Performance assessment of a wastewater treatment plant producing effluent for irrigation in Egypt

A conventional activated sludge treatment facility was the subject of this study. The assessment was directed at determining the characteristics of the raw wastewater, the quality of the treated effluent and the efficiency of the various treatment units. Furthermore, the water quality along the effluent irrigation canal was monitored. The assessment of the quality of the treated effluent for irrigation is based on the guidelines established by the World Health Organization and the Egyptian decree 9/89 for the use of wastewater in agriculture. The results of the study indicated that the concentration of the raw wastewater was considered moderate. The mean values of the COD (Chemical Oxygen Demand), BOD (Biological Oxygen Demand) and total suspended solids (TSS) were around 250, 102 and 142 mg l–1, respectively. This was attributed to the high quantities of wastewater from industrial sources. The overall efficiency of the treatment facility was good. The mean residual COD, BOD and TSS were 25, 8 and 21 mg l–1 and the corresponding percentage removal values were 90, 92 and 85%, respectively. The maximum percentage removal of oil and grease was 84% with a mean residual concentration of 24 mg l–1. The total viable count (22°C and 37°C), faecal coliform and aecal streptococci were reduced by 99.9% compared to only 99.5% for Salmonella. Bacteriological examination of the dried sludge indicated a reduction of nine logs of faecal coliform and faecal streptococci, as compared to thickened sludge. Analysis of the Ni, Cu, Pb and Cr in the dried sludge indicated that their concentrations are within the permissible limits. Zinc exceeded the consent standards by 50%. The results of the analyses of samples collected at the beginning of the irrigation canal indicated insignificant changes from the characteristics of the final effluent. Samples collected at a distance of 2km along the irrigation canal showed mean reductions in the COD and BOD of 28.6 and 47%, respectively, which could be attributed to sedimentation and/or a self-purification effect. An increase in the total nitrogen, total phosphorus and total viable count was also recorded, which could be due to seepage from the agricultural land. From the data available it is evident that the treated wastewater could be used for restricted irrigation. The design and implementation of a monitoring programme is recommended.     

Phytoremediation of dairy effluent by constructed wetland technology

Constructed wetlands are artificial wastewater treatment systems consisting of shallow ponds or channels which have been planted with aquatic plants and which rely upon natural microbial, biological, physical and chemical process to treat wastewater and are gaining acceptance in the recent years as a viable option for the treatment of industrial effluents and removal of toxic components. In this study, an attempt was made to compare the efficiency of aquatic macrophytes like Typha sp., Eichhornia sp., Salvinia sp., Pistia sp., Azolla sp. and Lemna sp. to treat the effluents from dairy factory, under laboratory conditions in constructed wetlands. The biological oxygen demand and chemical oxygen demand of dairy effluent were reduced up to 65.4–83.07% and 70.4–85.3%, respectively, after treatment with constructed wetland technology.     

Antibacterial behavior of silver-modified clinoptilolite-heulandite rich tuff on coliform microorganisms from wastewater in a column system

The water disinfecting behavior of silver-modified clinoptilolite–heulandite rich tuff (ZSAg) as an antibacterial agent against coliform microorganisms from water in a continuous mode was investigated. Silver recovery from the disinfected effluents by the sodium-modified clinoptilolite–heulandite rich tuff (ZSNa) was also considered. Escherichia coli (ATCC 8739) and total coliform microorganisms, as indicators of microbiological contamination of water, were chosen to achieve the disinfection of synthetic wastewater or municipal wastewater. Ammonium (NH₄⁺) and chloride (Cl⁻) ions were added to the synthetic wastewater as an interfering chemical species on the disinfection processes. The antibacterial activity of the ZSAg as a bactericide was measured by the coliform concentration as evaluated by the APHA method. The amount of silver in the disinfected effluents was determined using atomic absorption spectroscopy. The inactivation of the ZSAg was calculated from the breakthrough curves based on the model reported by Gupta et al. It was found that when the silver concentration in the effluent is less than 0.6 μg/mL, the bacterial survival percentage increased and the volume of disinfected water diminished. The total silver amounts found in the effluent at the end of the disinfection processes varied depending on the water treated (synthetic or municipal wastewater). The presence of NH₄⁺ ions in synthetic wastewater influent notably improved the disinfected water volume (zero NVC/100 mL), in comparison to the disinfection of the same influent without NH₄⁺ ions. A contrary water disinfection behavior was observed in the presence of Cl⁻ ions. The silver recovery does not depend on the mass of the sodium zeolitic bed according with the wastewater to be treated (synthetic or municipal wastewater) and the presence of NH₄⁺ or Cl⁻ ions in the influent also influenced the silver recovery from wastewater. The ZSNa did not have antibacterial activity. Therefore the amount of bactericide agent (silver-modified natural zeolite), coliform microorganisms from water (E. coli or consort of coliform microorganisms) as well as the water quality (synthetic wastewater or municipal wastewater) influenced both the disinfection process and the silver recovery in a column system.     

