中国固体废物进出口格局演化分析——以废纸为例

固体废物进出口是影响我国生态文明建设及区域可持续发展的重要因素,也是最近环境管理关注的焦点。为了认识我国固体废物的进出口形势和全球固体废物贸易的格局,本文以进口量最大的固体废物——废纸为例,系统总结梳理了近年来我国废纸进出口情况的演化,绘制了2016年国际废纸贸易的流向地图,从2015年以来的废物管理政策调整出发探讨未来废纸产业的发展和转变。研究发现:(1)作为主要的造纸原材料,我国废纸进口量从1996年的137万t增加到2016年的2850万t,增长了近20倍。(2)当前全球废纸贸易突出表现为发达国家出口、发展中国家进口的格局,我国作为最大的废纸进口国,进口约占全球总量55%的废纸,美国则为最大的废纸出口国,出口约占全球总量36%的废纸。(3)应对洋垃圾入境的挑战,未来我国应在进口管控、再生资源产业发展等多个方面继续加强政策的引导和调控作用,激励国内的再生资源市场,促使废纸利用企业调整产业布局,加快产业转型。     

大型PVC生产企业清洁生产分析研究——以新疆中泰化学华泰重化工有限责任公司为例

利用工艺设备先进、自动化程度高、管理良好、生产规模在同行业中位居全国前列的新疆中泰化学华泰重化工有限责任公司聚氯乙烯树脂(PVC)生产线的清洁生产审核及后评估,通过对其生产工艺、物耗能耗、浪费环节等多方面的分析,挖掘其清洁生产潜力,并通过Vmbeao软件分析其清洁生活水平,为同类企业的清洁生产审核提供借鉴实例,并总结出具有推广价值的清洁生产技术.     

A waste management planning based on substance flow analysis

The paper describes the results of a municipal solid waste management planning based on an extensive utilization of material and substance flow analysis, combined with the results of specific life cycle assessment studies. The mass flow rates of wastes and their main chemical elements were quantified with a view to providing scientific support to the decision-making process and to ensure that the technical inputs to this process are transparent and rigorous. The role of each waste management option (recycling chains, biological and thermal treatments), as well as that of different levels of household source separation and collection (SSC), was quantitatively determined. The plant requirements were consequently evaluated, by assessing the benefits afforded by the application of high quality SSC, biological treatment of the wet organic fraction, and thermal treatment of unsorted residual waste. Landfill volumes and greenhouse gas emissions are minimized, toxic organic materials are mineralized, heavy metals are concentrated in a small fraction of the total former solid waste volume, and the accumulation of atmophilic metals in the air pollution control residues allows new recycling schemes to be designed for metals. The results also highlight that the sustainability of very high levels of SSC is reduced by the large quantities of sorting and recycling residues, amounts of toxic substances in the recycled products, as well as logistic and economic difficulties of obtaining very high interception levels. The combination of material and substance flow analysis with an environmental assessment method such as life cycle assessment appears an attractive tool-box for comparing alternative waste management technologies and scenarios, and then to support waste management decisions on both strategic and operating levels.     

Energy recovery or material recovery for MSW treatments?

Whether to recycle the recyclable fraction in the MSW (municipal solid waste) or to incinerate it for energy recovery is a debating issue. In this paper we present a simple criterion to judge what type of waste components should be recycled or incinerated with energy recovery. According to the R1 formula presented by the waste framework directive (Directive 2008/98/EC of the European Parliament), this paper calculates the energy performances of MSW waste-to-energy plants currently operated in Taiwan firstly. By using the assumed value of energy recovery efficiency and carbon emission costs, we compare the treatment methods between recycling (material recovery) and energy recovery by the cost and benefit analysis, and examine the suitability of recycling for waste fractions of paper, food waste, PET, PVC, and plastic bags/films under a variety of scenarios. The results show that food waste is more appropriate to be treated by recycling while plastic bags/films are suggested to be incinerated with energy recovery.     

