Sound management of brominated flame retarded (BFR) plastics from electronic wastes: State of the art and options in Nigeria

Management of flame retarded plastics from waste electrical and electronic equipment (WEEE) has been posing a major challenge to waste management experts because of the potential environmental contamination issues especially the formation of polybrominated-dioxins and -furans (PBDD/F) during processing. In Nigeria, large quantities of electronic waste (e-waste) are currently being managed—a significant quantity of which is imported illegally as secondhand electronics. As much as 75% of these illegal imports are never reused but are rather discarded. These waste electronic devices are mostly older equipment that contains brominated flame retardants (BFRs) such as penta-brominated diphenyl ethers (PBDEs), and polybrominated biphenyls (PBBs) which are presently banned in Europe under the EU WEEE and RoHS Directives. Risk assessment studies found both to be persistent, bio-accumulative and toxic. The present management practices for waste plastics from WEEE in Nigeria, such as open burning and disposal at open dumps, creates potential for serious environmental pollution. This paper reviews the options in the environmentally sound management of waste plastics from electronic wastes. Options available include mechanical recycling, reprocessing into chemicals (chemical feedstock recycling) and energy recovery. The Creasolv^® and Centrevap^® processes, which are the outcome of the extensive research at achieving sound management of waste plastics from WEEE in Europe, are also reviewed. These are solvent-based methods of removing BFRs and they presently offer the best commercial and environmental option in the sound management of waste BFR-containing plastics. Because these developments have not been commercialized, WEEE and WEEE plastics are still being exported to developing countries. The industrial application of these processes and the development of eco-friendlier alternative flame retardants will help assure sound management of WEEE plastics.     

2010年上海世博会垃圾组分的预测

为了便于2010年上海世博会期间生活垃圾的处理与处置，选择了和世博园区垃圾性质相近似的南京路步行街为参照区，进行垃圾组分的调研，预测模拟世博园区垃圾的组成与性质。研究结果表明：南京路步行街垃圾中食物垃圾占50％左右，塑料和纸张占45％左右，而一般的城市生活垃圾中塑料和纸张只占20％～30％左右，可见对于类似的垃圾资源化程度非常高。因此对于世博园垃圾进行分选，实现各组分垃圾的分流，可以更好地实现垃圾的资源化、减量化。     

Municipal solid waste generation in Kathmandu, Nepal

Waste stream characteristics must be understood to tackle waste management problems in Kathmandu Metropolitan City (KMC), Nepal. Three-stage stratified cluster sampling was used to evaluate solid waste data collected from 336 households in KMC. This information was combined with data collected regarding waste from restaurants, hotels, schools and streets. The study found that 497.3 g capita(-1) day(-1) of solid waste was generated from households and 48.5, 113.3 and 26.1 kg facility(-1) day(-1) of waste was generated from restaurants, hotels and schools, respectively. Street litter measured 69.3 metric tons day(-1). The average municipal solid waste generation rate was 523.8 metric tons day(-1) or 0.66 kg capita(-1) day(-1) as compared to the 320 metric tons day(-1) reported by the city. The coefficient of correlation between the number of people and the amount of waste produced was 0.94. Key household waste constituents included 71% organic wastes, 12% plastics, 7.5% paper and paper products, 5% dirt and construction debris and 1% hazardous wastes. Although the waste composition varied depending on the source, the composition analysis of waste from restaurants, hotels, schools and streets showed a high percentage of organic wastes. These numbers suggest a greater potential for recovery of organic wastes via composting and there is an opportunity for recycling. Because there is no previous inquiry of this scale in reporting comprehensive municipal solid waste generation in Nepal, this study can be treated as a baseline for other Nepalese municipalities.     

Value from shredder waste: Ongoing limitations in the UK

Shredder residue is the residue from the shredding of end-of-life vehicles and white goods, after removal of the main metals. Approximately 850,000 tonnes of shredder waste is produced in the UK each year, and historically sent to landfill. Due to European legislation such as the End-of-Life Vehicle (ELV) Directive and the Landfill Directive there is pressure to minimise this waste through recycling and recovery.In this paper, primary data are presented showing that 40% of materials are potentially recoverable in the coarser fraction of UK automotive shredder residue (>30 mm). Barriers to such recycling are discussed in the context of several recent drivers, including this waste's possible reclassification as hazardous.The lack of full and timely implementation of the ELV Directive in the UK has made it an ineffective driver, and it is now unlikely that its 2006 recycling targets will be met as intended.     