四川某小区人工湿地中水回用技术

中水回用是提高生活用水重复利用率的主要形式。提高水的重复利用率,是实现城市污水资源化是解决水资源短缺的根本途径。人工湿地既具有景观价值,又有污水处理功能。可以为市政绿化、农田灌溉景观提供水资源。经人工湿地处理的中水水质,出水水质符合我国的城市杂用水水质标准(GB/T18920-2002)、景观环境用水水质标准(GB/T18920-2002)和农田灌溉水质标准(GB5084-2005)。     

Reduction of pathogen indicator organisms in dairy wastewater using an ecological treatment system

Ecological treatment systems can provide a sustainable, plant-based alternative to traditional wastewater treatment. One factor essential to the success of these systems is ensuring their ability to reduce coliform concentrations in wastewater. Wastewater is the primary source of fecal contamination in aquatic ecosystems, containing total and fecal coliforms on the order of 10(8)-10(10) and 10(7)-10(9) CFU L(-1), respectively. This study assessed the ability of an ecological treatment system to reduce concentrations of total coliforms and Escherichia coli from dairy wastewater. Low strength wastewater was pumped into the system during July of 2005 and high strength in September 2005. Wastewater passes through a series of anaerobic, aerobic, and clarifier reactors and wetland cells before exiting the system. Regardless of wastewater strength, average total coliform and E. coli concentrations were consistently reduced by at least 99% from influent to effluent, with the majority of the reduction (76%) occurring in the first two reactors. Relationships between internal concentrations of solids and coliforms indicated that increased reduction of solids may further reduce coliform concentrations. Although U.S. Environmental Protection Agency discharge requirements for E. coli were not always met, the substantial reductions achieved indicate that ecological treatment systems have the potential to successfully reduce coliforms in wastewater to meet discharge limits. The results from this study will be used to guide design and management of future ecological treatment systems, so that larger and more consistent coliform reductions can be achieved.     

NITROGEN ACCUMULATION IN A CONSTRUCTED WETLAND FOR DAIRY WASTEWATER TREATMENT1

ABSTRACT: A free water surface (FWS) constructed wetland was installed at a dairy in Glendale, Arizona, to study the potential of such a wetland to remove nitrogen (N) from wastewater. The study objectives were: (1) to determine N removal from the wastewater, and (2) to evaluate N accumulation in soil and plant tissues. The system consisted of eight cells (70 × 9 × 1.5 m) planted with Typha domingensis, Scirpus validus, and Phragmites australis. The four cells in series were lined with plastic, and the four cells in a parallel series were lined with clay. Cells received approximately 180 m³/d of partially treated dairy effluent. Plant tissues and soil samples were collected above and below ground from 24 locations during one year. Total N removal from wastewater was about 17 percent. Clay‐lined cells accumulated more N in the soil and less N in plant biomass compared with plastic lined cells. Plant biomass accounted for approximately 60 percent of total N accumulated in cells with dense plant communities. Ninety percent of accumulated soil N was organic. Total N accumulated in soil reached a maximum (1,100 mg/kg) eight months after the introduction of wastewater.     

