首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 722 毫秒
1.
Modern landfill understanding points out controlled operation of landfills. Emissions from landfills are caused mainly by anaerobic biodegradation processes which continue for very long time periods after landfill closure. In situ landfill stabilization aims controlled reduction of emissions towards reduced expenditures as well as aftercare measures. Since April 2010, a new in situ stabilization technique is being applied at a pilot scale landfill (BAIV) within Landfill Konstanz Dorfweiher. This new method utilizes intermittent aeration and leachate recirculation for waste stabilization. In this study, influence of this technique on leachate quality is investigated. Among many other parameters, leachate analyses were conducted for COD, BOD5, NH4–N, NO2–N, NO3–N, TKN and chloride besides continuously on site recorded pH, electrical conductivity and oxidation–reduction potential (ORP). Results from leachate quality analyses showed that biological activity in the landfill was accelerated resulting in initial higher leachate strength and reduced emission potential of landfill. During full scale in situ aeration, ambient conditions differ from optimized laboratory scale conditions which mainly concern temperature increase and deficient aeration of some landfill parts (Ritzkowski and Stegmann, 2005). Thus, as a field application results of this study have major importance on further process optimization and application.  相似文献   

2.
Emissions from old landfills via leachate and the gas phase are influenced by state and stability of the organic matter in the solid waste and by environmental conditions within the landfill. Remediation of landfills by means of in-situ aeration is one possibility to reduce these emissions. By establishing aerobic conditions, biological processes in the landfill are accelerated. To investigate the effects of this remediation technology, lab-scale experiments with column tests have been carried out. The main goal of the present work is to characterize the changes of the carbon and nitrogen compounds in the aerated solid waste, the leachate and the gas phase under varying conditions. The results demonstrate a clear reduction of emissions and a stabilization of the organic matter. Furthermore, it is shown that both the intensity of aeration and the amount of water affect biological processes to a certain extent. Even when columns were operated under anaerobic conditions after a long running period of aeration, the emissions remained low.  相似文献   

3.
Landfills are some of the major anthropogenic sources of methane emissions worldwide. The installation and operation of gas extraction systems for many landfills in Europe and the US, often including technical installations for energy recovery, significantly reduced these emissions during the last decades. Residual landfill gas, however, is still continuously produced after the energy recovery became economically unattractive, thus resulting in ongoing methane emissions for many years. By landfill in situ aeration these methane emissions can be widely avoided both, during the aeration process as well as in the subsequent aftercare period. Based on model calculations and online monitoring data the amount of avoided CO2-eq. can be determined. For an in situ aerated landfill in northern Germany, acting as a case study, 83–95% (depending on the kind and quality of top cover) of the greenhouse gas emission potential could be reduced under strictly controlled conditions. Recently the United Nations Framework Convention on Climate Change (UNFCCC) has approved a new methodology on the “Avoidance of landfill gas emissions by in situ aeration of landfills” (UNFCCC, 2009). Based on this methodology landfill aeration projects might be considered for generation of Certified Emission Reductions (CERs) in the course of CDM projects. This paper contributes towards an evaluation of the potential of landfill aeration for methane emissions reduction.  相似文献   

4.
Municipal solid waste (MSW) landfills worldwide are experiencing the consequences of conventional landfilling techniques, whereby anaerobic conditions are created within the landfilled waste. Under anaerobic conditions within a landfill site slow stabilization of the waste mass occurs, producing methane, (an explosive 'green house' gas) and leachate (which can pollute groundwater) over long periods of time. As a potential solution, it was demonstrated that the aerobic degradation of MSW within a landfill can significantly increase the rate of waste decomposition and settlement, decrease the methane production and leachate leaving the system, and potentially increase the operational life of the site. Readily integrated into the existing landfill infrastructure, this approach can safely and cost-effectively convert a MSW landfill from anaerobic to aerobic degradation processes, thereby effectively composting much of the organic portions (one of the potentially polluting elements in a conventional landfill site) of the waste. This paper summarizes the successful results of two separate aerobic landfill projects located in Georgia (USA) and discusses the potential economic and environmental impacts to worldwide solid waste management practices.  相似文献   