Risk explicit interval linear programming model for long-term planning of vehicle recycling in the EU legislative context under uncertainty

With the number of vehicles expected to increase to 1.85 billion by 2030 and the scrap generated from end-of-life vehicles (ELVs) expected to be 3.71 billion tonnes, there is a strong motivation to properly process the flow of these materials. The EU Directive on end-of-life vehicles (EU ELV Directive) aims to increase recovery and recycling rates of ELVs in order to reduce waste and improve environmental performances. Long-term optimization planning of vehicle recycling is increasingly important. However, there is a lack of research of uncertainties in the vehicle recycling system, none of the previous studies analyzed the linkage and trade-offs between decision risk and system performances, and no previous research was reported on interval-based programming for vehicle recycling planning problem. In order to meet the imposed eco-efficiency quotas, maximize system profit and minimize decision risk, and at the same time fill the identified research gaps, a risk explicit interval linear programming model for optimal long-term planning in the EU vehicle recycling factories was developed. It can create optimal plans for procuring vehicle hulks, sorting of generated material fractions, allocation of sorted waste flows and allocation of sorted metals for desired value of the system aspiration level. A numerical study demonstrated the potentials and applicability of the proposed model. Vehicle recycling factories aim at reaching the highest possible level of quantity and quality of sorted metal flows. The future eco-efficiency quotas will not endanger their business. The success of the final phase of implementation of the EU ELV Directive is not jeopardized, because even the future eco-efficiency quotas were reached in all created test problems. Quantity of land-filled wastes will be radically reduced after January 1, 2015. The model results and trade-offs would be valuable for supporting the EU vehicle recycling factories in creating optimal long-term production strategies and reducing the risk for uncertain situations.     

Mechanical performance of woodfibre–waste plastic composite materials

Plastic products used for packaging are often discarded after a single use resulting in an inexhaustible supply of waste polymeric materials. The stiffness and strength of polymeric materials have been known to improve with the addition of lignocellulosic fibres available in abundance in nature. Hence, composite materials containing natural fibres and waste plastics would result in the reduction of solid wastes and the use of cheap, renewable resources. Composite specimens, consisting of waste plastics obtained from a Kerbside collection (high density polyethylene (HDPE) waste, Janitorial waste, Kerbside waste I and Kerbside waste II) and Pinus radiata woodfibres (medium density fibres (MDF)), have been produced through melt blending and injection moulding. The effects of fibre content, matrix type and interfacial bonding on the tensile and flexural properties of these composite materials have been determined through extensive testing at various conditions. The mechanical properties of these composites at room temperature and humidity depend on the amount of woodfibres, the mechanical properties of the waste plastics used and the presence of a suitable coupling agent. The tensile strengths of MDF/waste plastic composites do not generally change with fibre content except for 40% MDF/HDPE waste and 40% MDF/Kerbside waste II (plus 1% Epolene™) composites, where the tensile strengths increase by about 25% compared to those of the corresponding waste plastics. Flexural strengths of MDF/waste plastic composites increase with the addition of medium density fibres with the exception of MDF/Kerbside waste I composites. The tensile and flexural moduli of MDF/waste plastic composites mostly increase with increasing fibre content.     

Health-care waste management in India.

Health-care waste management in India is receiving greater attention due to recent regulations (the Biomedical Wastes (Management & Handling) Rules, 1998). The prevailing situation is analysed covering various issues like quantities and proportion of different constituents of wastes, handling, treatment and disposal methods in various health-care units (HCUs). The waste generation rate ranges between 0.5 and 2.0 kg bed-1 day-1. It is estimated that annually about 0.33 million tonnes of waste are generated in India. The solid waste from the hospitals consists of bandages, linen and other infectious waste (30-35%), plastics (7-10%), disposable syringes (0.3-0.5%), glass (3-5%) and other general wastes including food (40-45%). In general, the wastes are collected in a mixed form, transported and disposed of along with municipal solid wastes. At many places, authorities are failing to install appropriate systems for a variety of reasons, such as non-availability of appropriate technologies, inadequate financial resources and absence of professional training on waste management. Hazards associated with health-care waste management and shortcomings in the existing system are identified. The rules for management and handling of biomedical wastes are summarised, giving the categories of different wastes, suggested storage containers including colour-coding and treatment options. Existing and proposed systems of health-care waste management are described. A waste-management plan for health-care establishments is also proposed, which includes institutional arrangements, appropriate technologies, operational plans, financial management and the drawing up of appropriate staff training programmes.     