Treatment of domestic wastewater using an anaerobic baffled reactor followed by a duckweed pond for agricultural purposes

The treatment and reuse of domestic wastewater using an anaerobic baffled reactor (ABR) followed by a duckweed pond (DWP) were the main theme of the present study. The ABR was fed continuously with domestic wastewater at four HRTs ranging from 8 to 24 h and corresponds to organic loading rates ranging from 0.67 to 2.1 kg COD/m³/day. The ABR effluent was fed to a DWP operating at 10 and 15 days. The performance of the ABR at the four HRTs gave satisfactory results. Chemical oxygen demand (COD) removal was between 68 and 82%. Fecal coliform removal was between 1 to 2 logs. The 12- and 18-h hydraulic retention times (HRTs) gave close results, as indication of the possible selection of the 12-h HRT as the optimum operation for the ABR based on economic advantage. The ABR compartmentalized structure gave results higher than those produced by the one-stage digester and similar to those produced by the two-phase anaerobic digestion process. Duckweed ponds as post-treatment operated at 10 days and 15 days gave the best results at 15-day HRT, where it was possible to remove 73.4% of nitrogen and 65% of phosphorus and produce protein-rich dry duckweed of 105 kg/ha/day on average. The removal of fecal coliform (FC) in duckweed ponds was 3–4 logs. The final treated domestic sewage characteristics proved its compliance with the Egyptian standards for reuse in restricted irrigation.     

Nutrient removal in a pilot and full scale constructed wetland, Putrajaya city, Malaysia

Putrajaya Wetlands in Malaysia, a 200ha constructed wetland system consisting of 24 cells, was created in 1997-1998 to treat surface runoff caused by development and agricultural activities from an upstream catchment before entering Putrajaya Lake (400ha). It was designed for stormwater treatment, flood control and amenity use. The water quality improvement performance of a section of the wetland cells is described. The nutrient removal performance was 82.11% for total nitrogen, 70.73% for nitrate-nitrogen and 84.32% for phosphate, respectively, along six wetland cells from Upper North UN6 to UN1 from April to December 2004. Nutrient removal in pilot scale tank systems, simulating a constructed wetland and planted with examples of common species at Putrajaya, the Common Reed Phragmites karka and Tube Sedge Lepironia articulata, and the capacity of these species to retain nutrients in above and below-ground plant biomass and substrate is reported. The uptake of nutrients by the Common Reed and Tube Sedge from the pilot tank system was 42.1% TKN; 28.9% P and 17.4% TKN; 26.1% P, respectively. The nutrient uptake efficiency of the Common Reed was higher in above-ground than in below-ground tissue. The results have implications for plant species selection in the design of constructed wetlands in Malaysia and for optimizing the performance of these systems.     

QUALITY STUDY OF GRAYWATER TREATMENT SYSTEMS1

ABSTRACT: A residential single family dwelling was retrofitted to recycle graywater for landscape irrigation and toilet flushing. The objective of this study was to determine improvements in graywater quality by evaluating five simple graywater treatment systems that were easily adapted to the household plumbing. The treatment systems consisted of (1) water hyacinths and sand filtration, (2) water hyacinths, copper ion disinfection, and sand filtration, (3) copper ion disinfection and sand filtration, (4) copper/silver ion disinfection and sand filtration, and (5) 20–μm cartridge filtration. Water quality parameters measured were fecal and total coliform indicator bacteria, nitrates, suspended solids, and turbidity. Reductions in bacterial concentration, suspended solids and turbidity were achieved by all systems tested. Treatment reduced nitrate concentrations to an average of 2.6 mg/liter. Reductions in suspended solids, and turbidity were influenced more by the quality of the graywater entering the treatment system than the efficiency of the systems themselves. The water hyacinths and sand filtration system provided the best graywater quality in terms of the concentrations of fecal indicator bacteria. The system providing the best water quality in regard to average suspended solids after treatment was the water hyacinths, copper ion, and sand filtration system, and the best average turbidity was achieved by the copper/silver ion generating unit with sand filtration. All systems were capable of significant reductions in fecal indicator bacteria, suspended solids, and turbidity; however, additional treatment or disinfection would be necessary to further reduce the level of coliform and fecal coliform bacteria to achieve regulatory standards in the State of Arizona.     

The effect of environmental conditions on the ability of a constructed wetland to disinfect municipal wastewaters

Constructed wetlands are widely used all over the world for the treatment of municipal wastewaters, which are characterized by high concentrations of pathogens. The objectives of this study were (1) to study the effect of solar radiation and temperature on the ability of a constructed wetland to reduce the concentration of total coliforms (TC), and (2) to evaluate the relationship between the presence of Salmonella spp. in the outflow and the concentration of TC. The results of this study showed that under Mediterranean environmental conditions, the percentage reduction in coliforms was lower during winter compared to all other seasons. Maximum removal of coliforms was achieved under conditions of high solar radiation and temperature. In addition, solar radiation was found to play a greater role in coliform die-off at low temperatures than at high temperatures. Finally, it was found that the probability of Salmonella spp. appearance in the outflow of the wetland was related to the concentration of TC. The increase in coliform bacteria in the effluents also increased the chances of Salmonella appearance. The risk of Salmonella spp. appearance in the outflow is minimized when the concentration of TC is below 10²/100 mL.     

