氧化法去除燃煤烟气中Hg~0技术的研究进展

燃煤烟气中汞的排放控制是大气污染治理的研究热点之一。氧化法可将烟气中不溶于水的气态单质汞(Hg~0)转化为易溶于水的氧化态汞(Hg~(2+)),然后利用湿式吸收设备去除。综述了国内外燃煤烟气氧化法脱汞技术的研究进展,比较了非催化氧化法和催化氧化法的优势与局限,对今后的发展趋势进行了展望。指出:选择使用高效且环境友好的氧化剂以及催化剂,研发高效、低成本、可回收的金属氧化物催化剂是该领域的主要研究方向。     

内地与香港燃煤电厂大气污染物排放控制政策与标准比较

香港特区与广东省政府联合成立粤港持续发展与环保合作小组,并发表《改善珠江三角洲空气质量的联合声明》（简称＂减排联合声明＂）,同意制定合理的减排方案,共同执行管理计划。总结分析了粤、港地区在治理燃煤电厂大气污染物方面的控制政策,并对大陆与香港特区燃煤电厂大气污染物的排放标准进行比较。     

Replacement of a multiple hearth by a fluid bed incinerator the Greensboro case history

The incinerator at the T.Z. Osborne Plant in Greensboro, North Carolina burns sludge from its own waste water treatment plant and sludge pumped from the nearby North Buffalo plant. The two plants have a combined capacity of 36 million gallons per day of wastewater. Because of the age of and increasing high maintenance on the existing multiple hearth incinerator, and the need to increase treatment capacity, the Osborne plant concluded a study in 1992 evaluating its options for future municipal sewage sludge disposal. Options which were evaluated during the study included; (i) rehabilitation of the existing eight-year old multiple hearth unit; (ii) addition of a new multiple hearth; (iii) addition of a new fluid bed system; (iv) drying, composting, or land application. The chosen option, based on both economic and environmental considerations, was a new fluid bed system with a capacity of 2.55 tons per hour, approximately double that of the existing multiple hearth. Design of the new fluid bed system began in December 1994 and equipment delivery for the incineration system was begun in April 1995. Initial operation occurred in August 1996. Primary and secondary sludge, dewatered to 28% dry solids by centrifuge, is delivered by piston pumps to the twenty-foot freeboard ID incinerator. A shell and tube heat exchanger recuperates heat from the exhaust gas and preheats the combustion air to 1250°F, resulting in minimal auxiliary fuel use. The air pollution control device is a high-energy Tandem Nozzle® scrubber. Greensboro was the initial installation of this scrubber design on a fluid bed incinerator and its characteristics and performance are discussed. Ash is dewatered in an ash thickener/belt press system prior to disposal to landfill. The system includes a state of the art Programmable Logic Controller (PLC) system for computer control of the operation. The unit was commissioned in August 1996 and has been in continuous operation since that time except for a one week inspection and maintenance shutdown in February 1999. The plant operates 24 h/day, 7 days per week. The initial performance test showed the system to readily meet federal and state air emission standards. Particulate released was 0.002 grains per dry standard cubic foot, carbon monoxide was 22.5 parts per million volumetric (ppmv) and opacity was 0.4%. These results show a significant emission reduction with the fluid bed when compared to the multiple hearth. Annual tests conducted since then and continuous emission monitoring have shown the unit to be in consistent compliance. Since the fluid bed system became operational, the old multiple hearth system has been maintained on standby as a backup, but its use has not been required. Operational experience is discussed, the most interesting of which is the relatively trouble-free operation. The minor problems which occurred and their solutions are detailed. Also included is a comparison of operation and maintenance experience of the fluid bed and the multiple hearth. Current sludge disposal actual cost data are also provided including the average cost per ton of dry solids treated. The almost three years of operational experience to date has shown that the decision to install a new fluid bed system was the correct one on both an environmental and economic basis. It has provided benefits to all interested parties — the wastewater treatment plant, the regulators, the taxpayers, and the surrounding community.     