5.
The time frame required for post-closure care of Municipal Solid Waste (MSW) landfills is often assessed over several decades or centuries. One possibility to significantly shorten this period and, at the same time, improve the emission behavior exists with in situ aeration. Positive effects in connection with this method for biological stabilization have been investigated and published elsewhere. However, until today neither generally accepted monitoring guidelines nor completion criteria have been defined. With the paper on hand the authors propose a methodology for the assessment of both, total and remaining stabilization periods for aerated landfills. The central component of this methodology is a carbon balance. The latter is based on a detailed waste characterization in combination with online monitoring of the emissions (gas and leachate). The methodology is exemplarily demonstrated by means of data derived from a full scale project in Northern Germany. Here it could be shown that the predicted aeration period of approximately 6.4 years was sufficient to bio-stabilize the landfill.Furthermore, proposals for the completion of landfill aeration are presented. In this connection, carbon balance is of particular importance since the amount of biodegradable organic carbon mainly determines the emission potential. Additional parameters, aiming at a validation of the state of biological stabilization achieved during aeration are proposed and described.  相似文献   

6.
Stable isotopic signatures of landfill leachates are influenced by processes within municipal solid waste (MSW) landfills mainly depending on the aerobic/anaerobic phase of the landfill. We investigated the isotopic signatures of δ13C, δ2H and δ18O of different leachates from lab-scale experiments, lysimeter experiments and a landfill under in situ aeration. In the laboratory, columns filled with MSW of different age and reactivity were percolated under aerobic and anaerobic conditions. In landfill simulation reactors, waste of a 25 year old landfill was kept under aerobic and anaerobic conditions. The lysimeter facility was filled with mechanically shredded fresh waste. After starting of the methane production the waste in the lysimeter containments was aerated in situ. Leachate and gas composition were monitored continuously. In addition the seepage water of an old landfill was collected and analysed periodically before and during an in situ aeration.We found significant differences in the δ13C-value of the dissolved inorganic carbon (δ13C-DIC) of the leachate between aerobic and anaerobic waste material. During aerobic degradation, the signature of δ13C-DIC was mainly dependent on the isotopic composition of the organic matter in the waste, resulting in a δ13C-DIC of ?20‰ to ?25‰. The production of methane under anaerobic conditions caused an increase in δ13C-DIC up to values of +10‰ and higher depending on the actual reactivity of the MSW. During aeration of a landfill the aerobic degradation of the remaining organic matter caused a decrease to a δ13C-DIC of about ?20‰. Therefore carbon isotope analysis in leachates and groundwater can be used for tracing the oxidation–reduction status of MSW landfills.Our results indicate that monitoring of stable isotopic signatures of landfill leachates over a longer time period (e.g. during in situ aeration) is a powerful and cost-effective tool for characterising the biodegradability and stability of the organic matter in landfilled municipal solid waste and can be used for monitoring the progress of in situ aeration.  相似文献   

7.
Sustainable landfilling has become a fundamental objective in many modern waste management concepts. In this context, the in situ aeration of landfills has been recognised for its potential to convert conventional anaerobic landfills into biological stabilised state, whereby both current and potential (long-term) emissions of the landfilled waste are mitigated. In recent years, different in situ aeration concepts have been successfully applied in Europe, North America and Asia, all pursuing different objectives and strategies.In Austria, the first full-scale application of in situ landfill aeration by means of low pressure air injection and simultaneous off-gas collection and treatment was implemented on an old, small municipal solid waste (MSW) landfill (2.6 ha) in autumn 2007. Complementary laboratory investigations were conducted with waste samples taken from the landfill site in order to provide more information on the transferability of the results from lab- to full-scale aeration measures. In addition, long-term emission development of the stabilised waste after aeration completion was assessed in an ongoing laboratory experiment. Although the initial waste material was described as mostly stable in terms of the biological parameters gas generation potential over 21 days (GP21) and respiration activity over 4 days (RA4), the lab-scale experiments indicated that aeration, which led to a significant improvement of leachate quality, was accompanied by further measurable changes in the solid waste material under optimised conditions. Even 75 weeks after aeration completion the leachate, as well as gaseous emissions from the stabilised waste material, remained low and stayed below the authorised Austrian discharge limits. However, the application of in situ aeration at the investigated landfill is a factor 10 behind the lab-based predictions after 3 years of operation, mainly due to technical limitations in the full-scale operation (e.g. high air flow resistivity due to high water content of waste and temporarily high water levels within the landfill; limited efficiency of the aeration wells). In addition, material preparation (e.g. sieving, sorting and homogenisation) prior to the emplacement in Landfill Simulation Reactors (LSRs) must be considered when transferring results from lab- to full-scale application.  相似文献   