表面活性剂废水处理技术的研究现状与问题分析

介绍了表面活性剂废水的特点及危害，概述了处理表面活性剂废水常用的物理法，化学法，生物法等方法，并对各类方法的应用现状和发展方向进行了分析和评价。提出了一种处理LAS废水十分具有前景的新方法——复极性固定床电解法，并提出这一新型的污水处理方法的优缺点及未来需要解决的问题。     

Use of cattails in treating wastewater from a Pb/Zn mine

This article describes the use of a combined treatment system, which includes an aquatic treatment pond withTypha latifolia Linn. (Typhaceae) as the dominant species and a stabilization pond, to treat the wastewater from a Pn/Zn mine at Shaoguan, Guangdong Province, China. In 1983, it was noted thatT. latifolia bloomed in areas affected by the wastewater emitted from the mine, hence a combined purification system was subsequently built. The influent contained high levels of total suspended solids (4635 mg/liter), chemical oxygen demand (14.5 mg/liter) as well as Pb (1.6 mg/liter) and Zn (1.9 mg/liter). The results of the effluent after treatment showed that the total suspended solids, chemical oxygen demand, Pb, and Zn had been reduced by 99%, 55%, 95%, and 80% respectively. The results of plant tissue analysis indicled thatT. latifolia assimilated significant amounts of Pb and Zn, especially in the root portion. During 1986 several species of algae and fish were present in the pond, usually with a higher density in areas containing lower metal concentrations in the water. Paper was presented in part at the conference “The Use of Constructed Wetlands in Water Pollution Control” held 24–28 September 1990, Cambridge, UK.     

Denitrification in constructed wetlands used for treatment of swine wastewater

Constructed wetland treatment of swine wastewater probably involves substantial denitrification. Our objective was to assess denitrification and denitrification enzyme activity (DEA) in such wetlands in relation to plant communities, N loading, carbon or nitrogen limitations, and water depth. Two wetland cells each 3.6 m wide and 33.5 m long were connected in series. One set of cells was planted with rushes and bulrushes, including soft rush (Juncus effusus L.), softstem bulrush [Schoenoplectus tabernaemontani (K.C. Gmel.) Pallal, American bulrush [Schoenoplectus americanus (Pers.) Volkart ex Schinz & R. Keller], and woolgrass bulrush [Scirpus cyperinus (L.) Kunth]. Another set was planted with bur-reeds and cattails, including American bur-reed (Sparganium americanum Nutt.), broadleaf cattail (Typha latifolia L.), and narrowleaf cattail (Typha angustifolia L.). The sets will be referred to herein as bulrush and cattail wetlands, respectively. Denitrification and DEA were measured via the acetylene inhibition method in intact soil cores and disturbed soil samples that were taken during four years (1994-1997). Although DEA in the disturbed samples was greater than denitrification in the core samples, the measurements were highly correlated (r2 > or = 0.82). The DEA was greater in the bulrush wetlands than the cattail wetlands, 0.516 and 0.210 mg N kg(-1) soil h(-1), respectively; and it increased with the cumulative applied N. The DEA mean was equivalent to 9.55 kg N ha(-1) d(-1) in the bulrush wetlands. We hypothesized and confirmed that DEA was generally limited by nitrate rather than carbon. Moreover, we determined that one of the most influential factors in DEA was wetland water depth. In bulrush wetlands, the slope and r2 values of the control treatment were -0.013 mg N kg(-1) soil h(-1) mm(-1) depth and r2 = 0.89, respectively. Results of this investigation indicate that DEA can be very significant in constructed wetlands used to treat swine wastewater.     