发电集团应对新火电厂大气污染物排放标准的思考

新的火电厂大气污染排放标准重点加大了对火电厂大气污染物中NOx的控制力度,收严了SO2、烟尘等污染物排放限值,增设了汞及其化合物控制指标。该标准的实施对发电企业的生存和发展带来一定的影响,为了落实新标准,发电集团应在法律法规政策及技术产业方面采取相应措施,加快除尘、脱硫、脱硝、脱汞等新技术的研究和应用,从单一污染物的总量控制向多污染物协同控制转变,积极探索和思考发电集团绿色低碳发展的道路。     

Fiberboard plant emissions control using a silent discharge plasma

A silent discharge plasma reactor was constructed to test a potential industrial application for controlling volatile organic carbon emission from fiberboard manufacturing plants. The reactor consisted of a cylindrical single barrier dielectric barrier discharge cell connected to a high‐voltage ac power supply. Various concentrations of turpene in air were introduced into the reactor under dry and wet conditions. The destruction removal efficiencies (DRE) were monitored using a gas chromatograph mass spectrometer (GCMS) and the concentrations of carbon dioxide generated from the oxidation ofturpene were monitored using a Fourier Transform Infrared Spectrometer (FTIR). It was found that 90 percent of the turpenes could be removed at modest energy densities and that adding water to the gas mix greatly enhanced the destruction of the turpenes. However, even at high energy densities, the oxidation of turpenes did not completely form carbon dioxide. The results suggest that the Silent Discharge Plasma (SDP) system can be used to control the emission of volatile organic compounds (VOCs) from fiberboard plants, but that further testing is needed to limit the emission of carbon monoxide.     

The benefits of flue gas recirculation in waste incineration

Flue gas recirculation in the incinerator combustion chamber is an operative technique that offers substantial benefits in managing waste incineration. The advantages that can be obtained are both economic and environmental and are determined by the low flow rate of fumes actually emitted if compared to the flue gas released when recirculation is not conducted. Simulations of two incineration processes, with and without flue gas recirculation, have been carried out by using a commercial flowsheeting simulator. The results of the simulations demonstrate that, from an economic point of view, the proposed technique permits a greater level of energy recovery (up to +3%) and, at the same time, lower investment costs as far as the equipment and machinery constituting the air pollution control section of the plant are concerned. At equal treatment system efficiencies, the environmental benefits stem from the decrease in the emission of atmospheric pollutants. Throughout the paper reference is made to the EC legislation in the field of environmental protection, thus ensuring the general validity in the EU of the foundations laid and conclusions drawn henceforth. A numerical example concerning mercury emission quantifies the reported considerations and illustrates that flue gas recirculation reduces emission of this pollutant by 50%.     

氮氧化物防治技术在台湾之应用及管制策略

主要探讨台湾过去二十年来,在治理氮氧化物(NOx)排放方面所作的努力,包括NOx防治技术的引进与开发,以及管制策略的制定.在防治技术的引进与开发方面,主要以在使用化石燃料的发电厂加装SCR(触媒除硝法)设备为主,此外,老的热电厂亦有加装SNCR(选择性非触媒还原法)以及采用再燃烧技术来抑制NOx的排放.进一步探讨了台湾使用的这些NOx防治技术的优缺点以及所获得的经验.在NOx管制策略的制定方面,可分为1995年以前所制定的《空气污染防制法》;1995年以后,基于污染者付费的原则,以及为了鼓励工业及发电厂加装高效率NOx污染防治设备,进一步制定《空气污染防制费收费办法》.此后,台湾固定污染源所排放的NOx已大为改善.     

SO2排污权交易在中国的发展与挑战

回顾了大气污染物排放总量控制和排污权交易在中国发展的历程.通过对美国SO2排放总量控制和排污权交易核心要素的分析,揭示了目前中国在排污权交易政策方面的欠缺.指出了排污权交易政策是帮助中国完成"十一五"计划环境目标的有效手段.     

A STUDY TO DEFINE A STANDARD HEALTH PROTECTION ZONE FOR SANITARY LANDFILL IN FU SHAN CITY

The concept of a Health Protection Zone for Sanitary Landfill of Urban Refuse has beeen established in Fu Shan City. It is based on a series of local air quality investigations and measurements. For determining major air pollutatns from a sanitary landfill, and area source dispersion model is used to calculate a fugitive emission rate of various air pollutatnts. According to the Ambient Air Quality Standard of China, (GB 3095-82), and by reference to Allowed Concentration in Habitable Areas of America and Japan, a Standard for a Health Protection Zone for Sanitary Landfill of Urban Refuse in Fu Shan has been developed.     

Critical Loads – Is There A Need For A New Concept?

The concept of critical loads has been an important andsuccessful tool for the development of control strategiesfor transboundary air pollution in Europe. The use of theconcept has led us to a situation where very few areas inEurope will have an exceedance of critical loads foracidification in 2010, indicating that the benefits offurther control acidifying substances will be lessuseful. The critical loads concept does not, however,take into account the large benefits of further controlin damaged systems but where critical loads are nolonger exceeded. In this paper we discuss the importanceof widening the critical loads concept to include thesebenefits and we propose an additional effect-relatedmeasure, Dynamic Impact Analysis, to be included infurther control strategies and assessments. With such aconcept the actual situation and its further developmentwill be included in assessments and control strategies.     