8.
The in situ stabilization of old deposits aims for a lasting and controlled reduction of pollutant emissions from the deposited waste in order to diminish expenditure and the duration of landfill aftercare measures. The stabilization operation so far, observed over a period of 1-2 years at three landfills in Germany, shows that leachate contamination is permanently reduced, biodegradation processes are significantly accelerated and main settlements take place within a short period of time.  相似文献   

9.
In situ aeration by means of the Airflow technology was proposed for landfill conditioning before landfill mining in the framework of a reclamation project in Northern Italy. A 1-year aeration project was carried out on part of the landfill with the objective of evaluating the effectiveness of the Airflow technology for landfill aerobization, the evolution of waste biological stability during aeration and the effects on leachate and biogas quality and emissions.The main outcomes of the 1-year aeration project are presented in the paper.The beneficial effect of the aeration on waste biological stability was clear (63% reduction of the respiration index); however, the effectiveness of aeration on the lower part of the landfill is questionable, due to the limited potential for air migration into the leachate saturated layers.During the 1-year in situ aeration project approx. 275 MgC were discharged from the landfill body with the extracted gas, corresponding to 4.6 gC/kgDM. However, due to the presence of anaerobic niches in the aerated landfill, approx. 46% of this amount was extracted as CH4, which is higher than reported in other aeration projects. The O2 conversion quota was lower than reported in other similar projects, mainly due to the higher air flow rates applied.The results obtained enabled valuable recommendations to be made for the subsequent application of the Airflow technology to the whole landfill.  相似文献   

10.
Recently, roofed landfills have been gaining popularity in Japan. Roofed landfills have several advantages over non-roofed landfills such as eliminating the visibility of waste and reducing the spread of offensive odours. This study examined the moisture balance and aeration conditions, which promote waste stabilisation, in a roofed landfill that included organic waste such as food waste. Moisture balance was estimated using waste characterization and the total amount of landfilled waste. Internal conditions were estimated based on the composition, flux, and temperature of the landfill gas. Finally, in situ aeration was performed to determine the integrity of the semi-aerobic structure of the landfill.With the effects of rainfall excluded, only 15% of the moisture held by the waste was discharged as leachate. The majority of the moisture remained in the waste layer, but was less than the optimal moisture level for biodegradation, indicating that an appropriate water spray should be administered. To assess waste degradation in this semi-aerobic landfill, the concentration and flow rate of landfill gas were measured and an in situ aeration test was performed. The results revealed that aerobic biodegradation had not occurred because of the unsatisfactory design and operation of the landfill.  相似文献   

11.
Investigations into laboratory reactors and landfills are used for simulating and predicting emissions from municipal solid waste landfills. We examined water flow and solute transport through the same waste body for different volumetric scales (laboratory experiment: 0.08 m3, landfill: 80,000 m3), and assessed the differences in water flow and leachate emissions of chloride, total organic carbon and Kjeldahl nitrogen. The results indicate that, due to preferential pathways, the flow of water in field-scale landfills is less uniform than in laboratory reactors. Based on tracer experiments, it can be discerned that in laboratory-scale experiments around 40% of pore water participates in advective solute transport, whereas this fraction amounts to less than 0.2% in the investigated full-scale landfill. Consequences of the difference in water flow and moisture distribution are: (1) leachate emissions from full-scale landfills decrease faster than predicted by laboratory experiments, and (2) the stock of materials remaining in the landfill body, and thus the long-term emission potential, is likely to be underestimated by laboratory landfill simulations.  相似文献   