Influence of vegetation on the removal of heavy metals and nutrients in a constructed wetland

A free water surface wetland was built to treat wastewater containing metals (Cr, Ni, Zn) and nutrients from a tool factory in Argentina. Water, sediment and macrophytes were sampled in the inlet and outlet area of the constructed wetland during three years. Three successive phases of vegetation dominance were developed and three different patterns of contaminant retention were observed. During the Eichhornia crassipes dominance, contaminants were retained in the macrophyte biomass; during the E. crassipes+Typha domingensis stage, contaminants were retained in the sediment and in the T. domingensis dominance stage, contaminants were retained in sediment and in the macrophyte biomass. Removal efficiency was not significantly different among the three vegetation stages, except for NH(4)(+) and i-P(diss). Because of its highest tolerance, T. domingensis is the best choice to treat wastewater of high pH and conductivity with heavy metals, a common result from many industrial processes.     

Some properties of a granular activated carbon-sequencing batch reactor (GAC-SBR) system for treatment of textile wastewater containing direct dyes

Resting (living) bio-sludge from a domestic wastewater treatment plant was used as an adsorbent of both direct dyes and organic matter in a sequencing batch reactor (SBR) system. The dye adsorption capacity of the bio-sludge was not increased by acclimatization with direct dyes. The adsorption of Direct Red 23 and Direct Blue 201 onto the bio-sludge was almost the same. The resting bio-sludge showed higher adsorption capacity than the autoclaved bio-sludge. The resting bio-sludge that was acclimatized with synthetic textile wastewater (STWW) without direct dyes showed the highest Direct Blue 201, COD, and BOD(5) removal capacities of 16.1+/-0.4, 453+/-7, and 293+/-9 mg/g of bio-sludge, respectively. After reuse, the dye adsorption ability of deteriorated bio-sludge was recovered by washing with 0.1% sodium dodecyl sulfate (SDS) solution. The direct dyes in the STWW were also easily removed by a GAC-SBR system. The dye removal efficiencies were higher than 80%, even when the system was operated under a high organic loading of 0.36kgBOD(5)/m(3)-d. The GAC-SBR system, however, showed a low direct dye removal efficiency of only 57+/-2.1% with raw textile wastewater (TWW) even though the system was operated with an organic loading of only 0.083kgBOD(5)/m(3)-d. The dyes, COD, BOD(5), and total kjeldalh nitrogen removal efficiencies increased up to 76.0+/-2.8%, 86.2+/-0.5%, 84.2+/-0.7%, and 68.2+/-2.1%, respectively, when 0.89 g/L glucose (organic loading of 0.17kgBOD(5)/m(3)-d) was supplemented into the TWW.     

Removal of nutrients and veterinary antibiotics from swine wastewater by a constructed macrophyte floating bed system

The potential of three varieties of Italian ryegrass (Lolium multiflorum Lam.), Dryan, Tachimasari and Waseyutaka, to improve the water quality of swine wastewater was evaluated using a constructed macrophyte floating bed system. With respect to reductions in levels of nutrients, chemical oxygen demand (COD), and sulfonamide antimicrobials (SAs, including sulfadiazine, sulfamethazine, and sulfamethoxazole), Dryan performed better than Tachimasari and Waseyutaka. For Dryan, total N was reduced by 84.0%, total P by 90.4%, COD by 83.4% and sulfonamide antimicrobials by 91.8–99.5%. Similar results were observed for Tachimasari and Waseyutaka. The results indicated that the treatment of swine wastewater using the constructed macrophyte floating bed system was effective in the removal of nutrients and veterinary antibiotics.     

PERFORMANCE VARIATIONS OF COD AND NITROGEN REMOVAL BY VEGETATED SUBMERGED BED WETLANDS1

ABSTRACT: Vegetated submerged bed wetlands can supplement treatment of onsite wastewater systems. This study evaluated vegetation, media, and seasonal impacts on system performance in six meso scale rock plant filters with and without narrow leaf cattails (Typha augustifolia). Daily chemical oxygen demand (COD) reductions in planted cells averaged 85 percent and weekly total nitrogen (TN) reductions averaged 50 percent. Planted cells had 17 percent greater COD reduction and 76 percent greater TN reduction than unplanted cells, both significant differences. Media type affected COD reduction, particularly in unplanted cells. COD treatment in planted cells was highest for fine crushed limestone (87±13 percent) and least variable for coarse river gravel (85±11 percent). No significant difference in TN reduction was observed for different media types (48 to 51 percent range). Seasonal influences on treatment included a significant decrease during late fall and early spring and a significant increase with temperature. After a step increase in organic loading, treatment efficiency decreased sharply but returned to prior levels after an adaptation period of about one month. Planted cells not only exhibited higher treatment efficiency but also had a retarded organic matter breakthrough, appearing after three to seven times the period for a bromide tracer. This supports a hypothesis that retardation of contaminant movement through the treatment cells results in enhanced removal. These results support the use of rock plant filters, but demonstrate the need to account for performance variations in system design. (KEY TERMS: constructed wetlands; seasonal effects; subsurface flow; Typha augustifolia; onsite wastewater treatment; water quality.)     