A future perspective on lithium-ion battery waste flows from electric vehicles

As a proactive step towards understanding future waste management challenges, this paper presents a future oriented material flow analysis (MFA) used to estimate the volume of lithium-ion battery (LIB) wastes to be potentially generated in the United States due to electric vehicle (EV) deployment in the near and long term future. Because future adoption of LIB and EV technology is uncertain, a set of scenarios was developed to bound the parameters most influential to the MFA model and to forecast “low,” “baseline,” and “high” projections of future end-of-life battery outflows from years 2015 to 2040. These models were implemented using technology forecasts, technical literature, and bench-scale data characterizing battery material composition. Considering the range from the most conservative to most extreme estimates, a cumulative outflow between 0.33 million metric tons and 4 million metric tons of lithium-ion cells could be generated between 2015 and 2040. Of this waste stream, only 42% of the expected materials (by weight) is currently recycled in the U.S., including metals such as aluminum, cobalt, copper, nickel, and steel. Another 10% of the projected EV battery waste stream (by weight) includes two high value materials that are currently not recycled at a significant rate: lithium and manganese. The remaining fraction of this waste stream will include materials with low recycling potential, for which safe disposal routes must be identified. Results also indicate that because of the potential “lifespan mismatch” between battery packs and the vehicles in which they are used, batteries with high reuse potential may also be entering the waste stream. As such, a robust end-of-life battery management system must include an increase in reuse avenues, expanded recycling capacity, and ultimate disposal routes that minimize risk to human and environmental health.     

Environmental impacts and use of brominated flame retardants in electrical and electronic equipment

Management of waste electrical and electronic equipment (WEEE) or e-waste is becoming a major issue as around 20–50 million tons of such waste is generated worldwide and increasing at a higher rate than other solid waste streams. Electrical and electronic equipment (EEE) contains over 1,000 materials of which brominated flame retardants (BFRs) such as polybrominated biphenyls (PBBs) and polybrominated diphenyl ethers (PBDEs) have been the target of the regulators forcing manufacturers to adopt halogen-free flame retardants. As far as these alternatives are concerned, key consideration should be its performance during the whole life cycle through design, use and end-of-life management. The global halogen-free flame retardant movement has reached a point of no return. The most important issue as far as the environment is concerned, for which the transformation to halogen-free retardants was initially targeted, is to make sure that life span of the EEE using the alternatives to BFRs is not shortened thereby resulting in unforeseen increases in e-waste to deal with. The aim of this article is to investigate the environmental issues and current developments related to the use of BFRs in EEE manufacture. It describes the sources, toxicity and human exposure of BFRs, EOL management such as recycling and thermal treatments, exposure of BFRs from e-waste processing facilities and the environment around them and examines the developments and feasibility of the alternatives to BFR in EEE manufacture.     

Survey of household waste composition and quantities in Abuja,Nigeria

Inadequate management of household solid waste is a serious problem in many developing cities. The study aimed to evaluate the quantities and composition of household solid waste generation in Abuja within different socioeconomic groups. The wastes from 74 households across different socioeconomic levels in Abuja were collected, weighted and classified on a daily basis for seven days in February 2012. The result showed that the average daily per capita household waste generation is 0.634 kg/capita/day. The characteristic of solid waste in Abuja are typical for the developing cities and dominated by organic waste. Households waste consisted of 63.6% organic waste, 9.7% paper, 8.7% plastics, 3.2% metal, 2.6% glass, 1.6% textile and 10.6% others (unclassified) and the bulk density was 240 kg/m³. The evaluation of relationship between income and daily per capita household waste generation showed a positive relationship. The study revealed a statistically significant difference between household size and daily per capita household waste generation in high-income group; a slight significant difference between household size and daily per capita household waste generation in medium income group and no statistically significant difference between household size and daily per capita household waste generation in low-income group.     

Electronic waste recycling: A review of U.S. infrastructure and technology options

The useful life of consumer electronic devices is relatively short, and decreasing as a result of rapid changes in equipment features and capabilities. This creates a large waste stream of obsolete electronic equipment, electronic waste (e-waste).Even though there are conventional disposal methods for e-waste, these methods have disadvantages from both the economic and environmental viewpoints. As a result, new e-waste management options need to be considered, for example, recycling. But electronic recycling has a short history, so there is not yet a solid infrastructure in place.In this paper, the first half describes trends in the amount of e-waste, existing recycling programs, and collection methods. The second half describes various methods available to recover materials from e-waste. In particular, various recycling technologies for the glass, plastics, and metals found in e-waste are discussed. For glass, glass-to-glass recycling and glass-to-lead recycling technologies are presented. For plastics, chemical (feedstock) recycling, mechanical recycling, and thermal recycling methods are analyzed. Recovery processes for copper, lead, and precious metals such as silver, gold, platinum, and palladium are reviewed. These processes are described and compared on the basis of available technologies, resources, and material input–output systems.     