12.
This paper describes a method developed for quantification of gas emissions from the leachate collection system at landfills and present emission data measured at two Danish landfills with no landfill gas collection systems in place: Fakse landfill and AV Miljø. Landfill top covers are often designed to prevent infiltration of water and thus are made from low permeable materials. At such sites a large part of the gas will often emit through other pathways such as the leachate collection system. These point releases of gaseous constituents from these locations cannot be measured using traditional flux chambers, which are often used to measure gas emissions from landfills. Comparing tracer measurements of methane (CH4) emissions from leachate systems at Fakse landfill and AV Miljø to measurements of total CH4 emissions, it was found that approximately 47% (351 kg CH4 d?1) and 27% (211 kg CH4 d?1), respectively, of the CH4 emitting from the sites occurred from the leachate collection systems. Emission rates observed from individual leachate collection wells at the two landfills ranged from 0.1 to 76 kg CH4 d?1. A strong influence on emission rates caused by rise and fall in atmospheric pressure was observed when continuously measuring emission from a leachate well over a week. Emission of CH4 was one to two orders of magnitude higher during periods of decreasing pressure compared to periods of increasing pressure.  相似文献   

13.
Landfill aeration by means of low pressure air injection is a promising tool to reduce long term emissions from organic waste fractions through accelerated biological stabilization. Top covers that enhance methane oxidation could provide a simple and economic way to mitigate residual greenhouse gas emissions from in situ aerated landfills, and may replace off-gas extraction and treatment, particularly at smaller and older sites. In this respect the installation of a landfill cover system adjusted to the forced-aerated landfill body is of great significance. Investigations into large scale lysimeters (2 × 2 × 3 m) under field conditions have been carried out using different top covers including compost materials and natural soils as a surrogate to gas extraction during active low pressure aeration. In the present study, the emission behaviour as well as the water balance performance of the lysimeters has been investigated, both prior to and during the first months of in situ aeration. Results reveal that mature sewage sludge compost (SSC) placed in one lysimeter exhibits in principle optimal ambient conditions for methanotrophic bacteria to enhance methane oxidation. Under laboratory conditions the mature compost mitigated CH4 loadings up to 300 l CH4/m2 d. In addition, the compost material provided high air permeability even at 100% water holding capacity (WHC). In contrast, the more cohesive, mineral soil cover was expected to cause a notably uniform distribution of the injected air within the waste layer. Laboratory results also revealed sufficient air permeability of the soil materials (TS-F and SS-Z) placed in lysimeter C. However, at higher compaction density SS-Z became impermeable at 100% WHC.Methane emissions from the reference lysimeter with the smaller substrate cover (12–52 g CH4/m2 d) were significantly higher than fluxes from the other lysimeters (0–19 g CH4/m2 d) during in situ aeration. Regarding water balance, lysimeters covered with compost and compost-sand mixture, showed the lowest leachate rate (18–26% of the precipitation) due to the high water holding capacity and more favourable plant growth conditions compared to the lysimeters with mineral, more cohesive, soil covers (27–45% of the precipitation).On the basis of these results, the authors suggest a layered top cover system using both compost material as well as mineral soil in order to support active low-pressure aeration. Conventional soil materials with lower permeability may be used on top of the landfill body for a more uniform aeration of the waste due to an increased resistance to vertical gas flow. A compost cover may be built on top of the soil cover underlain by a gas distribution layer to improve methane oxidation rates and minimise water infiltration. By planting vegetation with a high transpiration rate, the leachate amount emanating from the landfill could be further minimised. The suggested design may be particularly suitable in combination with intermittent in situ aeration, in the later stage of an aeration measure, or at very small sites and shallow deposits. The top cover system could further regulate water infiltration into the landfill and mitigate residual CH4 emissions, even beyond the time of active aeration.  相似文献   

14.
Because effective operation of bioreactor landfills involves careful operation and construction of infrastructure beyond that necessary in traditional landfills, upfront capital and operating costs are greater than those associated with traditional landfills. Prior to investing in bioreactor landfills, landfill owners must be convinced that larger short-term expenses (e.g., liquid and/or air injection infrastructure) will be balanced by future economic benefits (e.g., extension of landfill life, reduced leachate treatment costs, etc.). The purpose of this paper is to describe an economic model developed to evaluate the impact of various operational (anaerobic, aerobic, or hybrid) and construction (retrofit and as-built) bioreactor landfill strategies on project economics. Model results indicate retrofit bioreactor landfills are more expensive than traditional landfills, while both the as-built and aerobic bioreactor landfills are less costly. Simulation results indicate the parameters that influence bioreactor economics most significantly are airspace recovery, gas recovery and subsequent use to generate electricity, and savings resulting from reduced leachate treatment costs.  相似文献   

