Health risk assessment of an abandoned herbicide factory site for transportation use in Dalian,China

An abandoned herbicide factory site was used as an example of how planning should be considered for development of the site for transportation use in Dalian, China. Exposure pathways and parameters for three types of transportation use (land for a traffic hub, land for an urban road, and land for a subway) were developed. Twenty-five sampling sites were selected and 38 soil samples were collected in March 2015. Hexachlorobenzene and benzo(a)pyrene which were extracted by Soxhlet extraction and detected by gas chromatography mass spectrometry were the most significant pollutants detected. The maximum concentration of the two pollutants in the surface layer (0–0.5 m) were 0.57 and 3.10 mg/kg, and in the bottom layer (1.0 m) were 2.57 and 3.72 mg/kg, respectively. In this study, risk assessment results based on the established exposure scenario and parameters showed that there was a significant difference in traffic hub land use under specific exposure pathway and common insensitive land use exposure pathways (direct ingestion of soil, dermal contact with soil, and inhalation of soil-derived dust). Commonly considered hexachlorobenzene and benzo(a)pyrene carcinogenic risk values exceeded the maximum acceptable level (10⁻⁶) and were found to be 23.9-fold and 189-fold higher than the carcinogenic risk values, respectively. Parameter sensitivity analysis data showed that for transportation use, the two parameters “EFOa” and “OSIRa” were the most significant factors associated with variation of the carcinogenic risk value. For traffic hub land use, urban road land use, and subway land use, the main exposure pathways were through “inhalation of soil vapors outdoors (from surface soil),” “direct ingestion of soil,” and “inhalation of soil vapors indoors (from bottom soil),” which contributed 84.75, 73.00, and 100.00% to the total risk value, respectively.

     

Implementing Pollution Prevention: Incentives and Irrationalities

Widespread pollution prevention will turn on creative use of incentives, since prevention means decentralized changes in raw materials, products, production processes and disposal practices—in short, new ways of doing business—that are difficult to achieve through information transfer or regulatory mandates alone. But past experience with incentives and the context in which these approaches are used will shape both regulators’ attitudes and industry willingness to respond. Thus the choice of incentive mechanism (s) may well determine the extent to which “prevention” is implemented—as well as the extent to which implementation yields environmentally-sound rather than perverse results. Approaches now being debated could produce such perverse effects by treating recyclables as pollution and assuming all reductions towards zero are equally desirable, regardless of net risks reduced or costs incurred by waste generators. Another alternative— tradeable permits progressively reducing the amount of waste received by disposal facilities—could help agencies think through such consequences, force needed decisions on how much “prevention” of which “pollution” is appropriate, and encourage investment to reduce commercial as well as municipal waste. This alternative implies that the criteria for “appropriate prevention” are reduction in waste needing disposal and in overall environmental impact; that recycling should be equated with source reduction in waste management hierarchies, not placed on a lower rung; and that Air Toxics provisions of the pending Clean Air Act may require some adjustments if prevention is not to be aborted by the threat that voluntary reduction steps will become national requirements, for existing sources as well as new ones.     

Participatory conservation approaches for satoyama,the traditional forest and agricultural landscape of Japan

The traditional agricultural landscape of Japan, known as satoyama, consists of a mixture of forests, wet rice paddy fields, grasslands, and villages. This landscape supports a great diversity of plant and animal species, many of which are significant to the Japanese culture. The satoyama landscape is currently being rapidly converted to residential and industrial uses in Japan's expanding metropolitan areas, with the local loss of many species. Only 7% of the land in the Yokohama area remains as satoyama. City residents and older farmers have become key participants in programs to protect examples of satoyama. Many urban residents value the experience of participating in agricultural and conservation activities once they are made aware of the threat faced by the satoyama landscape. In one particularly successful program, conservation efforts and fund-raising are linked to "Totoro", an imaginary forest animal featured in a popular animated film.     

Perspectives on secondary forest management in tropical humid lowland America

Secondary forests regrowing on abandoned agricultural land constitute an important, albeit widely overlooked, component in the landscape matrix of tropical lowland America. These 'new' forest resources on private land-holdings derive either from unsustainable cattle-ranching practices of better-off farmers or are part of the crop/fallow system of resource-poor farmers. If previous land use was light, secondary forest management may offer an interesting use option to better-off farmers, providing that subsidies for stand improvement are given. Improved fallow systems using partly the successional vegetation may be a way to establish sustainable small-scale agriculture for resource-poor farmers. Given some technical and financial input, land-use systems based on secondary vegetation could play a vital role both in sustainable landscape management and biodiversity conservation.     

