 wells in shallow aquifers underlying grain producing regions of Illinois. Herbicide compounds with concentrations above 0.05 μg/L were detected in 56 percent of the samples. No concentrations exceeded regulatory drinking water standards. The six most frequently detected compounds were degradates. Water age was an important factor in determining vulnerability of ground water to transport of herbicide compounds. Unconsolidated aquifers, which were indicated to generally contain younger ground water than bedrock aquifers, had a higher occurrence of herbicides (73 percent of samples) than bedrock aquifers (22 percent). Temporal analysis to determine if changes in concentrations of selected herbicides and degradates could be observed over a near decadal period indicated a decrease in detection frequency (25 to 18 percent) between samplings in 1991 and 2000. Over this period, significant differences in concentrations were observed for atrazine (decrease) and total acetochlor (increase). The increase in acetochlor compound concentrations corresponds to an increase in acetochlor use during the study period, while the decrease in atrazine concentrations corresponds to relatively consistent use of atrazine. Changes in frequency of herbicide detection and concentration do not appear related to changes in land use near sampled wells.     

THE EFFECT OF RESIDENTIAL DEVELOPMENT ON GROUND‐WATER QUALITY NEAR DETROIT,MICHIGAN1

ABSTRACT: Two water‐quality studies were done on the outskirts of the Detroit metropolitan area to determine how recent residential development has affected ground‐water quality. Pairs of monitor and domestic wells were sampled in areas where residential land use overlies glacial outwash deposits. Young, shallow waters had significantly higher median concentrations of nitrate, chloride, and dissolved solids than older, deeper waters. Analysis of chloride/bromide ratios indicates that elevated salinities are due to human activities rather than natural factors, such as upward migration of brine. Trace concentrations of volatile organic compounds were detected in samples from 97 percent of the monitor wells. Pesticides were detected infrequently even though they are routinely applied to lawns and roadways in the study area. The greatest influence on ground‐water quality appears to be from septic‐system effluent (domestic sewage, household solvents, water‐softener backwash) and infiltration of storm‐water runoff from paved surfaces (road salt, fuel residue). No health‐related drinking‐water standards were exceeded in samples from domestic wells. However, the effects of human activities are apparent in 76 percent of young waters, and at depths far below 25 feet, which is the current minimum well‐depth requirement.     

GRADUATE TRAINING IN WATER TRACK ENVIRONMENTAL ENGINEERING: RESULTS OF A SURVEY OF EMPLOYERS1

ABSTRACT: The authors conducted a mail survey of 600 employers in the government and private sectors who were thought to hire water track environmental engineers. Of a total of 148 respondents, over 80 percent employed a combined total of over 2,800 environmental engineers. The survey addressed two basic questions: (1) what is the quality of graduate education recently trained engineers have received, and (2) what effect does a nonengineering undergraduate degree have on an engineering graduate student's employment potential. In answer to the first question, respondents indicated that engineering graduates were deficient in report writing, business law (contracts and specifications), economics and finance, and practical design. Many employers stated that students could better prepare themselves for employment by (1) obtaining professional experience through internships and summer or part-time jobs, and (2) learning to communicate effectively, both orally and in writing. In answer to the second question, 50 percent of the respondents indicated that engineers without an engineering undergraduate degree would not necessarily be limited in their abilities to perform engineering duties.     