Public participation in plastics recycling schemes

Without public contributions, recycling from domestic waste would not be possible. In order to support recycling projects it is important to try to understand who recycles, how they recycle, and why they recycle. This paper presents the results of a structured survey of 500 members of the public served by schemes to collect plastics waste for recycling. Data were gathered on the characteristics, behaviours and motivations of recyclers. The authors also sought to discover how the public perceive plastics compared to other materials, and as a recyclable material. Responses were collected in such a way that the awareness of the recyclability of materials could be compared with the recycling behaviour of respondents. An element of comparison was introduced between those served by a system of bottle banks (bring scheme) and those covered by a household collection (collect scheme). The survey results are reported and their implications for the management of post-consumer plastics waste collection schemes are discussed.     

Reclamation of wastes contaminated by copper,lead, and zinc

Waste materials containing toxic levels of copper, lead, and zinc, such as mine and smelter wastes, present difficult conditions for the establishment of vegetation. This article reviews the many attempts which have been made to reclaim these wastes. Inert wastes from mining and quarrying operations, such as slate quarry waste and certain colliery shales, seem to be good materials for reclaiming wastes contaminated by copper, lead, and zinc. Organic wastes, such as sewage sludge and domestic refuse, may provide only a temporary visual improvement and stabilization of the toxic materials.Nontolerant plant materials may often be planted directly on modern waste materials, which are less toxic than they were in the past. However, tolerant plant materials are needed for revegetating waste materials produced by early and more primitive extraction methods.     

Current Levels and Management of Solid Wastes in Nigeria

Solid waste is of serious concern in developing countries because of its high rate of generation and the low‐end quality of its management. Inefficient handling of solid wastes may result in deterioration of environmental quality, but it can also result in loss of potential resources. This study reviews current solid waste generation and management in Nigeria and the need for an effective collection, recovery, and recycling policy. Our review is based on literature searches and personal field surveys. Observations showed that uncontrolled electronic waste (e‐waste), agricultural‐waste (agro‐waste), scrap metals, waste polymers, and waste from the transportation sector are prevalent in Nigeria. Recent collection rates were less than 50% of the total solid waste generated (i.e., approximately 40% was collected). With an effective collection system and appropriate policies, the abundance of solid waste in the country could present material recovery and recycling opportunities that would boost the economy and move Nigeria closer to sustainable resource management.     

The recycling of rare earths from waste tricolor phosphors in fluorescent lamps: A review of processes and technologies

Rare earths have become the most important strategic resources, widely used as functional materials in industry and many other aspects of life due to its optical, electrical, and magnetic characteristics. As a consequence, a considerable number of wastes containing rare earths such as abandoned fluorescent lamps are generated and lost. Considering the scarcity in availability and supply of certain raw materials, waste tricolor phosphors are viewed as potential resources that can be mined in urban areas for their reutilization as rare earths. A number of studies in this area have been carried out all over the world.The purpose of this paper is to review the current status of recycling technologies of rare earths from waste tricolor phosphors in fluorescent lamps. The main characteristics of the tricolor phosphors were introduced, and also a detail review of the typical single recycling and reusing technologies with regard to waste tricolor phosphors was carried out in present paper. After that, several combined recycling processes and technologies were evaluated. Based on the review, the prospects of recycling technologies were suggested.     

A review on tertiary recycling of high-density polyethylene to fuel

Plastics have become an indispensable ingredient of human life. They are non-biodegradable polymers of mostly containing carbon, hydrogen, and few other elements such as chlorine, nitrogen etc. Rapid growth of the world population led to increased demand of commodity plastics. High density poly ethylene is one of the largest used commodity plastics due to its vast applications in many fields. Due to its non bio degradability and low life, HDPE contributes significantly to the problem of Municipal Waste Management. To avert environment pollution of HDPE wastes, they must be recycled and recovered. On the other hand, steady depletion of fossil fuel and increased energy demand, motivated the researchers and technologists to search and develop different energy sources. Waste to energy has been a significant way to utilize the waste sustainably, simultaneously add to meet the energy demand. Plastics being petrochemical origin have inherently high calorific value. Thus they can be converted back to useful energy. Many researches have been carried out to convert the waste plastics into liquid fuel by thermal and catalytic pyrolysis and this has led to establishment of a number of successful firms converting waste plastics to liquid fuels. This paper reviews the production and consumption HDPE, different methods of recycling of plastic with special reference to chemical degradation of HDPE to fuel. This also focuses on different factors that affect these degradations, the kinetics and mechanism of this reaction.     