Developing a predictive understanding of landscape importance to the Punan-Pelancau of East Kalimantan, Borneo

In order for local community views to be incorporated into new development initiatives, their perceptions need to be clearly understood and documented in a format that is readily accessible to planners and developers. The current study sought to develop a predictive understanding of how the Punan Pelancau community, living in a forested landscape in East Kalimantan, assigns importance to its surrounding landscapes and to present these perceptions in the form of maps. The approach entailed the iterative use of a combination of participatory community evaluation methods and more formal modeling and geographic information system techniques. Results suggest that landscape importance is largely dictated by potential benefits, such as inputs to production, health, and houses. Neither land types nor distance were good predictors of landscape importance. The grid-cell method, developed as part of the study, appears to offer a simple technique to capture and present the knowledge of local communities, even where their relationship to the land is highly complex, as was the case for this particular community.     

Literature Forensics? Door to What Was Known but Now Forgotten

Science's all-consuming drive to make new discoveries often risks losing sight of what was already known at one time—that which already exists in the published literature. Inadequate attention to the published literature and insufficient time devoted to its mining and synthesis into new knowledge is a problem faced by all disciplines, especially highly interdisciplinary fields such as environmental forensics, whose knowledge base is fragmented across numerous disciplines. While the conduct of science applies principles of quality assurance to a wide array of its processes, how pervasive are quality controls designed to ensure that planned or ongoing research has not been undertaken before? Has sufficient energy been devoted to mining what has already been discovered and synthesizing it into a larger, more useful perspective?This paper touches on the liabilities associated with insufficient examination of an exponentially growing published literature (“literature forensics”) and offers some suggestions for achieving a better balance between original work and capturing what has already been reported—all essential to the growing responsibility of knowledge management. By lessening the importance of the published literature, are we asymptotically approaching a point where science may be preoccupied with publishing “new” findings while few have time to assimilate what has already been published?     

Modeling the emissions of a dual fuel engine coupled with a biomass gasifier—supplementing the Wiebe function

There is a growing market demand for small-scale biomass gasifiers that is driven by the economic incentives and the legislative framework. Small-scale gasifiers produce a gaseous fuel, commonly referred to as producer gas, with relatively low heating value. Thus, the most common energy conversion systems that are coupled with small-scale gasifiers are internal combustion engines. In order to increase the electrical efficiency, the operators choose dual fuel engines and mix the producer gas with diesel. The Wiebe function has been a valuable tool for assessing the efficiency of dual fuel internal combustion engines. This study introduces a thermodynamic model that works in parallel with the Wiebe function and calculates the emissions of the engines. This “vis-à-vis” approach takes into consideration the actual conditions inside the cylinders—as they are returned by the Wiebe function—and calculates the final thermodynamic equilibrium of the flue gases mixture. This approach aims to enhance the operation of the dual fuel internal combustion engines by identifying the optimal operating conditions and—at the same time—advance pollution control and minimize the environmental impact.     

Chemical speciation of individual atmospheric particles using low-Z electron probe X-ray microanalysis:: characterizing “Asian Dust” deposited with rainwater in Seoul,Korea

Chemical speciation of individual microparticles is of much interest in environmental atmospheric chemistry; e.g. the determination of the elemental concentrations in individual atmospheric aerosol particles is important to study the chemical behavior of atmospheric pollution. Recently, an EPMA technique using an X-ray detector equipped with an ultra-thin window, allowing EPMA to determine concentrations of low-Z elements, such as C, N, and O, in individual particles of micrometer size, has been developed. This technique, called low-Z electron probe X-ray microanalysis (low-Z EPMA), is applied to characterize the water-insoluble part of “Asian Dust”, deposited by washout in the form of rainwater during an Asian Dust storm event and collected in Seoul, Korea. In this study, it was demonstrated that the single particle analysis using low-Z EPMA provided detailed information on various types of chemical species in the sample. In addition to aluminosilicates, silicon oxide, iron oxide, and calcium carbonate particles, which are expected to be present, carbonaceous particles are also observed in a significant fraction. This unexpected finding that particle sample originated from an arid area contains significant amount of carbonaceous particles is supported by the investigation of a “China Loess” sample. In addition, we also performed single particle analysis for a local soil sample, in order to check the possible influence from local sources on “Asian Dust”. The characteristics of the local soil particle sample, e.g. the types of aluminosilicate particles and the abdundance of particles with deviating chemical species, are clearly different from “Asian Dust” and “China Loess” samples, whereas those two are similar, implying that the “Asian Dust” sample was not much influenced by local sources.     