Draining us dry: scarcity discourses in contention over bottled water extraction

Water scarcity is a highly contested concept. The dominant narratives of water scarcity in policy debates have been criticised for prioritising purely quantitative metrics and eliding questions of inequality and power. While much scholarship on water scarcity examines contexts in the global South where potable water infrastructures do not reach most residents, this article examines conflict over commercial water extraction in a Northern setting where access to potable tap water is nearly universal, yet local water supplies are increasingly constrained. It addresses three main questions: (1) How are narratives or discourses of water scarcity mobilised by a range of actors in local conflicts over groundwater extraction for water bottling?; (2) To what extent do these discourses invoke biophysical versus socially produced scarcity, current versus future scarcity, and local versus regional or global scales of scarcity?; and (3) What are the implications of the findings for efforts by environmental advocates and communities to protect local water supplies? We explore these questions by analysing a local case study of conflict over groundwater extraction by the leading bottled water firm, Nestlé Waters, in southwestern Ontario, Canada. We find that the scarcity narratives deployed by local residents, activists, public officials, and bottling industry representatives illustrate the use of several forms of figurative conflation involving geographic and temporal scales of water scarcity, and economic and volumetric forms of scarcity. We argue that this conflation illuminates deeper issues of economic and social justice at the heart of the conflict, which transcend reductionist hydrological assessments of scarcity or abundance.     

Role of Wild Game in the Diet of Recreationists in South Carolina

Risk assessors have devoted considerable attention to the consumption of fish in the diet of recreational and subsistence anglers, but little attention has been directed toward the percentage that wild game contributes to total protein intake for people who engage in hunting and fishing. While recall studies have limitations, the relative errors should be similar for different types of fish and game. We interviewed 454 people attending the Palmetto Sportsmen's Classic in South Carolina to determine their consumption patterns of domesticated animals, fish (both wild-caught and commercial) and wild game. The percentage of people who consumed each type of meat was: chicken (98%); beef (95%); wild-caught fish (79%); deer (79%); restaurant fish (73%); pork (71%); dove (47%); commercial fish (41%); wild turkey (40%), duck, squirrel and self-caught quail (about 25% each); restaurant quail (10%); and raccoon (11%). Although a similar proportion of white respondents and black respondents consumed wild game overall (90%), there were ethnic differences in the number of meals of wild-caught fish and game. Black respondents ate more wild-caught fish, rabbit, raccoon and squirrel, and less deer, than did white respondents. Wild-caught fish and game made up 50% of the meat and fish diet of black sportsmen, but only 32% for whites. Wild-caught fish and game were being eaten disproportionately more by low-income black respondents, while more deer was consumed by higher-income black respondents. The data suggest that managers and planners should take into account age, ethnicity and income when (1) conducting exposure assessments, (2) considering consumption patterns for wild-caught fish and game and (3) managing risk from wild-caught fish and game. The data will be especially useful to policy makers and risk managers who are designing consumption advisories, for risk communicators in identifying the target audience and for managers designing long-term stewardship for sites with contamination.     

RECIRCULATING WELLS: GROUND WATER REMEDIATION AND PROTECTION OF SURFACE WATER RESOURCES1

ABSTRACT: Several chlorinated solvent plumes threaten the sole‐source aquifer underlying the Massachusetts Military Reservation at the western end of Cape Cod. Sensitive surface water features including ponds, cranberry bogs, and coastal wetlands are hydraulically connected to the aquifer. For one of the plumes (CS‐10 the original remedy of 120 extraction and reinjection wells has the potential for significant disruption of surface water hydrology, through the localized drawdown and mounding of the water table. Recirculating wells with in‐well air stripping offer a cost‐effective alternative to conventional pump‐and‐treat technology that does not adversely affect the configuration of the water table. Pilot testing of a two well system, pumping 300 gpm, showed a capture radius of > 200 feet per well, in‐well trichloroethylene (TCE) removal efficiencies of 92 to 98 percent per recirculation cycle, an average of three recirculation cycles within the capture zone, and no measurable effect on water table elevations at any point within the recirculation/treatment zone. During 120 days of operation, the mean concentration of TCE in the treatment zone was reduced by 83 percent, from 1,111 μg/l to 184 μg/l. Full‐scale design projections indicate that 60 wells at an average spacing of 160 feet, having an aggregate recirculation 11 MGD, can contain the CS‐b plume without ground water extraction or adverse hydraulic effects on surface water resources. The estimated capital costs for such a system are about $7 million, and annual operations‐and‐maintenance costs should be about $1.4 million, 40 percent of those associated with a pump and treat system over a 20‐year period.