Dynamic material flow analysis of zinc resources in China

Zinc is one of the most widely applied nonferrous metals in China. Study on the applications and recurrent situation of zinc resources is of great strategic importance for the sustainable development of China's economy. In this paper, a dynamic material flow analysis (MFA) method has been adopted to analyze quantificationally zinc resources in China, as well as to analyze and predict the quantity of zinc product scrap and their recycling situation. The weighted average method was applied to calculate average lifetimes of six major zinc products in China. The average lifetimes of battery, zinc oxide, zinc die-casting alloys, zinc material products, galvanized zinc and brass are 0.17, 5.3, 11.1, 12, 21 and 30 years, respectively. Assuming the lifetime of zinc product group obeys the Weibull distribution and the consumption of zinc products varies linearly with time, the future consumption and scrap generation of zinc products will increase continuously. It is expected that they would increase from 49% to 76% during 2004–2020, respectively. Assuming the recycling rate remains unchanged with time, the zinc old scrap index, both the theoretical and actual values, would continue increasing in China. The values are expected to reach 0.402 and 0.076 by 2020, respectively. Therefore, the regeneration resource of depreciated zinc is actually insufficient in China. According to the scenario analysis, the actual value of old scrap indexes is positively correlated with the recycling rate of zinc products. Because galvanized products are the largest consumption area of zinc products in China, the influence of their recycling rate on old scrap index is obviously larger than other zinc products. Through the analysis, this paper suggests that the increase of the recycling rate of zinc products could not only improve to a certain degree China's relative shortage of zinc resources, but greatly relive the supply pressure of zinc in the world.     

Integrating waste, manufacturing and industrial symbiosis: an analysis of recycling, remanufacturing and waste treatment firms in Texas

The continually increasing volume of the waste stream has led to numerous calls for strategies to close the loop on material use through industrial symbiosis strategies which direct used material and products (wastes) back to production processes. By use of a survey of recycling, remanufacturing and waste treatment firms in Texas, this paper asks if these firms can operate as a bridge between production and consumption/waste to efficiently increase the flow of used materials and products back to production processes at the local level. The results suggest that while most materials and used products are collected locally, only some can be re(consumed) locally. Moreover, the firms face negative perceptions about their activities from industry and the public at large that likely slow both the rate of entry of new firms into these markets and the expansion possibilities of existing firms. In addition, the types of conventions that characterize the interactions of more successful firms are not well developed in this sector(s). It is unlikely that recycling, remanufacturing and waste treatment firms can become central players in the production, consumption and waste cycle loop until society develops production design, marketing and consumption philosophies that include recycling and remanufacturing at a fundamental level.     

Integrating waste,manufacturing and industrial symbiosis: an analysis of recycling,remanufacturing and waste treatment firms in Texas

The continually increasing volume of the waste stream has led to numerous calls for strategies to close the loop on material use through industrial symbiosis strategies which direct used material and products (wastes) back to production processes. By use of a survey of recycling, remanufacturing and waste treatment firms in Texas, this paper asks if these firms can operate as a bridge between production and consumption/waste to efficiently increase the flow of used materials and products back to production processes at the local level. The results suggest that while most materials and used products are collected locally, only some can be re(consumed) locally. Moreover, the firms face negative perceptions about their activities from industry and the public at large that likely slow both the rate of entry of new firms into these markets and the expansion possibilities of existing firms. In addition, the types of conventions that characterize the interactions of more successful firms are not well developed in this sector(s). It is unlikely that recycling, remanufacturing and waste treatment firms can become central players in the production, consumption and waste cycle loop until society develops production design, marketing and consumption philosophies that include recycling and remanufacturing at a fundamental level.     

Facilitating substance phase‐out through material information systems and improving environmental impacts in the recycling stage of a product

The amount of electrical and electronic products is increasing rapidly, and this inevitably leads to the generation of large quantities of waste from these goods. Some of the generated e‐waste ends up in regions with sub‐standard recycling systems and may be processed under poor conditions. During uncontrolled incineration, halogenated dioxins and furans can be generated from brominated and chlorinated compounds in the products. In order to reduce the health and environmental risks involved in the recycling stage of the life cycle of electronics, an effective design‐for‐environment process must be established during the product development phase. Knowledge of the chemical substances in the product is crucial to being able to make informed decisions. Through full knowledge of the material content of procured components, phase‐outs of unwanted substances, such as halogenated substances, can be performed in an effective manner. Therefore, information is the key to success in phasing‐out substances; facilitating compliance of legal provisions for manufacturers of electrical and electronic devices; and improving the environmental footprint of products as they reach the end of the life cycle. After an introduction to the challenges of electronics waste management, this paper describes supply chain information systems and how they are used to facilitate substance phase‐outs in the electronics industry. Sony Ericsson has been working with phase‐outs of unwanted substances since it was founded in 2001. Through the introduction of a material declaration system that keeps track of all substances in the components used in the company's products, Sony Ericsson has been able to replace unwanted substances to improve environmental impacts at the recycling stage of a product.     