“The Clean Air Act — A Time for Evaluation”

The Third Government Affairs Seminar sponsored by the Air Pollution Control Association was held in Washington, D. C. on April 16-17, 1975. The APCA South Atlantic Section was host for this very successful meeting. The General Chairman of the Seminar Committee was John V. Brink and the Program Chairman was Richard D. Grundy.

The seminar this year was conducted in three sessions. The first session, entitled “The Clean Air Act: State vs Federal Roles,” considered a topic that is receiving increasing emphasis as the national air pollution control program matures. This discussion was chaired by M. Barry Meyer, Chief Counsel and Chief Clerk, Senate Committee on Public Works.

The second session was “Land Use Planning Aspects of the Clean Air Act—Federal, State and Regional Roles.” Mrs. Mary Jane Due, Chairman of the Public Land and Land Use Committee, Natural Resources Section, American Bar Association, served as Moderator of this discussion of indirect source regulations, no significant deterioration, air quality maintenance—concepts that rely heavily on comprehensive land use planning.

“Clean Air Priorities—The Need for Flexibility,” was the title of the third session which was chaired by Austin H. Phelps, Manager Corporate Air Pollution Control, Procter and Gamble Company and President of APCA. The panelists considered the question of how appropriate the standard setting mechanisms of the Clean Air Act are for the resolution of present and future problems.

In this report condensed versions of the prepared statements of the participants are presented. A more extensive summary of the Proceedings, which includes questions and answers, is available from APCA headquarters. The remarks of John R. Quarles, EPA Deputy Administrator, who was the luncheon speaker, were summarized in the June APCA Journal(p. 642).     

Observations on long-term air-soil exchange of organic contaminants

Evidence for long-term changes in the soil composition of selected organic compounds, brought about by exchanges with the atmosphere, is briefly reviewed. In the case of some compounds — such as benzo(a)pyrene and octachlorodibenzo-p-dioxin, soils may be significant long-term environmental sinks for atmospherically-derived material. In other cases — such as phenanthrene and some of the lighter PCBs, de-gassing or volatilisation from soil back to the air can occur under certain conditions. Hence the soil may act as a “short-term” sink, and a potential source to atmosphere. Indeed, for some ‘semi-volatile’ compounds used in large quantities in the past — such as PCBs, soil outgassing may actually be an extremely important source to contemporary air. Furthermore, soil outgassing from areas of former high use may provide an important driving mechanism for continued “global cycling” of a range of semi-volatile organochlorine compounds.     

The chemical and strontium isotope composition of atmospheric aerosols over Japan: the contribution of long-range-transported Asian dust (Kosa)

Atmospheric aerosols have been collected at four sites around Japan during 2000. From systematically monitoring the major (Na, Mg, Al, K, Ca, and Fe) and trace (Rb and Sr) elements, along with the Sr isotope composition, we have tried to estimate the contribution of long-range-transported Asian dust (“Kosa”) to the atmospheric aerosols.The results are summarized as follows:(1) The concentration of each element in the aerosols increased during the “Kosa” period. The increase was particularly obvious in samples collected on 8 April 2000, when the “Kosa Phenomenon” was observed at all the sampling sites in Japan, 2 days after a very heavy dust storm had occurred in China.(2) The Rb–Sr isotopic diagram shows a two-component mixing relationship: one with a high ⁸⁷Sr/⁸⁶Sr ratio and a high ⁸⁷Rb/⁸⁶Sr ratio, and the other with a low ⁸⁷Sr/⁸⁶Sr ratio and a low ⁸⁷Rb/⁸⁶Sr ratio. There is a significant difference between that of the expected end member of the Asian dust and that of the reported Asian loess, which is thought to be the possible source of the components of the “Kosa”, although the lower component is consistent with the local component at Wako.(3) Plots of the ⁸⁷Sr/⁸⁶Sr ratio vs the Ca/Al and Sr/Al ratios support a two-component mixing suggested by the Rb–Sr systematics, and they indicate that the contributing continental soil components to the “Kosa” aerosols should be composed of the silicate fraction of Asian loess.(4) The discrepancy in the Rb–Sr systematics between the expected end member and the possible sources may be caused by the dissolution of the Ca-bearing minerals via long-range dust transport, or by a combination of source characteristics and grain size separation.     