Air Quality Management in Izmir Region of Turkey as Required by Clean Air Plans

As a first step to work out an abatement plan against air pollution, a local emission inventory with 1 hr temporal and 1 km spatial resolution in the city of Izmir and its surroundings was prepared. The study area consisted of a 200 × 170 km² rectangle having the city of Izmir at the centre. The studied pollutants were total particulate matter (PM), sulfur oxides (SO_x), nitrogen oxides (NO_x), volatile organic compounds (VOC) and carbon monoxide (CO). Emissions of these pollutants were determined by estimation methods making use of suitable emission factors. Emission sources were evaluated in three categories; point, area and line sources. For year 2000 total emissions in the study area on an average day were estimated as 173 tons PM, 299 tons SOx, 136 tons NOx, 68 tons VOC and 320 tons CO. At the second part of the study, calculated emissions were transformed into air quality predictions in the area by using the Industrial Source Complex – Short Term (ISCST3) dispersion model. Model results were tested with monitoring data from urban air quality stations obtained during the year 2000. Results of the past, present and future air quality estimates in the region were discussed. In order to do so, future scenarios including various control technology applications were formulated and tested to see their effect on the future air quality.     

石油炼制行业新旧污染物排放标准的差异

分别介绍了旧标准GB 8978—1996《污水综合排放标准》、GB 16297—1996《大气污染物综合排放标准》和新标准GB 31570—2015《石油炼制工业污染物排放标准》的核心内容。从适用范围、排放限值和污染控制因子3个方面分析了石油炼制行业新旧污染物排放标准的差异。     

Mitigation of methane emission from Fakse landfill using a biowindow system

Landfills are significant sources of atmospheric methane (CH₄) that contributes to climate change, and therefore there is a need to reduce CH₄ emissions from landfills. A promising cost efficient technology is to integrate compost into landfill covers (so-called “biocovers”) to enhance biological oxidation of CH₄. A full scale biocover system to reduce CH₄ emissions was installed at Fakse landfill, Denmark using composted yard waste as active material supporting CH₄ oxidation. Ten biowindows with a total area of 5000 m² were integrated into the existing cover at the 12 ha site. To increase CH₄ load to the biowindows, leachate wells were capped, and clay was added to slopes at the site. Point measurements using flux chambers suggested in most cases that almost all CH₄ was oxidized, but more detailed studies on emissions from the site after installation of the biocover as well as measurements of total CH₄ emissions showed that a significant portion of the emission quantified in the baseline study continued unabated from the site. Total emission measurements suggested a reduction in CH₄ emission of approximately 28% at the end of the one year monitoring period. This was supported by analysis of stable carbon isotopes which showed an increase in oxidation efficiency from 16% to 41%. The project documented that integrating approaches such a whole landfill emission measurements using tracer techniques or stable carbon isotope measurements of ambient air samples are needed to document CH₄ mitigation efficiencies of biocover systems. The study also revealed that there still exist several challenges to better optimize the functionality. The most important challenges are to control gas flow and evenly distribute the gas into the biocovers.     

催化氧化技术在橡胶废气处理中的应用

采用催化氧化技术处理热塑性丁苯橡胶( SBS)生产装置D线后处理单元废气,废气的非甲烷总烃去除率和环己烷去除率均达到98％以上,非甲烷总烃质量浓度达到DB11/447-2007《炼油与石油化学工业大气污染物排放标准》的要求(小于100 mg/m3).对SBS生产装置凝聚单元进行两釜流程改三釜流程后,催化氧化反应器入口非甲烷总烃质量浓度由( 3.84～5.82)×103 mg/m3降至( 2.48～2.63)×103 mg/m3,反应器出口非甲烷总烃质量浓度均小于50 mg/m3.凝聚单元改造并采用催化氧化技术处理废气后,每年节约费用约80万元.     

State-of-the-art VOC abatement from soil-venting operations

The development of treatment technologies to limit the discharge of volatile organic compounds (VOCs) into the atmosphere has proceeded apace with the increasing use of soil venting for the remediation of contaminated soil. This article surveys the commonly-used emission control systems that have developed under air pollution control regulations in California. Emphasis is on equipment operating characteristics, typical performance results (destruction efficiencies of VOCs), and operating costs. A recently commercialized process for treating halogen-containing VOCs is described, and some operating and cost data are included.     