Trace element removal from coal ash leachate by a 10-year-old constructed wetland

This study investigated the ability of a 10-yr-old constructed wetland to treat metal-contaminated leachate emanating from a coal ash pile at the Widows Creek electric utility, Alabama (USA). The two vegetated cells, which were dominated by cattail (Typha latifolia L.) and soft rush (Juncus effusus L.), were very effective at removing Fe and Cd from the wastewater, but less efficient for Zn, S, B, and Mn. The concentrations were decreased by up to 99% for Fe, 91% for Cd, 63% for Zn, 61% for S, 58% for Mn, and 50% for B. Higher pH levels (>6) in standing water substantially improved the removing efficiency of the wetland for Mn only. The belowground tissues of both cattail and soft rush had high concentrations of all elements; only for Mn, however, did the concentration in the shoots exceed those in the belowground tissues. The concentrations of trace elements in fallen litter were higher than in the living shoots, but lower than in the belowground tissues. The trace element accumulation in the plants accounted for less than 2.5% of the annual loading of each trace element into the wetland. The sediments were the primary sinks for the elements removed from the wastewater. Except for Mn, the concentrations of trace elements in the upper layer (0-5 cm) of the sediment profile tended to be higher than the lower layers (5-10 and 10-15 cm). We conclude that constructed wetlands are still able to efficiently remove metals in the long term (i.e.,>10 yr after construction).     

Modeling of the denitrification/anaerobic digestion process of salmon fishery wastewater in a biofilm tubular reactor

The literature has paid scarce attention to the modeling of the denitrification-anaerobic digestion process in packed bed biofilm tubular reactors used to treat wastewater. The present study obtained a steady-state model for industrial salmon fishery wastewater treatment in a biofilm tubular reactor, including pH as a variable and the effect of biomass on hydrolysis. The axial profile of the reactor components and process efficiency were predicted with deviations below 6%. The optimal operating zone for the process was found at hydraulic retention time (HRT)>1.5d and inlet protein concentration (S(prot,0))<3000 mgTOCL(-1). Based on our results, we concluded that the removal of organic matter and nitrogen compounds depended mainly on HRT. The effluent pH was mainly affected by the C/N ratio, where a decrease increases pH. Organic matter removal was related with the anaerobic digestion process, while denitrification influenced mostly nitrate and nitrite removal.     

Evaluating microbial purification during soil treatment of wastewater with multicomponent tracer and surrogate tests

Soil treatment of wastewater has the potential to achieve high purification efficiency, yet the understanding and predictability of purification with respect to removal of viruses and other pathogens is limited. Research has been completed to quantify the removal of virus and bacteria through the use of microbial surrogates and conservative tracers during controlled experiments with three-dimensional pilot-scale soil treatment systems in the laboratory and during the testing of full-scale systems under field conditions. The surrogates and tracers employed included two viruses (MS-2 and PRD-1 bacteriophages), one bacterium (ice-nucleating active Pseudomonas), and one conservative tracer (bromide ion). Efforts have also been made to determine the relationship between viruses and fecal coliform bacteria in soil samples below the wastewater infiltrative surface, and the correlation between Escherichia coli concentrations measured in percolating soil solution as compared with those estimated from analyses of soil solids. The results suggest episodic breakthrough of virus and bacteria during soil treatment of wastewater and a 2 to 3 log (99-99.9%) removal of virus and near complete removal of fecal coliform bacteria during unsaturated flow through 60 to 90 cm of sandy medium. Results also suggest that the fate of fecal coliform bacteria may be indicative of that of viruses in soil media near the infiltrative surface receiving wastewater effluent. Concentrations of fecal coliform in percolating soil solution may be conservatively estimated from analysis of extracted soil solids.