From Site Data to Safety Assessment: Analysis of Present and Future Hydrological Conditions at a Coastal Site in Sweden

This paper presents an analysis of present and future hydrological conditions at the Forsmark site in Sweden, which has been proposed as the site for a geological repository for spent nuclear fuel. Forsmark is a coastal site that changes in response to shoreline displacement. In the considered time frame (until year 10 000 ad), the hydrological system will be affected by landscape succession associated with shoreline displacement and changes in vegetation, regolith stratigraphy, and climate. Based on extensive site investigations and modeling of present hydrological conditions, the effects of different processes on future site hydrology are quantified. As expected, shoreline displacement has a strong effect on local hydrology (e.g., groundwater flow) in areas that change from sea to land. The comparison between present and future land areas emphasizes the importance of climate variables relative to other factors for main hydrological features such as water balances.     

"三生空间"视角下乌鲁木齐市土地利用功能转型及其生态服务价值研究

为探寻快速城镇化地区资源优化配置方式,实现区域内“三生空间”可持续发展,以乌鲁木齐市2004—2018年间3期的Landsat遥感影像为数据源,并建立以“三生空间”为主导的土地利用类型分类体系,采用ArcGIS分析15年间乌鲁木齐市土地利用功能转型特征及生态服务价值时空演变规律。结果表明:(1)15年间乌鲁木齐市的生活生产空间呈现持续扩张的趋势,生产生态空间和生态生产空间都出现先上升后下降的趋势,生态空间持续下降,生活生产空间的大幅增长来自其对生态空间以及生产生态空间的占用;(2)2004—2018年间乌鲁木齐市生态服务价值下降了13.87%,生态空间的生态服务价值下降总量最大;(3)未来应重点保护和规划生态空间内的林地、草地以及湿地等,高效集约利用生活、生产功能用地。     

Glass Fibers and Their Use as Filter Media

Typical air quality effect levels of photochemical oxidants on specific plant substrates are illustrated. These include ambient oxidant exposure data measured as “total oxidant” as well as laboratory exposures to individual pure oxidants, ozone, or PAN compounds, since these oxidants are identified in photochemical smog. New terms, “PaNs” and “PAN-type” oxidant, have been proffered for purposes of clarification of the terminology. PAN-type oxidant more precisely defines the phytotoxicant complex causing silvering or bronzing of the lower leaf surfaces in lieu of the older term “oxidant.” Due to the recognition of several oxidizing phytotoxicants in recent years, it is recommended that the term oxidant be reserved for use as a generic term. A tabular classification of the oxidizing phytotoxicants found in community photochemical smog and the specific syndromes produced is provided.     

发达国家污染土地置换开发管理实践及其对我国的启示

污染土地置换开发是一个复杂的过程,涉及技术、法律、经济和社会等诸多问题.选择管理技术相对比较成熟和先进的美国、欧盟国家、加拿大以及日本作为案例,深刻剖析国际上污染土地置换开发管理的经验与教训,提出有效的城市土地利用规划、公平合理的经济责任界定、合适的资金筹措机制、灵活选择土壤污染修复目标、污染土地风险评估等级划分、多利益方的共同参与等6点启示,以期对我国日益受到重视的污染土地置换开发管理工作提供借鉴.     

Meteorological utilisation of horizontal microwave propagation measurements

A simple method, in real time, to detect an inversion layer in the lower atmosphere, can be that of monitoring horizontal microwave radiopropagation across the considered area, between two stations linked by radiowaves only during non-standard atmospheric conditions.Experimental results of the first three months of continuous measurements at 3cm, wave-lengths, are given for a path only over sea and for one only flat land.An attempt to find a connection with local meteorological ground data has shown a strong correlation between radio signal reception along super-standard distances and the water vapour pressure for the sea path. In this case, “radio ducting” seems to result from a steep monotonic decaying of the water content of the air.Radio measurements over the flat land path show radio ducting to be an almost nocturnal process. In this case, radiopropagation beyond the horizon detects temperature inversions caused by nocturnal cooling and, therefore, there is no correlation with meteorological ground data.Finally, the frequent presence of radio ducts (time efficiencies greater than 80% have been measured by the authors in certain periods of the year) could also be exploited by telecommunication users for inexpensive transmission, although not in real time, of pre-recorded data.     