用铁泥制氧化铁红

研究了以染化厂废料铁泥和工业废硫酸为原料,采用高温干法制取氧化铁红的工艺,简要介绍了该法生产氧化铁红的反应机理,探讨了氧化剂,氧化时间,氧化温度等对产品质量的影响,确定了适宜工艺条件,提出了工业生产流程和尾气治理方案。     

燃煤电厂汞减排技术研究

介绍了燃煤电厂汞的3种排放形态,分析了燃煤电厂汞减排技术,如燃烧添加剂技术、吸收剂喷射技术、稳定剂固汞防溢技术、络合剂絮凝脱汞技术等。在此基础上提出了燃煤电厂汞减排技术选择影响因素,即燃煤煤质、运行工况、脱汞后副产物等,为我国电力行业汞污染控制及减排提供了参考。     

沸腾炉大气污染物的生成与排放特征分析

以20台沸腾炉(功率小于等于60 MW)的燃料特性分析数据和大气污染物的排放实测数据为基础,利用统计分析方法,研究了燃烧过程中排放的颗粒物(PM)、SO_2和NO_x初始排放浓度的影响因素,分析了沸腾炉PM、SO_2和NO_x排放现状,探讨了我国中小型沸腾炉PM、SO_2和NO_x排放管理控制的潜力和可行性.实验结果表明:在锅炉运行负荷大于等于80%的条件下,中小型沸腾炉PM的初始排放浓度基本上不受锅炉出力、过量空气系数和燃煤灰分含量的影响;燃煤的硫含量越高,SO_2初始排放浓度越高;过量空气系数越大,燃煤挥发分越低,NO_x初始排放浓度越高.     

Size distribution and number concentration of particles at the stack of a municipal waste incinerator

A large number of particles and gaseous products are generated by waste combustion processes. Of particular importance are the ultrafine particles (less than 0.1 microm in aerodynamic diameter) that are emitted in large quantities from all the combustion sources. Recent findings of toxicological and epidemiological studies indicate that fine and ultrafine particles could represent health and environmental risks. Quantifying particulate emissions from combustion sources is important: (i) to examine the source status in compliance with regulations; (ii) to create inventories of such emissions at local, regional and national levels, for developing appropriate management and control strategies in relation to air quality; (iii) to predict ambient air quality in the areas involved at the source and (iv) to perform source apportionment and exposure assessment for the human populations and/or ecological systems involved. In order to control and mitigate the particles in the view of health and environmental risk reduction, a good understanding of the relative and absolute contribution from the emission sources to the airborne concentrations is necessary. For these purposes, the concentration and size distribution of particles in terms of mass and number in a waste gas of a municipal waste incineration plant were measured in the stack gas. The mass concentrations obtained are well below the imposed daily threshold value for both incineration lines and the mass size distribution is on average very stable. The total number concentrations are between 1 x 10(5) and 2 x 10(5)particles/cm(3) and are on average relatively stable from one test to another. The measured values and the comparison with other point sources show a very low total number concentration of particles at the stack gas, revealing the importance of the flue gas treatment also for ultrafine particles. Also in respect to linear sources (high and light duty vehicles), the comparison shows a negligible emission in terms of the total number of particles.     

Evaluation of aerated biofilter systems for microbial methane oxidation of poor landfill gas

In the long-term, landfills are producing landfill gas (LFG) with low calorific values. Therefore, the utilization of LFG in combined heat and power plants (CHP) is limited to a certain period of time. A feasible method for LFG treatment is microbial CH(4) oxidation. Different materials were tested in actively aerated lab-scale bio-filter systems with a volume of 0.167 m(3). The required oxygen for the microbial CH(4) oxidation was provided through perforated probes, which distributed ambient air into the filter material. Three air input levels were installed along the height of the filter, each of them adjusted to a particular flow rate. During the tests, stable degradation rates of around 28 g/(m(3) h) in a fine-grained compost material were observed at a CH(4) inlet concentration of 30% over a period of 148 days. Compared with passive (not aerated) tests, the CH(4) oxidation rate increased by a factor of 5.5. Therefore, the enhancement of active aeration on the microbial CH(4) oxidation was confirmed. At a O(2)/CH(4) ratio of 2.5, nearly 100% of the CH(4) load was decomposed. By lowering the ratio from 2.5 to 2, the efficiency fell to values from 88% to 92%. By varying the distribution to the three air input levels, the CH(4) oxidation process was spread more evenly over the filter volume.