15.
Uncontrolled leachate emissions are one of the key factors in the environmental impact of municipal solid waste (MSW) landfills. The concentration of ammonium, given the anaerobic conditions in traditional landfills, can remain significantly high for a very long period of time, as degradation does not take place and volatilisation is not significant (the pH is not high enough to considerably shift the equilibrium towards un-ionised ammonia). Recent years have witnessed a continuous enhancement of landfill technology in order to minimize uncontrolled emissions into the environment; bottom lining systems have been improved and more attention has been devoted to the study of the attenuation of the different chemicals in leachate in case of migration through the mineral barrier. Different natural materials have been considered for use as components of landfill liners in the last years and tested in order to evaluate the performance of the different alternatives. Among those materials, bentonite is often used, coupled with other materials in two different ways: in addition to in situ soil or in geocomposite clay liner (GCL). A lab-scale test was carried out in order to further investigate the influence of bentonite on the attenuation of ammonium in leachate passing through a landfill liner. Two different tests were conducted: a standardized batch test with pulverized bentonite and a batch test with compacted bentonite. The latter was proposed in order to better simulate the real conditions in a landfill liner. The two tests produced values for the partition coefficient K(d) higher than the average measured for other natural materials usually utilized as components of landfill liners. Moreover, the two tests showed similar results, thus providing a further validation of the suitability of the standard batch test with pulverized bentonite. A thorough knowledge of attenuation processes of ammonium in landfill liners is the basis for the application of risk analysis models for the evaluation of the failure of bottom liners or their components.  相似文献   

16.
Pilot-scale experiment on anaerobic bioreactor landfills in China   总被引:1,自引:0,他引:1  
Developing countries have begun to investigate bioreactor landfills for municipal solid waste management. This paper describes the impacts of leachate recirculation and recirculation loadings on waste stabilization, landfill gas (LFG) generation and leachate characteristics. Four simulated anaerobic columns, R1-R4, were each filled with about 30 tons of waste and recirculated weekly with 1.6, 0.8 and 0.2m(3) leachate and 0.1m(3) tap water. The results indicated that the chemical oxygen demand (COD) half-time of leachate from R1 was about 180 days, which was 8-14 weeks shorter than that of R2-R4. A large amount of LFG was first produced in R1, and its generation rate was positively correlated to the COD or volatile fatty acid concentrations of influent leachates after the 30th week. By the 50th week of recirculation, the waste in R1 was more stabilized, with 931.2 kg COD or 175.6 kg total organic carbon released and with the highest landfill gas production. However, this contributed mainly to washout by leachate, which also resulted in the reduction of LFG generation potential and accumulation of ammonia and/or phosphorus in the early stage. Therefore, the regimes of leachate recirculation should be adjusted to the phases of waste stabilization to enhance efficiency of energy recovery. Integrated with the strategy of in situ leachate management, extra pre-treatment or post-treatment methods to remove the nutrients are recommended.  相似文献   

17.
In situ ammonia removal in bioreactor landfill leachate   总被引:11,自引:0,他引:11  
Although bioreactor landfills have many advantages associated with them, challenges remain, including the persistence of NH(3)-N in the leachate. Because NH(3)-N is both persistent and toxic, it will likely influence when the landfill is biologically stable and when post-closure monitoring may end. An in situ nitrogen removal technique would be advantageous. Recent studies have shown the efficacy of such processes; however, they are lacking the data required to enable adequate implementation at field-scale bioreactor landfills. Research was conducted to evaluate the kinetics of in situ ammonia removal in both acclimated and unacclimated wastes to aid in developing guidance for field-scale implementation. Results demonstrate that in situ nitrification is feasible in an aerated solid waste environment and that the potential for simultaneous nitrification and denitrification (even under low biodegradable C:N conditions) in field-scale bioreactor landfills is significant due to the presence of both aerobic and anoxic areas. All rate data fit well to Monod kinetics, with specific rates of removal of 0.196 and 0.117 mgN/day-g dry waste and half-saturation constants of 59.6 and 147 mgN/L for acclimated and unacclimated wastes, respectively. Although specific rates of ammonia removal in the unacclimated waste are lower than in the acclimated waste, a relatively quick start-up of ammonia removal was observed in the unacclimated waste. Using the removal rate expressions developed will allow for estimation of the treatment times and volumes necessary to remove NH(3)-N from recirculated landfill leachate.  相似文献   