Soiling Potential—A New Method for Measuring Smoke Emission

There is a growing interest in effects of sub-micron, nonsettling particles in the atmosphere among air pollution control agencies throughout the country. This type of pollution, generally referred to as the “soiling index” of the atmosphere, is produced primarily by the incomplete combustion of fuels. The measurement procedure has been fairly well standardized, the values being reported as Cohs or Ruds per 1000 linear feet of air. Using a similar technique, a method of quantitating smoke emission in objective terms first demonstrated by W. C. L. Hemeon in 1953, has been applied to source testing at several operating plants by the Cincinnati Division of Air Pollution Control. The source strength will be called “soiling potential” while the effect in the general atmosphere is termed “soiling index.” The soiling potential unit is Rud-ft² per cubic foot exhaust gases or Rud-ft² per unit of fuel input. The “Soiling Potential” sampler is described and results of tests are given. Included is the use of soiling potential in quantitating smoke emission from single sources and for constructing area wide inventory of smoke emission. The use of an area wide smoke emission inventory in Rudft2 in a simple diffusion model for calculating the soiling index (Rud-ft²/1000 cu ft) in the general atmosphere at a given point is explored.     

Modeling effects of traffic and landscape characteristics on ambient nitrogen dioxide levels in Connecticut

An integrated exposure model was developed that estimates nitrogen dioxide (NO(2)) concentration at residences using geographic information systems (GIS) and variables derived within residential buffers representing traffic volume and landscape characteristics including land use, population density and elevation. Multiple measurements of NO(2) taken outside of 985 residences in Connecticut were used to develop the model. A second set of 120 outdoor NO(2) measurements as well as cross-validation were used to validate the model. The model suggests that approximately 67% of the variation in NO(2) levels can be explained by: traffic and land use primarily within 2 km of a residence; population density; elevation; and time of year. Potential benefits of this model for health effects research include improved spatial estimations of traffic-related pollutant exposure and reduced need for extensive pollutant measurements. The model, which could be calibrated and applied in areas other than Connecticut, has importance as a tool for exposure estimation in epidemiological studies of traffic-related air pollution.     

Spatial distribution and reduction of PCDD/PCDF Toxic Equivalents along three shallow lowland reservoirs

Reservoirs situated along a river continuum are ecosystems where rates of transfer of suspended matter and associated micropollutants are reduced due to sedimentation, accumulation, and biological and physical transformation processes. Among the micropollutants, PCDDs and PCDFs are substances that are highly toxic and carcinogenic for humans and animals. They are emitted and dispersed in the environment throughout the whole catchment area and may accumulate in aquatic and terrestrial food chains, creating a risk for human health. A wealth of data exists indicating the increase in the concentrations of pollutants along a river continuum. A comparative analysis of total, individual, and TEQ PCDD/PCDF concentrations in large lowland, shallow reservoirs located in different catchments (“I”—industrial/urban/agricultural, “U”—urban/agricultural, and “A”—agricultural/rural) showed decreases of the TEQ concentrations in bottom sediments along a gradient from the middle sections to the dam walls. Moreover, penta-, hexa-, and heptachlorinated CDD/CDF congeners were reduced from 28.8 up to 93.6 % in all three types of reservoirs. A further analysis of water samples from the inlets and outlets of the “A” reservoir confirmed this tendency.     

Structural Diversity: A Multi-dimensional Approach to Assess Recreational Services in Urban Parks

Urban green spaces provide important recreational services for urban residents. In general, when park visitors enjoy “the green,” they are in actuality appreciating a mix of biotic, abiotic, and man-made park infrastructure elements and qualities. We argue that these three dimensions of structural diversity have an influence on how people use and value urban parks. We present a straightforward approach for assessing urban parks that combines multi-dimensional landscape mapping and questionnaire surveys. We discuss the method as well the results from its application to differently sized parks in Berlin and Salzburg.