Implications for the carrying capacity of lithium reserve in China

China is a major supplier of rechargeable lithium batteries for the world's consumer electronics (CE) and electric vehicles (EV). Consequently, China's domestic lithium resources are being rapidly depleted, and the development of the CE and EV industries will be vulnerable to the carrying capacity of China's lithium reserves. Here we find that lithium demand in China will increase significantly due to the continuing growth of demand for CE and the briskly emerging market for EV, resulting in a short carrying duration of lithium, even with full recycling of end-of-life lithium products. With these applications increasing at an annual rate of 7%, the carrying duration of lithium reserves will oblige the end-of-life products recycling with a 90% rate. To sustain the lithium industry, one approach would be to develop the collection system and recycling technology of lithium-containing waste for closed-loop lithium recycling, and other future endeavors should include developing the low-lithium battery and optimizing lithium industrial structure.     

Dynamic material flow analysis of steel resources in Korea

Material flow analysis (MFA) is an evaluation technique that systematically identifies the flows and stocks of materials within predefined spatial and temporal boundaries. In this paper, the steel resources in Korea are investigated using dynamic MFA. Iron ore and steel scrap are added as raw material components during the production processes of steel, which is then used in a variety of product groups such as construction products, transportation equipment, machinery/metal products, electrical/electronic devices, and other products through fabrication and manufacturing processes. When such product groups are discarded, they are either recycled or landfilled. With consideration for the lifetimes of various product groups in conjunction with steel resource flows in Korea, dynamic MFA is conducted on the flows of steel stock change and annual scrap generation. By 2020, these two flows are expected to increase by as much as 40% and 30%, respectively, compared to 2008, with transportation equipment, in particular, envisaged to experience high growth. At the current recycling rate, however, it will be hard to meet future scrap demand. According to the scenario analysis, 100% of this future scrap demand can be supplied domestically if the recycling rate is increased to over 70% for all product groups, except construction products and transportation equipment, which already have high recycling rates. By 2020, the reduction in scrap importation costs is projected to offer a financial gain of 2.3 billion dollars.     

Modeling materials flow of waste concrete from construction and demolition wastes in Taiwan

Material flows of concrete from construction and demolition (C&D) waste in Taiwan have grown considerably over the last two decades, Hsiao et al. (2001). This increased flow puts pressure on limited national disposal capacity and has indirectly caused ecological damage to domestic riparian zones used as sources of natural aggregate. Using existing statistics and literature sources for C&D waste generation in Taiwan we have developed a dynamic model of domestic material flows of concrete waste and employ statistical analyses to obtain projections of future material flows. Our major findings are: (1) Taiwan’s rate of waste concrete generation in 2001 for the residential and commercial construction industry was approximately 2.4 Million Metric Tons (MMT) per year, averaging 0.11 metric tons of waste concrete generated annually by each Taiwanese; (2) Around the year 2009, the national rate will more than triple to exceed the spike in C&D concrete waste generation that occurred after the Chi Chi earthquake 9/21/99, 8.5 MMT. (3) Aside from pilot-scale development of waste concrete utilization technology, nationwide recycling rates remain negligible. Without resource recovery, the volume of C&D waste generation by 2009 is projected to occupy nearly 7% of all existing and planned domestic landfill capacity. A target is established to raise resource recovery rates for waste concrete to 50% by 2005 and a 100% nationwide recycling rate by 2009.     

废弃LCD的处理及其铟的回收技术

伴随着我国电子产业的蓬勃发展,电子产品生产及其废弃产生的金属资源浪费问题也日趋严重,国家在“十二五”规划中提出了新型液晶显示屏（LCD）的开发及其资源化回收处理,可见LCD的处理和从其废弃物中提取铟的技术亟待深入研究。本文介绍了LCD显示屏和主要含铟部件ITO材料之间的关系、生产和使用状况,重点详述了LCD和ITO材料资源化处理的研究现状,系统地总结了铟的回收方法,并展望了未来电子废弃物的处理方向。     

Reuse of ornamental rock-cutting waste in aluminous porcelain

Large amounts of solid wastes are discarded in the ornamental rocks industry. This work investigates the incorporation of ornamental rock-cutting waste as a raw material into an aluminous porcelain body, replacing natural feldspar material by up to 35 wt.%. Formulations containing rock-cutting waste were pressed and sintered at 1350 °C. The porcelain pieces were tested to determine their properties (linear shrinkage, water absorption, apparent density, mechanical strength, and electrical resistivity). Development of the microstructure was followed by scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses. The results showed that ornamental rock-cutting waste could be used in aluminous porcelains, in the range up to 10 wt.%, as a partial replacement for traditional flux material, resulting in a valid route for management of this abundant waste.     