18.
The main purpose of this research is to clarify and compare the mechanism of waste stabilization by a recirculatory semi-aerobic landfill with the aeration system. Our research is proposing the semi-aerobic landfill system for developing countries because of the simple and low-cost technology for the final disposal. Moreover, this system with leachate recirculation can be a more effective system for waste stabilization because of the improvement of leachate quality as an organic pollutant and, also, nitrogen removal. In this research, five different systems of landfill (Ae: aerobic, An: anaerobic, Se: semi-aerobic, SeR: recirculatory semi-aerobic landfill, and SeRA: recirculatory semi-aerobic landfill with aeration system) are compared with lysimeters which are 1 m high with a diameter of 0.3 m. The results of the leachate quality shows that the leachate treatment effect of the SeRA system can be observed to be as high as the Ae system. To determine the mechanism of this process, all lysimeters are dismantled after 1,100 days in the experimental period and the waste composition, the dissolution test, the mass balance of carbon and nitrogen, the determination of bacterial counts, etc., were analyzed. In this research, it was proven that the SeRA system has an optimal leachate treatment effect that is the same as the Ae system. And, from the results of the mass balance of carbon and nitrogen, the SeR and SeRA systems show higher waste stabilization effectiveness and nitrogen removal than the other systems. Moreover, the number of the aerobic bacteria can be observed to be higher in the SeR and SeRA systems. To determine these results, the waste stabilization mechanism is considered by the results of leachate quality, the mass balance of carbon and nitrogen, and, also, the bacterial numbers.  相似文献   

19.
The shredder residues from automobiles, home appliances and other metal containing products are often disposed in landfills, as recycling technologies for these materials are not common in many countries. Shredder waste contains rigid and soft foams from cushions and insulation panels blown with fluorocarbons. The objective of this study was to determine the gas composition, attenuation, and emission of fluorocarbons in a monofill shredder residue landfill cell by field investigation. Landfill gas generated within the shredder waste primarily consisted of CH4 (27%) and N2 (71%), without CO2, indicating that the gas composition was governed by chemical reactions in combination with anaerobic microbial reactions. The gas generated also contained different fluorocarbons (up to 27 μg L?1). The presence of HCFC-21 and HCFC-31 indicated that anaerobic degradation of CFC-11 occurred in the landfill cell, as neither of these compounds has been produced for industrial applications. This study demonstrates that a landfill cell containing shredder waste has a potential for attenuating CFC-11 released from polyurethane (PUR) insulation foam in the cell via aerobic and anaerobic biodegradation processes. In deeper, anaerobic zones of the cell, reductive dechlorination of CFCs to HCFCs was evident, while in the shallow, oxic zones, there was a high potential for biooxidation of both methane and lesser chlorinated fluorocarbons. These findings correlated well with both laboratory results (presented in a companion paper) and surface emission measurements that, with the exception from a few hot spots, indicated that surface emissions were negative or below detection.  相似文献   

20.
Management of landfill emissions, i.e., landfill gas (LFG) and landfill leachate, is an important and resource-intensive task. A long-term demonstration pilot, consisting of landfill simulation reactors (LSRs), was used to study the impact of temperature and the applied liquid/solid ratio (L/S ratio) on landfill emissions, characteristics, and trends. This pilot has already run for more than 1000 days since the end of 2004 and will continue to run for some time. The degradation of waste at different temperatures has impacts on the overall degradation degree and on the length of post-closure care required. Higher temperatures accelerated the degradation, but also resulted in higher leachate chemical oxygen demand (COD) and ammonia concentrations, which prolong the aftercare period. Meanwhile, at a given stabilization degree [e.g., 70 l gas/kg waste (dry)], the total leached nitrogen under psychrophilic conditions was 3.5 times that under mesophilic/thermophilic conditions, which resulted in a higher required effort for leachate treatment. The impact of L/S ratio or simulated annual L/S rates was also evaluated. The results show the significance of efficiently obtaining the targeted L/S ratio in order to achieve low landfill emission potential.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号