Effects of an educational campaign on public environmental attitudes and behaviour in Poland

This paper examines the effects of educational campaigns on municipal solid waste management in Jasło City (Poland). In Jasło, a separate waste collection system for recyclables was introduced 11 years ago. Although household segregation was extensively promoted, the quality of recycled materials collected remained low. The City Council decided in 1999 to adopt a British approach to public education, based on home advisors (selected from the local schools and trained on the sustainable waste management principles) visiting as many households as possible, informing residents about the local waste segregation system, conducting a short survey about residential attitudes and behaviour, and providing people with appropriate educational materials. In 2003 and 2004, home advisors visited 687 households in the private housing estates situated in 37 streets of the city. Their effectiveness and the tonnage of recyclables segregated were monitored across the city. The educational campaign has proved a success, resulting in an increase in recycled wastes collected and the number of inhabitants participating, with the home advisors having positively influenced the way residents think and act towards the wastes they produce. Residents valued the home advisors and appreciated the involvement of young people in the campaign. The education campaign also impacted positively upon the students’ (home advisors) knowledge about waste issues, and provided opportunities for students’ relatives and the whole local community to become more environmentally conscious, through the process of intergenerational communication and influence.     

Integrating waste,manufacturing and industrial symbiosis: an analysis of recycling,remanufacturing and waste treatment firms in Texas

The continually increasing volume of the waste stream has led to numerous calls for strategies to close the loop on material use through industrial symbiosis strategies which direct used material and products (wastes) back to production processes. By use of a survey of recycling, remanufacturing and waste treatment firms in Texas, this paper asks if these firms can operate as a bridge between production and consumption/waste to efficiently increase the flow of used materials and products back to production processes at the local level. The results suggest that while most materials and used products are collected locally, only some can be re(consumed) locally. Moreover, the firms face negative perceptions about their activities from industry and the public at large that likely slow both the rate of entry of new firms into these markets and the expansion possibilities of existing firms. In addition, the types of conventions that characterize the interactions of more successful firms are not well developed in this sector(s). It is unlikely that recycling, remanufacturing and waste treatment firms can become central players in the production, consumption and waste cycle loop until society develops production design, marketing and consumption philosophies that include recycling and remanufacturing at a fundamental level.     

Integrating waste, manufacturing and industrial symbiosis: an analysis of recycling, remanufacturing and waste treatment firms in Texas

The continually increasing volume of the waste stream has led to numerous calls for strategies to close the loop on material use through industrial symbiosis strategies which direct used material and products (wastes) back to production processes. By use of a survey of recycling, remanufacturing and waste treatment firms in Texas, this paper asks if these firms can operate as a bridge between production and consumption/waste to efficiently increase the flow of used materials and products back to production processes at the local level. The results suggest that while most materials and used products are collected locally, only some can be re(consumed) locally. Moreover, the firms face negative perceptions about their activities from industry and the public at large that likely slow both the rate of entry of new firms into these markets and the expansion possibilities of existing firms. In addition, the types of conventions that characterize the interactions of more successful firms are not well developed in this sector(s). It is unlikely that recycling, remanufacturing and waste treatment firms can become central players in the production, consumption and waste cycle loop until society develops production design, marketing and consumption philosophies that include recycling and remanufacturing at a fundamental level.     

Corporate waste accounting at PSE&G: Bringing a companywide system on-line

Waste accounting has become a necessary practice for companies endeavoring to track their wastes toward realizing discrete waste minimization and pollution prevention objectives. Measurement systems and program initiatives certainly must be tested to find out what will repeatedly work for and best serve a company. Public Service Electric and Gas Company (PSE&G) has committed to revolutionizing the processes of managing materials, wastes, and their associated information. In laying out their strategic plan, company representatives specified the need for a companywide waste accounting system to enable them to monitor progress toward achieving two important short-term waste management targets by the close of 1995. Together with the Electric Power Research Institute, PSE&G is implementing a four-year program to install such a system. The results of the first year-and-a-half's work are reported in this article. The purpose of this article is to discuss the results of implementing a waste accounting system on a utility companywide basis. We will address the experience of bringing such a system on-line at PSE&G. The Electric Power Research Institute (EPRI) previously developed a framework and approach for measuring the performance of utility pollution prevention programs called waste accounting, including the development of a software program called Accounting Software Application for Pollution Prevention or ASAPP.¹ These programs were devised to assimilate detailed information from the facility up through the corporate levels.