Economic viability of packaging waste recycling systems: A comparison between Belgium and Portugal

The Packaging and Packaging Waste Directive has had an undeniable impact on waste management throughout the European Union. Whereas recycling and recovery targets are the same, member states still enjoy a considerable degree of freedom with respect to the practical organization and management strategies adopted. Nevertheless, in all cases, the industry (which brings packaging material onto the market) should be responsible for the costs associated with packaging waste recycling/recovery (following the extended producer responsibility principle). The current paper compares and contrasts the institutional frameworks and financial costs and benefits of waste management operators for Belgium and Portugal. The unit costs of selective collection and sorting of packaging waste are provided for both countries. In Belgium, the costs of recycling seem to be fully supported by the industry (through Fost Plus, the national Green Dot agency). In Portugal the fairness of the recycling system depends on the perspective adopted (economic or strictly financial). Adopting a strictly financial perspective, it seems that Sociedade Ponto Verde (SPV, the Portuguese Green Dot agency) should increase the transfers to local authorities. However, the conclusions differ for this country if the avoided costs with refuse collection and other treatment are taken into account.     

Phosphorus recovery and recycling from waste: An appraisal based on a French case study

Phosphate rocks, used for phosphorus (P) fertilizer production, are a non-renewable resource at the human time scale. Their depletion at the global scale may threaten global food and feed security. To prevent this depletion, improved P resource recycling from food chain waste to agricultural soils and to the food and feed industry is often presented as a serious option. However, waste streams are often complex and their recycling efficiency is poorly characterized. The aim of this paper is to estimate the P recovery and recycling potential from waste, considering France as a case study. We assessed the P flows in food processing waste, household wastewater and municipal waste at the country scale using a substance flow analysis for the year 2006. We also quantified the P recycling efficiency as the fraction of P in waste that ultimately reached agricultural soils or was recycled in the food and feed industry. Efforts were made to limit data uncertainty by cross-checking multiple data sources concerning P content in waste materials. Results showed that, in general, P recovery in waste was high but that the overall P recycling efficiency was only 51% at the country scale. In particular, P recycling efficiency was 75% for industrial waste, 43% for household wastewater and 47% for municipal waste. The remaining P was discharged into water bodies or landfilled, causing P-induced environmental problems as well as losses of nutrient resources. Major P losses were through food waste (which amounted to 39% of P in available food) and treated wastewater, and the findings were confirmed through cross-checking with alternative data sources. Options for improving P resource recycling and, thereby, reducing P fertilizer use were quantified but appeared to be less promising than scenarios based on reduced food waste or redesigned agricultural systems.     

我国废旧机动车回收产生的二次污染及防治对策研究述评

随着我国社会经济的飞速发展,国民生活水平的提高,汽车行业飞速发展,我国汽车保有量大增,由废旧汽车带来的环境污染与安全压力也将会随之增大。目前,我国废旧汽车资源化关键技术落后,没有成套适用技术,维修方法粗糙,因此,造成的二次污染严重。综述了国内外废旧机动车回收产生的二次污染情况,总结国外的发展经验,提出适合我国国情的废旧机动车回收行业二次污染控制意见。     

Waste materials for activated carbon preparation and its use in aqueous-phase treatment: a review

Commercial activated carbon is a preferred adsorbent for the removal of micropollutants from the aqueous phase; however, its widespread use is restricted due to high associated costs. To decrease treatment costs, attempts have been made to find inexpensive alternative activated carbon (AC) precursors, such as waste materials. Some reviews report the use of waste materials for the preparation of AC; however, these studies are restricted to either type of wastes, preparation procedures, or specific aqueous-phase applications. The present work reviews and evaluates literature dedicated both to the preparation of AC by recycling different types of waste materials and also to its application in various aqueous-phase treatments. It is clear that conventional (from agriculture and wood industry) and non-conventional (from municipal and industrial activities) wastes can be used to prepare AC, that can be applied in various aqueous treatment processes, namely to remove organic pollutants, dyes, volatile organic compounds, and heavy metals. Moreover, high surface areas can be obtained using either physical or chemical activation; however, combined treatments might enhance the surface properties of the adsorbent, therefore increasing its adsorption capacity. It is evident from the revision made that AC prepared from both conventional and non-conventional wastes might effectively compete with the commercial ones. This happens mostly when the activation procedures are optimized considering both the raw material used to produce the carbons and the contaminants to be removed.     

Management of old landfills by utilizing forest and energy industry waste flows

The lack of landfill capacity, forthcoming EU waste disposal and landfill management legislation and the use of non-renewable and energy intensive natural resources for the end-treatment of old landfills increase pressures to develop new landfill management methods. This paper considers a method for the end-management of old landfills in Finland, which is based on the utilization of forest and paper industry waste flows, wastes from paper recycling (de-inking) and wastes from forest industry energy production. Fibre clay wastes from paper mills, de-inking sludges from de-inking of recovered waste paper and incineration ash from forest industry power plants serve to substitute the use of natural clay for the building of landfill structures for closed landfills. Arguably, this method is preferable to existing practices of natural clay use for landfill building, because it (1) substitutes non-renewable natural clay, (2) consumes less energy and generates less CO2 emissions than the use of natural clay, and (3) eliminates considerable amounts of wastes from paper production, paper consumption and from forest industry energy production. Some difficulties in the application of the method are considered and the waste flow utilization is incorporated into a local forest industry recycling network.     

我国城市生活垃圾回收利用率测算及其统计数据收集对策

我国将生活垃圾分类收集定位为重要民生工程和生态文明建设的工作内容,并对实施生活垃圾强制分类的示范城市明确提出了"生活垃圾回收利用率"的绩效考核目标。由于城市生活垃圾处理和再生资源回收利用由不同职能部门负责管理,不同来源的生活垃圾回收利用统计数据未有效整合,目前还缺乏我国城市生活垃圾回收利用率指标测算的相关研究。本文界定了"生活垃圾回收利用率"的科学内涵,并以城市建设、再生资源利用等统计资料和物质流分析文献为基础,初步测算了全国尺度的城市生活垃圾回收利用率。研究表明,我国2006—2015年的城市生活垃圾回收利用率从12.1%上升至17.0%,然后又缓慢下降至15.6%,由于数据缺乏,该数值可能在-28%~+32%波动。生活垃圾中回收利用量较大的可再生资源分别为废纸、废塑料、废钢铁、废玻璃等。本文还分析了目前测算生活垃圾回收利用率的数据不确定性和局限性,提出了面向生活垃圾分类管理实际评价的统计数据收集对策。     

Concrete block production from construction and demolition waste in Tanzania

In Tanzania, construction and demolition (C&D) waste is not recycled and knowledge on how it can be recycled especially into valuable products like building materials are still limited. This study aimed at investigating the possibility of recycling the C&D waste (mainly cementitious rubble) into building material in Tanzania. The building materials produced from C&D waste was concrete blocks. The concrete blocks were required to have a load bearing capacity that meets the building material standards and specifications. Eight C&D waste samples were collected from C&D building sites, transported to the recycling site, crushed, and screened (sieved) to get the required recycled aggregates. Natural aggregates were also used as control. The recycled aggregates were tested in the laboratory following the standard methods as specified in Tanzanian standards. The physical, mechanical and chemical characteristics were determined. The physical and mechanical results showed that recycled aggregates were weaker than natural aggregates. However, chemically they were close to natural aggregates and therefore suitable for use in new concrete block production. In the production process, each experiment utilized 100% recycled aggregates for both fine and coarse portions to replace natural aggregates. The Fuller's maximum density theory was used to determine the mix proportions of materials in which a method that specifies concrete mix by system of proportion or ratio was used. The concrete blocks production processes included batching, mixing (that was done manually to get homogeneous material), compacting and moulding by hand machine and curing in water. After 28 days of curing, the concrete blocks were tested in the laboratory on compressive strength, water absorption ratio and density. The results showed that the blocks produced with 100% recycled aggregates were weaker than those with natural aggregates. However, the results also showed that there is a possibility of recycling the C&D waste into building material because 85% of the tested concrete block specimens from recycled aggregates achieved a compressive strength of 7 N/mm², which is defined as the minimum required load bearing capacity in Tanzania. Therefore, the C&D waste could be a potential resource for building material production for sustainable construction in Tanzania rather than discarding it. Further work should focus on the economic feasibility of production of concrete blocks with recycled aggregates in Tanzania.